Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents

The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90...
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Autor*in:	Chiara Faverio [verfasserIn] Monica Fiorenza Boselli [verfasserIn] Tommaso Ruggiero [verfasserIn] Laura Raimondi [verfasserIn] Maurizio Benaglia [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Deep eutectic solvents Organocatalysis Enantioselective reduction Chiral nitro alkanes Hydrogen bond-mediated reactions

Übergeordnetes Werk:	In: Tetrahedron Chem - Elsevier, 2022, 6(2023), Seite 100038-
Übergeordnetes Werk:	volume:6 ; year:2023 ; pages:100038-

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1016/j.tchem.2023.100038

Katalog-ID:	DOAJ089270339

Internformat


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520			\|a The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90%, by a metal-free, hydrogen bond-mediated catalytic methodology, with a convenient experimental protocol that could be successfully applied to a gram-scale reaction.
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650		4	\|a Enantioselective reduction
650		4	\|a Chiral nitro alkanes
650		4	\|a Hydrogen bond-mediated reactions
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publishDate	2023
allfields	10.1016/j.tchem.2023.100038 doi (DE-627)DOAJ089270339 (DE-599)DOAJf27da0858b66494c8ec227e4138b2377 DE-627 ger DE-627 rakwb eng QD241-441 Chiara Faverio verfasserin aut Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90%, by a metal-free, hydrogen bond-mediated catalytic methodology, with a convenient experimental protocol that could be successfully applied to a gram-scale reaction. Deep eutectic solvents Organocatalysis Enantioselective reduction Chiral nitro alkanes Hydrogen bond-mediated reactions Organic chemistry Monica Fiorenza Boselli verfasserin aut Tommaso Ruggiero verfasserin aut Laura Raimondi verfasserin aut Maurizio Benaglia verfasserin aut In Tetrahedron Chem Elsevier, 2022 6(2023), Seite 100038- (DE-627)178621475X 2666951X nnns volume:6 year:2023 pages:100038- https://doi.org/10.1016/j.tchem.2023.100038 kostenfrei https://doaj.org/article/f27da0858b66494c8ec227e4138b2377 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666951X23000049 kostenfrei https://doaj.org/toc/2666-951X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 6 2023 100038-
spelling	10.1016/j.tchem.2023.100038 doi (DE-627)DOAJ089270339 (DE-599)DOAJf27da0858b66494c8ec227e4138b2377 DE-627 ger DE-627 rakwb eng QD241-441 Chiara Faverio verfasserin aut Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90%, by a metal-free, hydrogen bond-mediated catalytic methodology, with a convenient experimental protocol that could be successfully applied to a gram-scale reaction. Deep eutectic solvents Organocatalysis Enantioselective reduction Chiral nitro alkanes Hydrogen bond-mediated reactions Organic chemistry Monica Fiorenza Boselli verfasserin aut Tommaso Ruggiero verfasserin aut Laura Raimondi verfasserin aut Maurizio Benaglia verfasserin aut In Tetrahedron Chem Elsevier, 2022 6(2023), Seite 100038- (DE-627)178621475X 2666951X nnns volume:6 year:2023 pages:100038- https://doi.org/10.1016/j.tchem.2023.100038 kostenfrei https://doaj.org/article/f27da0858b66494c8ec227e4138b2377 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666951X23000049 kostenfrei https://doaj.org/toc/2666-951X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 6 2023 100038-
allfields_unstemmed	10.1016/j.tchem.2023.100038 doi (DE-627)DOAJ089270339 (DE-599)DOAJf27da0858b66494c8ec227e4138b2377 DE-627 ger DE-627 rakwb eng QD241-441 Chiara Faverio verfasserin aut Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90%, by a metal-free, hydrogen bond-mediated catalytic methodology, with a convenient experimental protocol that could be successfully applied to a gram-scale reaction. Deep eutectic solvents Organocatalysis Enantioselective reduction Chiral nitro alkanes Hydrogen bond-mediated reactions Organic chemistry Monica Fiorenza Boselli verfasserin aut Tommaso Ruggiero verfasserin aut Laura Raimondi verfasserin aut Maurizio Benaglia verfasserin aut In Tetrahedron Chem Elsevier, 2022 6(2023), Seite 100038- (DE-627)178621475X 2666951X nnns volume:6 year:2023 pages:100038- https://doi.org/10.1016/j.tchem.2023.100038 kostenfrei https://doaj.org/article/f27da0858b66494c8ec227e4138b2377 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666951X23000049 kostenfrei https://doaj.org/toc/2666-951X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 6 2023 100038-
allfieldsGer	10.1016/j.tchem.2023.100038 doi (DE-627)DOAJ089270339 (DE-599)DOAJf27da0858b66494c8ec227e4138b2377 DE-627 ger DE-627 rakwb eng QD241-441 Chiara Faverio verfasserin aut Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90%, by a metal-free, hydrogen bond-mediated catalytic methodology, with a convenient experimental protocol that could be successfully applied to a gram-scale reaction. Deep eutectic solvents Organocatalysis Enantioselective reduction Chiral nitro alkanes Hydrogen bond-mediated reactions Organic chemistry Monica Fiorenza Boselli verfasserin aut Tommaso Ruggiero verfasserin aut Laura Raimondi verfasserin aut Maurizio Benaglia verfasserin aut In Tetrahedron Chem Elsevier, 2022 6(2023), Seite 100038- (DE-627)178621475X 2666951X nnns volume:6 year:2023 pages:100038- https://doi.org/10.1016/j.tchem.2023.100038 kostenfrei https://doaj.org/article/f27da0858b66494c8ec227e4138b2377 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666951X23000049 kostenfrei https://doaj.org/toc/2666-951X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 6 2023 100038-
allfieldsSound	10.1016/j.tchem.2023.100038 doi (DE-627)DOAJ089270339 (DE-599)DOAJf27da0858b66494c8ec227e4138b2377 DE-627 ger DE-627 rakwb eng QD241-441 Chiara Faverio verfasserin aut Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90%, by a metal-free, hydrogen bond-mediated catalytic methodology, with a convenient experimental protocol that could be successfully applied to a gram-scale reaction. Deep eutectic solvents Organocatalysis Enantioselective reduction Chiral nitro alkanes Hydrogen bond-mediated reactions Organic chemistry Monica Fiorenza Boselli verfasserin aut Tommaso Ruggiero verfasserin aut Laura Raimondi verfasserin aut Maurizio Benaglia verfasserin aut In Tetrahedron Chem Elsevier, 2022 6(2023), Seite 100038- (DE-627)178621475X 2666951X nnns volume:6 year:2023 pages:100038- https://doi.org/10.1016/j.tchem.2023.100038 kostenfrei https://doaj.org/article/f27da0858b66494c8ec227e4138b2377 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666951X23000049 kostenfrei https://doaj.org/toc/2666-951X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 6 2023 100038-
language	English
source	In Tetrahedron Chem 6(2023), Seite 100038- volume:6 year:2023 pages:100038-
sourceStr	In Tetrahedron Chem 6(2023), Seite 100038- volume:6 year:2023 pages:100038-
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Deep eutectic solvents Organocatalysis Enantioselective reduction Chiral nitro alkanes Hydrogen bond-mediated reactions Organic chemistry
isfreeaccess_bool	true
container_title	Tetrahedron Chem
authorswithroles_txt_mv	Chiara Faverio @@aut@@ Monica Fiorenza Boselli @@aut@@ Tommaso Ruggiero @@aut@@ Laura Raimondi @@aut@@ Maurizio Benaglia @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	178621475X
id	DOAJ089270339
language_de	englisch
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callnumber-first	Q - Science
author	Chiara Faverio
spellingShingle	Chiara Faverio misc QD241-441 misc Deep eutectic solvents misc Organocatalysis misc Enantioselective reduction misc Chiral nitro alkanes misc Hydrogen bond-mediated reactions misc Organic chemistry Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents
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topic_title	QD241-441 Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents Deep eutectic solvents Organocatalysis Enantioselective reduction Chiral nitro alkanes Hydrogen bond-mediated reactions
topic	misc QD241-441 misc Deep eutectic solvents misc Organocatalysis misc Enantioselective reduction misc Chiral nitro alkanes misc Hydrogen bond-mediated reactions misc Organic chemistry
topic_unstemmed	misc QD241-441 misc Deep eutectic solvents misc Organocatalysis misc Enantioselective reduction misc Chiral nitro alkanes misc Hydrogen bond-mediated reactions misc Organic chemistry
topic_browse	misc QD241-441 misc Deep eutectic solvents misc Organocatalysis misc Enantioselective reduction misc Chiral nitro alkanes misc Hydrogen bond-mediated reactions misc Organic chemistry
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title	Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents
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title_full	Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents
author_sort	Chiara Faverio
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title_sort	hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents
callnumber	QD241-441
title_auth	Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents
abstract	The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90%, by a metal-free, hydrogen bond-mediated catalytic methodology, with a convenient experimental protocol that could be successfully applied to a gram-scale reaction.
abstractGer	The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90%, by a metal-free, hydrogen bond-mediated catalytic methodology, with a convenient experimental protocol that could be successfully applied to a gram-scale reaction.
abstract_unstemmed	The catalytic enantioselective reduction of β,β-disubstituted nitroalkenes was performed in deep eutectic solvents, avoiding the use of volatile organic compounds (VOCs) as reaction medium. The desired enantioenriched nitroalkanes were obtained in high yields and high enantiomeric excesses, up to 90%, by a metal-free, hydrogen bond-mediated catalytic methodology, with a convenient experimental protocol that could be successfully applied to a gram-scale reaction.
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title_short	Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents
url	https://doi.org/10.1016/j.tchem.2023.100038 https://doaj.org/article/f27da0858b66494c8ec227e4138b2377 http://www.sciencedirect.com/science/article/pii/S2666951X23000049 https://doaj.org/toc/2666-951X
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up_date	2024-07-03T22:12:35.379Z
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Hydrogen bond-mediated organocatalytic enantioselective reduction of nitroalkenes in deep eutectic solvents

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