Green Approach for Synthesizing Copper-Containing ZIFs as Efficient Catalysts for Click Chemistry

ZIF-8 and ZIF-67 containing various percentages of copper were successfully synthesized through a green in-situ thermal (IST) approach based on 2-methylimidazole (2-MIM) as the organic linker. The IST method has several advantages over previously reported studies, including solvent and additive-free...
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Autor*in:	Alireza Pourvahabi Anbari [verfasserIn] Shima Rahmdel Delcheh [verfasserIn] Philippe M. Heynderickx [verfasserIn] Somboon Chaemcheun [verfasserIn] Serge Zhuiykov [verfasserIn] Francis Verpoort [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	zeolitic imidazole frameworks green chemistry click reaction azide-alkyne cycloaddition CuAAC

Übergeordnetes Werk:	In: Catalysts - MDPI AG, 2012, 13(2023), 6, p 1003
Übergeordnetes Werk:	volume:13 ; year:2023 ; number:6, p 1003

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/catal13061003

Katalog-ID:	DOAJ094187967

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authorswithroles_txt_mv	Alireza Pourvahabi Anbari @@aut@@ Shima Rahmdel Delcheh @@aut@@ Philippe M. Heynderickx @@aut@@ Somboon Chaemcheun @@aut@@ Serge Zhuiykov @@aut@@ Francis Verpoort @@aut@@
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callnumber-first	T - Technology
author	Alireza Pourvahabi Anbari
spellingShingle	Alireza Pourvahabi Anbari misc TP1-1185 misc QD1-999 misc zeolitic imidazole frameworks misc green chemistry misc click reaction misc azide-alkyne cycloaddition misc CuAAC misc Chemical technology misc Chemistry Green Approach for Synthesizing Copper-Containing ZIFs as Efficient Catalysts for Click Chemistry
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topic_title	TP1-1185 QD1-999 Green Approach for Synthesizing Copper-Containing ZIFs as Efficient Catalysts for Click Chemistry zeolitic imidazole frameworks green chemistry click reaction azide-alkyne cycloaddition CuAAC
topic	misc TP1-1185 misc QD1-999 misc zeolitic imidazole frameworks misc green chemistry misc click reaction misc azide-alkyne cycloaddition misc CuAAC misc Chemical technology misc Chemistry
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title	Green Approach for Synthesizing Copper-Containing ZIFs as Efficient Catalysts for Click Chemistry
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title_full	Green Approach for Synthesizing Copper-Containing ZIFs as Efficient Catalysts for Click Chemistry
author_sort	Alireza Pourvahabi Anbari
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author_browse	Alireza Pourvahabi Anbari Shima Rahmdel Delcheh Philippe M. Heynderickx Somboon Chaemcheun Serge Zhuiykov Francis Verpoort
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title_sort	green approach for synthesizing copper-containing zifs as efficient catalysts for click chemistry
callnumber	TP1-1185
title_auth	Green Approach for Synthesizing Copper-Containing ZIFs as Efficient Catalysts for Click Chemistry
abstract	ZIF-8 and ZIF-67 containing various percentages of copper were successfully synthesized through a green in-situ thermal (IST) approach based on 2-methylimidazole (2-MIM) as the organic linker. The IST method has several advantages over previously reported studies, including solvent and additive-free reaction conditions, a mild reaction temperature, a single-step procedure, no activation requirements, and the use of the smallest precursor ratio (M/L). The high catalytic performance of Cu/ZIF-8 and Cu/ZIF-67 in click chemistry is attributed to their high specific surface area, excellent porosity, and structural stability. To achieve these features, a range of parameters—such as time, temperature, gas atmosphere, and precursor ratio—were optimized. Several characterization methods were used to confirm the features of the produced catalysts. Overall, the synthesis strategy for achieving the targeted ZIFs with unique features is “green” and does not require further activation or treatment to eliminate side products. This method has great potential for manufacturing metal-organic frameworks on a large scale. Moreover, water was used as a solvent during the click reaction, resulting in high yields and making this an attractive, green, and eco-friendly procedure.
abstractGer	ZIF-8 and ZIF-67 containing various percentages of copper were successfully synthesized through a green in-situ thermal (IST) approach based on 2-methylimidazole (2-MIM) as the organic linker. The IST method has several advantages over previously reported studies, including solvent and additive-free reaction conditions, a mild reaction temperature, a single-step procedure, no activation requirements, and the use of the smallest precursor ratio (M/L). The high catalytic performance of Cu/ZIF-8 and Cu/ZIF-67 in click chemistry is attributed to their high specific surface area, excellent porosity, and structural stability. To achieve these features, a range of parameters—such as time, temperature, gas atmosphere, and precursor ratio—were optimized. Several characterization methods were used to confirm the features of the produced catalysts. Overall, the synthesis strategy for achieving the targeted ZIFs with unique features is “green” and does not require further activation or treatment to eliminate side products. This method has great potential for manufacturing metal-organic frameworks on a large scale. Moreover, water was used as a solvent during the click reaction, resulting in high yields and making this an attractive, green, and eco-friendly procedure.
abstract_unstemmed	ZIF-8 and ZIF-67 containing various percentages of copper were successfully synthesized through a green in-situ thermal (IST) approach based on 2-methylimidazole (2-MIM) as the organic linker. The IST method has several advantages over previously reported studies, including solvent and additive-free reaction conditions, a mild reaction temperature, a single-step procedure, no activation requirements, and the use of the smallest precursor ratio (M/L). The high catalytic performance of Cu/ZIF-8 and Cu/ZIF-67 in click chemistry is attributed to their high specific surface area, excellent porosity, and structural stability. To achieve these features, a range of parameters—such as time, temperature, gas atmosphere, and precursor ratio—were optimized. Several characterization methods were used to confirm the features of the produced catalysts. Overall, the synthesis strategy for achieving the targeted ZIFs with unique features is “green” and does not require further activation or treatment to eliminate side products. This method has great potential for manufacturing metal-organic frameworks on a large scale. Moreover, water was used as a solvent during the click reaction, resulting in high yields and making this an attractive, green, and eco-friendly procedure.
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title_short	Green Approach for Synthesizing Copper-Containing ZIFs as Efficient Catalysts for Click Chemistry
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author2	Shima Rahmdel Delcheh Philippe M. Heynderickx Somboon Chaemcheun Serge Zhuiykov Francis Verpoort
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up_date	2024-07-03T21:45:50.188Z
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