Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil

The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachate...
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Autor*in:	Lana Filipović [verfasserIn] Jasmina Defterdarović [verfasserIn] Rui Chen [verfasserIn] Vedran Krevh [verfasserIn] Horst H. Gerke [verfasserIn] Thomas Baumgartl [verfasserIn] Zoran Kovač [verfasserIn] Gabrijel Ondrašek [verfasserIn] Stanko Ružičić [verfasserIn] Hailong He [verfasserIn] Jaromir Dusek [verfasserIn] Vilim Filipović [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	trace metal mobility in soil hillslope landscape soil organic carbon copper oxychloride vineyard management

Übergeordnetes Werk:	In: Water - MDPI AG, 2010, 15(2023), 4, p 800
Übergeordnetes Werk:	volume:15 ; year:2023 ; number:4, p 800

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/w15040800

Katalog-ID:	DOAJ079947883

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520			\|a The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted.
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allfields	10.3390/w15040800 doi (DE-627)DOAJ079947883 (DE-599)DOAJe52861967b6d4fa1bfa9c549bb2f676e DE-627 ger DE-627 rakwb eng TC1-978 TD201-500 Lana Filipović verfasserin aut Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted. trace metal mobility in soil hillslope landscape soil organic carbon copper oxychloride vineyard management Hydraulic engineering Water supply for domestic and industrial purposes Jasmina Defterdarović verfasserin aut Rui Chen verfasserin aut Vedran Krevh verfasserin aut Horst H. Gerke verfasserin aut Thomas Baumgartl verfasserin aut Zoran Kovač verfasserin aut Gabrijel Ondrašek verfasserin aut Stanko Ružičić verfasserin aut Hailong He verfasserin aut Jaromir Dusek verfasserin aut Vilim Filipović verfasserin aut In Water MDPI AG, 2010 15(2023), 4, p 800 (DE-627)611729008 (DE-600)2521238-2 20734441 nnns volume:15 year:2023 number:4, p 800 https://doi.org/10.3390/w15040800 kostenfrei https://doaj.org/article/e52861967b6d4fa1bfa9c549bb2f676e kostenfrei https://www.mdpi.com/2073-4441/15/4/800 kostenfrei https://doaj.org/toc/2073-4441 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4367 GBV_ILN_4700 AR 15 2023 4, p 800
spelling	10.3390/w15040800 doi (DE-627)DOAJ079947883 (DE-599)DOAJe52861967b6d4fa1bfa9c549bb2f676e DE-627 ger DE-627 rakwb eng TC1-978 TD201-500 Lana Filipović verfasserin aut Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted. trace metal mobility in soil hillslope landscape soil organic carbon copper oxychloride vineyard management Hydraulic engineering Water supply for domestic and industrial purposes Jasmina Defterdarović verfasserin aut Rui Chen verfasserin aut Vedran Krevh verfasserin aut Horst H. Gerke verfasserin aut Thomas Baumgartl verfasserin aut Zoran Kovač verfasserin aut Gabrijel Ondrašek verfasserin aut Stanko Ružičić verfasserin aut Hailong He verfasserin aut Jaromir Dusek verfasserin aut Vilim Filipović verfasserin aut In Water MDPI AG, 2010 15(2023), 4, p 800 (DE-627)611729008 (DE-600)2521238-2 20734441 nnns volume:15 year:2023 number:4, p 800 https://doi.org/10.3390/w15040800 kostenfrei https://doaj.org/article/e52861967b6d4fa1bfa9c549bb2f676e kostenfrei https://www.mdpi.com/2073-4441/15/4/800 kostenfrei https://doaj.org/toc/2073-4441 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4367 GBV_ILN_4700 AR 15 2023 4, p 800
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allfieldsSound	10.3390/w15040800 doi (DE-627)DOAJ079947883 (DE-599)DOAJe52861967b6d4fa1bfa9c549bb2f676e DE-627 ger DE-627 rakwb eng TC1-978 TD201-500 Lana Filipović verfasserin aut Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted. trace metal mobility in soil hillslope landscape soil organic carbon copper oxychloride vineyard management Hydraulic engineering Water supply for domestic and industrial purposes Jasmina Defterdarović verfasserin aut Rui Chen verfasserin aut Vedran Krevh verfasserin aut Horst H. Gerke verfasserin aut Thomas Baumgartl verfasserin aut Zoran Kovač verfasserin aut Gabrijel Ondrašek verfasserin aut Stanko Ružičić verfasserin aut Hailong He verfasserin aut Jaromir Dusek verfasserin aut Vilim Filipović verfasserin aut In Water MDPI AG, 2010 15(2023), 4, p 800 (DE-627)611729008 (DE-600)2521238-2 20734441 nnns volume:15 year:2023 number:4, p 800 https://doi.org/10.3390/w15040800 kostenfrei https://doaj.org/article/e52861967b6d4fa1bfa9c549bb2f676e kostenfrei https://www.mdpi.com/2073-4441/15/4/800 kostenfrei https://doaj.org/toc/2073-4441 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4367 GBV_ILN_4700 AR 15 2023 4, p 800
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authorswithroles_txt_mv	Lana Filipović @@aut@@ Jasmina Defterdarović @@aut@@ Rui Chen @@aut@@ Vedran Krevh @@aut@@ Horst H. Gerke @@aut@@ Thomas Baumgartl @@aut@@ Zoran Kovač @@aut@@ Gabrijel Ondrašek @@aut@@ Stanko Ružičić @@aut@@ Hailong He @@aut@@ Jaromir Dusek @@aut@@ Vilim Filipović @@aut@@
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callnumber-first	T - Technology
author	Lana Filipović
spellingShingle	Lana Filipović misc TC1-978 misc TD201-500 misc trace metal mobility in soil misc hillslope landscape misc soil organic carbon misc copper oxychloride misc vineyard management misc Hydraulic engineering misc Water supply for domestic and industrial purposes Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil
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topic_title	TC1-978 TD201-500 Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil trace metal mobility in soil hillslope landscape soil organic carbon copper oxychloride vineyard management
topic	misc TC1-978 misc TD201-500 misc trace metal mobility in soil misc hillslope landscape misc soil organic carbon misc copper oxychloride misc vineyard management misc Hydraulic engineering misc Water supply for domestic and industrial purposes
topic_unstemmed	misc TC1-978 misc TD201-500 misc trace metal mobility in soil misc hillslope landscape misc soil organic carbon misc copper oxychloride misc vineyard management misc Hydraulic engineering misc Water supply for domestic and industrial purposes
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title	Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil
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title_full	Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil
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author_browse	Lana Filipović Jasmina Defterdarović Rui Chen Vedran Krevh Horst H. Gerke Thomas Baumgartl Zoran Kovač Gabrijel Ondrašek Stanko Ružičić Hailong He Jaromir Dusek Vilim Filipović
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title_sort	leached copper correlation with dissolved organic carbon in sloped vineyard soil
callnumber	TC1-978
title_auth	Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil
abstract	The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted.
abstractGer	The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted.
abstract_unstemmed	The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted.
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title_short	Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil
url	https://doi.org/10.3390/w15040800 https://doaj.org/article/e52861967b6d4fa1bfa9c549bb2f676e https://www.mdpi.com/2073-4441/15/4/800 https://doaj.org/toc/2073-4441
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author2	Jasmina Defterdarović Rui Chen Vedran Krevh Horst H. Gerke Thomas Baumgartl Zoran Kovač Gabrijel Ondrašek Stanko Ružičić Hailong He Jaromir Dusek Vilim Filipović
author2Str	Jasmina Defterdarović Rui Chen Vedran Krevh Horst H. Gerke Thomas Baumgartl Zoran Kovač Gabrijel Ondrašek Stanko Ružičić Hailong He Jaromir Dusek Vilim Filipović
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up_date	2024-07-04T01:27:57.719Z
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Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil

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