Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries

Sodium batteries are receiving increasing interest as an alternative to reduce dependence on lithium-based systems. Furthermore, the development of solid-state electrolytes will lead to higher-performing and safer devices. In this work, a Zn-based metal–organic framework (Zn-MOF-74) is combined as a...
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Autor*in:	Alexander Mirandona-Olaeta [verfasserIn] Eider Goikolea [verfasserIn] Senentxu Lanceros-Mendez [verfasserIn] Arkaitz Fidalgo-Marijuan [verfasserIn] Idoia Ruiz de Larramendi [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	metal–organic framework ionic liquid solid-state electrolyte sodium battery

Übergeordnetes Werk:	In: Batteries - MDPI AG, 2016, 9(2023), 12, p 588
Übergeordnetes Werk:	volume:9 ; year:2023 ; number:12, p 588

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/batteries9120588

Katalog-ID:	DOAJ098912070

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allfields	10.3390/batteries9120588 doi (DE-627)DOAJ098912070 (DE-599)DOAJ4df4e580b9d440c6b9045c65b07f400d DE-627 ger DE-627 rakwb eng TK1001-1841 TP250-261 Alexander Mirandona-Olaeta verfasserin aut Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Sodium batteries are receiving increasing interest as an alternative to reduce dependence on lithium-based systems. Furthermore, the development of solid-state electrolytes will lead to higher-performing and safer devices. In this work, a Zn-based metal–organic framework (Zn-MOF-74) is combined as a physical barrier against the growth of dendrites, together with 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIm][TFSI]) ionic liquid, which provides improved mobility to sodium ions. It is demonstrated that the incorporation of the appropriate amount of ionic liquid within the pores of the MOF produces a considerable increase in ionic conductivity, achieving values as high as 5 × 10<sup<−4</sup< S cm<sup<−1</sup< at room temperature, in addition to an acceptable Na<sup<+</sup< transference number. Furthermore, the developed Na[EMIm][TFSI]Zn-MOF-74 hybrid solid electrolyte contributes to stable and dendrite-free sodium plating/stripping for more than 100 h. Finally, a more than notable extension of the electrochemical stability window of the electrolyte has been determined, being useful even above 7 V vs. Na<sup<+</sup</Na. Overall, this work presents a suitable strategy for the next generation of solid-state sodium batteries. metal–organic framework ionic liquid solid-state electrolyte sodium battery Production of electric energy or power. Powerplants. Central stations Industrial electrochemistry Eider Goikolea verfasserin aut Senentxu Lanceros-Mendez verfasserin aut Arkaitz Fidalgo-Marijuan verfasserin aut Idoia Ruiz de Larramendi verfasserin aut In Batteries MDPI AG, 2016 9(2023), 12, p 588 (DE-627)820684066 (DE-600)2813972-0 23130105 nnns volume:9 year:2023 number:12, p 588 https://doi.org/10.3390/batteries9120588 kostenfrei https://doaj.org/article/4df4e580b9d440c6b9045c65b07f400d kostenfrei https://www.mdpi.com/2313-0105/9/12/588 kostenfrei https://doaj.org/toc/2313-0105 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2023 12, p 588
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allfieldsGer	10.3390/batteries9120588 doi (DE-627)DOAJ098912070 (DE-599)DOAJ4df4e580b9d440c6b9045c65b07f400d DE-627 ger DE-627 rakwb eng TK1001-1841 TP250-261 Alexander Mirandona-Olaeta verfasserin aut Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Sodium batteries are receiving increasing interest as an alternative to reduce dependence on lithium-based systems. Furthermore, the development of solid-state electrolytes will lead to higher-performing and safer devices. In this work, a Zn-based metal–organic framework (Zn-MOF-74) is combined as a physical barrier against the growth of dendrites, together with 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIm][TFSI]) ionic liquid, which provides improved mobility to sodium ions. It is demonstrated that the incorporation of the appropriate amount of ionic liquid within the pores of the MOF produces a considerable increase in ionic conductivity, achieving values as high as 5 × 10<sup<−4</sup< S cm<sup<−1</sup< at room temperature, in addition to an acceptable Na<sup<+</sup< transference number. Furthermore, the developed Na[EMIm][TFSI]Zn-MOF-74 hybrid solid electrolyte contributes to stable and dendrite-free sodium plating/stripping for more than 100 h. Finally, a more than notable extension of the electrochemical stability window of the electrolyte has been determined, being useful even above 7 V vs. Na<sup<+</sup</Na. Overall, this work presents a suitable strategy for the next generation of solid-state sodium batteries. metal–organic framework ionic liquid solid-state electrolyte sodium battery Production of electric energy or power. Powerplants. Central stations Industrial electrochemistry Eider Goikolea verfasserin aut Senentxu Lanceros-Mendez verfasserin aut Arkaitz Fidalgo-Marijuan verfasserin aut Idoia Ruiz de Larramendi verfasserin aut In Batteries MDPI AG, 2016 9(2023), 12, p 588 (DE-627)820684066 (DE-600)2813972-0 23130105 nnns volume:9 year:2023 number:12, p 588 https://doi.org/10.3390/batteries9120588 kostenfrei https://doaj.org/article/4df4e580b9d440c6b9045c65b07f400d kostenfrei https://www.mdpi.com/2313-0105/9/12/588 kostenfrei https://doaj.org/toc/2313-0105 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2023 12, p 588
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authorswithroles_txt_mv	Alexander Mirandona-Olaeta @@aut@@ Eider Goikolea @@aut@@ Senentxu Lanceros-Mendez @@aut@@ Arkaitz Fidalgo-Marijuan @@aut@@ Idoia Ruiz de Larramendi @@aut@@
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callnumber-first	T - Technology
author	Alexander Mirandona-Olaeta
spellingShingle	Alexander Mirandona-Olaeta misc TK1001-1841 misc TP250-261 misc metal–organic framework misc ionic liquid misc solid-state electrolyte misc sodium battery misc Production of electric energy or power. Powerplants. Central stations misc Industrial electrochemistry Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries
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topic_title	TK1001-1841 TP250-261 Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries metal–organic framework ionic liquid solid-state electrolyte sodium battery
topic	misc TK1001-1841 misc TP250-261 misc metal–organic framework misc ionic liquid misc solid-state electrolyte misc sodium battery misc Production of electric energy or power. Powerplants. Central stations misc Industrial electrochemistry
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title	Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries
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title_full	Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries
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author_browse	Alexander Mirandona-Olaeta Eider Goikolea Senentxu Lanceros-Mendez Arkaitz Fidalgo-Marijuan Idoia Ruiz de Larramendi
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title_sort	ionic liquid-laden zn-mof-74-based solid-state electrolyte for sodium batteries
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title_auth	Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries
abstract	Sodium batteries are receiving increasing interest as an alternative to reduce dependence on lithium-based systems. Furthermore, the development of solid-state electrolytes will lead to higher-performing and safer devices. In this work, a Zn-based metal–organic framework (Zn-MOF-74) is combined as a physical barrier against the growth of dendrites, together with 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIm][TFSI]) ionic liquid, which provides improved mobility to sodium ions. It is demonstrated that the incorporation of the appropriate amount of ionic liquid within the pores of the MOF produces a considerable increase in ionic conductivity, achieving values as high as 5 × 10<sup<−4</sup< S cm<sup<−1</sup< at room temperature, in addition to an acceptable Na<sup<+</sup< transference number. Furthermore, the developed Na[EMIm][TFSI]Zn-MOF-74 hybrid solid electrolyte contributes to stable and dendrite-free sodium plating/stripping for more than 100 h. Finally, a more than notable extension of the electrochemical stability window of the electrolyte has been determined, being useful even above 7 V vs. Na<sup<+</sup</Na. Overall, this work presents a suitable strategy for the next generation of solid-state sodium batteries.
abstractGer	Sodium batteries are receiving increasing interest as an alternative to reduce dependence on lithium-based systems. Furthermore, the development of solid-state electrolytes will lead to higher-performing and safer devices. In this work, a Zn-based metal–organic framework (Zn-MOF-74) is combined as a physical barrier against the growth of dendrites, together with 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIm][TFSI]) ionic liquid, which provides improved mobility to sodium ions. It is demonstrated that the incorporation of the appropriate amount of ionic liquid within the pores of the MOF produces a considerable increase in ionic conductivity, achieving values as high as 5 × 10<sup<−4</sup< S cm<sup<−1</sup< at room temperature, in addition to an acceptable Na<sup<+</sup< transference number. Furthermore, the developed Na[EMIm][TFSI]Zn-MOF-74 hybrid solid electrolyte contributes to stable and dendrite-free sodium plating/stripping for more than 100 h. Finally, a more than notable extension of the electrochemical stability window of the electrolyte has been determined, being useful even above 7 V vs. Na<sup<+</sup</Na. Overall, this work presents a suitable strategy for the next generation of solid-state sodium batteries.
abstract_unstemmed	Sodium batteries are receiving increasing interest as an alternative to reduce dependence on lithium-based systems. Furthermore, the development of solid-state electrolytes will lead to higher-performing and safer devices. In this work, a Zn-based metal–organic framework (Zn-MOF-74) is combined as a physical barrier against the growth of dendrites, together with 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIm][TFSI]) ionic liquid, which provides improved mobility to sodium ions. It is demonstrated that the incorporation of the appropriate amount of ionic liquid within the pores of the MOF produces a considerable increase in ionic conductivity, achieving values as high as 5 × 10<sup<−4</sup< S cm<sup<−1</sup< at room temperature, in addition to an acceptable Na<sup<+</sup< transference number. Furthermore, the developed Na[EMIm][TFSI]Zn-MOF-74 hybrid solid electrolyte contributes to stable and dendrite-free sodium plating/stripping for more than 100 h. Finally, a more than notable extension of the electrochemical stability window of the electrolyte has been determined, being useful even above 7 V vs. Na<sup<+</sup</Na. Overall, this work presents a suitable strategy for the next generation of solid-state sodium batteries.
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title_short	Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries
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up_date	2024-07-03T19:56:46.463Z
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Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries

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