Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex

The investigation of the interaction of cyclic trinuclear silver(I) pyrazolate [AgPz]<sub<3</sub< (Pz = 3,5-bis(trifluoromethyl)pyrazolate) with pyridine-based chalcones (anthracen-9-yl and phenyl-substituted ones) has been performed by IR-, UV-vis, and NMR spectroscopies in the solution...
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Gespeichert in:

Autor*in:	Arina Olbrykh [verfasserIn] Aleksei Titov [verfasserIn] Alexander Smol’yakov [verfasserIn] Oleg Filippov [verfasserIn] Elena S. Shubina [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	cyclic trinuclear complex pyrazolate adducts silver(I) non-covalent interactions photoluminescence

Übergeordnetes Werk:	In: Inorganics - MDPI AG, 2014, 11(2023), 4, p 175
Übergeordnetes Werk:	volume:11 ; year:2023 ; number:4, p 175

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/inorganics11040175

Katalog-ID:	DOAJ089839390

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allfields	10.3390/inorganics11040175 doi (DE-627)DOAJ089839390 (DE-599)DOAJcca0b3e310b6476f8702416d4bd61376 DE-627 ger DE-627 rakwb eng QD146-197 Arina Olbrykh verfasserin aut Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The investigation of the interaction of cyclic trinuclear silver(I) pyrazolate [AgPz]<sub<3</sub< (Pz = 3,5-bis(trifluoromethyl)pyrazolate) with pyridine-based chalcones (anthracen-9-yl and phenyl-substituted ones) has been performed by IR-, UV-vis, and NMR spectroscopies in the solution. The carbonyl group participates in coordination with metal ions in all complexes. However, the network of π-π/M-π non-covalent intermolecular interactions mainly influences complex formation. The spectral data suggest retaining the structures for all studied complexes in the solution and solid state. E-Z isomerization in the case of anthracene-containing compounds significantly influences the complexation. E-isomer of chalcones seeks the planar structure in the complexes with [AgPz]<sub<3</sub<. In contrast, the Z-isomer of chalcone demonstrates the chelating coordination of O- and N atoms to silver ions. The complexation of anthracene-containing chalcones allows the switching of the emission nature from charge transfer to ligand-centered at 77 K. In contrast, phenyl-substituted chalcone in complex with macrocycle demonstrates that the emission significantly shifted (Δ = ca. 155 nm) to the low-energy region compared to the free base. cyclic trinuclear complex pyrazolate adducts silver(I) non-covalent interactions photoluminescence Inorganic chemistry Aleksei Titov verfasserin aut Alexander Smol’yakov verfasserin aut Oleg Filippov verfasserin aut Elena S. Shubina verfasserin aut In Inorganics MDPI AG, 2014 11(2023), 4, p 175 (DE-627)769223451 (DE-600)2735043-5 23046740 nnns volume:11 year:2023 number:4, p 175 https://doi.org/10.3390/inorganics11040175 kostenfrei https://doaj.org/article/cca0b3e310b6476f8702416d4bd61376 kostenfrei https://www.mdpi.com/2304-6740/11/4/175 kostenfrei https://doaj.org/toc/2304-6740 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2023 4, p 175
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allfieldsGer	10.3390/inorganics11040175 doi (DE-627)DOAJ089839390 (DE-599)DOAJcca0b3e310b6476f8702416d4bd61376 DE-627 ger DE-627 rakwb eng QD146-197 Arina Olbrykh verfasserin aut Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The investigation of the interaction of cyclic trinuclear silver(I) pyrazolate [AgPz]<sub<3</sub< (Pz = 3,5-bis(trifluoromethyl)pyrazolate) with pyridine-based chalcones (anthracen-9-yl and phenyl-substituted ones) has been performed by IR-, UV-vis, and NMR spectroscopies in the solution. The carbonyl group participates in coordination with metal ions in all complexes. However, the network of π-π/M-π non-covalent intermolecular interactions mainly influences complex formation. The spectral data suggest retaining the structures for all studied complexes in the solution and solid state. E-Z isomerization in the case of anthracene-containing compounds significantly influences the complexation. E-isomer of chalcones seeks the planar structure in the complexes with [AgPz]<sub<3</sub<. In contrast, the Z-isomer of chalcone demonstrates the chelating coordination of O- and N atoms to silver ions. The complexation of anthracene-containing chalcones allows the switching of the emission nature from charge transfer to ligand-centered at 77 K. In contrast, phenyl-substituted chalcone in complex with macrocycle demonstrates that the emission significantly shifted (Δ = ca. 155 nm) to the low-energy region compared to the free base. cyclic trinuclear complex pyrazolate adducts silver(I) non-covalent interactions photoluminescence Inorganic chemistry Aleksei Titov verfasserin aut Alexander Smol’yakov verfasserin aut Oleg Filippov verfasserin aut Elena S. Shubina verfasserin aut In Inorganics MDPI AG, 2014 11(2023), 4, p 175 (DE-627)769223451 (DE-600)2735043-5 23046740 nnns volume:11 year:2023 number:4, p 175 https://doi.org/10.3390/inorganics11040175 kostenfrei https://doaj.org/article/cca0b3e310b6476f8702416d4bd61376 kostenfrei https://www.mdpi.com/2304-6740/11/4/175 kostenfrei https://doaj.org/toc/2304-6740 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2023 4, p 175
allfieldsSound	10.3390/inorganics11040175 doi (DE-627)DOAJ089839390 (DE-599)DOAJcca0b3e310b6476f8702416d4bd61376 DE-627 ger DE-627 rakwb eng QD146-197 Arina Olbrykh verfasserin aut Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The investigation of the interaction of cyclic trinuclear silver(I) pyrazolate [AgPz]<sub<3</sub< (Pz = 3,5-bis(trifluoromethyl)pyrazolate) with pyridine-based chalcones (anthracen-9-yl and phenyl-substituted ones) has been performed by IR-, UV-vis, and NMR spectroscopies in the solution. The carbonyl group participates in coordination with metal ions in all complexes. However, the network of π-π/M-π non-covalent intermolecular interactions mainly influences complex formation. The spectral data suggest retaining the structures for all studied complexes in the solution and solid state. E-Z isomerization in the case of anthracene-containing compounds significantly influences the complexation. E-isomer of chalcones seeks the planar structure in the complexes with [AgPz]<sub<3</sub<. In contrast, the Z-isomer of chalcone demonstrates the chelating coordination of O- and N atoms to silver ions. The complexation of anthracene-containing chalcones allows the switching of the emission nature from charge transfer to ligand-centered at 77 K. In contrast, phenyl-substituted chalcone in complex with macrocycle demonstrates that the emission significantly shifted (Δ = ca. 155 nm) to the low-energy region compared to the free base. cyclic trinuclear complex pyrazolate adducts silver(I) non-covalent interactions photoluminescence Inorganic chemistry Aleksei Titov verfasserin aut Alexander Smol’yakov verfasserin aut Oleg Filippov verfasserin aut Elena S. Shubina verfasserin aut In Inorganics MDPI AG, 2014 11(2023), 4, p 175 (DE-627)769223451 (DE-600)2735043-5 23046740 nnns volume:11 year:2023 number:4, p 175 https://doi.org/10.3390/inorganics11040175 kostenfrei https://doaj.org/article/cca0b3e310b6476f8702416d4bd61376 kostenfrei https://www.mdpi.com/2304-6740/11/4/175 kostenfrei https://doaj.org/toc/2304-6740 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2023 4, p 175
language	English
source	In Inorganics 11(2023), 4, p 175 volume:11 year:2023 number:4, p 175
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authorswithroles_txt_mv	Arina Olbrykh @@aut@@ Aleksei Titov @@aut@@ Alexander Smol’yakov @@aut@@ Oleg Filippov @@aut@@ Elena S. Shubina @@aut@@
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callnumber-first	Q - Science
author	Arina Olbrykh
spellingShingle	Arina Olbrykh misc QD146-197 misc cyclic trinuclear complex misc pyrazolate adducts misc silver(I) misc non-covalent interactions misc photoluminescence misc Inorganic chemistry Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex
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topic_title	QD146-197 Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex cyclic trinuclear complex pyrazolate adducts silver(I) non-covalent interactions photoluminescence
topic	misc QD146-197 misc cyclic trinuclear complex misc pyrazolate adducts misc silver(I) misc non-covalent interactions misc photoluminescence misc Inorganic chemistry
topic_unstemmed	misc QD146-197 misc cyclic trinuclear complex misc pyrazolate adducts misc silver(I) misc non-covalent interactions misc photoluminescence misc Inorganic chemistry
topic_browse	misc QD146-197 misc cyclic trinuclear complex misc pyrazolate adducts misc silver(I) misc non-covalent interactions misc photoluminescence misc Inorganic chemistry
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title	Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex
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title_full	Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex
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author_browse	Arina Olbrykh Aleksei Titov Alexander Smol’yakov Oleg Filippov Elena S. Shubina
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title_sort	exploring the interaction of pyridine-based chalcones with trinuclear silver(i) pyrazolate complex
callnumber	QD146-197
title_auth	Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex
abstract	The investigation of the interaction of cyclic trinuclear silver(I) pyrazolate [AgPz]<sub<3</sub< (Pz = 3,5-bis(trifluoromethyl)pyrazolate) with pyridine-based chalcones (anthracen-9-yl and phenyl-substituted ones) has been performed by IR-, UV-vis, and NMR spectroscopies in the solution. The carbonyl group participates in coordination with metal ions in all complexes. However, the network of π-π/M-π non-covalent intermolecular interactions mainly influences complex formation. The spectral data suggest retaining the structures for all studied complexes in the solution and solid state. E-Z isomerization in the case of anthracene-containing compounds significantly influences the complexation. E-isomer of chalcones seeks the planar structure in the complexes with [AgPz]<sub<3</sub<. In contrast, the Z-isomer of chalcone demonstrates the chelating coordination of O- and N atoms to silver ions. The complexation of anthracene-containing chalcones allows the switching of the emission nature from charge transfer to ligand-centered at 77 K. In contrast, phenyl-substituted chalcone in complex with macrocycle demonstrates that the emission significantly shifted (Δ = ca. 155 nm) to the low-energy region compared to the free base.
abstractGer	The investigation of the interaction of cyclic trinuclear silver(I) pyrazolate [AgPz]<sub<3</sub< (Pz = 3,5-bis(trifluoromethyl)pyrazolate) with pyridine-based chalcones (anthracen-9-yl and phenyl-substituted ones) has been performed by IR-, UV-vis, and NMR spectroscopies in the solution. The carbonyl group participates in coordination with metal ions in all complexes. However, the network of π-π/M-π non-covalent intermolecular interactions mainly influences complex formation. The spectral data suggest retaining the structures for all studied complexes in the solution and solid state. E-Z isomerization in the case of anthracene-containing compounds significantly influences the complexation. E-isomer of chalcones seeks the planar structure in the complexes with [AgPz]<sub<3</sub<. In contrast, the Z-isomer of chalcone demonstrates the chelating coordination of O- and N atoms to silver ions. The complexation of anthracene-containing chalcones allows the switching of the emission nature from charge transfer to ligand-centered at 77 K. In contrast, phenyl-substituted chalcone in complex with macrocycle demonstrates that the emission significantly shifted (Δ = ca. 155 nm) to the low-energy region compared to the free base.
abstract_unstemmed	The investigation of the interaction of cyclic trinuclear silver(I) pyrazolate [AgPz]<sub<3</sub< (Pz = 3,5-bis(trifluoromethyl)pyrazolate) with pyridine-based chalcones (anthracen-9-yl and phenyl-substituted ones) has been performed by IR-, UV-vis, and NMR spectroscopies in the solution. The carbonyl group participates in coordination with metal ions in all complexes. However, the network of π-π/M-π non-covalent intermolecular interactions mainly influences complex formation. The spectral data suggest retaining the structures for all studied complexes in the solution and solid state. E-Z isomerization in the case of anthracene-containing compounds significantly influences the complexation. E-isomer of chalcones seeks the planar structure in the complexes with [AgPz]<sub<3</sub<. In contrast, the Z-isomer of chalcone demonstrates the chelating coordination of O- and N atoms to silver ions. The complexation of anthracene-containing chalcones allows the switching of the emission nature from charge transfer to ligand-centered at 77 K. In contrast, phenyl-substituted chalcone in complex with macrocycle demonstrates that the emission significantly shifted (Δ = ca. 155 nm) to the low-energy region compared to the free base.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700
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title_short	Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex
url	https://doi.org/10.3390/inorganics11040175 https://doaj.org/article/cca0b3e310b6476f8702416d4bd61376 https://www.mdpi.com/2304-6740/11/4/175 https://doaj.org/toc/2304-6740
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author2	Aleksei Titov Alexander Smol’yakov Oleg Filippov Elena S. Shubina
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up_date	2024-07-04T00:52:08.903Z
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Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex

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