Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions

The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<...
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Autor*in:	Xiaoyu Zhou [verfasserIn] Jiaxin Yang [verfasserIn] Zhiqiang Hao [verfasserIn] Zhangang Han [verfasserIn] Jin Lin [verfasserIn] Guo-Liang Lu [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	anilido-imine ligands copper complexes benzimidazole Chan–Lam coupling

Übergeordnetes Werk:	In: Molecules - MDPI AG, 2003, 28(2023), 21, p 7406
Übergeordnetes Werk:	volume:28 ; year:2023 ; number:21, p 7406

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/molecules28217406

Katalog-ID:	DOAJ095449361

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520			\|a The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<5</b< Cu[{2-[ArN=C(H)]C<sub<6</sub<H<sub<4</sub<}N(8-C<sub<9</sub<H<sub<6</sub<N)]Cl (Ar = 2,6-<i<<sup<i</sup<</i<Pr<sub<2</sub<C<sub<6</sub<H<sub<3</sub< (<b<1</b<), 2,4,6-(CH<sub<3</sub<)<sub<3</sub<C<sub<6</sub<H<sub<2</sub< (<b<2</b<), 4-OCH<sub<3</sub<C<sub<6</sub<H<sub<4</sub< (<b<3</b<), 4-BrC<sub<6</sub<H<sub<4</sub< (<b<4</b<), 4-ClC<sub<6</sub<H<sub<4</sub< (<b<5</b<)), respectively. All the copper complexes were fully characterized by IR, EPR and HR-MS spectra. The X-ray diffraction analysis reveals that <b<2</b< and <b<4</b< are mononuclear complexes, and the Cu atom is sitting in a slightly square-planar geometry. These Cu(II) complexes have exhibited excellent catalytic activity in the Chan–Lam coupling reactions of benzimidazole derivatives with arylboronic acids, achieving the highest yields of up to 96%.
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allfields	10.3390/molecules28217406 doi (DE-627)DOAJ095449361 (DE-599)DOAJ0e086ee2677748299894368af950548e DE-627 ger DE-627 rakwb eng QD241-441 Xiaoyu Zhou verfasserin aut Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<5</b< Cu[{2-[ArN=C(H)]C<sub<6</sub<H<sub<4</sub<}N(8-C<sub<9</sub<H<sub<6</sub<N)]Cl (Ar = 2,6-<i<<sup<i</sup<</i<Pr<sub<2</sub<C<sub<6</sub<H<sub<3</sub< (<b<1</b<), 2,4,6-(CH<sub<3</sub<)<sub<3</sub<C<sub<6</sub<H<sub<2</sub< (<b<2</b<), 4-OCH<sub<3</sub<C<sub<6</sub<H<sub<4</sub< (<b<3</b<), 4-BrC<sub<6</sub<H<sub<4</sub< (<b<4</b<), 4-ClC<sub<6</sub<H<sub<4</sub< (<b<5</b<)), respectively. All the copper complexes were fully characterized by IR, EPR and HR-MS spectra. The X-ray diffraction analysis reveals that <b<2</b< and <b<4</b< are mononuclear complexes, and the Cu atom is sitting in a slightly square-planar geometry. These Cu(II) complexes have exhibited excellent catalytic activity in the Chan–Lam coupling reactions of benzimidazole derivatives with arylboronic acids, achieving the highest yields of up to 96%. anilido-imine ligands copper complexes benzimidazole Chan–Lam coupling Organic chemistry Jiaxin Yang verfasserin aut Zhiqiang Hao verfasserin aut Zhangang Han verfasserin aut Jin Lin verfasserin aut Guo-Liang Lu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 21, p 7406 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:21, p 7406 https://doi.org/10.3390/molecules28217406 kostenfrei https://doaj.org/article/0e086ee2677748299894368af950548e kostenfrei https://www.mdpi.com/1420-3049/28/21/7406 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 21, p 7406
spelling	10.3390/molecules28217406 doi (DE-627)DOAJ095449361 (DE-599)DOAJ0e086ee2677748299894368af950548e DE-627 ger DE-627 rakwb eng QD241-441 Xiaoyu Zhou verfasserin aut Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<5</b< Cu[{2-[ArN=C(H)]C<sub<6</sub<H<sub<4</sub<}N(8-C<sub<9</sub<H<sub<6</sub<N)]Cl (Ar = 2,6-<i<<sup<i</sup<</i<Pr<sub<2</sub<C<sub<6</sub<H<sub<3</sub< (<b<1</b<), 2,4,6-(CH<sub<3</sub<)<sub<3</sub<C<sub<6</sub<H<sub<2</sub< (<b<2</b<), 4-OCH<sub<3</sub<C<sub<6</sub<H<sub<4</sub< (<b<3</b<), 4-BrC<sub<6</sub<H<sub<4</sub< (<b<4</b<), 4-ClC<sub<6</sub<H<sub<4</sub< (<b<5</b<)), respectively. All the copper complexes were fully characterized by IR, EPR and HR-MS spectra. The X-ray diffraction analysis reveals that <b<2</b< and <b<4</b< are mononuclear complexes, and the Cu atom is sitting in a slightly square-planar geometry. These Cu(II) complexes have exhibited excellent catalytic activity in the Chan–Lam coupling reactions of benzimidazole derivatives with arylboronic acids, achieving the highest yields of up to 96%. anilido-imine ligands copper complexes benzimidazole Chan–Lam coupling Organic chemistry Jiaxin Yang verfasserin aut Zhiqiang Hao verfasserin aut Zhangang Han verfasserin aut Jin Lin verfasserin aut Guo-Liang Lu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 21, p 7406 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:21, p 7406 https://doi.org/10.3390/molecules28217406 kostenfrei https://doaj.org/article/0e086ee2677748299894368af950548e kostenfrei https://www.mdpi.com/1420-3049/28/21/7406 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 21, p 7406
allfields_unstemmed	10.3390/molecules28217406 doi (DE-627)DOAJ095449361 (DE-599)DOAJ0e086ee2677748299894368af950548e DE-627 ger DE-627 rakwb eng QD241-441 Xiaoyu Zhou verfasserin aut Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<5</b< Cu[{2-[ArN=C(H)]C<sub<6</sub<H<sub<4</sub<}N(8-C<sub<9</sub<H<sub<6</sub<N)]Cl (Ar = 2,6-<i<<sup<i</sup<</i<Pr<sub<2</sub<C<sub<6</sub<H<sub<3</sub< (<b<1</b<), 2,4,6-(CH<sub<3</sub<)<sub<3</sub<C<sub<6</sub<H<sub<2</sub< (<b<2</b<), 4-OCH<sub<3</sub<C<sub<6</sub<H<sub<4</sub< (<b<3</b<), 4-BrC<sub<6</sub<H<sub<4</sub< (<b<4</b<), 4-ClC<sub<6</sub<H<sub<4</sub< (<b<5</b<)), respectively. All the copper complexes were fully characterized by IR, EPR and HR-MS spectra. The X-ray diffraction analysis reveals that <b<2</b< and <b<4</b< are mononuclear complexes, and the Cu atom is sitting in a slightly square-planar geometry. These Cu(II) complexes have exhibited excellent catalytic activity in the Chan–Lam coupling reactions of benzimidazole derivatives with arylboronic acids, achieving the highest yields of up to 96%. anilido-imine ligands copper complexes benzimidazole Chan–Lam coupling Organic chemistry Jiaxin Yang verfasserin aut Zhiqiang Hao verfasserin aut Zhangang Han verfasserin aut Jin Lin verfasserin aut Guo-Liang Lu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 21, p 7406 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:21, p 7406 https://doi.org/10.3390/molecules28217406 kostenfrei https://doaj.org/article/0e086ee2677748299894368af950548e kostenfrei https://www.mdpi.com/1420-3049/28/21/7406 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 21, p 7406
allfieldsGer	10.3390/molecules28217406 doi (DE-627)DOAJ095449361 (DE-599)DOAJ0e086ee2677748299894368af950548e DE-627 ger DE-627 rakwb eng QD241-441 Xiaoyu Zhou verfasserin aut Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<5</b< Cu[{2-[ArN=C(H)]C<sub<6</sub<H<sub<4</sub<}N(8-C<sub<9</sub<H<sub<6</sub<N)]Cl (Ar = 2,6-<i<<sup<i</sup<</i<Pr<sub<2</sub<C<sub<6</sub<H<sub<3</sub< (<b<1</b<), 2,4,6-(CH<sub<3</sub<)<sub<3</sub<C<sub<6</sub<H<sub<2</sub< (<b<2</b<), 4-OCH<sub<3</sub<C<sub<6</sub<H<sub<4</sub< (<b<3</b<), 4-BrC<sub<6</sub<H<sub<4</sub< (<b<4</b<), 4-ClC<sub<6</sub<H<sub<4</sub< (<b<5</b<)), respectively. All the copper complexes were fully characterized by IR, EPR and HR-MS spectra. The X-ray diffraction analysis reveals that <b<2</b< and <b<4</b< are mononuclear complexes, and the Cu atom is sitting in a slightly square-planar geometry. These Cu(II) complexes have exhibited excellent catalytic activity in the Chan–Lam coupling reactions of benzimidazole derivatives with arylboronic acids, achieving the highest yields of up to 96%. anilido-imine ligands copper complexes benzimidazole Chan–Lam coupling Organic chemistry Jiaxin Yang verfasserin aut Zhiqiang Hao verfasserin aut Zhangang Han verfasserin aut Jin Lin verfasserin aut Guo-Liang Lu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 21, p 7406 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:21, p 7406 https://doi.org/10.3390/molecules28217406 kostenfrei https://doaj.org/article/0e086ee2677748299894368af950548e kostenfrei https://www.mdpi.com/1420-3049/28/21/7406 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 21, p 7406
allfieldsSound	10.3390/molecules28217406 doi (DE-627)DOAJ095449361 (DE-599)DOAJ0e086ee2677748299894368af950548e DE-627 ger DE-627 rakwb eng QD241-441 Xiaoyu Zhou verfasserin aut Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<5</b< Cu[{2-[ArN=C(H)]C<sub<6</sub<H<sub<4</sub<}N(8-C<sub<9</sub<H<sub<6</sub<N)]Cl (Ar = 2,6-<i<<sup<i</sup<</i<Pr<sub<2</sub<C<sub<6</sub<H<sub<3</sub< (<b<1</b<), 2,4,6-(CH<sub<3</sub<)<sub<3</sub<C<sub<6</sub<H<sub<2</sub< (<b<2</b<), 4-OCH<sub<3</sub<C<sub<6</sub<H<sub<4</sub< (<b<3</b<), 4-BrC<sub<6</sub<H<sub<4</sub< (<b<4</b<), 4-ClC<sub<6</sub<H<sub<4</sub< (<b<5</b<)), respectively. All the copper complexes were fully characterized by IR, EPR and HR-MS spectra. The X-ray diffraction analysis reveals that <b<2</b< and <b<4</b< are mononuclear complexes, and the Cu atom is sitting in a slightly square-planar geometry. These Cu(II) complexes have exhibited excellent catalytic activity in the Chan–Lam coupling reactions of benzimidazole derivatives with arylboronic acids, achieving the highest yields of up to 96%. anilido-imine ligands copper complexes benzimidazole Chan–Lam coupling Organic chemistry Jiaxin Yang verfasserin aut Zhiqiang Hao verfasserin aut Zhangang Han verfasserin aut Jin Lin verfasserin aut Guo-Liang Lu verfasserin aut In Molecules MDPI AG, 2003 28(2023), 21, p 7406 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:28 year:2023 number:21, p 7406 https://doi.org/10.3390/molecules28217406 kostenfrei https://doaj.org/article/0e086ee2677748299894368af950548e kostenfrei https://www.mdpi.com/1420-3049/28/21/7406 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 28 2023 21, p 7406
language	English
source	In Molecules 28(2023), 21, p 7406 volume:28 year:2023 number:21, p 7406
sourceStr	In Molecules 28(2023), 21, p 7406 volume:28 year:2023 number:21, p 7406
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institution	findex.gbv.de
topic_facet	anilido-imine ligands copper complexes benzimidazole Chan–Lam coupling Organic chemistry
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container_title	Molecules
authorswithroles_txt_mv	Xiaoyu Zhou @@aut@@ Jiaxin Yang @@aut@@ Zhiqiang Hao @@aut@@ Zhangang Han @@aut@@ Jin Lin @@aut@@ Guo-Liang Lu @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
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callnumber-first	Q - Science
author	Xiaoyu Zhou
spellingShingle	Xiaoyu Zhou misc QD241-441 misc anilido-imine ligands misc copper complexes misc benzimidazole misc Chan–Lam coupling misc Organic chemistry Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions
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topic_title	QD241-441 Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions anilido-imine ligands copper complexes benzimidazole Chan–Lam coupling
topic	misc QD241-441 misc anilido-imine ligands misc copper complexes misc benzimidazole misc Chan–Lam coupling misc Organic chemistry
topic_unstemmed	misc QD241-441 misc anilido-imine ligands misc copper complexes misc benzimidazole misc Chan–Lam coupling misc Organic chemistry
topic_browse	misc QD241-441 misc anilido-imine ligands misc copper complexes misc benzimidazole misc Chan–Lam coupling misc Organic chemistry
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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title	Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions
ctrlnum	(DE-627)DOAJ095449361 (DE-599)DOAJ0e086ee2677748299894368af950548e
title_full	Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions
author_sort	Xiaoyu Zhou
journal	Molecules
journalStr	Molecules
callnumber-first-code	Q
lang_code	eng
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publishDateSort	2023
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author_browse	Xiaoyu Zhou Jiaxin Yang Zhiqiang Hao Zhangang Han Jin Lin Guo-Liang Lu
container_volume	28
class	QD241-441
format_se	Elektronische Aufsätze
author-letter	Xiaoyu Zhou
doi_str_mv	10.3390/molecules28217406
author2-role	verfasserin
title_sort	copper complexes with n,n,n-tridentate quinolinyl anilido-imine ligands: synthesis and their catalytic application in chan−lam reactions
callnumber	QD241-441
title_auth	Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions
abstract	The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<5</b< Cu[{2-[ArN=C(H)]C<sub<6</sub<H<sub<4</sub<}N(8-C<sub<9</sub<H<sub<6</sub<N)]Cl (Ar = 2,6-<i<<sup<i</sup<</i<Pr<sub<2</sub<C<sub<6</sub<H<sub<3</sub< (<b<1</b<), 2,4,6-(CH<sub<3</sub<)<sub<3</sub<C<sub<6</sub<H<sub<2</sub< (<b<2</b<), 4-OCH<sub<3</sub<C<sub<6</sub<H<sub<4</sub< (<b<3</b<), 4-BrC<sub<6</sub<H<sub<4</sub< (<b<4</b<), 4-ClC<sub<6</sub<H<sub<4</sub< (<b<5</b<)), respectively. All the copper complexes were fully characterized by IR, EPR and HR-MS spectra. The X-ray diffraction analysis reveals that <b<2</b< and <b<4</b< are mononuclear complexes, and the Cu atom is sitting in a slightly square-planar geometry. These Cu(II) complexes have exhibited excellent catalytic activity in the Chan–Lam coupling reactions of benzimidazole derivatives with arylboronic acids, achieving the highest yields of up to 96%.
abstractGer	The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<5</b< Cu[{2-[ArN=C(H)]C<sub<6</sub<H<sub<4</sub<}N(8-C<sub<9</sub<H<sub<6</sub<N)]Cl (Ar = 2,6-<i<<sup<i</sup<</i<Pr<sub<2</sub<C<sub<6</sub<H<sub<3</sub< (<b<1</b<), 2,4,6-(CH<sub<3</sub<)<sub<3</sub<C<sub<6</sub<H<sub<2</sub< (<b<2</b<), 4-OCH<sub<3</sub<C<sub<6</sub<H<sub<4</sub< (<b<3</b<), 4-BrC<sub<6</sub<H<sub<4</sub< (<b<4</b<), 4-ClC<sub<6</sub<H<sub<4</sub< (<b<5</b<)), respectively. All the copper complexes were fully characterized by IR, EPR and HR-MS spectra. The X-ray diffraction analysis reveals that <b<2</b< and <b<4</b< are mononuclear complexes, and the Cu atom is sitting in a slightly square-planar geometry. These Cu(II) complexes have exhibited excellent catalytic activity in the Chan–Lam coupling reactions of benzimidazole derivatives with arylboronic acids, achieving the highest yields of up to 96%.
abstract_unstemmed	The treatment of 2-(ArNC(H))C<sub<6</sub<H<sub<4</sub<-HNC<sub<9</sub<H<sub<6</sub<N with <i<n</i<-BuLi and the subsequent addition of CuCl<sub<2</sub< afforded the anilido-aldimine Cu(II) complexes <b<1</b<-<b<5</b< Cu[{2-[ArN=C(H)]C<sub<6</sub<H<sub<4</sub<}N(8-C<sub<9</sub<H<sub<6</sub<N)]Cl (Ar = 2,6-<i<<sup<i</sup<</i<Pr<sub<2</sub<C<sub<6</sub<H<sub<3</sub< (<b<1</b<), 2,4,6-(CH<sub<3</sub<)<sub<3</sub<C<sub<6</sub<H<sub<2</sub< (<b<2</b<), 4-OCH<sub<3</sub<C<sub<6</sub<H<sub<4</sub< (<b<3</b<), 4-BrC<sub<6</sub<H<sub<4</sub< (<b<4</b<), 4-ClC<sub<6</sub<H<sub<4</sub< (<b<5</b<)), respectively. All the copper complexes were fully characterized by IR, EPR and HR-MS spectra. The X-ray diffraction analysis reveals that <b<2</b< and <b<4</b< are mononuclear complexes, and the Cu atom is sitting in a slightly square-planar geometry. These Cu(II) complexes have exhibited excellent catalytic activity in the Chan–Lam coupling reactions of benzimidazole derivatives with arylboronic acids, achieving the highest yields of up to 96%.
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container_issue	21, p 7406
title_short	Copper Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligands: Synthesis and Their Catalytic Application in Chan−Lam Reactions
url	https://doi.org/10.3390/molecules28217406 https://doaj.org/article/0e086ee2677748299894368af950548e https://www.mdpi.com/1420-3049/28/21/7406 https://doaj.org/toc/1420-3049
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author2	Jiaxin Yang Zhiqiang Hao Zhangang Han Jin Lin Guo-Liang Lu
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doi_str	10.3390/molecules28217406
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up_date	2024-07-03T14:43:44.780Z
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