Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach

Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead hali...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Yu Sun [verfasserIn] Jin Chen [verfasserIn] Fengchao Wang [verfasserIn] Yi Yin [verfasserIn] Yan Jin [verfasserIn] Jun Wang [verfasserIn] Xiaogai Peng [verfasserIn] Ruiyi Han [verfasserIn] Canyun Zhang [verfasserIn] Jinfang Kong [verfasserIn] Jing Yang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	MnCl CsPb thin films solution spraying

Übergeordnetes Werk:	In: Nanomaterials - MDPI AG, 2012, 11(2021), 12, p 3242
Übergeordnetes Werk:	volume:11 ; year:2021 ; number:12, p 3242

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/nano11123242

Katalog-ID:	DOAJ074352946

Internformat


LEADER	01000caa a22002652 4500
001	DOAJ074352946
003	DE-627
005	20240414223321.0
007	cr uuu---uuuuu
008	230228s2021 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.3390/nano11123242 \|2 doi
035			\|a (DE-627)DOAJ074352946
035			\|a (DE-599)DOAJef57581bcf75463384c1dd8580f0ab13
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
050		0	\|a QD1-999
100	0		\|a Yu Sun \|e verfasserin \|4 aut
245	1	0	\|a Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach
264		1	\|c 2021
336			\|a Text \|b txt \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material.
650		4	\|a MnCl<sub<2</sub< doping
650		4	\|a CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub<
650		4	\|a thin films
650		4	\|a solution spraying
653		0	\|a Chemistry
700	0		\|a Jin Chen \|e verfasserin \|4 aut
700	0		\|a Fengchao Wang \|e verfasserin \|4 aut
700	0		\|a Yi Yin \|e verfasserin \|4 aut
700	0		\|a Yan Jin \|e verfasserin \|4 aut
700	0		\|a Jun Wang \|e verfasserin \|4 aut
700	0		\|a Xiaogai Peng \|e verfasserin \|4 aut
700	0		\|a Ruiyi Han \|e verfasserin \|4 aut
700	0		\|a Canyun Zhang \|e verfasserin \|4 aut
700	0		\|a Jinfang Kong \|e verfasserin \|4 aut
700	0		\|a Jing Yang \|e verfasserin \|4 aut
773	0	8	\|i In \|t Nanomaterials \|d MDPI AG, 2012 \|g 11(2021), 12, p 3242 \|w (DE-627)718627199 \|w (DE-600)2662255-5 \|x 20794991 \|7 nnns
773	1	8	\|g volume:11 \|g year:2021 \|g number:12, p 3242
856	4	0	\|u https://doi.org/10.3390/nano11123242 \|z kostenfrei
856	4	0	\|u https://doaj.org/article/ef57581bcf75463384c1dd8580f0ab13 \|z kostenfrei
856	4	0	\|u https://www.mdpi.com/2079-4991/11/12/3242 \|z kostenfrei
856	4	2	\|u https://doaj.org/toc/2079-4991 \|y Journal toc \|z kostenfrei
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_DOAJ
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_95
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_151
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_213
912			\|a GBV_ILN_230
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_602
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4367
912			\|a GBV_ILN_4700
951			\|a AR
952			\|d 11 \|j 2021 \|e 12, p 3242

Indexfelder

author_variant	y s ys j c jc f w fw y y yy y j yj j w jw x p xp r h rh c z cz j k jk j y jy
matchkey_str	article:20794991:2021----::ietarctoocpsbsbnu1sbrlu3utiflbaaie
hierarchy_sort_str	2021
callnumber-subject-code	QD
publishDate	2021
allfields	10.3390/nano11123242 doi (DE-627)DOAJ074352946 (DE-599)DOAJef57581bcf75463384c1dd8580f0ab13 DE-627 ger DE-627 rakwb eng QD1-999 Yu Sun verfasserin aut Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material. MnCl<sub<2</sub< doping CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< thin films solution spraying Chemistry Jin Chen verfasserin aut Fengchao Wang verfasserin aut Yi Yin verfasserin aut Yan Jin verfasserin aut Jun Wang verfasserin aut Xiaogai Peng verfasserin aut Ruiyi Han verfasserin aut Canyun Zhang verfasserin aut Jinfang Kong verfasserin aut Jing Yang verfasserin aut In Nanomaterials MDPI AG, 2012 11(2021), 12, p 3242 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:11 year:2021 number:12, p 3242 https://doi.org/10.3390/nano11123242 kostenfrei https://doaj.org/article/ef57581bcf75463384c1dd8580f0ab13 kostenfrei https://www.mdpi.com/2079-4991/11/12/3242 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 12, p 3242
spelling	10.3390/nano11123242 doi (DE-627)DOAJ074352946 (DE-599)DOAJef57581bcf75463384c1dd8580f0ab13 DE-627 ger DE-627 rakwb eng QD1-999 Yu Sun verfasserin aut Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material. MnCl<sub<2</sub< doping CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< thin films solution spraying Chemistry Jin Chen verfasserin aut Fengchao Wang verfasserin aut Yi Yin verfasserin aut Yan Jin verfasserin aut Jun Wang verfasserin aut Xiaogai Peng verfasserin aut Ruiyi Han verfasserin aut Canyun Zhang verfasserin aut Jinfang Kong verfasserin aut Jing Yang verfasserin aut In Nanomaterials MDPI AG, 2012 11(2021), 12, p 3242 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:11 year:2021 number:12, p 3242 https://doi.org/10.3390/nano11123242 kostenfrei https://doaj.org/article/ef57581bcf75463384c1dd8580f0ab13 kostenfrei https://www.mdpi.com/2079-4991/11/12/3242 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 12, p 3242
allfields_unstemmed	10.3390/nano11123242 doi (DE-627)DOAJ074352946 (DE-599)DOAJef57581bcf75463384c1dd8580f0ab13 DE-627 ger DE-627 rakwb eng QD1-999 Yu Sun verfasserin aut Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material. MnCl<sub<2</sub< doping CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< thin films solution spraying Chemistry Jin Chen verfasserin aut Fengchao Wang verfasserin aut Yi Yin verfasserin aut Yan Jin verfasserin aut Jun Wang verfasserin aut Xiaogai Peng verfasserin aut Ruiyi Han verfasserin aut Canyun Zhang verfasserin aut Jinfang Kong verfasserin aut Jing Yang verfasserin aut In Nanomaterials MDPI AG, 2012 11(2021), 12, p 3242 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:11 year:2021 number:12, p 3242 https://doi.org/10.3390/nano11123242 kostenfrei https://doaj.org/article/ef57581bcf75463384c1dd8580f0ab13 kostenfrei https://www.mdpi.com/2079-4991/11/12/3242 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 12, p 3242
allfieldsGer	10.3390/nano11123242 doi (DE-627)DOAJ074352946 (DE-599)DOAJef57581bcf75463384c1dd8580f0ab13 DE-627 ger DE-627 rakwb eng QD1-999 Yu Sun verfasserin aut Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material. MnCl<sub<2</sub< doping CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< thin films solution spraying Chemistry Jin Chen verfasserin aut Fengchao Wang verfasserin aut Yi Yin verfasserin aut Yan Jin verfasserin aut Jun Wang verfasserin aut Xiaogai Peng verfasserin aut Ruiyi Han verfasserin aut Canyun Zhang verfasserin aut Jinfang Kong verfasserin aut Jing Yang verfasserin aut In Nanomaterials MDPI AG, 2012 11(2021), 12, p 3242 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:11 year:2021 number:12, p 3242 https://doi.org/10.3390/nano11123242 kostenfrei https://doaj.org/article/ef57581bcf75463384c1dd8580f0ab13 kostenfrei https://www.mdpi.com/2079-4991/11/12/3242 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 12, p 3242
allfieldsSound	10.3390/nano11123242 doi (DE-627)DOAJ074352946 (DE-599)DOAJef57581bcf75463384c1dd8580f0ab13 DE-627 ger DE-627 rakwb eng QD1-999 Yu Sun verfasserin aut Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material. MnCl<sub<2</sub< doping CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< thin films solution spraying Chemistry Jin Chen verfasserin aut Fengchao Wang verfasserin aut Yi Yin verfasserin aut Yan Jin verfasserin aut Jun Wang verfasserin aut Xiaogai Peng verfasserin aut Ruiyi Han verfasserin aut Canyun Zhang verfasserin aut Jinfang Kong verfasserin aut Jing Yang verfasserin aut In Nanomaterials MDPI AG, 2012 11(2021), 12, p 3242 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:11 year:2021 number:12, p 3242 https://doi.org/10.3390/nano11123242 kostenfrei https://doaj.org/article/ef57581bcf75463384c1dd8580f0ab13 kostenfrei https://www.mdpi.com/2079-4991/11/12/3242 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 12, p 3242
language	English
source	In Nanomaterials 11(2021), 12, p 3242 volume:11 year:2021 number:12, p 3242
sourceStr	In Nanomaterials 11(2021), 12, p 3242 volume:11 year:2021 number:12, p 3242
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	MnCl<sub<2</sub< doping CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< thin films solution spraying Chemistry
isfreeaccess_bool	true
container_title	Nanomaterials
authorswithroles_txt_mv	Yu Sun @@aut@@ Jin Chen @@aut@@ Fengchao Wang @@aut@@ Yi Yin @@aut@@ Yan Jin @@aut@@ Jun Wang @@aut@@ Xiaogai Peng @@aut@@ Ruiyi Han @@aut@@ Canyun Zhang @@aut@@ Jinfang Kong @@aut@@ Jing Yang @@aut@@
publishDateDaySort_date	2021-01-01T00:00:00Z
hierarchy_top_id	718627199
id	DOAJ074352946
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">DOAJ074352946</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240414223321.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230228s2021 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.3390/nano11123242</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ074352946</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJef57581bcf75463384c1dd8580f0ab13</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD1-999</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Yu Sun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2021</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">MnCl<sub<2</sub< doping</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub<</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">thin films</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">solution spraying</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Chemistry</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Jin Chen</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Fengchao Wang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Yi Yin</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Yan Jin</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Jun Wang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiaogai Peng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Ruiyi Han</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Canyun Zhang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Jinfang Kong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Jing Yang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="t">Nanomaterials</subfield><subfield code="d">MDPI AG, 2012</subfield><subfield code="g">11(2021), 12, p 3242</subfield><subfield code="w">(DE-627)718627199</subfield><subfield code="w">(DE-600)2662255-5</subfield><subfield code="x">20794991</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:11</subfield><subfield code="g">year:2021</subfield><subfield code="g">number:12, p 3242</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.3390/nano11123242</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doaj.org/article/ef57581bcf75463384c1dd8580f0ab13</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.mdpi.com/2079-4991/11/12/3242</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://doaj.org/toc/2079-4991</subfield><subfield code="y">Journal toc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_DOAJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2119</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4367</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">11</subfield><subfield code="j">2021</subfield><subfield code="e">12, p 3242</subfield></datafield></record></collection>
callnumber-first	Q - Science
author	Yu Sun
spellingShingle	Yu Sun misc QD1-999 misc MnCl<sub<2</sub< doping misc CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< misc thin films misc solution spraying misc Chemistry Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach
authorStr	Yu Sun
ppnlink_with_tag_str_mv	@@773@@(DE-627)718627199
format	electronic Article
delete_txt_mv	keep
author_role	aut aut aut aut aut aut aut aut aut aut aut
collection	DOAJ
remote_str	true
callnumber-label	QD1-999
illustrated	Not Illustrated
issn	20794991
topic_title	QD1-999 Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach MnCl<sub<2</sub< doping CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< thin films solution spraying
topic	misc QD1-999 misc MnCl<sub<2</sub< doping misc CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< misc thin films misc solution spraying misc Chemistry
topic_unstemmed	misc QD1-999 misc MnCl<sub<2</sub< doping misc CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< misc thin films misc solution spraying misc Chemistry
topic_browse	misc QD1-999 misc MnCl<sub<2</sub< doping misc CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< misc thin films misc solution spraying misc Chemistry
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	Nanomaterials
hierarchy_parent_id	718627199
hierarchy_top_title	Nanomaterials
isfreeaccess_txt	true
familylinks_str_mv	(DE-627)718627199 (DE-600)2662255-5
title	Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach
ctrlnum	(DE-627)DOAJ074352946 (DE-599)DOAJef57581bcf75463384c1dd8580f0ab13
title_full	Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach
author_sort	Yu Sun
journal	Nanomaterials
journalStr	Nanomaterials
callnumber-first-code	Q
lang_code	eng
isOA_bool	true
recordtype	marc
publishDateSort	2021
contenttype_str_mv	txt
author_browse	Yu Sun Jin Chen Fengchao Wang Yi Yin Yan Jin Jun Wang Xiaogai Peng Ruiyi Han Canyun Zhang Jinfang Kong Jing Yang
container_volume	11
class	QD1-999
format_se	Elektronische Aufsätze
author-letter	Yu Sun
doi_str_mv	10.3390/nano11123242
author2-role	verfasserin
title_sort	direct fabrication of cspb<sub<x</sub<mn<sub<1−x</sub<(br,cl)<sub<3</sub< thin film by a facile solution spraying approach
callnumber	QD1-999
title_auth	Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach
abstract	Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material.
abstractGer	Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material.
abstract_unstemmed	Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700
container_issue	12, p 3242
title_short	Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach
url	https://doi.org/10.3390/nano11123242 https://doaj.org/article/ef57581bcf75463384c1dd8580f0ab13 https://www.mdpi.com/2079-4991/11/12/3242 https://doaj.org/toc/2079-4991
remote_bool	true
author2	Jin Chen Fengchao Wang Yi Yin Yan Jin Jun Wang Xiaogai Peng Ruiyi Han Canyun Zhang Jinfang Kong Jing Yang
author2Str	Jin Chen Fengchao Wang Yi Yin Yan Jin Jun Wang Xiaogai Peng Ruiyi Han Canyun Zhang Jinfang Kong Jing Yang
ppnlink	718627199
callnumber-subject	QD - Chemistry
mediatype_str_mv	c
isOA_txt	true
hochschulschrift_bool	false
doi_str	10.3390/nano11123242
callnumber-a	QD1-999
up_date	2024-07-03T22:40:46.162Z
_version_	1803599422332862465
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">DOAJ074352946</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240414223321.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230228s2021 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.3390/nano11123242</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ074352946</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJef57581bcf75463384c1dd8580f0ab13</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD1-999</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Yu Sun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2021</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX<sub<3</sub< perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< film through MnCl<sub<2</sub< doping in host CsPbBr<sub<3</sub< material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr<sub<2</sub<:MnCl<sub<2</sub< increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl<sub<2</sub< doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX<sub<3</sub< film material.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">MnCl<sub<2</sub< doping</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub<</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">thin films</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">solution spraying</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Chemistry</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Jin Chen</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Fengchao Wang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Yi Yin</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Yan Jin</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Jun Wang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiaogai Peng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Ruiyi Han</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Canyun Zhang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Jinfang Kong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Jing Yang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="t">Nanomaterials</subfield><subfield code="d">MDPI AG, 2012</subfield><subfield code="g">11(2021), 12, p 3242</subfield><subfield code="w">(DE-627)718627199</subfield><subfield code="w">(DE-600)2662255-5</subfield><subfield code="x">20794991</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:11</subfield><subfield code="g">year:2021</subfield><subfield code="g">number:12, p 3242</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.3390/nano11123242</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doaj.org/article/ef57581bcf75463384c1dd8580f0ab13</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.mdpi.com/2079-4991/11/12/3242</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://doaj.org/toc/2079-4991</subfield><subfield code="y">Journal toc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_DOAJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2119</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4367</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">11</subfield><subfield code="j">2021</subfield><subfield code="e">12, p 3242</subfield></datafield></record></collection>
score	7.4019423

Nicht das Richtige dabei?

Schreiben Sie uns!

Direct Fabrication of CsPb<sub<x</sub<Mn<sub<1−x</sub<(Br,Cl)<sub<3</sub< Thin Film by a Facile Solution Spraying Approach

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?