Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis

Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< (LNCM) has been intensively investigated owing to its high capacity and large voltage window. However, despite its high performance, the synthesis of LNCM can...
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Autor*in:	Jotti Karunawan [verfasserIn] Oktaviardi Bityasmawan Abdillah [verfasserIn] Octia Floweri [verfasserIn] Mahardika Prasetya Aji [verfasserIn] Sigit Puji Santosa [verfasserIn] Afriyanti Sumboja [verfasserIn] Ferry Iskandar [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	cycling stability facile microwave synthesis high-capacity cathode lithium-ion battery low cation mixing

Übergeordnetes Werk:	In: Batteries - MDPI AG, 2016, 9(2022), 1, p 31
Übergeordnetes Werk:	volume:9 ; year:2022 ; number:1, p 31

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/batteries9010031

Katalog-ID:	DOAJ081848978

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spelling	10.3390/batteries9010031 doi (DE-627)DOAJ081848978 (DE-599)DOAJ54c62092df83444683ab332e10dbf993 DE-627 ger DE-627 rakwb eng TK1001-1841 TP250-261 Jotti Karunawan verfasserin aut Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< (LNCM) has been intensively investigated owing to its high capacity and large voltage window. However, despite its high performance, the synthesis of LNCM can be challenging as it usually contains structural disorders and particle-size inhomogeneities, especially via a solid-state method. This work introduces microwave irradiation treatment on the LNCM fabricated via a solid-state method. The as-treated LNCM has low structural disorders, as indicated by the smaller cation mixing, better hexagonal ordering, and higher <i<c/a</i< ratio compared to the non-treated LNCM. Furthermore, the particle-size homogeneities of as-treated LNCM improved, as characterized by scanning electron microscopy (SEM) and particle size analyzer (PSA) measurements. The improved structural ordering and particle-size homogeneity of the treated sample enhances the specific capacity, initial Coulombic efficiency, and rate capability of the cathode material. The LNCM sample with 20 min of microwave treatment exhibits an optimum performance, showing a large specific capacity (259.84 mAh/g), a high first-cycle Coulombic efficiency (81.45%), and good rate capability. It also showed a stable electrochemical performance with 80.57% capacity retention after 200 cycles (at a charge/discharge of 0.2C/0.5C), which is 13% higher than samples without microwave irradiation. cycling stability facile microwave synthesis high-capacity cathode lithium-ion battery low cation mixing Production of electric energy or power. Powerplants. Central stations Industrial electrochemistry Oktaviardi Bityasmawan Abdillah verfasserin aut Octia Floweri verfasserin aut Mahardika Prasetya Aji verfasserin aut Sigit Puji Santosa verfasserin aut Afriyanti Sumboja verfasserin aut Ferry Iskandar verfasserin aut In Batteries MDPI AG, 2016 9(2022), 1, p 31 (DE-627)820684066 (DE-600)2813972-0 23130105 nnns volume:9 year:2022 number:1, p 31 https://doi.org/10.3390/batteries9010031 kostenfrei https://doaj.org/article/54c62092df83444683ab332e10dbf993 kostenfrei https://www.mdpi.com/2313-0105/9/1/31 kostenfrei https://doaj.org/toc/2313-0105 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2022 1, p 31
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allfieldsSound	10.3390/batteries9010031 doi (DE-627)DOAJ081848978 (DE-599)DOAJ54c62092df83444683ab332e10dbf993 DE-627 ger DE-627 rakwb eng TK1001-1841 TP250-261 Jotti Karunawan verfasserin aut Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< (LNCM) has been intensively investigated owing to its high capacity and large voltage window. However, despite its high performance, the synthesis of LNCM can be challenging as it usually contains structural disorders and particle-size inhomogeneities, especially via a solid-state method. This work introduces microwave irradiation treatment on the LNCM fabricated via a solid-state method. The as-treated LNCM has low structural disorders, as indicated by the smaller cation mixing, better hexagonal ordering, and higher <i<c/a</i< ratio compared to the non-treated LNCM. Furthermore, the particle-size homogeneities of as-treated LNCM improved, as characterized by scanning electron microscopy (SEM) and particle size analyzer (PSA) measurements. The improved structural ordering and particle-size homogeneity of the treated sample enhances the specific capacity, initial Coulombic efficiency, and rate capability of the cathode material. The LNCM sample with 20 min of microwave treatment exhibits an optimum performance, showing a large specific capacity (259.84 mAh/g), a high first-cycle Coulombic efficiency (81.45%), and good rate capability. It also showed a stable electrochemical performance with 80.57% capacity retention after 200 cycles (at a charge/discharge of 0.2C/0.5C), which is 13% higher than samples without microwave irradiation. cycling stability facile microwave synthesis high-capacity cathode lithium-ion battery low cation mixing Production of electric energy or power. Powerplants. Central stations Industrial electrochemistry Oktaviardi Bityasmawan Abdillah verfasserin aut Octia Floweri verfasserin aut Mahardika Prasetya Aji verfasserin aut Sigit Puji Santosa verfasserin aut Afriyanti Sumboja verfasserin aut Ferry Iskandar verfasserin aut In Batteries MDPI AG, 2016 9(2022), 1, p 31 (DE-627)820684066 (DE-600)2813972-0 23130105 nnns volume:9 year:2022 number:1, p 31 https://doi.org/10.3390/batteries9010031 kostenfrei https://doaj.org/article/54c62092df83444683ab332e10dbf993 kostenfrei https://www.mdpi.com/2313-0105/9/1/31 kostenfrei https://doaj.org/toc/2313-0105 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2022 1, p 31
language	English
source	In Batteries 9(2022), 1, p 31 volume:9 year:2022 number:1, p 31
sourceStr	In Batteries 9(2022), 1, p 31 volume:9 year:2022 number:1, p 31
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authorswithroles_txt_mv	Jotti Karunawan @@aut@@ Oktaviardi Bityasmawan Abdillah @@aut@@ Octia Floweri @@aut@@ Mahardika Prasetya Aji @@aut@@ Sigit Puji Santosa @@aut@@ Afriyanti Sumboja @@aut@@ Ferry Iskandar @@aut@@
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callnumber-first	T - Technology
author	Jotti Karunawan
spellingShingle	Jotti Karunawan misc TK1001-1841 misc TP250-261 misc cycling stability misc facile microwave synthesis misc high-capacity cathode misc lithium-ion battery misc low cation mixing misc Production of electric energy or power. Powerplants. Central stations misc Industrial electrochemistry Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis
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topic_title	TK1001-1841 TP250-261 Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis cycling stability facile microwave synthesis high-capacity cathode lithium-ion battery low cation mixing
topic	misc TK1001-1841 misc TP250-261 misc cycling stability misc facile microwave synthesis misc high-capacity cathode misc lithium-ion battery misc low cation mixing misc Production of electric energy or power. Powerplants. Central stations misc Industrial electrochemistry
topic_unstemmed	misc TK1001-1841 misc TP250-261 misc cycling stability misc facile microwave synthesis misc high-capacity cathode misc lithium-ion battery misc low cation mixing misc Production of electric energy or power. Powerplants. Central stations misc Industrial electrochemistry
topic_browse	misc TK1001-1841 misc TP250-261 misc cycling stability misc facile microwave synthesis misc high-capacity cathode misc lithium-ion battery misc low cation mixing misc Production of electric energy or power. Powerplants. Central stations misc Industrial electrochemistry
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title	Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis
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title_full	Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis
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author_browse	Jotti Karunawan Oktaviardi Bityasmawan Abdillah Octia Floweri Mahardika Prasetya Aji Sigit Puji Santosa Afriyanti Sumboja Ferry Iskandar
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title_sort	improving the structural ordering and particle-size homogeneity of li-rich layered li<sub<1.2</sub<ni<sub<0.13</sub<co<sub<0.13</sub<mn<sub<0.54</sub<o<sub<2</sub< cathode materials through microwave irradiation solid-state synthesis
callnumber	TK1001-1841
title_auth	Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis
abstract	Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< (LNCM) has been intensively investigated owing to its high capacity and large voltage window. However, despite its high performance, the synthesis of LNCM can be challenging as it usually contains structural disorders and particle-size inhomogeneities, especially via a solid-state method. This work introduces microwave irradiation treatment on the LNCM fabricated via a solid-state method. The as-treated LNCM has low structural disorders, as indicated by the smaller cation mixing, better hexagonal ordering, and higher <i<c/a</i< ratio compared to the non-treated LNCM. Furthermore, the particle-size homogeneities of as-treated LNCM improved, as characterized by scanning electron microscopy (SEM) and particle size analyzer (PSA) measurements. The improved structural ordering and particle-size homogeneity of the treated sample enhances the specific capacity, initial Coulombic efficiency, and rate capability of the cathode material. The LNCM sample with 20 min of microwave treatment exhibits an optimum performance, showing a large specific capacity (259.84 mAh/g), a high first-cycle Coulombic efficiency (81.45%), and good rate capability. It also showed a stable electrochemical performance with 80.57% capacity retention after 200 cycles (at a charge/discharge of 0.2C/0.5C), which is 13% higher than samples without microwave irradiation.
abstractGer	Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< (LNCM) has been intensively investigated owing to its high capacity and large voltage window. However, despite its high performance, the synthesis of LNCM can be challenging as it usually contains structural disorders and particle-size inhomogeneities, especially via a solid-state method. This work introduces microwave irradiation treatment on the LNCM fabricated via a solid-state method. The as-treated LNCM has low structural disorders, as indicated by the smaller cation mixing, better hexagonal ordering, and higher <i<c/a</i< ratio compared to the non-treated LNCM. Furthermore, the particle-size homogeneities of as-treated LNCM improved, as characterized by scanning electron microscopy (SEM) and particle size analyzer (PSA) measurements. The improved structural ordering and particle-size homogeneity of the treated sample enhances the specific capacity, initial Coulombic efficiency, and rate capability of the cathode material. The LNCM sample with 20 min of microwave treatment exhibits an optimum performance, showing a large specific capacity (259.84 mAh/g), a high first-cycle Coulombic efficiency (81.45%), and good rate capability. It also showed a stable electrochemical performance with 80.57% capacity retention after 200 cycles (at a charge/discharge of 0.2C/0.5C), which is 13% higher than samples without microwave irradiation.
abstract_unstemmed	Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< (LNCM) has been intensively investigated owing to its high capacity and large voltage window. However, despite its high performance, the synthesis of LNCM can be challenging as it usually contains structural disorders and particle-size inhomogeneities, especially via a solid-state method. This work introduces microwave irradiation treatment on the LNCM fabricated via a solid-state method. The as-treated LNCM has low structural disorders, as indicated by the smaller cation mixing, better hexagonal ordering, and higher <i<c/a</i< ratio compared to the non-treated LNCM. Furthermore, the particle-size homogeneities of as-treated LNCM improved, as characterized by scanning electron microscopy (SEM) and particle size analyzer (PSA) measurements. The improved structural ordering and particle-size homogeneity of the treated sample enhances the specific capacity, initial Coulombic efficiency, and rate capability of the cathode material. The LNCM sample with 20 min of microwave treatment exhibits an optimum performance, showing a large specific capacity (259.84 mAh/g), a high first-cycle Coulombic efficiency (81.45%), and good rate capability. It also showed a stable electrochemical performance with 80.57% capacity retention after 200 cycles (at a charge/discharge of 0.2C/0.5C), which is 13% higher than samples without microwave irradiation.
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container_issue	1, p 31
title_short	Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis
url	https://doi.org/10.3390/batteries9010031 https://doaj.org/article/54c62092df83444683ab332e10dbf993 https://www.mdpi.com/2313-0105/9/1/31 https://doaj.org/toc/2313-0105
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up_date	2024-07-03T22:18:02.370Z
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However, despite its high performance, the synthesis of LNCM can be challenging as it usually contains structural disorders and particle-size inhomogeneities, especially via a solid-state method. This work introduces microwave irradiation treatment on the LNCM fabricated via a solid-state method. The as-treated LNCM has low structural disorders, as indicated by the smaller cation mixing, better hexagonal ordering, and higher <i<c/a</i< ratio compared to the non-treated LNCM. Furthermore, the particle-size homogeneities of as-treated LNCM improved, as characterized by scanning electron microscopy (SEM) and particle size analyzer (PSA) measurements. The improved structural ordering and particle-size homogeneity of the treated sample enhances the specific capacity, initial Coulombic efficiency, and rate capability of the cathode material. 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Improving the Structural Ordering and Particle-Size Homogeneity of Li-Rich Layered Li<sub<1.2</sub<Ni<sub<0.13</sub<Co<sub<0.13</sub<Mn<sub<0.54</sub<O<sub<2</sub< Cathode Materials through Microwave Irradiation Solid-State Synthesis

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