Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries

Lithium-ion solid-state batteries with spinel Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheri...
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Autor*in:	Xinghua Liang [verfasserIn] Yuying Wang [verfasserIn] Zhida Liang [verfasserIn] Ge Yan [verfasserIn] Lingxiao Lan [verfasserIn] Yujiang Wang [verfasserIn] Xueli Shi [verfasserIn] Shuhong Yun [verfasserIn] Meihong Huang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Li atmospheric plasma spraying (APS) in situ solid-state batteries ultraviolet curing (UV-curing)

Übergeordnetes Werk:	In: Polymers - MDPI AG, 2011, 16(2023), 1, p 55
Übergeordnetes Werk:	volume:16 ; year:2023 ; number:1, p 55

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/polym16010055

Katalog-ID:	DOAJ097775339

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allfields	10.3390/polym16010055 doi (DE-627)DOAJ097775339 (DE-599)DOAJ8acc435fb4204e7297936374ce310228 DE-627 ger DE-627 rakwb eng QD241-441 Xinghua Liang verfasserin aut Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Lithium-ion solid-state batteries with spinel Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheric plasma spraying method, and a composite solid electrolyte was prepared by in situ ultraviolet (UV) curing on the LTO electrode. The composite solid electrolyte was designed using a soft–hard combination strategy, and the electrolyte was prepared into a composite of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flexible structure and high-conductivity Li<sub<1.3</sub<Al<sub<0.3</sub<Ti<sub<1.7</sub<(PO<sub<4</sub<)<sub<3</sub< (LATP) hard particles. The composite electrolyte exhibited a good ionic conductivity up to 0.35 mS cm<sup<−1</sup< at 30 °C and an electrochemical window above 4.0 V. In situ and ex situ electrolytes were assembled into LTO//electrolyte//Li solid-state batteries to investigate their impact on the electrochemical performance of the batteries. As a result, the assembled Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub<//in situ electrolytes//Li batteries exhibited excellent rate of performance, and their capacity retention rate was 90% at 0.2 mA/cm<sup<2</sup< after 300 cycles. This work provides a new method for the fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries. Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< atmospheric plasma spraying (APS) in situ solid-state batteries ultraviolet curing (UV-curing) Organic chemistry Yuying Wang verfasserin aut Zhida Liang verfasserin aut Ge Yan verfasserin aut Lingxiao Lan verfasserin aut Yujiang Wang verfasserin aut Xueli Shi verfasserin aut Shuhong Yun verfasserin aut Meihong Huang verfasserin aut In Polymers MDPI AG, 2011 16(2023), 1, p 55 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:16 year:2023 number:1, p 55 https://doi.org/10.3390/polym16010055 kostenfrei https://doaj.org/article/8acc435fb4204e7297936374ce310228 kostenfrei https://www.mdpi.com/2073-4360/16/1/55 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 16 2023 1, p 55
spelling	10.3390/polym16010055 doi (DE-627)DOAJ097775339 (DE-599)DOAJ8acc435fb4204e7297936374ce310228 DE-627 ger DE-627 rakwb eng QD241-441 Xinghua Liang verfasserin aut Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Lithium-ion solid-state batteries with spinel Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheric plasma spraying method, and a composite solid electrolyte was prepared by in situ ultraviolet (UV) curing on the LTO electrode. The composite solid electrolyte was designed using a soft–hard combination strategy, and the electrolyte was prepared into a composite of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flexible structure and high-conductivity Li<sub<1.3</sub<Al<sub<0.3</sub<Ti<sub<1.7</sub<(PO<sub<4</sub<)<sub<3</sub< (LATP) hard particles. The composite electrolyte exhibited a good ionic conductivity up to 0.35 mS cm<sup<−1</sup< at 30 °C and an electrochemical window above 4.0 V. In situ and ex situ electrolytes were assembled into LTO//electrolyte//Li solid-state batteries to investigate their impact on the electrochemical performance of the batteries. As a result, the assembled Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub<//in situ electrolytes//Li batteries exhibited excellent rate of performance, and their capacity retention rate was 90% at 0.2 mA/cm<sup<2</sup< after 300 cycles. This work provides a new method for the fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries. Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< atmospheric plasma spraying (APS) in situ solid-state batteries ultraviolet curing (UV-curing) Organic chemistry Yuying Wang verfasserin aut Zhida Liang verfasserin aut Ge Yan verfasserin aut Lingxiao Lan verfasserin aut Yujiang Wang verfasserin aut Xueli Shi verfasserin aut Shuhong Yun verfasserin aut Meihong Huang verfasserin aut In Polymers MDPI AG, 2011 16(2023), 1, p 55 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:16 year:2023 number:1, p 55 https://doi.org/10.3390/polym16010055 kostenfrei https://doaj.org/article/8acc435fb4204e7297936374ce310228 kostenfrei https://www.mdpi.com/2073-4360/16/1/55 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 16 2023 1, p 55
allfields_unstemmed	10.3390/polym16010055 doi (DE-627)DOAJ097775339 (DE-599)DOAJ8acc435fb4204e7297936374ce310228 DE-627 ger DE-627 rakwb eng QD241-441 Xinghua Liang verfasserin aut Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Lithium-ion solid-state batteries with spinel Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheric plasma spraying method, and a composite solid electrolyte was prepared by in situ ultraviolet (UV) curing on the LTO electrode. The composite solid electrolyte was designed using a soft–hard combination strategy, and the electrolyte was prepared into a composite of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flexible structure and high-conductivity Li<sub<1.3</sub<Al<sub<0.3</sub<Ti<sub<1.7</sub<(PO<sub<4</sub<)<sub<3</sub< (LATP) hard particles. The composite electrolyte exhibited a good ionic conductivity up to 0.35 mS cm<sup<−1</sup< at 30 °C and an electrochemical window above 4.0 V. In situ and ex situ electrolytes were assembled into LTO//electrolyte//Li solid-state batteries to investigate their impact on the electrochemical performance of the batteries. As a result, the assembled Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub<//in situ electrolytes//Li batteries exhibited excellent rate of performance, and their capacity retention rate was 90% at 0.2 mA/cm<sup<2</sup< after 300 cycles. This work provides a new method for the fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries. Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< atmospheric plasma spraying (APS) in situ solid-state batteries ultraviolet curing (UV-curing) Organic chemistry Yuying Wang verfasserin aut Zhida Liang verfasserin aut Ge Yan verfasserin aut Lingxiao Lan verfasserin aut Yujiang Wang verfasserin aut Xueli Shi verfasserin aut Shuhong Yun verfasserin aut Meihong Huang verfasserin aut In Polymers MDPI AG, 2011 16(2023), 1, p 55 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:16 year:2023 number:1, p 55 https://doi.org/10.3390/polym16010055 kostenfrei https://doaj.org/article/8acc435fb4204e7297936374ce310228 kostenfrei https://www.mdpi.com/2073-4360/16/1/55 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 16 2023 1, p 55
allfieldsGer	10.3390/polym16010055 doi (DE-627)DOAJ097775339 (DE-599)DOAJ8acc435fb4204e7297936374ce310228 DE-627 ger DE-627 rakwb eng QD241-441 Xinghua Liang verfasserin aut Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Lithium-ion solid-state batteries with spinel Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheric plasma spraying method, and a composite solid electrolyte was prepared by in situ ultraviolet (UV) curing on the LTO electrode. The composite solid electrolyte was designed using a soft–hard combination strategy, and the electrolyte was prepared into a composite of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flexible structure and high-conductivity Li<sub<1.3</sub<Al<sub<0.3</sub<Ti<sub<1.7</sub<(PO<sub<4</sub<)<sub<3</sub< (LATP) hard particles. The composite electrolyte exhibited a good ionic conductivity up to 0.35 mS cm<sup<−1</sup< at 30 °C and an electrochemical window above 4.0 V. In situ and ex situ electrolytes were assembled into LTO//electrolyte//Li solid-state batteries to investigate their impact on the electrochemical performance of the batteries. As a result, the assembled Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub<//in situ electrolytes//Li batteries exhibited excellent rate of performance, and their capacity retention rate was 90% at 0.2 mA/cm<sup<2</sup< after 300 cycles. This work provides a new method for the fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries. Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< atmospheric plasma spraying (APS) in situ solid-state batteries ultraviolet curing (UV-curing) Organic chemistry Yuying Wang verfasserin aut Zhida Liang verfasserin aut Ge Yan verfasserin aut Lingxiao Lan verfasserin aut Yujiang Wang verfasserin aut Xueli Shi verfasserin aut Shuhong Yun verfasserin aut Meihong Huang verfasserin aut In Polymers MDPI AG, 2011 16(2023), 1, p 55 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:16 year:2023 number:1, p 55 https://doi.org/10.3390/polym16010055 kostenfrei https://doaj.org/article/8acc435fb4204e7297936374ce310228 kostenfrei https://www.mdpi.com/2073-4360/16/1/55 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 16 2023 1, p 55
allfieldsSound	10.3390/polym16010055 doi (DE-627)DOAJ097775339 (DE-599)DOAJ8acc435fb4204e7297936374ce310228 DE-627 ger DE-627 rakwb eng QD241-441 Xinghua Liang verfasserin aut Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Lithium-ion solid-state batteries with spinel Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheric plasma spraying method, and a composite solid electrolyte was prepared by in situ ultraviolet (UV) curing on the LTO electrode. The composite solid electrolyte was designed using a soft–hard combination strategy, and the electrolyte was prepared into a composite of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flexible structure and high-conductivity Li<sub<1.3</sub<Al<sub<0.3</sub<Ti<sub<1.7</sub<(PO<sub<4</sub<)<sub<3</sub< (LATP) hard particles. The composite electrolyte exhibited a good ionic conductivity up to 0.35 mS cm<sup<−1</sup< at 30 °C and an electrochemical window above 4.0 V. In situ and ex situ electrolytes were assembled into LTO//electrolyte//Li solid-state batteries to investigate their impact on the electrochemical performance of the batteries. As a result, the assembled Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub<//in situ electrolytes//Li batteries exhibited excellent rate of performance, and their capacity retention rate was 90% at 0.2 mA/cm<sup<2</sup< after 300 cycles. This work provides a new method for the fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries. Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< atmospheric plasma spraying (APS) in situ solid-state batteries ultraviolet curing (UV-curing) Organic chemistry Yuying Wang verfasserin aut Zhida Liang verfasserin aut Ge Yan verfasserin aut Lingxiao Lan verfasserin aut Yujiang Wang verfasserin aut Xueli Shi verfasserin aut Shuhong Yun verfasserin aut Meihong Huang verfasserin aut In Polymers MDPI AG, 2011 16(2023), 1, p 55 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:16 year:2023 number:1, p 55 https://doi.org/10.3390/polym16010055 kostenfrei https://doaj.org/article/8acc435fb4204e7297936374ce310228 kostenfrei https://www.mdpi.com/2073-4360/16/1/55 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 16 2023 1, p 55
language	English
source	In Polymers 16(2023), 1, p 55 volume:16 year:2023 number:1, p 55
sourceStr	In Polymers 16(2023), 1, p 55 volume:16 year:2023 number:1, p 55
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< atmospheric plasma spraying (APS) in situ solid-state batteries ultraviolet curing (UV-curing) Organic chemistry
isfreeaccess_bool	true
container_title	Polymers
authorswithroles_txt_mv	Xinghua Liang @@aut@@ Yuying Wang @@aut@@ Zhida Liang @@aut@@ Ge Yan @@aut@@ Lingxiao Lan @@aut@@ Yujiang Wang @@aut@@ Xueli Shi @@aut@@ Shuhong Yun @@aut@@ Meihong Huang @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	61409612X
id	DOAJ097775339
language_de	englisch
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callnumber-first	Q - Science
author	Xinghua Liang
spellingShingle	Xinghua Liang misc QD241-441 misc Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< misc atmospheric plasma spraying (APS) misc in situ misc solid-state batteries misc ultraviolet curing (UV-curing) misc Organic chemistry Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries
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topic_title	QD241-441 Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< atmospheric plasma spraying (APS) in situ solid-state batteries ultraviolet curing (UV-curing)
topic	misc QD241-441 misc Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< misc atmospheric plasma spraying (APS) misc in situ misc solid-state batteries misc ultraviolet curing (UV-curing) misc Organic chemistry
topic_unstemmed	misc QD241-441 misc Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< misc atmospheric plasma spraying (APS) misc in situ misc solid-state batteries misc ultraviolet curing (UV-curing) misc Organic chemistry
topic_browse	misc QD241-441 misc Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< misc atmospheric plasma spraying (APS) misc in situ misc solid-state batteries misc ultraviolet curing (UV-curing) misc Organic chemistry
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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title	Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries
ctrlnum	(DE-627)DOAJ097775339 (DE-599)DOAJ8acc435fb4204e7297936374ce310228
title_full	Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries
author_sort	Xinghua Liang
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author_browse	Xinghua Liang Yuying Wang Zhida Liang Ge Yan Lingxiao Lan Yujiang Wang Xueli Shi Shuhong Yun Meihong Huang
container_volume	16
class	QD241-441
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author-letter	Xinghua Liang
doi_str_mv	10.3390/polym16010055
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title_sort	long-cycle stability of in situ ultraviolet curable organic/inorganic composite electrolyte for solid-state batteries
callnumber	QD241-441
title_auth	Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries
abstract	Lithium-ion solid-state batteries with spinel Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheric plasma spraying method, and a composite solid electrolyte was prepared by in situ ultraviolet (UV) curing on the LTO electrode. The composite solid electrolyte was designed using a soft–hard combination strategy, and the electrolyte was prepared into a composite of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flexible structure and high-conductivity Li<sub<1.3</sub<Al<sub<0.3</sub<Ti<sub<1.7</sub<(PO<sub<4</sub<)<sub<3</sub< (LATP) hard particles. The composite electrolyte exhibited a good ionic conductivity up to 0.35 mS cm<sup<−1</sup< at 30 °C and an electrochemical window above 4.0 V. In situ and ex situ electrolytes were assembled into LTO//electrolyte//Li solid-state batteries to investigate their impact on the electrochemical performance of the batteries. As a result, the assembled Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub<//in situ electrolytes//Li batteries exhibited excellent rate of performance, and their capacity retention rate was 90% at 0.2 mA/cm<sup<2</sup< after 300 cycles. This work provides a new method for the fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries.
abstractGer	Lithium-ion solid-state batteries with spinel Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheric plasma spraying method, and a composite solid electrolyte was prepared by in situ ultraviolet (UV) curing on the LTO electrode. The composite solid electrolyte was designed using a soft–hard combination strategy, and the electrolyte was prepared into a composite of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flexible structure and high-conductivity Li<sub<1.3</sub<Al<sub<0.3</sub<Ti<sub<1.7</sub<(PO<sub<4</sub<)<sub<3</sub< (LATP) hard particles. The composite electrolyte exhibited a good ionic conductivity up to 0.35 mS cm<sup<−1</sup< at 30 °C and an electrochemical window above 4.0 V. In situ and ex situ electrolytes were assembled into LTO//electrolyte//Li solid-state batteries to investigate their impact on the electrochemical performance of the batteries. As a result, the assembled Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub<//in situ electrolytes//Li batteries exhibited excellent rate of performance, and their capacity retention rate was 90% at 0.2 mA/cm<sup<2</sup< after 300 cycles. This work provides a new method for the fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries.
abstract_unstemmed	Lithium-ion solid-state batteries with spinel Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub< (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheric plasma spraying method, and a composite solid electrolyte was prepared by in situ ultraviolet (UV) curing on the LTO electrode. The composite solid electrolyte was designed using a soft–hard combination strategy, and the electrolyte was prepared into a composite of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flexible structure and high-conductivity Li<sub<1.3</sub<Al<sub<0.3</sub<Ti<sub<1.7</sub<(PO<sub<4</sub<)<sub<3</sub< (LATP) hard particles. The composite electrolyte exhibited a good ionic conductivity up to 0.35 mS cm<sup<−1</sup< at 30 °C and an electrochemical window above 4.0 V. In situ and ex situ electrolytes were assembled into LTO//electrolyte//Li solid-state batteries to investigate their impact on the electrochemical performance of the batteries. As a result, the assembled Li<sub<4</sub<Ti<sub<5</sub<O<sub<12</sub<//in situ electrolytes//Li batteries exhibited excellent rate of performance, and their capacity retention rate was 90% at 0.2 mA/cm<sup<2</sup< after 300 cycles. This work provides a new method for the fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries.
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container_issue	1, p 55
title_short	Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries
url	https://doi.org/10.3390/polym16010055 https://doaj.org/article/8acc435fb4204e7297936374ce310228 https://www.mdpi.com/2073-4360/16/1/55 https://doaj.org/toc/2073-4360
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up_date	2024-07-03T13:42:52.318Z
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