The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu

Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract Ausführliche Beschreibung

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Autor*in:	Minako Hashiguchi [verfasserIn] Dan Aoki [verfasserIn] Kazuhiko Fukushima [verfasserIn] Hiroshi Naraoka [verfasserIn] Yoshinori Takano [verfasserIn] Jason P. Dworkin [verfasserIn] Karin E. Dworkin [verfasserIn] José C. Aponte [verfasserIn] Jamie E. Elsila [verfasserIn] John M. Eiler [verfasserIn] Yoshihiro Furukawa [verfasserIn] Aogu Furusho [verfasserIn] Daniel P. Glavin [verfasserIn] Heather V. Graham [verfasserIn] Kenji Hamase [verfasserIn] Norbert Hertkorn [verfasserIn] Junko Isa [verfasserIn] Toshiki Koga [verfasserIn] Hannah L. McLain [verfasserIn] Hajime Mita [verfasserIn] Yasuhiro Oba [verfasserIn] Nanako O. Ogawa [verfasserIn] Naohiko Ohkouchi [verfasserIn] Francois-Regis Orthous-Daunay [verfasserIn] Eric T. Parker [verfasserIn] Alexander Ruf [verfasserIn] Saburo Sakai [verfasserIn] Philippe Schmitt-Kopplin [verfasserIn] Haruna Sugahara [verfasserIn] Roland Thissen [verfasserIn] Véronique Vuitton [verfasserIn] Cédric Wolters [verfasserIn] Toshihiro Yoshimura [verfasserIn] Hisayoshi Yurimoto [verfasserIn] Tomoki Nakamura [verfasserIn] Takaaki Noguchi [verfasserIn] Ryuji Okazaki [verfasserIn] Hikaru Yabuta [verfasserIn] Kanako Sakamoto [verfasserIn] Shogo Tachibana [verfasserIn] Toru Yada [verfasserIn] Masahiro Nishimura [verfasserIn] Aiko Nakato [verfasserIn] Akiko Miyazaki [verfasserIn] Kasumi Yogata [verfasserIn] Masanao Abe [verfasserIn] Tomohiro Usui [verfasserIn] Makoto Yoshikawa [verfasserIn] Takanao Saiki [verfasserIn] Satoshi Tanaka [verfasserIn] Fuyuto Terui [verfasserIn] Satoru Nakazawa [verfasserIn] Sei-ichiro Watanabe [verfasserIn] Yuichi Tsuda [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Ryugu Hayabusa2 Spatial distribution of soluble organic compounds DESI-HRMS imaging ToF–SIMS analysis

Übergeordnetes Werk:	In: Earth, Planets and Space - SpringerOpen, 2015, 75(2023), 1, Seite 25
Übergeordnetes Werk:	volume:75 ; year:2023 ; number:1 ; pages:25

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1186/s40623-023-01792-w

Katalog-ID:	DOAJ090279557

Internformat


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245	1	4	\|a The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu
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520			\|a Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract
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650		4	\|a Spatial distribution of soluble organic compounds
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700	0		\|a Yoshinori Takano \|e verfasserin \|4 aut
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700	0		\|a John M. Eiler \|e verfasserin \|4 aut
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700	0		\|a Heather V. Graham \|e verfasserin \|4 aut
700	0		\|a Kenji Hamase \|e verfasserin \|4 aut
700	0		\|a Norbert Hertkorn \|e verfasserin \|4 aut
700	0		\|a Junko Isa \|e verfasserin \|4 aut
700	0		\|a Toshiki Koga \|e verfasserin \|4 aut
700	0		\|a Hannah L. McLain \|e verfasserin \|4 aut
700	0		\|a Hajime Mita \|e verfasserin \|4 aut
700	0		\|a Yasuhiro Oba \|e verfasserin \|4 aut
700	0		\|a Nanako O. Ogawa \|e verfasserin \|4 aut
700	0		\|a Naohiko Ohkouchi \|e verfasserin \|4 aut
700	0		\|a Francois-Regis Orthous-Daunay \|e verfasserin \|4 aut
700	0		\|a Eric T. Parker \|e verfasserin \|4 aut
700	0		\|a Alexander Ruf \|e verfasserin \|4 aut
700	0		\|a Saburo Sakai \|e verfasserin \|4 aut
700	0		\|a Philippe Schmitt-Kopplin \|e verfasserin \|4 aut
700	0		\|a Haruna Sugahara \|e verfasserin \|4 aut
700	0		\|a Roland Thissen \|e verfasserin \|4 aut
700	0		\|a Véronique Vuitton \|e verfasserin \|4 aut
700	0		\|a Cédric Wolters \|e verfasserin \|4 aut
700	0		\|a Toshihiro Yoshimura \|e verfasserin \|4 aut
700	0		\|a Hisayoshi Yurimoto \|e verfasserin \|4 aut
700	0		\|a Tomoki Nakamura \|e verfasserin \|4 aut
700	0		\|a Takaaki Noguchi \|e verfasserin \|4 aut
700	0		\|a Ryuji Okazaki \|e verfasserin \|4 aut
700	0		\|a Hikaru Yabuta \|e verfasserin \|4 aut
700	0		\|a Kanako Sakamoto \|e verfasserin \|4 aut
700	0		\|a Shogo Tachibana \|e verfasserin \|4 aut
700	0		\|a Toru Yada \|e verfasserin \|4 aut
700	0		\|a Masahiro Nishimura \|e verfasserin \|4 aut
700	0		\|a Aiko Nakato \|e verfasserin \|4 aut
700	0		\|a Akiko Miyazaki \|e verfasserin \|4 aut
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700	0		\|a Masanao Abe \|e verfasserin \|4 aut
700	0		\|a Tomohiro Usui \|e verfasserin \|4 aut
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700	0		\|a Takanao Saiki \|e verfasserin \|4 aut
700	0		\|a Satoshi Tanaka \|e verfasserin \|4 aut
700	0		\|a Fuyuto Terui \|e verfasserin \|4 aut
700	0		\|a Satoru Nakazawa \|e verfasserin \|4 aut
700	0		\|a Sei-ichiro Watanabe \|e verfasserin \|4 aut
700	0		\|a Yuichi Tsuda \|e verfasserin \|4 aut
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allfields	10.1186/s40623-023-01792-w doi (DE-627)DOAJ090279557 (DE-599)DOAJ9c42a14dfb8b4ad99257c12821b27206 DE-627 ger DE-627 rakwb eng QB275-343 QE1-996.5 Minako Hashiguchi verfasserin aut The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract Ryugu Hayabusa2 Spatial distribution of soluble organic compounds DESI-HRMS imaging ToF–SIMS analysis Geography. Anthropology. Recreation G Geodesy Geology Dan Aoki verfasserin aut Kazuhiko Fukushima verfasserin aut Hiroshi Naraoka verfasserin aut Yoshinori Takano verfasserin aut Jason P. Dworkin verfasserin aut Karin E. Dworkin verfasserin aut José C. Aponte verfasserin aut Jamie E. Elsila verfasserin aut John M. Eiler verfasserin aut Yoshihiro Furukawa verfasserin aut Aogu Furusho verfasserin aut Daniel P. Glavin verfasserin aut Heather V. Graham verfasserin aut Kenji Hamase verfasserin aut Norbert Hertkorn verfasserin aut Junko Isa verfasserin aut Toshiki Koga verfasserin aut Hannah L. McLain verfasserin aut Hajime Mita verfasserin aut Yasuhiro Oba verfasserin aut Nanako O. Ogawa verfasserin aut Naohiko Ohkouchi verfasserin aut Francois-Regis Orthous-Daunay verfasserin aut Eric T. Parker verfasserin aut Alexander Ruf verfasserin aut Saburo Sakai verfasserin aut Philippe Schmitt-Kopplin verfasserin aut Haruna Sugahara verfasserin aut Roland Thissen verfasserin aut Véronique Vuitton verfasserin aut Cédric Wolters verfasserin aut Toshihiro Yoshimura verfasserin aut Hisayoshi Yurimoto verfasserin aut Tomoki Nakamura verfasserin aut Takaaki Noguchi verfasserin aut Ryuji Okazaki verfasserin aut Hikaru Yabuta verfasserin aut Kanako Sakamoto verfasserin aut Shogo Tachibana verfasserin aut Toru Yada verfasserin aut Masahiro Nishimura verfasserin aut Aiko Nakato verfasserin aut Akiko Miyazaki verfasserin aut Kasumi Yogata verfasserin aut Masanao Abe verfasserin aut Tomohiro Usui verfasserin aut Makoto Yoshikawa verfasserin aut Takanao Saiki verfasserin aut Satoshi Tanaka verfasserin aut Fuyuto Terui verfasserin aut Satoru Nakazawa verfasserin aut Sei-ichiro Watanabe verfasserin aut Yuichi Tsuda verfasserin aut In Earth, Planets and Space SpringerOpen, 2015 75(2023), 1, Seite 25 (DE-627)353898597 (DE-600)2087663-4 18805981 nnns volume:75 year:2023 number:1 pages:25 https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/article/9c42a14dfb8b4ad99257c12821b27206 kostenfrei https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/toc/1880-5981 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 75 2023 1 25
spelling	10.1186/s40623-023-01792-w doi (DE-627)DOAJ090279557 (DE-599)DOAJ9c42a14dfb8b4ad99257c12821b27206 DE-627 ger DE-627 rakwb eng QB275-343 QE1-996.5 Minako Hashiguchi verfasserin aut The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract Ryugu Hayabusa2 Spatial distribution of soluble organic compounds DESI-HRMS imaging ToF–SIMS analysis Geography. Anthropology. Recreation G Geodesy Geology Dan Aoki verfasserin aut Kazuhiko Fukushima verfasserin aut Hiroshi Naraoka verfasserin aut Yoshinori Takano verfasserin aut Jason P. Dworkin verfasserin aut Karin E. Dworkin verfasserin aut José C. Aponte verfasserin aut Jamie E. Elsila verfasserin aut John M. Eiler verfasserin aut Yoshihiro Furukawa verfasserin aut Aogu Furusho verfasserin aut Daniel P. Glavin verfasserin aut Heather V. Graham verfasserin aut Kenji Hamase verfasserin aut Norbert Hertkorn verfasserin aut Junko Isa verfasserin aut Toshiki Koga verfasserin aut Hannah L. McLain verfasserin aut Hajime Mita verfasserin aut Yasuhiro Oba verfasserin aut Nanako O. Ogawa verfasserin aut Naohiko Ohkouchi verfasserin aut Francois-Regis Orthous-Daunay verfasserin aut Eric T. Parker verfasserin aut Alexander Ruf verfasserin aut Saburo Sakai verfasserin aut Philippe Schmitt-Kopplin verfasserin aut Haruna Sugahara verfasserin aut Roland Thissen verfasserin aut Véronique Vuitton verfasserin aut Cédric Wolters verfasserin aut Toshihiro Yoshimura verfasserin aut Hisayoshi Yurimoto verfasserin aut Tomoki Nakamura verfasserin aut Takaaki Noguchi verfasserin aut Ryuji Okazaki verfasserin aut Hikaru Yabuta verfasserin aut Kanako Sakamoto verfasserin aut Shogo Tachibana verfasserin aut Toru Yada verfasserin aut Masahiro Nishimura verfasserin aut Aiko Nakato verfasserin aut Akiko Miyazaki verfasserin aut Kasumi Yogata verfasserin aut Masanao Abe verfasserin aut Tomohiro Usui verfasserin aut Makoto Yoshikawa verfasserin aut Takanao Saiki verfasserin aut Satoshi Tanaka verfasserin aut Fuyuto Terui verfasserin aut Satoru Nakazawa verfasserin aut Sei-ichiro Watanabe verfasserin aut Yuichi Tsuda verfasserin aut In Earth, Planets and Space SpringerOpen, 2015 75(2023), 1, Seite 25 (DE-627)353898597 (DE-600)2087663-4 18805981 nnns volume:75 year:2023 number:1 pages:25 https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/article/9c42a14dfb8b4ad99257c12821b27206 kostenfrei https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/toc/1880-5981 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 75 2023 1 25
allfields_unstemmed	10.1186/s40623-023-01792-w doi (DE-627)DOAJ090279557 (DE-599)DOAJ9c42a14dfb8b4ad99257c12821b27206 DE-627 ger DE-627 rakwb eng QB275-343 QE1-996.5 Minako Hashiguchi verfasserin aut The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract Ryugu Hayabusa2 Spatial distribution of soluble organic compounds DESI-HRMS imaging ToF–SIMS analysis Geography. Anthropology. Recreation G Geodesy Geology Dan Aoki verfasserin aut Kazuhiko Fukushima verfasserin aut Hiroshi Naraoka verfasserin aut Yoshinori Takano verfasserin aut Jason P. Dworkin verfasserin aut Karin E. Dworkin verfasserin aut José C. Aponte verfasserin aut Jamie E. Elsila verfasserin aut John M. Eiler verfasserin aut Yoshihiro Furukawa verfasserin aut Aogu Furusho verfasserin aut Daniel P. Glavin verfasserin aut Heather V. Graham verfasserin aut Kenji Hamase verfasserin aut Norbert Hertkorn verfasserin aut Junko Isa verfasserin aut Toshiki Koga verfasserin aut Hannah L. McLain verfasserin aut Hajime Mita verfasserin aut Yasuhiro Oba verfasserin aut Nanako O. Ogawa verfasserin aut Naohiko Ohkouchi verfasserin aut Francois-Regis Orthous-Daunay verfasserin aut Eric T. Parker verfasserin aut Alexander Ruf verfasserin aut Saburo Sakai verfasserin aut Philippe Schmitt-Kopplin verfasserin aut Haruna Sugahara verfasserin aut Roland Thissen verfasserin aut Véronique Vuitton verfasserin aut Cédric Wolters verfasserin aut Toshihiro Yoshimura verfasserin aut Hisayoshi Yurimoto verfasserin aut Tomoki Nakamura verfasserin aut Takaaki Noguchi verfasserin aut Ryuji Okazaki verfasserin aut Hikaru Yabuta verfasserin aut Kanako Sakamoto verfasserin aut Shogo Tachibana verfasserin aut Toru Yada verfasserin aut Masahiro Nishimura verfasserin aut Aiko Nakato verfasserin aut Akiko Miyazaki verfasserin aut Kasumi Yogata verfasserin aut Masanao Abe verfasserin aut Tomohiro Usui verfasserin aut Makoto Yoshikawa verfasserin aut Takanao Saiki verfasserin aut Satoshi Tanaka verfasserin aut Fuyuto Terui verfasserin aut Satoru Nakazawa verfasserin aut Sei-ichiro Watanabe verfasserin aut Yuichi Tsuda verfasserin aut In Earth, Planets and Space SpringerOpen, 2015 75(2023), 1, Seite 25 (DE-627)353898597 (DE-600)2087663-4 18805981 nnns volume:75 year:2023 number:1 pages:25 https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/article/9c42a14dfb8b4ad99257c12821b27206 kostenfrei https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/toc/1880-5981 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 75 2023 1 25
allfieldsGer	10.1186/s40623-023-01792-w doi (DE-627)DOAJ090279557 (DE-599)DOAJ9c42a14dfb8b4ad99257c12821b27206 DE-627 ger DE-627 rakwb eng QB275-343 QE1-996.5 Minako Hashiguchi verfasserin aut The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract Ryugu Hayabusa2 Spatial distribution of soluble organic compounds DESI-HRMS imaging ToF–SIMS analysis Geography. Anthropology. Recreation G Geodesy Geology Dan Aoki verfasserin aut Kazuhiko Fukushima verfasserin aut Hiroshi Naraoka verfasserin aut Yoshinori Takano verfasserin aut Jason P. Dworkin verfasserin aut Karin E. Dworkin verfasserin aut José C. Aponte verfasserin aut Jamie E. Elsila verfasserin aut John M. Eiler verfasserin aut Yoshihiro Furukawa verfasserin aut Aogu Furusho verfasserin aut Daniel P. Glavin verfasserin aut Heather V. Graham verfasserin aut Kenji Hamase verfasserin aut Norbert Hertkorn verfasserin aut Junko Isa verfasserin aut Toshiki Koga verfasserin aut Hannah L. McLain verfasserin aut Hajime Mita verfasserin aut Yasuhiro Oba verfasserin aut Nanako O. Ogawa verfasserin aut Naohiko Ohkouchi verfasserin aut Francois-Regis Orthous-Daunay verfasserin aut Eric T. Parker verfasserin aut Alexander Ruf verfasserin aut Saburo Sakai verfasserin aut Philippe Schmitt-Kopplin verfasserin aut Haruna Sugahara verfasserin aut Roland Thissen verfasserin aut Véronique Vuitton verfasserin aut Cédric Wolters verfasserin aut Toshihiro Yoshimura verfasserin aut Hisayoshi Yurimoto verfasserin aut Tomoki Nakamura verfasserin aut Takaaki Noguchi verfasserin aut Ryuji Okazaki verfasserin aut Hikaru Yabuta verfasserin aut Kanako Sakamoto verfasserin aut Shogo Tachibana verfasserin aut Toru Yada verfasserin aut Masahiro Nishimura verfasserin aut Aiko Nakato verfasserin aut Akiko Miyazaki verfasserin aut Kasumi Yogata verfasserin aut Masanao Abe verfasserin aut Tomohiro Usui verfasserin aut Makoto Yoshikawa verfasserin aut Takanao Saiki verfasserin aut Satoshi Tanaka verfasserin aut Fuyuto Terui verfasserin aut Satoru Nakazawa verfasserin aut Sei-ichiro Watanabe verfasserin aut Yuichi Tsuda verfasserin aut In Earth, Planets and Space SpringerOpen, 2015 75(2023), 1, Seite 25 (DE-627)353898597 (DE-600)2087663-4 18805981 nnns volume:75 year:2023 number:1 pages:25 https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/article/9c42a14dfb8b4ad99257c12821b27206 kostenfrei https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/toc/1880-5981 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 75 2023 1 25
allfieldsSound	10.1186/s40623-023-01792-w doi (DE-627)DOAJ090279557 (DE-599)DOAJ9c42a14dfb8b4ad99257c12821b27206 DE-627 ger DE-627 rakwb eng QB275-343 QE1-996.5 Minako Hashiguchi verfasserin aut The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract Ryugu Hayabusa2 Spatial distribution of soluble organic compounds DESI-HRMS imaging ToF–SIMS analysis Geography. Anthropology. Recreation G Geodesy Geology Dan Aoki verfasserin aut Kazuhiko Fukushima verfasserin aut Hiroshi Naraoka verfasserin aut Yoshinori Takano verfasserin aut Jason P. Dworkin verfasserin aut Karin E. Dworkin verfasserin aut José C. Aponte verfasserin aut Jamie E. Elsila verfasserin aut John M. Eiler verfasserin aut Yoshihiro Furukawa verfasserin aut Aogu Furusho verfasserin aut Daniel P. Glavin verfasserin aut Heather V. Graham verfasserin aut Kenji Hamase verfasserin aut Norbert Hertkorn verfasserin aut Junko Isa verfasserin aut Toshiki Koga verfasserin aut Hannah L. McLain verfasserin aut Hajime Mita verfasserin aut Yasuhiro Oba verfasserin aut Nanako O. Ogawa verfasserin aut Naohiko Ohkouchi verfasserin aut Francois-Regis Orthous-Daunay verfasserin aut Eric T. Parker verfasserin aut Alexander Ruf verfasserin aut Saburo Sakai verfasserin aut Philippe Schmitt-Kopplin verfasserin aut Haruna Sugahara verfasserin aut Roland Thissen verfasserin aut Véronique Vuitton verfasserin aut Cédric Wolters verfasserin aut Toshihiro Yoshimura verfasserin aut Hisayoshi Yurimoto verfasserin aut Tomoki Nakamura verfasserin aut Takaaki Noguchi verfasserin aut Ryuji Okazaki verfasserin aut Hikaru Yabuta verfasserin aut Kanako Sakamoto verfasserin aut Shogo Tachibana verfasserin aut Toru Yada verfasserin aut Masahiro Nishimura verfasserin aut Aiko Nakato verfasserin aut Akiko Miyazaki verfasserin aut Kasumi Yogata verfasserin aut Masanao Abe verfasserin aut Tomohiro Usui verfasserin aut Makoto Yoshikawa verfasserin aut Takanao Saiki verfasserin aut Satoshi Tanaka verfasserin aut Fuyuto Terui verfasserin aut Satoru Nakazawa verfasserin aut Sei-ichiro Watanabe verfasserin aut Yuichi Tsuda verfasserin aut In Earth, Planets and Space SpringerOpen, 2015 75(2023), 1, Seite 25 (DE-627)353898597 (DE-600)2087663-4 18805981 nnns volume:75 year:2023 number:1 pages:25 https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/article/9c42a14dfb8b4ad99257c12821b27206 kostenfrei https://doi.org/10.1186/s40623-023-01792-w kostenfrei https://doaj.org/toc/1880-5981 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 75 2023 1 25
language	English
source	In Earth, Planets and Space 75(2023), 1, Seite 25 volume:75 year:2023 number:1 pages:25
sourceStr	In Earth, Planets and Space 75(2023), 1, Seite 25 volume:75 year:2023 number:1 pages:25
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Ryugu Hayabusa2 Spatial distribution of soluble organic compounds DESI-HRMS imaging ToF–SIMS analysis Geography. Anthropology. Recreation G Geodesy Geology
isfreeaccess_bool	true
container_title	Earth, Planets and Space
authorswithroles_txt_mv	Minako Hashiguchi @@aut@@ Dan Aoki @@aut@@ Kazuhiko Fukushima @@aut@@ Hiroshi Naraoka @@aut@@ Yoshinori Takano @@aut@@ Jason P. Dworkin @@aut@@ Karin E. Dworkin @@aut@@ José C. Aponte @@aut@@ Jamie E. Elsila @@aut@@ John M. Eiler @@aut@@ Yoshihiro Furukawa @@aut@@ Aogu Furusho @@aut@@ Daniel P. Glavin @@aut@@ Heather V. Graham @@aut@@ Kenji Hamase @@aut@@ Norbert Hertkorn @@aut@@ Junko Isa @@aut@@ Toshiki Koga @@aut@@ Hannah L. McLain @@aut@@ Hajime Mita @@aut@@ Yasuhiro Oba @@aut@@ Nanako O. Ogawa @@aut@@ Naohiko Ohkouchi @@aut@@ Francois-Regis Orthous-Daunay @@aut@@ Eric T. Parker @@aut@@ Alexander Ruf @@aut@@ Saburo Sakai @@aut@@ Philippe Schmitt-Kopplin @@aut@@ Haruna Sugahara @@aut@@ Roland Thissen @@aut@@ Véronique Vuitton @@aut@@ Cédric Wolters @@aut@@ Toshihiro Yoshimura @@aut@@ Hisayoshi Yurimoto @@aut@@ Tomoki Nakamura @@aut@@ Takaaki Noguchi @@aut@@ Ryuji Okazaki @@aut@@ Hikaru Yabuta @@aut@@ Kanako Sakamoto @@aut@@ Shogo Tachibana @@aut@@ Toru Yada @@aut@@ Masahiro Nishimura @@aut@@ Aiko Nakato @@aut@@ Akiko Miyazaki @@aut@@ Kasumi Yogata @@aut@@ Masanao Abe @@aut@@ Tomohiro Usui @@aut@@ Makoto Yoshikawa @@aut@@ Takanao Saiki @@aut@@ Satoshi Tanaka @@aut@@ Fuyuto Terui @@aut@@ Satoru Nakazawa @@aut@@ Sei-ichiro Watanabe @@aut@@ Yuichi Tsuda @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	353898597
id	DOAJ090279557
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fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">DOAJ090279557</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230526110325.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230526s2023 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1186/s40623-023-01792-w</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ090279557</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJ9c42a14dfb8b4ad99257c12821b27206</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QB275-343</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QE1-996.5</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Minako Hashiguchi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="4"><subfield code="a">The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ryugu</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hayabusa2</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Spatial distribution of soluble organic compounds</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">DESI-HRMS imaging</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">ToF–SIMS analysis</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Geography. Anthropology. 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callnumber-first	Q - Science
author	Minako Hashiguchi
spellingShingle	Minako Hashiguchi misc QB275-343 misc QE1-996.5 misc Ryugu misc Hayabusa2 misc Spatial distribution of soluble organic compounds misc DESI-HRMS imaging misc ToF–SIMS analysis misc Geography. Anthropology. Recreation misc G misc Geodesy misc Geology The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu
authorStr	Minako Hashiguchi
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topic_title	QB275-343 QE1-996.5 The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu Ryugu Hayabusa2 Spatial distribution of soluble organic compounds DESI-HRMS imaging ToF–SIMS analysis
topic	misc QB275-343 misc QE1-996.5 misc Ryugu misc Hayabusa2 misc Spatial distribution of soluble organic compounds misc DESI-HRMS imaging misc ToF–SIMS analysis misc Geography. Anthropology. Recreation misc G misc Geodesy misc Geology
topic_unstemmed	misc QB275-343 misc QE1-996.5 misc Ryugu misc Hayabusa2 misc Spatial distribution of soluble organic compounds misc DESI-HRMS imaging misc ToF–SIMS analysis misc Geography. Anthropology. Recreation misc G misc Geodesy misc Geology
topic_browse	misc QB275-343 misc QE1-996.5 misc Ryugu misc Hayabusa2 misc Spatial distribution of soluble organic compounds misc DESI-HRMS imaging misc ToF–SIMS analysis misc Geography. Anthropology. Recreation misc G misc Geodesy misc Geology
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title	The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu
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title_full	The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu
author_sort	Minako Hashiguchi
journal	Earth, Planets and Space
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author_browse	Minako Hashiguchi Dan Aoki Kazuhiko Fukushima Hiroshi Naraoka Yoshinori Takano Jason P. Dworkin Karin E. Dworkin José C. Aponte Jamie E. Elsila John M. Eiler Yoshihiro Furukawa Aogu Furusho Daniel P. Glavin Heather V. Graham Kenji Hamase Norbert Hertkorn Junko Isa Toshiki Koga Hannah L. McLain Hajime Mita Yasuhiro Oba Nanako O. Ogawa Naohiko Ohkouchi Francois-Regis Orthous-Daunay Eric T. Parker Alexander Ruf Saburo Sakai Philippe Schmitt-Kopplin Haruna Sugahara Roland Thissen Véronique Vuitton Cédric Wolters Toshihiro Yoshimura Hisayoshi Yurimoto Tomoki Nakamura Takaaki Noguchi Ryuji Okazaki Hikaru Yabuta Kanako Sakamoto Shogo Tachibana Toru Yada Masahiro Nishimura Aiko Nakato Akiko Miyazaki Kasumi Yogata Masanao Abe Tomohiro Usui Makoto Yoshikawa Takanao Saiki Satoshi Tanaka Fuyuto Terui Satoru Nakazawa Sei-ichiro Watanabe Yuichi Tsuda
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author-letter	Minako Hashiguchi
doi_str_mv	10.1186/s40623-023-01792-w
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title_sort	spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) ryugu
callnumber	QB275-343
title_auth	The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu
abstract	Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract
abstractGer	Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract
abstract_unstemmed	Abstract We performed in-situ analysis on a ~ 1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu. Graphical Abstract
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container_issue	1
title_short	The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu
url	https://doi.org/10.1186/s40623-023-01792-w https://doaj.org/article/9c42a14dfb8b4ad99257c12821b27206 https://doaj.org/toc/1880-5981
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author2	Dan Aoki Kazuhiko Fukushima Hiroshi Naraoka Yoshinori Takano Jason P. Dworkin Karin E. Dworkin José C. Aponte Jamie E. Elsila John M. Eiler Yoshihiro Furukawa Aogu Furusho Daniel P. Glavin Heather V. Graham Kenji Hamase Norbert Hertkorn Junko Isa Toshiki Koga Hannah L. McLain Hajime Mita Yasuhiro Oba Nanako O. Ogawa Naohiko Ohkouchi Francois-Regis Orthous-Daunay Eric T. Parker Alexander Ruf Saburo Sakai Philippe Schmitt-Kopplin Haruna Sugahara Roland Thissen Véronique Vuitton Cédric Wolters Toshihiro Yoshimura Hisayoshi Yurimoto Tomoki Nakamura Takaaki Noguchi Ryuji Okazaki Hikaru Yabuta Kanako Sakamoto Shogo Tachibana Toru Yada Masahiro Nishimura Aiko Nakato Akiko Miyazaki Kasumi Yogata Masanao Abe Tomohiro Usui Makoto Yoshikawa Takanao Saiki Satoshi Tanaka Fuyuto Terui Satoru Nakazawa Sei-ichiro Watanabe Yuichi Tsuda
author2Str	Dan Aoki Kazuhiko Fukushima Hiroshi Naraoka Yoshinori Takano Jason P. Dworkin Karin E. Dworkin José C. Aponte Jamie E. Elsila John M. Eiler Yoshihiro Furukawa Aogu Furusho Daniel P. Glavin Heather V. Graham Kenji Hamase Norbert Hertkorn Junko Isa Toshiki Koga Hannah L. McLain Hajime Mita Yasuhiro Oba Nanako O. Ogawa Naohiko Ohkouchi Francois-Regis Orthous-Daunay Eric T. Parker Alexander Ruf Saburo Sakai Philippe Schmitt-Kopplin Haruna Sugahara Roland Thissen Véronique Vuitton Cédric Wolters Toshihiro Yoshimura Hisayoshi Yurimoto Tomoki Nakamura Takaaki Noguchi Ryuji Okazaki Hikaru Yabuta Kanako Sakamoto Shogo Tachibana Toru Yada Masahiro Nishimura Aiko Nakato Akiko Miyazaki Kasumi Yogata Masanao Abe Tomohiro Usui Makoto Yoshikawa Takanao Saiki Satoshi Tanaka Fuyuto Terui Satoru Nakazawa Sei-ichiro Watanabe Yuichi Tsuda
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doi_str	10.1186/s40623-023-01792-w
callnumber-a	QB275-343
up_date	2024-07-03T13:49:31.253Z
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The spatial distribution of soluble organic matter and their relationship to minerals in the asteroid (162173) Ryugu

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