Biocidal Coatings from Complexes of Carboxylated Latex Particles and a Linear Cationic Polymer
A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation g...
Ausführliche Beschreibung
Autor*in: |
Irina G. Panova [verfasserIn] Evgeniya A. Shevaleva [verfasserIn] Inessa A. Gritskova [verfasserIn] Nataliya G. Loiko [verfasserIn] Yury A. Nikolaev [verfasserIn] Olga A. Novoskoltseva [verfasserIn] Alexander A. Yaroslavov [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2022 |
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Übergeordnetes Werk: |
In: Polymers - MDPI AG, 2011, 14(2022), 21, p 4598 |
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Übergeordnetes Werk: |
volume:14 ; year:2022 ; number:21, p 4598 |
Links: |
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DOI / URN: |
10.3390/polym14214598 |
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Katalog-ID: |
DOAJ086450883 |
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10.3390/polym14214598 doi (DE-627)DOAJ086450883 (DE-599)DOAJ27eddc5f117c42c1b73aeaa30954e686 DE-627 ger DE-627 rakwb eng QD241-441 Irina G. Panova verfasserin aut Biocidal Coatings from Complexes of Carboxylated Latex Particles and a Linear Cationic Polymer 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation groups occurs at <i<W</i< = latex/polycation = 50 <i<w/w</i< ratio. At <i<W</i< = 27, an ultimate polycation adsorption is reached, resulting in the formation of positive polycomplex particles, while at <i<W</i< ˂ 27, two-component systems are formed composed of positive polycomplex particles and free polycation. A film created from the <i<W</i< = 12 formulation shows a high toxicity to Gram-positive and Gram-negative bacteria and yeast. Repeated washing the film leads to partial removal of polycation and a 50% decrease in the activity of the film only towards Gram-negative <i<Pseudomonas aeruginosa</i<. The results indicate the potential for use of the mixed polymer formulations for the fabrication of antimicrobial films and coatings. carboxylated butadiene–styrene latex biocidal polycation interpolyelectrolyte complex antimicrobial film Organic chemistry Evgeniya A. Shevaleva verfasserin aut Inessa A. Gritskova verfasserin aut Nataliya G. Loiko verfasserin aut Yury A. Nikolaev verfasserin aut Olga A. Novoskoltseva verfasserin aut Alexander A. Yaroslavov verfasserin aut In Polymers MDPI AG, 2011 14(2022), 21, p 4598 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:14 year:2022 number:21, p 4598 https://doi.org/10.3390/polym14214598 kostenfrei https://doaj.org/article/27eddc5f117c42c1b73aeaa30954e686 kostenfrei https://www.mdpi.com/2073-4360/14/21/4598 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2022 21, p 4598 |
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10.3390/polym14214598 doi (DE-627)DOAJ086450883 (DE-599)DOAJ27eddc5f117c42c1b73aeaa30954e686 DE-627 ger DE-627 rakwb eng QD241-441 Irina G. Panova verfasserin aut Biocidal Coatings from Complexes of Carboxylated Latex Particles and a Linear Cationic Polymer 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation groups occurs at <i<W</i< = latex/polycation = 50 <i<w/w</i< ratio. At <i<W</i< = 27, an ultimate polycation adsorption is reached, resulting in the formation of positive polycomplex particles, while at <i<W</i< ˂ 27, two-component systems are formed composed of positive polycomplex particles and free polycation. A film created from the <i<W</i< = 12 formulation shows a high toxicity to Gram-positive and Gram-negative bacteria and yeast. Repeated washing the film leads to partial removal of polycation and a 50% decrease in the activity of the film only towards Gram-negative <i<Pseudomonas aeruginosa</i<. The results indicate the potential for use of the mixed polymer formulations for the fabrication of antimicrobial films and coatings. carboxylated butadiene–styrene latex biocidal polycation interpolyelectrolyte complex antimicrobial film Organic chemistry Evgeniya A. Shevaleva verfasserin aut Inessa A. Gritskova verfasserin aut Nataliya G. Loiko verfasserin aut Yury A. Nikolaev verfasserin aut Olga A. Novoskoltseva verfasserin aut Alexander A. Yaroslavov verfasserin aut In Polymers MDPI AG, 2011 14(2022), 21, p 4598 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:14 year:2022 number:21, p 4598 https://doi.org/10.3390/polym14214598 kostenfrei https://doaj.org/article/27eddc5f117c42c1b73aeaa30954e686 kostenfrei https://www.mdpi.com/2073-4360/14/21/4598 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2022 21, p 4598 |
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10.3390/polym14214598 doi (DE-627)DOAJ086450883 (DE-599)DOAJ27eddc5f117c42c1b73aeaa30954e686 DE-627 ger DE-627 rakwb eng QD241-441 Irina G. Panova verfasserin aut Biocidal Coatings from Complexes of Carboxylated Latex Particles and a Linear Cationic Polymer 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation groups occurs at <i<W</i< = latex/polycation = 50 <i<w/w</i< ratio. At <i<W</i< = 27, an ultimate polycation adsorption is reached, resulting in the formation of positive polycomplex particles, while at <i<W</i< ˂ 27, two-component systems are formed composed of positive polycomplex particles and free polycation. A film created from the <i<W</i< = 12 formulation shows a high toxicity to Gram-positive and Gram-negative bacteria and yeast. Repeated washing the film leads to partial removal of polycation and a 50% decrease in the activity of the film only towards Gram-negative <i<Pseudomonas aeruginosa</i<. The results indicate the potential for use of the mixed polymer formulations for the fabrication of antimicrobial films and coatings. carboxylated butadiene–styrene latex biocidal polycation interpolyelectrolyte complex antimicrobial film Organic chemistry Evgeniya A. Shevaleva verfasserin aut Inessa A. Gritskova verfasserin aut Nataliya G. Loiko verfasserin aut Yury A. Nikolaev verfasserin aut Olga A. Novoskoltseva verfasserin aut Alexander A. Yaroslavov verfasserin aut In Polymers MDPI AG, 2011 14(2022), 21, p 4598 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:14 year:2022 number:21, p 4598 https://doi.org/10.3390/polym14214598 kostenfrei https://doaj.org/article/27eddc5f117c42c1b73aeaa30954e686 kostenfrei https://www.mdpi.com/2073-4360/14/21/4598 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2022 21, p 4598 |
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10.3390/polym14214598 doi (DE-627)DOAJ086450883 (DE-599)DOAJ27eddc5f117c42c1b73aeaa30954e686 DE-627 ger DE-627 rakwb eng QD241-441 Irina G. Panova verfasserin aut Biocidal Coatings from Complexes of Carboxylated Latex Particles and a Linear Cationic Polymer 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation groups occurs at <i<W</i< = latex/polycation = 50 <i<w/w</i< ratio. At <i<W</i< = 27, an ultimate polycation adsorption is reached, resulting in the formation of positive polycomplex particles, while at <i<W</i< ˂ 27, two-component systems are formed composed of positive polycomplex particles and free polycation. A film created from the <i<W</i< = 12 formulation shows a high toxicity to Gram-positive and Gram-negative bacteria and yeast. Repeated washing the film leads to partial removal of polycation and a 50% decrease in the activity of the film only towards Gram-negative <i<Pseudomonas aeruginosa</i<. The results indicate the potential for use of the mixed polymer formulations for the fabrication of antimicrobial films and coatings. carboxylated butadiene–styrene latex biocidal polycation interpolyelectrolyte complex antimicrobial film Organic chemistry Evgeniya A. Shevaleva verfasserin aut Inessa A. Gritskova verfasserin aut Nataliya G. Loiko verfasserin aut Yury A. Nikolaev verfasserin aut Olga A. Novoskoltseva verfasserin aut Alexander A. Yaroslavov verfasserin aut In Polymers MDPI AG, 2011 14(2022), 21, p 4598 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:14 year:2022 number:21, p 4598 https://doi.org/10.3390/polym14214598 kostenfrei https://doaj.org/article/27eddc5f117c42c1b73aeaa30954e686 kostenfrei https://www.mdpi.com/2073-4360/14/21/4598 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2022 21, p 4598 |
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10.3390/polym14214598 doi (DE-627)DOAJ086450883 (DE-599)DOAJ27eddc5f117c42c1b73aeaa30954e686 DE-627 ger DE-627 rakwb eng QD241-441 Irina G. Panova verfasserin aut Biocidal Coatings from Complexes of Carboxylated Latex Particles and a Linear Cationic Polymer 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation groups occurs at <i<W</i< = latex/polycation = 50 <i<w/w</i< ratio. At <i<W</i< = 27, an ultimate polycation adsorption is reached, resulting in the formation of positive polycomplex particles, while at <i<W</i< ˂ 27, two-component systems are formed composed of positive polycomplex particles and free polycation. A film created from the <i<W</i< = 12 formulation shows a high toxicity to Gram-positive and Gram-negative bacteria and yeast. Repeated washing the film leads to partial removal of polycation and a 50% decrease in the activity of the film only towards Gram-negative <i<Pseudomonas aeruginosa</i<. The results indicate the potential for use of the mixed polymer formulations for the fabrication of antimicrobial films and coatings. carboxylated butadiene–styrene latex biocidal polycation interpolyelectrolyte complex antimicrobial film Organic chemistry Evgeniya A. Shevaleva verfasserin aut Inessa A. Gritskova verfasserin aut Nataliya G. Loiko verfasserin aut Yury A. Nikolaev verfasserin aut Olga A. Novoskoltseva verfasserin aut Alexander A. Yaroslavov verfasserin aut In Polymers MDPI AG, 2011 14(2022), 21, p 4598 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:14 year:2022 number:21, p 4598 https://doi.org/10.3390/polym14214598 kostenfrei https://doaj.org/article/27eddc5f117c42c1b73aeaa30954e686 kostenfrei https://www.mdpi.com/2073-4360/14/21/4598 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2022 21, p 4598 |
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Biocidal Coatings from Complexes of Carboxylated Latex Particles and a Linear Cationic Polymer |
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A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation groups occurs at <i<W</i< = latex/polycation = 50 <i<w/w</i< ratio. At <i<W</i< = 27, an ultimate polycation adsorption is reached, resulting in the formation of positive polycomplex particles, while at <i<W</i< ˂ 27, two-component systems are formed composed of positive polycomplex particles and free polycation. A film created from the <i<W</i< = 12 formulation shows a high toxicity to Gram-positive and Gram-negative bacteria and yeast. Repeated washing the film leads to partial removal of polycation and a 50% decrease in the activity of the film only towards Gram-negative <i<Pseudomonas aeruginosa</i<. The results indicate the potential for use of the mixed polymer formulations for the fabrication of antimicrobial films and coatings. |
abstractGer |
A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation groups occurs at <i<W</i< = latex/polycation = 50 <i<w/w</i< ratio. At <i<W</i< = 27, an ultimate polycation adsorption is reached, resulting in the formation of positive polycomplex particles, while at <i<W</i< ˂ 27, two-component systems are formed composed of positive polycomplex particles and free polycation. A film created from the <i<W</i< = 12 formulation shows a high toxicity to Gram-positive and Gram-negative bacteria and yeast. Repeated washing the film leads to partial removal of polycation and a 50% decrease in the activity of the film only towards Gram-negative <i<Pseudomonas aeruginosa</i<. The results indicate the potential for use of the mixed polymer formulations for the fabrication of antimicrobial films and coatings. |
abstract_unstemmed |
A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation groups occurs at <i<W</i< = latex/polycation = 50 <i<w/w</i< ratio. At <i<W</i< = 27, an ultimate polycation adsorption is reached, resulting in the formation of positive polycomplex particles, while at <i<W</i< ˂ 27, two-component systems are formed composed of positive polycomplex particles and free polycation. A film created from the <i<W</i< = 12 formulation shows a high toxicity to Gram-positive and Gram-negative bacteria and yeast. Repeated washing the film leads to partial removal of polycation and a 50% decrease in the activity of the film only towards Gram-negative <i<Pseudomonas aeruginosa</i<. The results indicate the potential for use of the mixed polymer formulations for the fabrication of antimicrobial films and coatings. |
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