Reaction Kinetic Parameters and Surface Thermodynamic Properties of Cu2O Nanocubes

Cuprous oxide (Cu2O) nanocubes were synthesized by reducing Cu(OH)2 in the presence of sodium citrate at room temperature. The samples were characterized in detail by field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-r...
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Autor*in:	Xingxing Li [verfasserIn] Huanfeng Tang [verfasserIn] Xianrui Lu [verfasserIn] Shi Lin [verfasserIn] Lili Shi [verfasserIn] Zaiyin Huang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2015

Schlagwörter:	nanothermodynamics cuprous oxide nanocrystal specific surface enthalpy specific surface Gibbs free energy specific surface entropy

Übergeordnetes Werk:	In: Entropy - MDPI AG, 2003, 17(2015), 8, Seite 5437-5449
Übergeordnetes Werk:	volume:17 ; year:2015 ; number:8 ; pages:5437-5449

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/e17085437

Katalog-ID:	DOAJ085465437

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520			\|a Cuprous oxide (Cu2O) nanocubes were synthesized by reducing Cu(OH)2 in the presence of sodium citrate at room temperature. The samples were characterized in detail by field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, and N2 absorption (BET specific surface area). The equations for acquiring reaction kinetic parameters and surface thermodynamic properties of Cu2O nanocubes were deduced by establishment of the relations between thermodynamic functions of Cu2O nanocubes and these of the bulk Cu2O. Combined with thermochemical cycle, transition state theory, basic theory of chemical thermodynamics, and in situ microcalorimetry, reaction kinetic parameters, specific surface enthalpy, specific surface Gibbs free energy, and specific surface entropy of Cu2O nanocubes were successfully determined. We also introduced a universal route for gaining reaction kinetic parameters and surface thermodynamic properties of nanomaterials.
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language	English
source	In Entropy 17(2015), 8, Seite 5437-5449 volume:17 year:2015 number:8 pages:5437-5449
sourceStr	In Entropy 17(2015), 8, Seite 5437-5449 volume:17 year:2015 number:8 pages:5437-5449
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	nanothermodynamics cuprous oxide nanocrystal specific surface enthalpy specific surface Gibbs free energy specific surface entropy Science Q Astrophysics Physics
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container_title	Entropy
authorswithroles_txt_mv	Xingxing Li @@aut@@ Huanfeng Tang @@aut@@ Xianrui Lu @@aut@@ Shi Lin @@aut@@ Lili Shi @@aut@@ Zaiyin Huang @@aut@@
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callnumber-first	Q - Science
author	Xingxing Li
spellingShingle	Xingxing Li misc QB460-466 misc QC1-999 misc nanothermodynamics misc cuprous oxide misc nanocrystal misc specific surface enthalpy misc specific surface Gibbs free energy misc specific surface entropy misc Science misc Q misc Astrophysics misc Physics Reaction Kinetic Parameters and Surface Thermodynamic Properties of Cu2O Nanocubes
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topic_title	QB460-466 QC1-999 Reaction Kinetic Parameters and Surface Thermodynamic Properties of Cu2O Nanocubes nanothermodynamics cuprous oxide nanocrystal specific surface enthalpy specific surface Gibbs free energy specific surface entropy
topic	misc QB460-466 misc QC1-999 misc nanothermodynamics misc cuprous oxide misc nanocrystal misc specific surface enthalpy misc specific surface Gibbs free energy misc specific surface entropy misc Science misc Q misc Astrophysics misc Physics
topic_unstemmed	misc QB460-466 misc QC1-999 misc nanothermodynamics misc cuprous oxide misc nanocrystal misc specific surface enthalpy misc specific surface Gibbs free energy misc specific surface entropy misc Science misc Q misc Astrophysics misc Physics
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title	Reaction Kinetic Parameters and Surface Thermodynamic Properties of Cu2O Nanocubes
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title_full	Reaction Kinetic Parameters and Surface Thermodynamic Properties of Cu2O Nanocubes
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title_sort	reaction kinetic parameters and surface thermodynamic properties of cu2o nanocubes
callnumber	QB460-466
title_auth	Reaction Kinetic Parameters and Surface Thermodynamic Properties of Cu2O Nanocubes
abstract	Cuprous oxide (Cu2O) nanocubes were synthesized by reducing Cu(OH)2 in the presence of sodium citrate at room temperature. The samples were characterized in detail by field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, and N2 absorption (BET specific surface area). The equations for acquiring reaction kinetic parameters and surface thermodynamic properties of Cu2O nanocubes were deduced by establishment of the relations between thermodynamic functions of Cu2O nanocubes and these of the bulk Cu2O. Combined with thermochemical cycle, transition state theory, basic theory of chemical thermodynamics, and in situ microcalorimetry, reaction kinetic parameters, specific surface enthalpy, specific surface Gibbs free energy, and specific surface entropy of Cu2O nanocubes were successfully determined. We also introduced a universal route for gaining reaction kinetic parameters and surface thermodynamic properties of nanomaterials.
abstractGer	Cuprous oxide (Cu2O) nanocubes were synthesized by reducing Cu(OH)2 in the presence of sodium citrate at room temperature. The samples were characterized in detail by field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, and N2 absorption (BET specific surface area). The equations for acquiring reaction kinetic parameters and surface thermodynamic properties of Cu2O nanocubes were deduced by establishment of the relations between thermodynamic functions of Cu2O nanocubes and these of the bulk Cu2O. Combined with thermochemical cycle, transition state theory, basic theory of chemical thermodynamics, and in situ microcalorimetry, reaction kinetic parameters, specific surface enthalpy, specific surface Gibbs free energy, and specific surface entropy of Cu2O nanocubes were successfully determined. We also introduced a universal route for gaining reaction kinetic parameters and surface thermodynamic properties of nanomaterials.
abstract_unstemmed	Cuprous oxide (Cu2O) nanocubes were synthesized by reducing Cu(OH)2 in the presence of sodium citrate at room temperature. The samples were characterized in detail by field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, and N2 absorption (BET specific surface area). The equations for acquiring reaction kinetic parameters and surface thermodynamic properties of Cu2O nanocubes were deduced by establishment of the relations between thermodynamic functions of Cu2O nanocubes and these of the bulk Cu2O. Combined with thermochemical cycle, transition state theory, basic theory of chemical thermodynamics, and in situ microcalorimetry, reaction kinetic parameters, specific surface enthalpy, specific surface Gibbs free energy, and specific surface entropy of Cu2O nanocubes were successfully determined. We also introduced a universal route for gaining reaction kinetic parameters and surface thermodynamic properties of nanomaterials.
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container_issue	8
title_short	Reaction Kinetic Parameters and Surface Thermodynamic Properties of Cu2O Nanocubes
url	https://doi.org/10.3390/e17085437 https://doaj.org/article/10d9a1202654489180105d1d55045f34 http://www.mdpi.com/1099-4300/17/8/5437 https://doaj.org/toc/1099-4300
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author2	Huanfeng Tang Xianrui Lu Shi Lin Lili Shi Zaiyin Huang
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doi_str	10.3390/e17085437
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up_date	2024-07-03T14:54:21.192Z
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