One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction

Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we ai...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Risako Kamoto [verfasserIn] Kenjiro Onimura [verfasserIn] Kazuhiro Yamabuki [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	[c2]daisy-chain rotaxane metathesis reaction thiol-ene reaction

Übergeordnetes Werk:	In: Reactions - MDPI AG, 2020, 4(2023), 27, Seite 448-464
Übergeordnetes Werk:	volume:4 ; year:2023 ; number:27 ; pages:448-464

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/reactions4030027

Katalog-ID:	DOAJ093295812

Internformat


LEADER	01000naa a22002652 4500
001	DOAJ093295812
003	DE-627
005	20240413211335.0
007	cr uuu---uuuuu
008	240413s2023 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.3390/reactions4030027 \|2 doi
035			\|a (DE-627)DOAJ093295812
035			\|a (DE-599)DOAJ21ca261c87be490abf0de4ee544a00cc
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
050		0	\|a QD1-999
100	0		\|a Risako Kamoto \|e verfasserin \|4 aut
245	1	0	\|a One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction
264		1	\|c 2023
336			\|a Text \|b txt \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures.
650		4	\|a [c2]daisy-chain rotaxane
650		4	\|a metathesis reaction
650		4	\|a thiol-ene reaction
653		0	\|a Chemistry
700	0		\|a Kenjiro Onimura \|e verfasserin \|4 aut
700	0		\|a Kazuhiro Yamabuki \|e verfasserin \|4 aut
773	0	8	\|i In \|t Reactions \|d MDPI AG, 2020 \|g 4(2023), 27, Seite 448-464 \|w (DE-627)169822415X \|x 2624781X \|7 nnns
773	1	8	\|g volume:4 \|g year:2023 \|g number:27 \|g pages:448-464
856	4	0	\|u https://doi.org/10.3390/reactions4030027 \|z kostenfrei
856	4	0	\|u https://doaj.org/article/21ca261c87be490abf0de4ee544a00cc \|z kostenfrei
856	4	0	\|u https://www.mdpi.com/2624-781X/4/3/27 \|z kostenfrei
856	4	2	\|u https://doaj.org/toc/2624-781X \|y Journal toc \|z kostenfrei
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_DOAJ
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_95
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_151
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_213
912			\|a GBV_ILN_230
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_602
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4367
912			\|a GBV_ILN_4700
951			\|a AR
952			\|d 4 \|j 2023 \|e 27 \|h 448-464

Indexfelder

author_variant	r k rk k o ko k y ky
matchkey_str	article:2624781X:2023----::nptyteiosalplcdiyhirtxnwtpedsoprimtteir
hierarchy_sort_str	2023
callnumber-subject-code	QD
publishDate	2023
allfields	10.3390/reactions4030027 doi (DE-627)DOAJ093295812 (DE-599)DOAJ21ca261c87be490abf0de4ee544a00cc DE-627 ger DE-627 rakwb eng QD1-999 Risako Kamoto verfasserin aut One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures. [c2]daisy-chain rotaxane metathesis reaction thiol-ene reaction Chemistry Kenjiro Onimura verfasserin aut Kazuhiro Yamabuki verfasserin aut In Reactions MDPI AG, 2020 4(2023), 27, Seite 448-464 (DE-627)169822415X 2624781X nnns volume:4 year:2023 number:27 pages:448-464 https://doi.org/10.3390/reactions4030027 kostenfrei https://doaj.org/article/21ca261c87be490abf0de4ee544a00cc kostenfrei https://www.mdpi.com/2624-781X/4/3/27 kostenfrei https://doaj.org/toc/2624-781X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2023 27 448-464
spelling	10.3390/reactions4030027 doi (DE-627)DOAJ093295812 (DE-599)DOAJ21ca261c87be490abf0de4ee544a00cc DE-627 ger DE-627 rakwb eng QD1-999 Risako Kamoto verfasserin aut One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures. [c2]daisy-chain rotaxane metathesis reaction thiol-ene reaction Chemistry Kenjiro Onimura verfasserin aut Kazuhiro Yamabuki verfasserin aut In Reactions MDPI AG, 2020 4(2023), 27, Seite 448-464 (DE-627)169822415X 2624781X nnns volume:4 year:2023 number:27 pages:448-464 https://doi.org/10.3390/reactions4030027 kostenfrei https://doaj.org/article/21ca261c87be490abf0de4ee544a00cc kostenfrei https://www.mdpi.com/2624-781X/4/3/27 kostenfrei https://doaj.org/toc/2624-781X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2023 27 448-464
allfields_unstemmed	10.3390/reactions4030027 doi (DE-627)DOAJ093295812 (DE-599)DOAJ21ca261c87be490abf0de4ee544a00cc DE-627 ger DE-627 rakwb eng QD1-999 Risako Kamoto verfasserin aut One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures. [c2]daisy-chain rotaxane metathesis reaction thiol-ene reaction Chemistry Kenjiro Onimura verfasserin aut Kazuhiro Yamabuki verfasserin aut In Reactions MDPI AG, 2020 4(2023), 27, Seite 448-464 (DE-627)169822415X 2624781X nnns volume:4 year:2023 number:27 pages:448-464 https://doi.org/10.3390/reactions4030027 kostenfrei https://doaj.org/article/21ca261c87be490abf0de4ee544a00cc kostenfrei https://www.mdpi.com/2624-781X/4/3/27 kostenfrei https://doaj.org/toc/2624-781X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2023 27 448-464
allfieldsGer	10.3390/reactions4030027 doi (DE-627)DOAJ093295812 (DE-599)DOAJ21ca261c87be490abf0de4ee544a00cc DE-627 ger DE-627 rakwb eng QD1-999 Risako Kamoto verfasserin aut One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures. [c2]daisy-chain rotaxane metathesis reaction thiol-ene reaction Chemistry Kenjiro Onimura verfasserin aut Kazuhiro Yamabuki verfasserin aut In Reactions MDPI AG, 2020 4(2023), 27, Seite 448-464 (DE-627)169822415X 2624781X nnns volume:4 year:2023 number:27 pages:448-464 https://doi.org/10.3390/reactions4030027 kostenfrei https://doaj.org/article/21ca261c87be490abf0de4ee544a00cc kostenfrei https://www.mdpi.com/2624-781X/4/3/27 kostenfrei https://doaj.org/toc/2624-781X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2023 27 448-464
allfieldsSound	10.3390/reactions4030027 doi (DE-627)DOAJ093295812 (DE-599)DOAJ21ca261c87be490abf0de4ee544a00cc DE-627 ger DE-627 rakwb eng QD1-999 Risako Kamoto verfasserin aut One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures. [c2]daisy-chain rotaxane metathesis reaction thiol-ene reaction Chemistry Kenjiro Onimura verfasserin aut Kazuhiro Yamabuki verfasserin aut In Reactions MDPI AG, 2020 4(2023), 27, Seite 448-464 (DE-627)169822415X 2624781X nnns volume:4 year:2023 number:27 pages:448-464 https://doi.org/10.3390/reactions4030027 kostenfrei https://doaj.org/article/21ca261c87be490abf0de4ee544a00cc kostenfrei https://www.mdpi.com/2624-781X/4/3/27 kostenfrei https://doaj.org/toc/2624-781X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2023 27 448-464
language	English
source	In Reactions 4(2023), 27, Seite 448-464 volume:4 year:2023 number:27 pages:448-464
sourceStr	In Reactions 4(2023), 27, Seite 448-464 volume:4 year:2023 number:27 pages:448-464
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	[c2]daisy-chain rotaxane metathesis reaction thiol-ene reaction Chemistry
isfreeaccess_bool	true
container_title	Reactions
authorswithroles_txt_mv	Risako Kamoto @@aut@@ Kenjiro Onimura @@aut@@ Kazuhiro Yamabuki @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	169822415X
id	DOAJ093295812
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">DOAJ093295812</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240413211335.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">240413s2023 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.3390/reactions4030027</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ093295812</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJ21ca261c87be490abf0de4ee544a00cc</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD1-999</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Risako Kamoto</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">[c2]daisy-chain rotaxane</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">metathesis reaction</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">thiol-ene reaction</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Chemistry</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Kenjiro Onimura</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Kazuhiro Yamabuki</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="t">Reactions</subfield><subfield code="d">MDPI AG, 2020</subfield><subfield code="g">4(2023), 27, Seite 448-464</subfield><subfield code="w">(DE-627)169822415X</subfield><subfield code="x">2624781X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:4</subfield><subfield code="g">year:2023</subfield><subfield code="g">number:27</subfield><subfield code="g">pages:448-464</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.3390/reactions4030027</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doaj.org/article/21ca261c87be490abf0de4ee544a00cc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.mdpi.com/2624-781X/4/3/27</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://doaj.org/toc/2624-781X</subfield><subfield code="y">Journal toc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_DOAJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4367</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">4</subfield><subfield code="j">2023</subfield><subfield code="e">27</subfield><subfield code="h">448-464</subfield></datafield></record></collection>
callnumber-first	Q - Science
author	Risako Kamoto
spellingShingle	Risako Kamoto misc QD1-999 misc [c2]daisy-chain rotaxane misc metathesis reaction misc thiol-ene reaction misc Chemistry One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction
authorStr	Risako Kamoto
ppnlink_with_tag_str_mv	@@773@@(DE-627)169822415X
format	electronic Article
delete_txt_mv	keep
author_role	aut aut aut
collection	DOAJ
remote_str	true
callnumber-label	QD1-999
illustrated	Not Illustrated
issn	2624781X
topic_title	QD1-999 One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction [c2]daisy-chain rotaxane metathesis reaction thiol-ene reaction
topic	misc QD1-999 misc [c2]daisy-chain rotaxane misc metathesis reaction misc thiol-ene reaction misc Chemistry
topic_unstemmed	misc QD1-999 misc [c2]daisy-chain rotaxane misc metathesis reaction misc thiol-ene reaction misc Chemistry
topic_browse	misc QD1-999 misc [c2]daisy-chain rotaxane misc metathesis reaction misc thiol-ene reaction misc Chemistry
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	Reactions
hierarchy_parent_id	169822415X
hierarchy_top_title	Reactions
isfreeaccess_txt	true
familylinks_str_mv	(DE-627)169822415X
title	One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction
ctrlnum	(DE-627)DOAJ093295812 (DE-599)DOAJ21ca261c87be490abf0de4ee544a00cc
title_full	One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction
author_sort	Risako Kamoto
journal	Reactions
journalStr	Reactions
callnumber-first-code	Q
lang_code	eng
isOA_bool	true
recordtype	marc
publishDateSort	2023
contenttype_str_mv	txt
container_start_page	448
author_browse	Risako Kamoto Kenjiro Onimura Kazuhiro Yamabuki
container_volume	4
class	QD1-999
format_se	Elektronische Aufsätze
author-letter	Risako Kamoto
doi_str_mv	10.3390/reactions4030027
author2-role	verfasserin
title_sort	one-pot synthesis of stable poly([c2]daisy–chain rotaxane) with pseudo-stopper via metathesis reaction and thiol-ene reaction
callnumber	QD1-999
title_auth	One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction
abstract	Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures.
abstractGer	Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures.
abstract_unstemmed	Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700
container_issue	27
title_short	One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction
url	https://doi.org/10.3390/reactions4030027 https://doaj.org/article/21ca261c87be490abf0de4ee544a00cc https://www.mdpi.com/2624-781X/4/3/27 https://doaj.org/toc/2624-781X
remote_bool	true
author2	Kenjiro Onimura Kazuhiro Yamabuki
author2Str	Kenjiro Onimura Kazuhiro Yamabuki
ppnlink	169822415X
callnumber-subject	QD - Chemistry
mediatype_str_mv	c
isOA_txt	true
hochschulschrift_bool	false
doi_str	10.3390/reactions4030027
callnumber-a	QD1-999
up_date	2024-07-03T16:27:29.725Z
_version_	1803575937965490176
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">DOAJ093295812</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240413211335.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">240413s2023 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.3390/reactions4030027</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ093295812</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJ21ca261c87be490abf0de4ee544a00cc</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD1-999</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Risako Kamoto</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">[c2]daisy-chain rotaxane</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">metathesis reaction</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">thiol-ene reaction</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Chemistry</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Kenjiro Onimura</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Kazuhiro Yamabuki</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="t">Reactions</subfield><subfield code="d">MDPI AG, 2020</subfield><subfield code="g">4(2023), 27, Seite 448-464</subfield><subfield code="w">(DE-627)169822415X</subfield><subfield code="x">2624781X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:4</subfield><subfield code="g">year:2023</subfield><subfield code="g">number:27</subfield><subfield code="g">pages:448-464</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.3390/reactions4030027</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doaj.org/article/21ca261c87be490abf0de4ee544a00cc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.mdpi.com/2624-781X/4/3/27</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://doaj.org/toc/2624-781X</subfield><subfield code="y">Journal toc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_DOAJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4367</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">4</subfield><subfield code="j">2023</subfield><subfield code="e">27</subfield><subfield code="h">448-464</subfield></datafield></record></collection>
score	7.3995247

Nicht das Richtige dabei?

Schreiben Sie uns!

One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?