Ameliorating Phosphonic-Based Nonflammable Electrolytes Towards Safe and Stable Lithium Metal Batteries
High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl...
Ausführliche Beschreibung
Autor*in: |
Sha Fu [verfasserIn] Xuanzhi Xie [verfasserIn] Xiaoyi Huangyang [verfasserIn] Longxi Yang [verfasserIn] Xianxiang Zeng [verfasserIn] Qiang Ma [verfasserIn] Xiongwei Wu [verfasserIn] Mingtao Xiao [verfasserIn] Yuping Wu [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2023 |
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In: Molecules - MDPI AG, 2003, 28(2023), 10, p 4106 |
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Übergeordnetes Werk: |
volume:28 ; year:2023 ; number:10, p 4106 |
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DOI / URN: |
10.3390/molecules28104106 |
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Katalog-ID: |
DOAJ094331731 |
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10.3390/molecules28104106 doi (DE-627)DOAJ094331731 (DE-599)DOAJefa8e04601304cedb0ca9ddcfee1a9dc DE-627 ger DE-627 rakwb eng QD241-441 Sha Fu verfasserin aut Ameliorating Phosphonic-Based Nonflammable Electrolytes Towards Safe and Stable Lithium Metal Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl-phosphate and fluoroethylene carbonate were introduced to triethyl phosphate electrolytes to stabilize the deposition of metallic lithium and accommodate the electrode–electrolyte interface. In comparison with traditional carbonate electrolyte, the designed electrolyte shows high thermostability and inflaming retarding characteristics. Meanwhile, the Li||Li symmetrical batteries with designed phosphonic-based electrolytes exhibit a superior cycling stability of 700 h at the condition of 0.2 mA cm<sup<−2</sup<, 0.2 mAh cm<sup<−2</sup<. Additionally, the smooth- and dense-deposited morphology was observed on an cycled Li anode surface, demonstrating that the designed electrolytes show better interface compatibility with metallic lithium anodes. The Li||LiNi<sub<0.8</sub<Co<sub<0.1</sub<Mn<sub<0.1</sub<O<sub<2</sub< and Li||LiNi<sub<0.6</sub<Co<sub<0.2</sub<Mn<sub<0.2</sub<O<sub<2</sub< batteries paired with phosphonic-based electrolytes show better cycling stability after 200 and 450 cycles at the rate of 0.2 C, respectively. Our work provides a new way to ameliorate nonflammable electrolytes in advanced energy storage systems. lithium metal batteries metallic lithium anode electrode–electrolyte interface interface compatibility nonflammable electrolytes Organic chemistry Xuanzhi Xie verfasserin aut Xiaoyi Huangyang verfasserin aut Longxi Yang verfasserin aut Xianxiang Zeng verfasserin aut Qiang Ma verfasserin aut Xiongwei Wu verfasserin aut Mingtao Xiao verfasserin aut Yuping Wu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 10, p 4106 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:10, p 4106 https://doi.org/10.3390/molecules28104106 kostenfrei https://doaj.org/article/efa8e04601304cedb0ca9ddcfee1a9dc kostenfrei https://www.mdpi.com/1420-3049/28/10/4106 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 10, p 4106 |
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10.3390/molecules28104106 doi (DE-627)DOAJ094331731 (DE-599)DOAJefa8e04601304cedb0ca9ddcfee1a9dc DE-627 ger DE-627 rakwb eng QD241-441 Sha Fu verfasserin aut Ameliorating Phosphonic-Based Nonflammable Electrolytes Towards Safe and Stable Lithium Metal Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl-phosphate and fluoroethylene carbonate were introduced to triethyl phosphate electrolytes to stabilize the deposition of metallic lithium and accommodate the electrode–electrolyte interface. In comparison with traditional carbonate electrolyte, the designed electrolyte shows high thermostability and inflaming retarding characteristics. Meanwhile, the Li||Li symmetrical batteries with designed phosphonic-based electrolytes exhibit a superior cycling stability of 700 h at the condition of 0.2 mA cm<sup<−2</sup<, 0.2 mAh cm<sup<−2</sup<. Additionally, the smooth- and dense-deposited morphology was observed on an cycled Li anode surface, demonstrating that the designed electrolytes show better interface compatibility with metallic lithium anodes. The Li||LiNi<sub<0.8</sub<Co<sub<0.1</sub<Mn<sub<0.1</sub<O<sub<2</sub< and Li||LiNi<sub<0.6</sub<Co<sub<0.2</sub<Mn<sub<0.2</sub<O<sub<2</sub< batteries paired with phosphonic-based electrolytes show better cycling stability after 200 and 450 cycles at the rate of 0.2 C, respectively. Our work provides a new way to ameliorate nonflammable electrolytes in advanced energy storage systems. lithium metal batteries metallic lithium anode electrode–electrolyte interface interface compatibility nonflammable electrolytes Organic chemistry Xuanzhi Xie verfasserin aut Xiaoyi Huangyang verfasserin aut Longxi Yang verfasserin aut Xianxiang Zeng verfasserin aut Qiang Ma verfasserin aut Xiongwei Wu verfasserin aut Mingtao Xiao verfasserin aut Yuping Wu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 10, p 4106 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:10, p 4106 https://doi.org/10.3390/molecules28104106 kostenfrei https://doaj.org/article/efa8e04601304cedb0ca9ddcfee1a9dc kostenfrei https://www.mdpi.com/1420-3049/28/10/4106 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 10, p 4106 |
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10.3390/molecules28104106 doi (DE-627)DOAJ094331731 (DE-599)DOAJefa8e04601304cedb0ca9ddcfee1a9dc DE-627 ger DE-627 rakwb eng QD241-441 Sha Fu verfasserin aut Ameliorating Phosphonic-Based Nonflammable Electrolytes Towards Safe and Stable Lithium Metal Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl-phosphate and fluoroethylene carbonate were introduced to triethyl phosphate electrolytes to stabilize the deposition of metallic lithium and accommodate the electrode–electrolyte interface. In comparison with traditional carbonate electrolyte, the designed electrolyte shows high thermostability and inflaming retarding characteristics. Meanwhile, the Li||Li symmetrical batteries with designed phosphonic-based electrolytes exhibit a superior cycling stability of 700 h at the condition of 0.2 mA cm<sup<−2</sup<, 0.2 mAh cm<sup<−2</sup<. Additionally, the smooth- and dense-deposited morphology was observed on an cycled Li anode surface, demonstrating that the designed electrolytes show better interface compatibility with metallic lithium anodes. The Li||LiNi<sub<0.8</sub<Co<sub<0.1</sub<Mn<sub<0.1</sub<O<sub<2</sub< and Li||LiNi<sub<0.6</sub<Co<sub<0.2</sub<Mn<sub<0.2</sub<O<sub<2</sub< batteries paired with phosphonic-based electrolytes show better cycling stability after 200 and 450 cycles at the rate of 0.2 C, respectively. Our work provides a new way to ameliorate nonflammable electrolytes in advanced energy storage systems. lithium metal batteries metallic lithium anode electrode–electrolyte interface interface compatibility nonflammable electrolytes Organic chemistry Xuanzhi Xie verfasserin aut Xiaoyi Huangyang verfasserin aut Longxi Yang verfasserin aut Xianxiang Zeng verfasserin aut Qiang Ma verfasserin aut Xiongwei Wu verfasserin aut Mingtao Xiao verfasserin aut Yuping Wu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 10, p 4106 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:10, p 4106 https://doi.org/10.3390/molecules28104106 kostenfrei https://doaj.org/article/efa8e04601304cedb0ca9ddcfee1a9dc kostenfrei https://www.mdpi.com/1420-3049/28/10/4106 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 10, p 4106 |
allfieldsGer |
10.3390/molecules28104106 doi (DE-627)DOAJ094331731 (DE-599)DOAJefa8e04601304cedb0ca9ddcfee1a9dc DE-627 ger DE-627 rakwb eng QD241-441 Sha Fu verfasserin aut Ameliorating Phosphonic-Based Nonflammable Electrolytes Towards Safe and Stable Lithium Metal Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl-phosphate and fluoroethylene carbonate were introduced to triethyl phosphate electrolytes to stabilize the deposition of metallic lithium and accommodate the electrode–electrolyte interface. In comparison with traditional carbonate electrolyte, the designed electrolyte shows high thermostability and inflaming retarding characteristics. Meanwhile, the Li||Li symmetrical batteries with designed phosphonic-based electrolytes exhibit a superior cycling stability of 700 h at the condition of 0.2 mA cm<sup<−2</sup<, 0.2 mAh cm<sup<−2</sup<. Additionally, the smooth- and dense-deposited morphology was observed on an cycled Li anode surface, demonstrating that the designed electrolytes show better interface compatibility with metallic lithium anodes. The Li||LiNi<sub<0.8</sub<Co<sub<0.1</sub<Mn<sub<0.1</sub<O<sub<2</sub< and Li||LiNi<sub<0.6</sub<Co<sub<0.2</sub<Mn<sub<0.2</sub<O<sub<2</sub< batteries paired with phosphonic-based electrolytes show better cycling stability after 200 and 450 cycles at the rate of 0.2 C, respectively. Our work provides a new way to ameliorate nonflammable electrolytes in advanced energy storage systems. lithium metal batteries metallic lithium anode electrode–electrolyte interface interface compatibility nonflammable electrolytes Organic chemistry Xuanzhi Xie verfasserin aut Xiaoyi Huangyang verfasserin aut Longxi Yang verfasserin aut Xianxiang Zeng verfasserin aut Qiang Ma verfasserin aut Xiongwei Wu verfasserin aut Mingtao Xiao verfasserin aut Yuping Wu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 10, p 4106 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:10, p 4106 https://doi.org/10.3390/molecules28104106 kostenfrei https://doaj.org/article/efa8e04601304cedb0ca9ddcfee1a9dc kostenfrei https://www.mdpi.com/1420-3049/28/10/4106 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 10, p 4106 |
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10.3390/molecules28104106 doi (DE-627)DOAJ094331731 (DE-599)DOAJefa8e04601304cedb0ca9ddcfee1a9dc DE-627 ger DE-627 rakwb eng QD241-441 Sha Fu verfasserin aut Ameliorating Phosphonic-Based Nonflammable Electrolytes Towards Safe and Stable Lithium Metal Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl-phosphate and fluoroethylene carbonate were introduced to triethyl phosphate electrolytes to stabilize the deposition of metallic lithium and accommodate the electrode–electrolyte interface. In comparison with traditional carbonate electrolyte, the designed electrolyte shows high thermostability and inflaming retarding characteristics. Meanwhile, the Li||Li symmetrical batteries with designed phosphonic-based electrolytes exhibit a superior cycling stability of 700 h at the condition of 0.2 mA cm<sup<−2</sup<, 0.2 mAh cm<sup<−2</sup<. Additionally, the smooth- and dense-deposited morphology was observed on an cycled Li anode surface, demonstrating that the designed electrolytes show better interface compatibility with metallic lithium anodes. The Li||LiNi<sub<0.8</sub<Co<sub<0.1</sub<Mn<sub<0.1</sub<O<sub<2</sub< and Li||LiNi<sub<0.6</sub<Co<sub<0.2</sub<Mn<sub<0.2</sub<O<sub<2</sub< batteries paired with phosphonic-based electrolytes show better cycling stability after 200 and 450 cycles at the rate of 0.2 C, respectively. Our work provides a new way to ameliorate nonflammable electrolytes in advanced energy storage systems. lithium metal batteries metallic lithium anode electrode–electrolyte interface interface compatibility nonflammable electrolytes Organic chemistry Xuanzhi Xie verfasserin aut Xiaoyi Huangyang verfasserin aut Longxi Yang verfasserin aut Xianxiang Zeng verfasserin aut Qiang Ma verfasserin aut Xiongwei Wu verfasserin aut Mingtao Xiao verfasserin aut Yuping Wu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 10, p 4106 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:10, p 4106 https://doi.org/10.3390/molecules28104106 kostenfrei https://doaj.org/article/efa8e04601304cedb0ca9ddcfee1a9dc kostenfrei https://www.mdpi.com/1420-3049/28/10/4106 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 10, p 4106 |
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In Molecules 28(2023), 10, p 4106 volume:28 year:2023 number:10, p 4106 |
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Ameliorating Phosphonic-Based Nonflammable Electrolytes Towards Safe and Stable Lithium Metal Batteries |
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High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl-phosphate and fluoroethylene carbonate were introduced to triethyl phosphate electrolytes to stabilize the deposition of metallic lithium and accommodate the electrode–electrolyte interface. In comparison with traditional carbonate electrolyte, the designed electrolyte shows high thermostability and inflaming retarding characteristics. Meanwhile, the Li||Li symmetrical batteries with designed phosphonic-based electrolytes exhibit a superior cycling stability of 700 h at the condition of 0.2 mA cm<sup<−2</sup<, 0.2 mAh cm<sup<−2</sup<. Additionally, the smooth- and dense-deposited morphology was observed on an cycled Li anode surface, demonstrating that the designed electrolytes show better interface compatibility with metallic lithium anodes. The Li||LiNi<sub<0.8</sub<Co<sub<0.1</sub<Mn<sub<0.1</sub<O<sub<2</sub< and Li||LiNi<sub<0.6</sub<Co<sub<0.2</sub<Mn<sub<0.2</sub<O<sub<2</sub< batteries paired with phosphonic-based electrolytes show better cycling stability after 200 and 450 cycles at the rate of 0.2 C, respectively. Our work provides a new way to ameliorate nonflammable electrolytes in advanced energy storage systems. |
abstractGer |
High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl-phosphate and fluoroethylene carbonate were introduced to triethyl phosphate electrolytes to stabilize the deposition of metallic lithium and accommodate the electrode–electrolyte interface. In comparison with traditional carbonate electrolyte, the designed electrolyte shows high thermostability and inflaming retarding characteristics. Meanwhile, the Li||Li symmetrical batteries with designed phosphonic-based electrolytes exhibit a superior cycling stability of 700 h at the condition of 0.2 mA cm<sup<−2</sup<, 0.2 mAh cm<sup<−2</sup<. Additionally, the smooth- and dense-deposited morphology was observed on an cycled Li anode surface, demonstrating that the designed electrolytes show better interface compatibility with metallic lithium anodes. The Li||LiNi<sub<0.8</sub<Co<sub<0.1</sub<Mn<sub<0.1</sub<O<sub<2</sub< and Li||LiNi<sub<0.6</sub<Co<sub<0.2</sub<Mn<sub<0.2</sub<O<sub<2</sub< batteries paired with phosphonic-based electrolytes show better cycling stability after 200 and 450 cycles at the rate of 0.2 C, respectively. Our work provides a new way to ameliorate nonflammable electrolytes in advanced energy storage systems. |
abstract_unstemmed |
High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl-phosphate and fluoroethylene carbonate were introduced to triethyl phosphate electrolytes to stabilize the deposition of metallic lithium and accommodate the electrode–electrolyte interface. In comparison with traditional carbonate electrolyte, the designed electrolyte shows high thermostability and inflaming retarding characteristics. Meanwhile, the Li||Li symmetrical batteries with designed phosphonic-based electrolytes exhibit a superior cycling stability of 700 h at the condition of 0.2 mA cm<sup<−2</sup<, 0.2 mAh cm<sup<−2</sup<. Additionally, the smooth- and dense-deposited morphology was observed on an cycled Li anode surface, demonstrating that the designed electrolytes show better interface compatibility with metallic lithium anodes. The Li||LiNi<sub<0.8</sub<Co<sub<0.1</sub<Mn<sub<0.1</sub<O<sub<2</sub< and Li||LiNi<sub<0.6</sub<Co<sub<0.2</sub<Mn<sub<0.2</sub<O<sub<2</sub< batteries paired with phosphonic-based electrolytes show better cycling stability after 200 and 450 cycles at the rate of 0.2 C, respectively. Our work provides a new way to ameliorate nonflammable electrolytes in advanced energy storage systems. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">DOAJ094331731</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20240413033312.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">240413s2023 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.3390/molecules28104106</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ094331731</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJefa8e04601304cedb0ca9ddcfee1a9dc</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD241-441</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Sha Fu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Ameliorating Phosphonic-Based Nonflammable Electrolytes Towards Safe and Stable Lithium Metal Batteries</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">High-energy-density lithium metal batteries with high safety and stability are urgently needed. Designing the novel nonflammable electrolytes possessing superior interface compatibility and stability is critical to achieve the stable cycling of battery. Herein, the functional additive dimethyl allyl-phosphate and fluoroethylene carbonate were introduced to triethyl phosphate electrolytes to stabilize the deposition of metallic lithium and accommodate the electrode–electrolyte interface. In comparison with traditional carbonate electrolyte, the designed electrolyte shows high thermostability and inflaming retarding characteristics. Meanwhile, the Li||Li symmetrical batteries with designed phosphonic-based electrolytes exhibit a superior cycling stability of 700 h at the condition of 0.2 mA cm<sup<−2</sup<, 0.2 mAh cm<sup<−2</sup<. Additionally, the smooth- and dense-deposited morphology was observed on an cycled Li anode surface, demonstrating that the designed electrolytes show better interface compatibility with metallic lithium anodes. The Li||LiNi<sub<0.8</sub<Co<sub<0.1</sub<Mn<sub<0.1</sub<O<sub<2</sub< and Li||LiNi<sub<0.6</sub<Co<sub<0.2</sub<Mn<sub<0.2</sub<O<sub<2</sub< batteries paired with phosphonic-based electrolytes show better cycling stability after 200 and 450 cycles at the rate of 0.2 C, respectively. 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