Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<

Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of severa...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Jianjun Li [verfasserIn] Yuyu Zheng [verfasserIn] Xuesong Liu [verfasserIn] Guihua Li [verfasserIn] Xiaoyan Yu [verfasserIn] Yue Wang [verfasserIn] Hejun Li [verfasserIn] Haibin Liu [verfasserIn] Guangqi Shan [verfasserIn] Ting Li [verfasserIn] Xiuyun Ding [verfasserIn] Xiaoxue Zhao [verfasserIn] Zhun Huang [verfasserIn] Ran Du [verfasserIn] Minmin Tian [verfasserIn] Fei Yan [verfasserIn] Bing Sun [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	rock crystal thermal process origin of the 3585 cm

Übergeordnetes Werk:	In: Crystals - MDPI AG, 2011, 11(2021), 9, p 1083
Übergeordnetes Werk:	volume:11 ; year:2021 ; number:9, p 1083

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/cryst11091083

Katalog-ID:	DOAJ086629204

Internformat


LEADER	01000caa a22002652 4500
001	DOAJ086629204
003	DE-627
005	20240412160817.0
007	cr uuu---uuuuu
008	230311s2021 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.3390/cryst11091083 \|2 doi
035			\|a (DE-627)DOAJ086629204
035			\|a (DE-599)DOAJdaf2b38a4deb4388adce32b027ca7676
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
050		0	\|a QD901-999
100	0		\|a Jianjun Li \|e verfasserin \|4 aut
245	1	0	\|a Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<
264		1	\|c 2021
336			\|a Text \|b txt \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band.
650		4	\|a rock crystal
650		4	\|a thermal process
650		4	\|a origin of the 3585 cm<sup<−1</sup< infrared band
653		0	\|a Crystallography
700	0		\|a Yuyu Zheng \|e verfasserin \|4 aut
700	0		\|a Xuesong Liu \|e verfasserin \|4 aut
700	0		\|a Guihua Li \|e verfasserin \|4 aut
700	0		\|a Xiaoyan Yu \|e verfasserin \|4 aut
700	0		\|a Yue Wang \|e verfasserin \|4 aut
700	0		\|a Hejun Li \|e verfasserin \|4 aut
700	0		\|a Haibin Liu \|e verfasserin \|4 aut
700	0		\|a Guangqi Shan \|e verfasserin \|4 aut
700	0		\|a Ting Li \|e verfasserin \|4 aut
700	0		\|a Xiuyun Ding \|e verfasserin \|4 aut
700	0		\|a Xiaoxue Zhao \|e verfasserin \|4 aut
700	0		\|a Zhun Huang \|e verfasserin \|4 aut
700	0		\|a Ran Du \|e verfasserin \|4 aut
700	0		\|a Minmin Tian \|e verfasserin \|4 aut
700	0		\|a Fei Yan \|e verfasserin \|4 aut
700	0		\|a Bing Sun \|e verfasserin \|4 aut
773	0	8	\|i In \|t Crystals \|d MDPI AG, 2011 \|g 11(2021), 9, p 1083 \|w (DE-627)718303067 \|w (DE-600)2661516-2 \|x 20734352 \|7 nnns
773	1	8	\|g volume:11 \|g year:2021 \|g number:9, p 1083
856	4	0	\|u https://doi.org/10.3390/cryst11091083 \|z kostenfrei
856	4	0	\|u https://doaj.org/article/daf2b38a4deb4388adce32b027ca7676 \|z kostenfrei
856	4	0	\|u https://www.mdpi.com/2073-4352/11/9/1083 \|z kostenfrei
856	4	2	\|u https://doaj.org/toc/2073-4352 \|y Journal toc \|z kostenfrei
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_DOAJ
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_95
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_151
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_213
912			\|a GBV_ILN_230
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_602
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4367
912			\|a GBV_ILN_4700
951			\|a AR
952			\|d 11 \|j 2021 \|e 9, p 1083

Indexfelder

author_variant	j l jl y z yz x l xl g l gl x y xy y w yw h l hl h l hl g s gs t l tl x d xd x z xz z h zh r d rd m t mt f y fy b s bs
matchkey_str	article:20734352:2021----::hrapoesfokrsacuefnrrdbopi
hierarchy_sort_str	2021
callnumber-subject-code	QD
publishDate	2021
allfields	10.3390/cryst11091083 doi (DE-627)DOAJ086629204 (DE-599)DOAJdaf2b38a4deb4388adce32b027ca7676 DE-627 ger DE-627 rakwb eng QD901-999 Jianjun Li verfasserin aut Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup< 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band. rock crystal thermal process origin of the 3585 cm<sup<−1</sup< infrared band Crystallography Yuyu Zheng verfasserin aut Xuesong Liu verfasserin aut Guihua Li verfasserin aut Xiaoyan Yu verfasserin aut Yue Wang verfasserin aut Hejun Li verfasserin aut Haibin Liu verfasserin aut Guangqi Shan verfasserin aut Ting Li verfasserin aut Xiuyun Ding verfasserin aut Xiaoxue Zhao verfasserin aut Zhun Huang verfasserin aut Ran Du verfasserin aut Minmin Tian verfasserin aut Fei Yan verfasserin aut Bing Sun verfasserin aut In Crystals MDPI AG, 2011 11(2021), 9, p 1083 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:11 year:2021 number:9, p 1083 https://doi.org/10.3390/cryst11091083 kostenfrei https://doaj.org/article/daf2b38a4deb4388adce32b027ca7676 kostenfrei https://www.mdpi.com/2073-4352/11/9/1083 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 9, p 1083
spelling	10.3390/cryst11091083 doi (DE-627)DOAJ086629204 (DE-599)DOAJdaf2b38a4deb4388adce32b027ca7676 DE-627 ger DE-627 rakwb eng QD901-999 Jianjun Li verfasserin aut Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup< 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band. rock crystal thermal process origin of the 3585 cm<sup<−1</sup< infrared band Crystallography Yuyu Zheng verfasserin aut Xuesong Liu verfasserin aut Guihua Li verfasserin aut Xiaoyan Yu verfasserin aut Yue Wang verfasserin aut Hejun Li verfasserin aut Haibin Liu verfasserin aut Guangqi Shan verfasserin aut Ting Li verfasserin aut Xiuyun Ding verfasserin aut Xiaoxue Zhao verfasserin aut Zhun Huang verfasserin aut Ran Du verfasserin aut Minmin Tian verfasserin aut Fei Yan verfasserin aut Bing Sun verfasserin aut In Crystals MDPI AG, 2011 11(2021), 9, p 1083 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:11 year:2021 number:9, p 1083 https://doi.org/10.3390/cryst11091083 kostenfrei https://doaj.org/article/daf2b38a4deb4388adce32b027ca7676 kostenfrei https://www.mdpi.com/2073-4352/11/9/1083 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 9, p 1083
allfields_unstemmed	10.3390/cryst11091083 doi (DE-627)DOAJ086629204 (DE-599)DOAJdaf2b38a4deb4388adce32b027ca7676 DE-627 ger DE-627 rakwb eng QD901-999 Jianjun Li verfasserin aut Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup< 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band. rock crystal thermal process origin of the 3585 cm<sup<−1</sup< infrared band Crystallography Yuyu Zheng verfasserin aut Xuesong Liu verfasserin aut Guihua Li verfasserin aut Xiaoyan Yu verfasserin aut Yue Wang verfasserin aut Hejun Li verfasserin aut Haibin Liu verfasserin aut Guangqi Shan verfasserin aut Ting Li verfasserin aut Xiuyun Ding verfasserin aut Xiaoxue Zhao verfasserin aut Zhun Huang verfasserin aut Ran Du verfasserin aut Minmin Tian verfasserin aut Fei Yan verfasserin aut Bing Sun verfasserin aut In Crystals MDPI AG, 2011 11(2021), 9, p 1083 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:11 year:2021 number:9, p 1083 https://doi.org/10.3390/cryst11091083 kostenfrei https://doaj.org/article/daf2b38a4deb4388adce32b027ca7676 kostenfrei https://www.mdpi.com/2073-4352/11/9/1083 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 9, p 1083
allfieldsGer	10.3390/cryst11091083 doi (DE-627)DOAJ086629204 (DE-599)DOAJdaf2b38a4deb4388adce32b027ca7676 DE-627 ger DE-627 rakwb eng QD901-999 Jianjun Li verfasserin aut Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup< 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band. rock crystal thermal process origin of the 3585 cm<sup<−1</sup< infrared band Crystallography Yuyu Zheng verfasserin aut Xuesong Liu verfasserin aut Guihua Li verfasserin aut Xiaoyan Yu verfasserin aut Yue Wang verfasserin aut Hejun Li verfasserin aut Haibin Liu verfasserin aut Guangqi Shan verfasserin aut Ting Li verfasserin aut Xiuyun Ding verfasserin aut Xiaoxue Zhao verfasserin aut Zhun Huang verfasserin aut Ran Du verfasserin aut Minmin Tian verfasserin aut Fei Yan verfasserin aut Bing Sun verfasserin aut In Crystals MDPI AG, 2011 11(2021), 9, p 1083 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:11 year:2021 number:9, p 1083 https://doi.org/10.3390/cryst11091083 kostenfrei https://doaj.org/article/daf2b38a4deb4388adce32b027ca7676 kostenfrei https://www.mdpi.com/2073-4352/11/9/1083 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 9, p 1083
allfieldsSound	10.3390/cryst11091083 doi (DE-627)DOAJ086629204 (DE-599)DOAJdaf2b38a4deb4388adce32b027ca7676 DE-627 ger DE-627 rakwb eng QD901-999 Jianjun Li verfasserin aut Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup< 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band. rock crystal thermal process origin of the 3585 cm<sup<−1</sup< infrared band Crystallography Yuyu Zheng verfasserin aut Xuesong Liu verfasserin aut Guihua Li verfasserin aut Xiaoyan Yu verfasserin aut Yue Wang verfasserin aut Hejun Li verfasserin aut Haibin Liu verfasserin aut Guangqi Shan verfasserin aut Ting Li verfasserin aut Xiuyun Ding verfasserin aut Xiaoxue Zhao verfasserin aut Zhun Huang verfasserin aut Ran Du verfasserin aut Minmin Tian verfasserin aut Fei Yan verfasserin aut Bing Sun verfasserin aut In Crystals MDPI AG, 2011 11(2021), 9, p 1083 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:11 year:2021 number:9, p 1083 https://doi.org/10.3390/cryst11091083 kostenfrei https://doaj.org/article/daf2b38a4deb4388adce32b027ca7676 kostenfrei https://www.mdpi.com/2073-4352/11/9/1083 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 9, p 1083
language	English
source	In Crystals 11(2021), 9, p 1083 volume:11 year:2021 number:9, p 1083
sourceStr	In Crystals 11(2021), 9, p 1083 volume:11 year:2021 number:9, p 1083
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	rock crystal thermal process origin of the 3585 cm<sup<−1</sup< infrared band Crystallography
isfreeaccess_bool	true
container_title	Crystals
authorswithroles_txt_mv	Jianjun Li @@aut@@ Yuyu Zheng @@aut@@ Xuesong Liu @@aut@@ Guihua Li @@aut@@ Xiaoyan Yu @@aut@@ Yue Wang @@aut@@ Hejun Li @@aut@@ Haibin Liu @@aut@@ Guangqi Shan @@aut@@ Ting Li @@aut@@ Xiuyun Ding @@aut@@ Xiaoxue Zhao @@aut@@ Zhun Huang @@aut@@ Ran Du @@aut@@ Minmin Tian @@aut@@ Fei Yan @@aut@@ Bing Sun @@aut@@
publishDateDaySort_date	2021-01-01T00:00:00Z
hierarchy_top_id	718303067
id	DOAJ086629204
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">DOAJ086629204</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240412160817.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230311s2021 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.3390/cryst11091083</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ086629204</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJdaf2b38a4deb4388adce32b027ca7676</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD901-999</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Jianjun Li</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2021</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">rock crystal</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">thermal process</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">origin of the 3585 cm<sup<−1</sup< infrared band</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Crystallography</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Yuyu Zheng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xuesong Liu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Guihua Li</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiaoyan Yu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Yue Wang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Hejun Li</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Haibin Liu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Guangqi Shan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Ting Li</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiuyun Ding</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiaoxue Zhao</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Zhun Huang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Ran Du</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Minmin Tian</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Fei Yan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Bing Sun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="t">Crystals</subfield><subfield code="d">MDPI AG, 2011</subfield><subfield code="g">11(2021), 9, p 1083</subfield><subfield code="w">(DE-627)718303067</subfield><subfield code="w">(DE-600)2661516-2</subfield><subfield code="x">20734352</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:11</subfield><subfield code="g">year:2021</subfield><subfield code="g">number:9, p 1083</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.3390/cryst11091083</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doaj.org/article/daf2b38a4deb4388adce32b027ca7676</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.mdpi.com/2073-4352/11/9/1083</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://doaj.org/toc/2073-4352</subfield><subfield code="y">Journal toc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_DOAJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4367</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">11</subfield><subfield code="j">2021</subfield><subfield code="e">9, p 1083</subfield></datafield></record></collection>
callnumber-first	Q - Science
author	Jianjun Li
spellingShingle	Jianjun Li misc QD901-999 misc rock crystal misc thermal process misc origin of the 3585 cm<sup<−1</sup< infrared band misc Crystallography Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<
authorStr	Jianjun Li
ppnlink_with_tag_str_mv	@@773@@(DE-627)718303067
format	electronic Article
delete_txt_mv	keep
author_role	aut aut aut aut aut aut aut aut aut aut aut aut aut aut aut aut aut
collection	DOAJ
remote_str	true
callnumber-label	QD901-999
illustrated	Not Illustrated
issn	20734352
topic_title	QD901-999 Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup< rock crystal thermal process origin of the 3585 cm<sup<−1</sup< infrared band
topic	misc QD901-999 misc rock crystal misc thermal process misc origin of the 3585 cm<sup<−1</sup< infrared band misc Crystallography
topic_unstemmed	misc QD901-999 misc rock crystal misc thermal process misc origin of the 3585 cm<sup<−1</sup< infrared band misc Crystallography
topic_browse	misc QD901-999 misc rock crystal misc thermal process misc origin of the 3585 cm<sup<−1</sup< infrared band misc Crystallography
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	Crystals
hierarchy_parent_id	718303067
hierarchy_top_title	Crystals
isfreeaccess_txt	true
familylinks_str_mv	(DE-627)718303067 (DE-600)2661516-2
title	Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<
ctrlnum	(DE-627)DOAJ086629204 (DE-599)DOAJdaf2b38a4deb4388adce32b027ca7676
title_full	Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<
author_sort	Jianjun Li
journal	Crystals
journalStr	Crystals
callnumber-first-code	Q
lang_code	eng
isOA_bool	true
recordtype	marc
publishDateSort	2021
contenttype_str_mv	txt
author_browse	Jianjun Li Yuyu Zheng Xuesong Liu Guihua Li Xiaoyan Yu Yue Wang Hejun Li Haibin Liu Guangqi Shan Ting Li Xiuyun Ding Xiaoxue Zhao Zhun Huang Ran Du Minmin Tian Fei Yan Bing Sun
container_volume	11
class	QD901-999
format_se	Elektronische Aufsätze
author-letter	Jianjun Li
doi_str_mv	10.3390/cryst11091083
author2-role	verfasserin
title_sort	thermal process of rock crystal: cause of infrared absorption band at 3585 cm<sup<−1</sup<
callnumber	QD901-999
title_auth	Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<
abstract	Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band.
abstractGer	Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band.
abstract_unstemmed	Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700
container_issue	9, p 1083
title_short	Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<
url	https://doi.org/10.3390/cryst11091083 https://doaj.org/article/daf2b38a4deb4388adce32b027ca7676 https://www.mdpi.com/2073-4352/11/9/1083 https://doaj.org/toc/2073-4352
remote_bool	true
author2	Yuyu Zheng Xuesong Liu Guihua Li Xiaoyan Yu Yue Wang Hejun Li Haibin Liu Guangqi Shan Ting Li Xiuyun Ding Xiaoxue Zhao Zhun Huang Ran Du Minmin Tian Fei Yan Bing Sun
author2Str	Yuyu Zheng Xuesong Liu Guihua Li Xiaoyan Yu Yue Wang Hejun Li Haibin Liu Guangqi Shan Ting Li Xiuyun Ding Xiaoxue Zhao Zhun Huang Ran Du Minmin Tian Fei Yan Bing Sun
ppnlink	718303067
callnumber-subject	QD - Chemistry
mediatype_str_mv	c
isOA_txt	true
hochschulschrift_bool	false
doi_str	10.3390/cryst11091083
callnumber-a	QD901-999
up_date	2024-07-03T21:50:08.789Z
_version_	1803596237421674496
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">DOAJ086629204</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240412160817.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230311s2021 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.3390/cryst11091083</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ086629204</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJdaf2b38a4deb4388adce32b027ca7676</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD901-999</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Jianjun Li</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2021</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm<sup<−1</sup<. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm<sup<−1</sup< was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm<sup<−1</sup< band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH<sup<−</sup< defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm<sup<−1</sup< band.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">rock crystal</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">thermal process</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">origin of the 3585 cm<sup<−1</sup< infrared band</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Crystallography</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Yuyu Zheng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xuesong Liu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Guihua Li</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiaoyan Yu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Yue Wang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Hejun Li</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Haibin Liu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Guangqi Shan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Ting Li</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiuyun Ding</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiaoxue Zhao</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Zhun Huang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Ran Du</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Minmin Tian</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Fei Yan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Bing Sun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="t">Crystals</subfield><subfield code="d">MDPI AG, 2011</subfield><subfield code="g">11(2021), 9, p 1083</subfield><subfield code="w">(DE-627)718303067</subfield><subfield code="w">(DE-600)2661516-2</subfield><subfield code="x">20734352</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:11</subfield><subfield code="g">year:2021</subfield><subfield code="g">number:9, p 1083</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.3390/cryst11091083</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doaj.org/article/daf2b38a4deb4388adce32b027ca7676</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.mdpi.com/2073-4352/11/9/1083</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://doaj.org/toc/2073-4352</subfield><subfield code="y">Journal toc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_DOAJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4367</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">11</subfield><subfield code="j">2021</subfield><subfield code="e">9, p 1083</subfield></datafield></record></collection>
score	7.399356

Nicht das Richtige dabei?

Schreiben Sie uns!

Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm<sup<−1</sup<

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?