Poly[μ-aqua-μ5-[2-(2,3,6-trichlorophenyl)acetato]-caesium]
In the structure of the title complex, [Cs(C8H4Cl3O2)(H2O)]n, the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs+ comprises a bidentate O:Cl-chelate interaction involving a carboxylate-O atom and an ortho-related ring-su...
Ausführliche Beschreibung
Autor*in: |
Graham Smith [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2013 |
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Übergeordnetes Werk: |
In: Acta Crystallographica Section E - International Union of Crystallography, 2005, 69(2013), 12, Seite m628-m628 |
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Übergeordnetes Werk: |
volume:69 ; year:2013 ; number:12 ; pages:m628-m628 |
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DOI / URN: |
10.1107/S1600536813029395 |
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Katalog-ID: |
DOAJ075820811 |
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10.1107/S1600536813029395 doi (DE-627)DOAJ075820811 (DE-599)DOAJ97d27ab185aa406ea53ef27a98d0ee38 DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[μ-aqua-μ5-[2-(2,3,6-trichlorophenyl)acetato]-caesium] 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of the title complex, [Cs(C8H4Cl3O2)(H2O)]n, the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs+ comprises a bidentate O:Cl-chelate interaction involving a carboxylate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxylate-O atom and a bridging water molecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxylate O—H...O hydrogen-bonding interactions. Crystallography In Acta Crystallographica Section E International Union of Crystallography, 2005 69(2013), 12, Seite m628-m628 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:69 year:2013 number:12 pages:m628-m628 https://doi.org/10.1107/S1600536813029395 kostenfrei https://doaj.org/article/97d27ab185aa406ea53ef27a98d0ee38 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536813029395 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 69 2013 12 m628-m628 |
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10.1107/S1600536813029395 doi (DE-627)DOAJ075820811 (DE-599)DOAJ97d27ab185aa406ea53ef27a98d0ee38 DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[μ-aqua-μ5-[2-(2,3,6-trichlorophenyl)acetato]-caesium] 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of the title complex, [Cs(C8H4Cl3O2)(H2O)]n, the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs+ comprises a bidentate O:Cl-chelate interaction involving a carboxylate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxylate-O atom and a bridging water molecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxylate O—H...O hydrogen-bonding interactions. Crystallography In Acta Crystallographica Section E International Union of Crystallography, 2005 69(2013), 12, Seite m628-m628 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:69 year:2013 number:12 pages:m628-m628 https://doi.org/10.1107/S1600536813029395 kostenfrei https://doaj.org/article/97d27ab185aa406ea53ef27a98d0ee38 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536813029395 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 69 2013 12 m628-m628 |
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10.1107/S1600536813029395 doi (DE-627)DOAJ075820811 (DE-599)DOAJ97d27ab185aa406ea53ef27a98d0ee38 DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[μ-aqua-μ5-[2-(2,3,6-trichlorophenyl)acetato]-caesium] 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of the title complex, [Cs(C8H4Cl3O2)(H2O)]n, the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs+ comprises a bidentate O:Cl-chelate interaction involving a carboxylate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxylate-O atom and a bridging water molecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxylate O—H...O hydrogen-bonding interactions. Crystallography In Acta Crystallographica Section E International Union of Crystallography, 2005 69(2013), 12, Seite m628-m628 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:69 year:2013 number:12 pages:m628-m628 https://doi.org/10.1107/S1600536813029395 kostenfrei https://doaj.org/article/97d27ab185aa406ea53ef27a98d0ee38 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536813029395 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 69 2013 12 m628-m628 |
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Poly[μ-aqua-μ5-[2-(2,3,6-trichlorophenyl)acetato]-caesium] |
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In the structure of the title complex, [Cs(C8H4Cl3O2)(H2O)]n, the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs+ comprises a bidentate O:Cl-chelate interaction involving a carboxylate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxylate-O atom and a bridging water molecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxylate O—H...O hydrogen-bonding interactions. |
abstractGer |
In the structure of the title complex, [Cs(C8H4Cl3O2)(H2O)]n, the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs+ comprises a bidentate O:Cl-chelate interaction involving a carboxylate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxylate-O atom and a bridging water molecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxylate O—H...O hydrogen-bonding interactions. |
abstract_unstemmed |
In the structure of the title complex, [Cs(C8H4Cl3O2)(H2O)]n, the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs+ comprises a bidentate O:Cl-chelate interaction involving a carboxylate-O atom and an ortho-related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxylate-O atom and a bridging water molecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxylate O—H...O hydrogen-bonding interactions. |
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