Poly[di-μ-aqua-bis(μ-2-amino-4-nitrobenzoato)dicaesium]
In the structure of title compound, [Cs2(C7H5N2O4)2(H2O)2]n, the asymmetric unit contains two independent Cs atoms comprising different coordination polyhedra. One is nine-coordinate, the other seven-coordinate, both having irregular configurations. The CsO9 coordination polyhedron comprises O-atom...
Ausführliche Beschreibung
Autor*in: |
Graham Smith [verfasserIn] Urs D. Wermuth [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2011 |
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Übergeordnetes Werk: |
In: Acta Crystallographica Section E - International Union of Crystallography, 2005, 67(2011), 8, Seite m1047-m1048 |
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Übergeordnetes Werk: |
volume:67 ; year:2011 ; number:8 ; pages:m1047-m1048 |
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DOI / URN: |
10.1107/S1600536811026614 |
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Katalog-ID: |
DOAJ086579444 |
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10.1107/S1600536811026614 doi (DE-627)DOAJ086579444 (DE-599)DOAJa32306f197e6453e8b0b96d3904b7154 DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[di-μ-aqua-bis(μ-2-amino-4-nitrobenzoato)dicaesium] 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of title compound, [Cs2(C7H5N2O4)2(H2O)2]n, the asymmetric unit contains two independent Cs atoms comprising different coordination polyhedra. One is nine-coordinate, the other seven-coordinate, both having irregular configurations. The CsO9 coordination polyhedron comprises O-atom donors from three bridging water molecules, one of which is doubly bridging, three from carboxylate groups, and three from nitro groups, of which two are bidentate chelate bridging. The CsO6N coordination polyhedron comprises the two bridging water molecules, one amine N-atom donor, one carboxylate O-atom donor and four O-atom donors from nitro groups (two from the chelate bridges). The extension of the dimeric unit gives a three-dimensional polymeric structure, which is stabilized by both intra- and intermolecular amine N—H...O and water O—H...O hydrogen bonds to carboxylate O-atom acceptors, as well as inter-ring π–π interactions [minimum ring centroid–centroid separation = 3.4172 (15) Å]. Crystallography Urs D. Wermuth verfasserin aut In Acta Crystallographica Section E International Union of Crystallography, 2005 67(2011), 8, Seite m1047-m1048 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:67 year:2011 number:8 pages:m1047-m1048 https://doi.org/10.1107/S1600536811026614 kostenfrei https://doaj.org/article/a32306f197e6453e8b0b96d3904b7154 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536811026614 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 67 2011 8 m1047-m1048 |
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10.1107/S1600536811026614 doi (DE-627)DOAJ086579444 (DE-599)DOAJa32306f197e6453e8b0b96d3904b7154 DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[di-μ-aqua-bis(μ-2-amino-4-nitrobenzoato)dicaesium] 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of title compound, [Cs2(C7H5N2O4)2(H2O)2]n, the asymmetric unit contains two independent Cs atoms comprising different coordination polyhedra. One is nine-coordinate, the other seven-coordinate, both having irregular configurations. The CsO9 coordination polyhedron comprises O-atom donors from three bridging water molecules, one of which is doubly bridging, three from carboxylate groups, and three from nitro groups, of which two are bidentate chelate bridging. The CsO6N coordination polyhedron comprises the two bridging water molecules, one amine N-atom donor, one carboxylate O-atom donor and four O-atom donors from nitro groups (two from the chelate bridges). The extension of the dimeric unit gives a three-dimensional polymeric structure, which is stabilized by both intra- and intermolecular amine N—H...O and water O—H...O hydrogen bonds to carboxylate O-atom acceptors, as well as inter-ring π–π interactions [minimum ring centroid–centroid separation = 3.4172 (15) Å]. Crystallography Urs D. Wermuth verfasserin aut In Acta Crystallographica Section E International Union of Crystallography, 2005 67(2011), 8, Seite m1047-m1048 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:67 year:2011 number:8 pages:m1047-m1048 https://doi.org/10.1107/S1600536811026614 kostenfrei https://doaj.org/article/a32306f197e6453e8b0b96d3904b7154 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536811026614 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 67 2011 8 m1047-m1048 |
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10.1107/S1600536811026614 doi (DE-627)DOAJ086579444 (DE-599)DOAJa32306f197e6453e8b0b96d3904b7154 DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[di-μ-aqua-bis(μ-2-amino-4-nitrobenzoato)dicaesium] 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of title compound, [Cs2(C7H5N2O4)2(H2O)2]n, the asymmetric unit contains two independent Cs atoms comprising different coordination polyhedra. One is nine-coordinate, the other seven-coordinate, both having irregular configurations. The CsO9 coordination polyhedron comprises O-atom donors from three bridging water molecules, one of which is doubly bridging, three from carboxylate groups, and three from nitro groups, of which two are bidentate chelate bridging. The CsO6N coordination polyhedron comprises the two bridging water molecules, one amine N-atom donor, one carboxylate O-atom donor and four O-atom donors from nitro groups (two from the chelate bridges). The extension of the dimeric unit gives a three-dimensional polymeric structure, which is stabilized by both intra- and intermolecular amine N—H...O and water O—H...O hydrogen bonds to carboxylate O-atom acceptors, as well as inter-ring π–π interactions [minimum ring centroid–centroid separation = 3.4172 (15) Å]. Crystallography Urs D. Wermuth verfasserin aut In Acta Crystallographica Section E International Union of Crystallography, 2005 67(2011), 8, Seite m1047-m1048 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:67 year:2011 number:8 pages:m1047-m1048 https://doi.org/10.1107/S1600536811026614 kostenfrei https://doaj.org/article/a32306f197e6453e8b0b96d3904b7154 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536811026614 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 67 2011 8 m1047-m1048 |
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10.1107/S1600536811026614 doi (DE-627)DOAJ086579444 (DE-599)DOAJa32306f197e6453e8b0b96d3904b7154 DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[di-μ-aqua-bis(μ-2-amino-4-nitrobenzoato)dicaesium] 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of title compound, [Cs2(C7H5N2O4)2(H2O)2]n, the asymmetric unit contains two independent Cs atoms comprising different coordination polyhedra. One is nine-coordinate, the other seven-coordinate, both having irregular configurations. The CsO9 coordination polyhedron comprises O-atom donors from three bridging water molecules, one of which is doubly bridging, three from carboxylate groups, and three from nitro groups, of which two are bidentate chelate bridging. The CsO6N coordination polyhedron comprises the two bridging water molecules, one amine N-atom donor, one carboxylate O-atom donor and four O-atom donors from nitro groups (two from the chelate bridges). The extension of the dimeric unit gives a three-dimensional polymeric structure, which is stabilized by both intra- and intermolecular amine N—H...O and water O—H...O hydrogen bonds to carboxylate O-atom acceptors, as well as inter-ring π–π interactions [minimum ring centroid–centroid separation = 3.4172 (15) Å]. Crystallography Urs D. Wermuth verfasserin aut In Acta Crystallographica Section E International Union of Crystallography, 2005 67(2011), 8, Seite m1047-m1048 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:67 year:2011 number:8 pages:m1047-m1048 https://doi.org/10.1107/S1600536811026614 kostenfrei https://doaj.org/article/a32306f197e6453e8b0b96d3904b7154 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536811026614 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 67 2011 8 m1047-m1048 |
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In the structure of title compound, [Cs2(C7H5N2O4)2(H2O)2]n, the asymmetric unit contains two independent Cs atoms comprising different coordination polyhedra. One is nine-coordinate, the other seven-coordinate, both having irregular configurations. The CsO9 coordination polyhedron comprises O-atom donors from three bridging water molecules, one of which is doubly bridging, three from carboxylate groups, and three from nitro groups, of which two are bidentate chelate bridging. The CsO6N coordination polyhedron comprises the two bridging water molecules, one amine N-atom donor, one carboxylate O-atom donor and four O-atom donors from nitro groups (two from the chelate bridges). The extension of the dimeric unit gives a three-dimensional polymeric structure, which is stabilized by both intra- and intermolecular amine N—H...O and water O—H...O hydrogen bonds to carboxylate O-atom acceptors, as well as inter-ring π–π interactions [minimum ring centroid–centroid separation = 3.4172 (15) Å]. |
abstractGer |
In the structure of title compound, [Cs2(C7H5N2O4)2(H2O)2]n, the asymmetric unit contains two independent Cs atoms comprising different coordination polyhedra. One is nine-coordinate, the other seven-coordinate, both having irregular configurations. The CsO9 coordination polyhedron comprises O-atom donors from three bridging water molecules, one of which is doubly bridging, three from carboxylate groups, and three from nitro groups, of which two are bidentate chelate bridging. The CsO6N coordination polyhedron comprises the two bridging water molecules, one amine N-atom donor, one carboxylate O-atom donor and four O-atom donors from nitro groups (two from the chelate bridges). The extension of the dimeric unit gives a three-dimensional polymeric structure, which is stabilized by both intra- and intermolecular amine N—H...O and water O—H...O hydrogen bonds to carboxylate O-atom acceptors, as well as inter-ring π–π interactions [minimum ring centroid–centroid separation = 3.4172 (15) Å]. |
abstract_unstemmed |
In the structure of title compound, [Cs2(C7H5N2O4)2(H2O)2]n, the asymmetric unit contains two independent Cs atoms comprising different coordination polyhedra. One is nine-coordinate, the other seven-coordinate, both having irregular configurations. The CsO9 coordination polyhedron comprises O-atom donors from three bridging water molecules, one of which is doubly bridging, three from carboxylate groups, and three from nitro groups, of which two are bidentate chelate bridging. The CsO6N coordination polyhedron comprises the two bridging water molecules, one amine N-atom donor, one carboxylate O-atom donor and four O-atom donors from nitro groups (two from the chelate bridges). The extension of the dimeric unit gives a three-dimensional polymeric structure, which is stabilized by both intra- and intermolecular amine N—H...O and water O—H...O hydrogen bonds to carboxylate O-atom acceptors, as well as inter-ring π–π interactions [minimum ring centroid–centroid separation = 3.4172 (15) Å]. |
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Poly[di-μ-aqua-bis(μ-2-amino-4-nitrobenzoato)dicaesium] |
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https://doi.org/10.1107/S1600536811026614 https://doaj.org/article/a32306f197e6453e8b0b96d3904b7154 http://scripts.iucr.org/cgi-bin/paper?S1600536811026614 https://doaj.org/toc/1600-5368 |
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|
score |
7.3994865 |