Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs)

Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular metal–organic frameworks (SMOFs) are stable u...
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Autor*in:	Arkaitz Fidalgo-Marijuan [verfasserIn] Eder Amayuelas [verfasserIn] Gotzone Barandika [verfasserIn] Edurne S. Larrea [verfasserIn] Begoña Bazán [verfasserIn] Miren Karmele Urtiaga [verfasserIn] Marta Iglesias [verfasserIn] María Isabel Arriortua [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	metalloporphyrins supramolecular MOFs heterogeneous catalysts Knoevenagel condensations aldol condensations one-pot cascade reactions

Übergeordnetes Werk:	In: IUCrJ - International Union of Crystallography, 2014, 5(2018), 5, Seite 559-568
Übergeordnetes Werk:	volume:5 ; year:2018 ; number:5 ; pages:559-568

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1107/S2052252518007856

Katalog-ID:	DOAJ086225561

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allfields	10.1107/S2052252518007856 doi (DE-627)DOAJ086225561 (DE-599)DOAJc347a3aa19564be9be1053c2d06aab39 DE-627 ger DE-627 rakwb eng QD901-999 Arkaitz Fidalgo-Marijuan verfasserin aut Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs) 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular metal–organic frameworks (SMOFs) are stable under ambient conditions and those with anchored catalysts exhibit favourable properties. However, this paper presents an innovative approach that consists of using metal nodes as both structural synthons and catalysts. Regarding the latter, metalloporphyrins are suitable candidates to play both roles simultaneously. In fact, there are a number of papers that report coordination compounds based on metalloporphyrins exhibiting these features. Thus, the aim of this bioinspired work was to obtain stable SMOFs (at room temperature) based on metalloporphyrins and explore their catalytic activity. This work reports the environmentally friendly microwave-assisted synthesis and characterization of the compound [H(bipy)]2[(MnTPPS)(H2O)2]·2bipy·14H2O (TPPS = meso-tetraphenylporphine-4,4′,4′′,4′′′-tetrasulfonic acid and bipy = 4,4′-bipyridine). This compound is the first example of an MnTPPS-based SMOF, as far as we are aware, and has been structurally and thermally characterized through single-crystal X-ray diffraction, IR spectroscopy, thermogravimetry and transmission electron microscopy. Additionally, this work explores not only the catalytic activity of this compound but also of the compounds μ-O-[FeTCPP]2·16DMF and [CoTPPS0.5(bipy)(H2O)2]·6H2O. The structural features of these supramolecular materials, with accessible networks and high thermal stability, are responsible for their excellent behaviour as heterogeneous catalysts for different oxidation, condensation (aldol and Knoevenagel) and one-pot cascade reactions. metalloporphyrins supramolecular MOFs heterogeneous catalysts Knoevenagel condensations aldol condensations one-pot cascade reactions Crystallography Eder Amayuelas verfasserin aut Gotzone Barandika verfasserin aut Edurne S. Larrea verfasserin aut Begoña Bazán verfasserin aut Miren Karmele Urtiaga verfasserin aut Marta Iglesias verfasserin aut María Isabel Arriortua verfasserin aut In IUCrJ International Union of Crystallography, 2014 5(2018), 5, Seite 559-568 (DE-627)777782758 (DE-600)2754953-7 20522525 nnns volume:5 year:2018 number:5 pages:559-568 https://doi.org/10.1107/S2052252518007856 kostenfrei https://doaj.org/article/c347a3aa19564be9be1053c2d06aab39 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2052252518007856 kostenfrei https://doaj.org/toc/2052-2525 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 5 2018 5 559-568
spelling	10.1107/S2052252518007856 doi (DE-627)DOAJ086225561 (DE-599)DOAJc347a3aa19564be9be1053c2d06aab39 DE-627 ger DE-627 rakwb eng QD901-999 Arkaitz Fidalgo-Marijuan verfasserin aut Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs) 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular metal–organic frameworks (SMOFs) are stable under ambient conditions and those with anchored catalysts exhibit favourable properties. However, this paper presents an innovative approach that consists of using metal nodes as both structural synthons and catalysts. Regarding the latter, metalloporphyrins are suitable candidates to play both roles simultaneously. In fact, there are a number of papers that report coordination compounds based on metalloporphyrins exhibiting these features. Thus, the aim of this bioinspired work was to obtain stable SMOFs (at room temperature) based on metalloporphyrins and explore their catalytic activity. This work reports the environmentally friendly microwave-assisted synthesis and characterization of the compound [H(bipy)]2[(MnTPPS)(H2O)2]·2bipy·14H2O (TPPS = meso-tetraphenylporphine-4,4′,4′′,4′′′-tetrasulfonic acid and bipy = 4,4′-bipyridine). This compound is the first example of an MnTPPS-based SMOF, as far as we are aware, and has been structurally and thermally characterized through single-crystal X-ray diffraction, IR spectroscopy, thermogravimetry and transmission electron microscopy. Additionally, this work explores not only the catalytic activity of this compound but also of the compounds μ-O-[FeTCPP]2·16DMF and [CoTPPS0.5(bipy)(H2O)2]·6H2O. The structural features of these supramolecular materials, with accessible networks and high thermal stability, are responsible for their excellent behaviour as heterogeneous catalysts for different oxidation, condensation (aldol and Knoevenagel) and one-pot cascade reactions. metalloporphyrins supramolecular MOFs heterogeneous catalysts Knoevenagel condensations aldol condensations one-pot cascade reactions Crystallography Eder Amayuelas verfasserin aut Gotzone Barandika verfasserin aut Edurne S. Larrea verfasserin aut Begoña Bazán verfasserin aut Miren Karmele Urtiaga verfasserin aut Marta Iglesias verfasserin aut María Isabel Arriortua verfasserin aut In IUCrJ International Union of Crystallography, 2014 5(2018), 5, Seite 559-568 (DE-627)777782758 (DE-600)2754953-7 20522525 nnns volume:5 year:2018 number:5 pages:559-568 https://doi.org/10.1107/S2052252518007856 kostenfrei https://doaj.org/article/c347a3aa19564be9be1053c2d06aab39 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2052252518007856 kostenfrei https://doaj.org/toc/2052-2525 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 5 2018 5 559-568
allfields_unstemmed	10.1107/S2052252518007856 doi (DE-627)DOAJ086225561 (DE-599)DOAJc347a3aa19564be9be1053c2d06aab39 DE-627 ger DE-627 rakwb eng QD901-999 Arkaitz Fidalgo-Marijuan verfasserin aut Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs) 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular metal–organic frameworks (SMOFs) are stable under ambient conditions and those with anchored catalysts exhibit favourable properties. However, this paper presents an innovative approach that consists of using metal nodes as both structural synthons and catalysts. Regarding the latter, metalloporphyrins are suitable candidates to play both roles simultaneously. In fact, there are a number of papers that report coordination compounds based on metalloporphyrins exhibiting these features. Thus, the aim of this bioinspired work was to obtain stable SMOFs (at room temperature) based on metalloporphyrins and explore their catalytic activity. This work reports the environmentally friendly microwave-assisted synthesis and characterization of the compound [H(bipy)]2[(MnTPPS)(H2O)2]·2bipy·14H2O (TPPS = meso-tetraphenylporphine-4,4′,4′′,4′′′-tetrasulfonic acid and bipy = 4,4′-bipyridine). This compound is the first example of an MnTPPS-based SMOF, as far as we are aware, and has been structurally and thermally characterized through single-crystal X-ray diffraction, IR spectroscopy, thermogravimetry and transmission electron microscopy. Additionally, this work explores not only the catalytic activity of this compound but also of the compounds μ-O-[FeTCPP]2·16DMF and [CoTPPS0.5(bipy)(H2O)2]·6H2O. The structural features of these supramolecular materials, with accessible networks and high thermal stability, are responsible for their excellent behaviour as heterogeneous catalysts for different oxidation, condensation (aldol and Knoevenagel) and one-pot cascade reactions. metalloporphyrins supramolecular MOFs heterogeneous catalysts Knoevenagel condensations aldol condensations one-pot cascade reactions Crystallography Eder Amayuelas verfasserin aut Gotzone Barandika verfasserin aut Edurne S. Larrea verfasserin aut Begoña Bazán verfasserin aut Miren Karmele Urtiaga verfasserin aut Marta Iglesias verfasserin aut María Isabel Arriortua verfasserin aut In IUCrJ International Union of Crystallography, 2014 5(2018), 5, Seite 559-568 (DE-627)777782758 (DE-600)2754953-7 20522525 nnns volume:5 year:2018 number:5 pages:559-568 https://doi.org/10.1107/S2052252518007856 kostenfrei https://doaj.org/article/c347a3aa19564be9be1053c2d06aab39 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2052252518007856 kostenfrei https://doaj.org/toc/2052-2525 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 5 2018 5 559-568
allfieldsGer	10.1107/S2052252518007856 doi (DE-627)DOAJ086225561 (DE-599)DOAJc347a3aa19564be9be1053c2d06aab39 DE-627 ger DE-627 rakwb eng QD901-999 Arkaitz Fidalgo-Marijuan verfasserin aut Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs) 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular metal–organic frameworks (SMOFs) are stable under ambient conditions and those with anchored catalysts exhibit favourable properties. However, this paper presents an innovative approach that consists of using metal nodes as both structural synthons and catalysts. Regarding the latter, metalloporphyrins are suitable candidates to play both roles simultaneously. In fact, there are a number of papers that report coordination compounds based on metalloporphyrins exhibiting these features. Thus, the aim of this bioinspired work was to obtain stable SMOFs (at room temperature) based on metalloporphyrins and explore their catalytic activity. This work reports the environmentally friendly microwave-assisted synthesis and characterization of the compound [H(bipy)]2[(MnTPPS)(H2O)2]·2bipy·14H2O (TPPS = meso-tetraphenylporphine-4,4′,4′′,4′′′-tetrasulfonic acid and bipy = 4,4′-bipyridine). This compound is the first example of an MnTPPS-based SMOF, as far as we are aware, and has been structurally and thermally characterized through single-crystal X-ray diffraction, IR spectroscopy, thermogravimetry and transmission electron microscopy. Additionally, this work explores not only the catalytic activity of this compound but also of the compounds μ-O-[FeTCPP]2·16DMF and [CoTPPS0.5(bipy)(H2O)2]·6H2O. The structural features of these supramolecular materials, with accessible networks and high thermal stability, are responsible for their excellent behaviour as heterogeneous catalysts for different oxidation, condensation (aldol and Knoevenagel) and one-pot cascade reactions. metalloporphyrins supramolecular MOFs heterogeneous catalysts Knoevenagel condensations aldol condensations one-pot cascade reactions Crystallography Eder Amayuelas verfasserin aut Gotzone Barandika verfasserin aut Edurne S. Larrea verfasserin aut Begoña Bazán verfasserin aut Miren Karmele Urtiaga verfasserin aut Marta Iglesias verfasserin aut María Isabel Arriortua verfasserin aut In IUCrJ International Union of Crystallography, 2014 5(2018), 5, Seite 559-568 (DE-627)777782758 (DE-600)2754953-7 20522525 nnns volume:5 year:2018 number:5 pages:559-568 https://doi.org/10.1107/S2052252518007856 kostenfrei https://doaj.org/article/c347a3aa19564be9be1053c2d06aab39 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2052252518007856 kostenfrei https://doaj.org/toc/2052-2525 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 5 2018 5 559-568
allfieldsSound	10.1107/S2052252518007856 doi (DE-627)DOAJ086225561 (DE-599)DOAJc347a3aa19564be9be1053c2d06aab39 DE-627 ger DE-627 rakwb eng QD901-999 Arkaitz Fidalgo-Marijuan verfasserin aut Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs) 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular metal–organic frameworks (SMOFs) are stable under ambient conditions and those with anchored catalysts exhibit favourable properties. However, this paper presents an innovative approach that consists of using metal nodes as both structural synthons and catalysts. Regarding the latter, metalloporphyrins are suitable candidates to play both roles simultaneously. In fact, there are a number of papers that report coordination compounds based on metalloporphyrins exhibiting these features. Thus, the aim of this bioinspired work was to obtain stable SMOFs (at room temperature) based on metalloporphyrins and explore their catalytic activity. This work reports the environmentally friendly microwave-assisted synthesis and characterization of the compound [H(bipy)]2[(MnTPPS)(H2O)2]·2bipy·14H2O (TPPS = meso-tetraphenylporphine-4,4′,4′′,4′′′-tetrasulfonic acid and bipy = 4,4′-bipyridine). This compound is the first example of an MnTPPS-based SMOF, as far as we are aware, and has been structurally and thermally characterized through single-crystal X-ray diffraction, IR spectroscopy, thermogravimetry and transmission electron microscopy. Additionally, this work explores not only the catalytic activity of this compound but also of the compounds μ-O-[FeTCPP]2·16DMF and [CoTPPS0.5(bipy)(H2O)2]·6H2O. The structural features of these supramolecular materials, with accessible networks and high thermal stability, are responsible for their excellent behaviour as heterogeneous catalysts for different oxidation, condensation (aldol and Knoevenagel) and one-pot cascade reactions. metalloporphyrins supramolecular MOFs heterogeneous catalysts Knoevenagel condensations aldol condensations one-pot cascade reactions Crystallography Eder Amayuelas verfasserin aut Gotzone Barandika verfasserin aut Edurne S. Larrea verfasserin aut Begoña Bazán verfasserin aut Miren Karmele Urtiaga verfasserin aut Marta Iglesias verfasserin aut María Isabel Arriortua verfasserin aut In IUCrJ International Union of Crystallography, 2014 5(2018), 5, Seite 559-568 (DE-627)777782758 (DE-600)2754953-7 20522525 nnns volume:5 year:2018 number:5 pages:559-568 https://doi.org/10.1107/S2052252518007856 kostenfrei https://doaj.org/article/c347a3aa19564be9be1053c2d06aab39 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2052252518007856 kostenfrei https://doaj.org/toc/2052-2525 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 5 2018 5 559-568
language	English
source	In IUCrJ 5(2018), 5, Seite 559-568 volume:5 year:2018 number:5 pages:559-568
sourceStr	In IUCrJ 5(2018), 5, Seite 559-568 volume:5 year:2018 number:5 pages:559-568
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	metalloporphyrins supramolecular MOFs heterogeneous catalysts Knoevenagel condensations aldol condensations one-pot cascade reactions Crystallography
isfreeaccess_bool	true
container_title	IUCrJ
authorswithroles_txt_mv	Arkaitz Fidalgo-Marijuan @@aut@@ Eder Amayuelas @@aut@@ Gotzone Barandika @@aut@@ Edurne S. Larrea @@aut@@ Begoña Bazán @@aut@@ Miren Karmele Urtiaga @@aut@@ Marta Iglesias @@aut@@ María Isabel Arriortua @@aut@@
publishDateDaySort_date	2018-01-01T00:00:00Z
hierarchy_top_id	777782758
id	DOAJ086225561
language_de	englisch
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author	Arkaitz Fidalgo-Marijuan
spellingShingle	Arkaitz Fidalgo-Marijuan misc QD901-999 misc metalloporphyrins misc supramolecular MOFs misc heterogeneous catalysts misc Knoevenagel condensations misc aldol condensations misc one-pot cascade reactions misc Crystallography Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs)
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topic_title	QD901-999 Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs) metalloporphyrins supramolecular MOFs heterogeneous catalysts Knoevenagel condensations aldol condensations one-pot cascade reactions
topic	misc QD901-999 misc metalloporphyrins misc supramolecular MOFs misc heterogeneous catalysts misc Knoevenagel condensations misc aldol condensations misc one-pot cascade reactions misc Crystallography
topic_unstemmed	misc QD901-999 misc metalloporphyrins misc supramolecular MOFs misc heterogeneous catalysts misc Knoevenagel condensations misc aldol condensations misc one-pot cascade reactions misc Crystallography
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title	Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs)
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title_full	Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs)
author_sort	Arkaitz Fidalgo-Marijuan
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author_browse	Arkaitz Fidalgo-Marijuan Eder Amayuelas Gotzone Barandika Edurne S. Larrea Begoña Bazán Miren Karmele Urtiaga Marta Iglesias María Isabel Arriortua
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author-letter	Arkaitz Fidalgo-Marijuan
doi_str_mv	10.1107/S2052252518007856
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title_sort	double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (smofs)
callnumber	QD901-999
title_auth	Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs)
abstract	Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular metal–organic frameworks (SMOFs) are stable under ambient conditions and those with anchored catalysts exhibit favourable properties. However, this paper presents an innovative approach that consists of using metal nodes as both structural synthons and catalysts. Regarding the latter, metalloporphyrins are suitable candidates to play both roles simultaneously. In fact, there are a number of papers that report coordination compounds based on metalloporphyrins exhibiting these features. Thus, the aim of this bioinspired work was to obtain stable SMOFs (at room temperature) based on metalloporphyrins and explore their catalytic activity. This work reports the environmentally friendly microwave-assisted synthesis and characterization of the compound [H(bipy)]2[(MnTPPS)(H2O)2]·2bipy·14H2O (TPPS = meso-tetraphenylporphine-4,4′,4′′,4′′′-tetrasulfonic acid and bipy = 4,4′-bipyridine). This compound is the first example of an MnTPPS-based SMOF, as far as we are aware, and has been structurally and thermally characterized through single-crystal X-ray diffraction, IR spectroscopy, thermogravimetry and transmission electron microscopy. Additionally, this work explores not only the catalytic activity of this compound but also of the compounds μ-O-[FeTCPP]2·16DMF and [CoTPPS0.5(bipy)(H2O)2]·6H2O. The structural features of these supramolecular materials, with accessible networks and high thermal stability, are responsible for their excellent behaviour as heterogeneous catalysts for different oxidation, condensation (aldol and Knoevenagel) and one-pot cascade reactions.
abstractGer	Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular metal–organic frameworks (SMOFs) are stable under ambient conditions and those with anchored catalysts exhibit favourable properties. However, this paper presents an innovative approach that consists of using metal nodes as both structural synthons and catalysts. Regarding the latter, metalloporphyrins are suitable candidates to play both roles simultaneously. In fact, there are a number of papers that report coordination compounds based on metalloporphyrins exhibiting these features. Thus, the aim of this bioinspired work was to obtain stable SMOFs (at room temperature) based on metalloporphyrins and explore their catalytic activity. This work reports the environmentally friendly microwave-assisted synthesis and characterization of the compound [H(bipy)]2[(MnTPPS)(H2O)2]·2bipy·14H2O (TPPS = meso-tetraphenylporphine-4,4′,4′′,4′′′-tetrasulfonic acid and bipy = 4,4′-bipyridine). This compound is the first example of an MnTPPS-based SMOF, as far as we are aware, and has been structurally and thermally characterized through single-crystal X-ray diffraction, IR spectroscopy, thermogravimetry and transmission electron microscopy. Additionally, this work explores not only the catalytic activity of this compound but also of the compounds μ-O-[FeTCPP]2·16DMF and [CoTPPS0.5(bipy)(H2O)2]·6H2O. The structural features of these supramolecular materials, with accessible networks and high thermal stability, are responsible for their excellent behaviour as heterogeneous catalysts for different oxidation, condensation (aldol and Knoevenagel) and one-pot cascade reactions.
abstract_unstemmed	Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular metal–organic frameworks (SMOFs) are stable under ambient conditions and those with anchored catalysts exhibit favourable properties. However, this paper presents an innovative approach that consists of using metal nodes as both structural synthons and catalysts. Regarding the latter, metalloporphyrins are suitable candidates to play both roles simultaneously. In fact, there are a number of papers that report coordination compounds based on metalloporphyrins exhibiting these features. Thus, the aim of this bioinspired work was to obtain stable SMOFs (at room temperature) based on metalloporphyrins and explore their catalytic activity. This work reports the environmentally friendly microwave-assisted synthesis and characterization of the compound [H(bipy)]2[(MnTPPS)(H2O)2]·2bipy·14H2O (TPPS = meso-tetraphenylporphine-4,4′,4′′,4′′′-tetrasulfonic acid and bipy = 4,4′-bipyridine). This compound is the first example of an MnTPPS-based SMOF, as far as we are aware, and has been structurally and thermally characterized through single-crystal X-ray diffraction, IR spectroscopy, thermogravimetry and transmission electron microscopy. Additionally, this work explores not only the catalytic activity of this compound but also of the compounds μ-O-[FeTCPP]2·16DMF and [CoTPPS0.5(bipy)(H2O)2]·6H2O. The structural features of these supramolecular materials, with accessible networks and high thermal stability, are responsible for their excellent behaviour as heterogeneous catalysts for different oxidation, condensation (aldol and Knoevenagel) and one-pot cascade reactions.
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container_issue	5
title_short	Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs)
url	https://doi.org/10.1107/S2052252518007856 https://doaj.org/article/c347a3aa19564be9be1053c2d06aab39 http://scripts.iucr.org/cgi-bin/paper?S2052252518007856 https://doaj.org/toc/2052-2525
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author2	Eder Amayuelas Gotzone Barandika Edurne S. Larrea Begoña Bazán Miren Karmele Urtiaga Marta Iglesias María Isabel Arriortua
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up_date	2024-07-03T19:24:55.687Z
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