Evidence of the chemical stability of the garnet-type solid electrolyte Li
The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated o...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Fingerle, Mathias [verfasserIn] Loho, Christoph [verfasserIn] Ferber, Thimo [verfasserIn] Hahn, Horst [verfasserIn] Hausbrand, René [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of power sources - New York, NY [u.a.] : Elsevier, 1976, 366, Seite 72-79 |
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| Übergeordnetes Werk: |
volume:366 ; pages:72-79 |
| DOI / URN: |
10.1016/j.jpowsour.2017.08.109 |
|---|
| Katalog-ID: |
ELV000447609 |
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| 245 | 1 | 0 | |a Evidence of the chemical stability of the garnet-type solid electrolyte Li |
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| 520 | |a The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated on an LLTaO thin film grown by CO2-laser assisted chemical vapor deposition. By annealing of the LLTaO thin film, the Li2CO3 surface layer can be removed, leaving only small traces of Li2CO3, Li2O2 and Li2O behind. The interface formation of LLTaO towards lithium is then monitored by means of X-ray and ultraviolet photoelectron spectroscopy. Neither reaction products related to decomposition nor structural changes in the matrix of the Ta-based garnet-type solid-electrolyte can be detected, indicating that LLTaO exhibits chemical stability under equilibrium conditions. Furthermore, a model for the energy level alignment at the LLTaO/Li interface is discussed. | ||
| 650 | 4 | |a Garnet-type solid electrolyte | |
| 650 | 4 | |a Photoelectron spectroscopy | |
| 650 | 4 | |a CO | |
| 650 | 4 | |a Interface stability | |
| 650 | 4 | |a Electrolyte-electrode interface | |
| 650 | 4 | |a All-solid-state battery | |
| 700 | 1 | |a Loho, Christoph |e verfasserin |4 aut | |
| 700 | 1 | |a Ferber, Thimo |e verfasserin |4 aut | |
| 700 | 1 | |a Hahn, Horst |e verfasserin |4 aut | |
| 700 | 1 | |a Hausbrand, René |e verfasserin |4 aut | |
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10.1016/j.jpowsour.2017.08.109 doi (DE-627)ELV000447609 (ELSEVIER)S0378-7753(17)31142-4 DE-627 ger DE-627 rda eng 620 DE-600 52.57 bkl 53.36 bkl Fingerle, Mathias verfasserin (orcid)0000-0002-5416-7055 aut Evidence of the chemical stability of the garnet-type solid electrolyte Li 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated on an LLTaO thin film grown by CO2-laser assisted chemical vapor deposition. By annealing of the LLTaO thin film, the Li2CO3 surface layer can be removed, leaving only small traces of Li2CO3, Li2O2 and Li2O behind. The interface formation of LLTaO towards lithium is then monitored by means of X-ray and ultraviolet photoelectron spectroscopy. Neither reaction products related to decomposition nor structural changes in the matrix of the Ta-based garnet-type solid-electrolyte can be detected, indicating that LLTaO exhibits chemical stability under equilibrium conditions. Furthermore, a model for the energy level alignment at the LLTaO/Li interface is discussed. Garnet-type solid electrolyte Photoelectron spectroscopy CO Interface stability Electrolyte-electrode interface All-solid-state battery Loho, Christoph verfasserin aut Ferber, Thimo verfasserin aut Hahn, Horst verfasserin aut Hausbrand, René verfasserin aut Enthalten in Journal of power sources New York, NY [u.a.] : Elsevier, 1976 366, Seite 72-79 Online-Ressource (DE-627)302718923 (DE-600)1491915-1 (DE-576)259483958 1873-2755 nnns volume:366 pages:72-79 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.57 Energiespeicherung 53.36 Energiedirektumwandler elektrische Energiespeicher AR 366 72-79 |
| spelling |
10.1016/j.jpowsour.2017.08.109 doi (DE-627)ELV000447609 (ELSEVIER)S0378-7753(17)31142-4 DE-627 ger DE-627 rda eng 620 DE-600 52.57 bkl 53.36 bkl Fingerle, Mathias verfasserin (orcid)0000-0002-5416-7055 aut Evidence of the chemical stability of the garnet-type solid electrolyte Li 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated on an LLTaO thin film grown by CO2-laser assisted chemical vapor deposition. By annealing of the LLTaO thin film, the Li2CO3 surface layer can be removed, leaving only small traces of Li2CO3, Li2O2 and Li2O behind. The interface formation of LLTaO towards lithium is then monitored by means of X-ray and ultraviolet photoelectron spectroscopy. Neither reaction products related to decomposition nor structural changes in the matrix of the Ta-based garnet-type solid-electrolyte can be detected, indicating that LLTaO exhibits chemical stability under equilibrium conditions. Furthermore, a model for the energy level alignment at the LLTaO/Li interface is discussed. Garnet-type solid electrolyte Photoelectron spectroscopy CO Interface stability Electrolyte-electrode interface All-solid-state battery Loho, Christoph verfasserin aut Ferber, Thimo verfasserin aut Hahn, Horst verfasserin aut Hausbrand, René verfasserin aut Enthalten in Journal of power sources New York, NY [u.a.] : Elsevier, 1976 366, Seite 72-79 Online-Ressource (DE-627)302718923 (DE-600)1491915-1 (DE-576)259483958 1873-2755 nnns volume:366 pages:72-79 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.57 Energiespeicherung 53.36 Energiedirektumwandler elektrische Energiespeicher AR 366 72-79 |
| allfields_unstemmed |
10.1016/j.jpowsour.2017.08.109 doi (DE-627)ELV000447609 (ELSEVIER)S0378-7753(17)31142-4 DE-627 ger DE-627 rda eng 620 DE-600 52.57 bkl 53.36 bkl Fingerle, Mathias verfasserin (orcid)0000-0002-5416-7055 aut Evidence of the chemical stability of the garnet-type solid electrolyte Li 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated on an LLTaO thin film grown by CO2-laser assisted chemical vapor deposition. By annealing of the LLTaO thin film, the Li2CO3 surface layer can be removed, leaving only small traces of Li2CO3, Li2O2 and Li2O behind. The interface formation of LLTaO towards lithium is then monitored by means of X-ray and ultraviolet photoelectron spectroscopy. Neither reaction products related to decomposition nor structural changes in the matrix of the Ta-based garnet-type solid-electrolyte can be detected, indicating that LLTaO exhibits chemical stability under equilibrium conditions. Furthermore, a model for the energy level alignment at the LLTaO/Li interface is discussed. Garnet-type solid electrolyte Photoelectron spectroscopy CO Interface stability Electrolyte-electrode interface All-solid-state battery Loho, Christoph verfasserin aut Ferber, Thimo verfasserin aut Hahn, Horst verfasserin aut Hausbrand, René verfasserin aut Enthalten in Journal of power sources New York, NY [u.a.] : Elsevier, 1976 366, Seite 72-79 Online-Ressource (DE-627)302718923 (DE-600)1491915-1 (DE-576)259483958 1873-2755 nnns volume:366 pages:72-79 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.57 Energiespeicherung 53.36 Energiedirektumwandler elektrische Energiespeicher AR 366 72-79 |
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10.1016/j.jpowsour.2017.08.109 doi (DE-627)ELV000447609 (ELSEVIER)S0378-7753(17)31142-4 DE-627 ger DE-627 rda eng 620 DE-600 52.57 bkl 53.36 bkl Fingerle, Mathias verfasserin (orcid)0000-0002-5416-7055 aut Evidence of the chemical stability of the garnet-type solid electrolyte Li 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated on an LLTaO thin film grown by CO2-laser assisted chemical vapor deposition. By annealing of the LLTaO thin film, the Li2CO3 surface layer can be removed, leaving only small traces of Li2CO3, Li2O2 and Li2O behind. The interface formation of LLTaO towards lithium is then monitored by means of X-ray and ultraviolet photoelectron spectroscopy. Neither reaction products related to decomposition nor structural changes in the matrix of the Ta-based garnet-type solid-electrolyte can be detected, indicating that LLTaO exhibits chemical stability under equilibrium conditions. Furthermore, a model for the energy level alignment at the LLTaO/Li interface is discussed. Garnet-type solid electrolyte Photoelectron spectroscopy CO Interface stability Electrolyte-electrode interface All-solid-state battery Loho, Christoph verfasserin aut Ferber, Thimo verfasserin aut Hahn, Horst verfasserin aut Hausbrand, René verfasserin aut Enthalten in Journal of power sources New York, NY [u.a.] : Elsevier, 1976 366, Seite 72-79 Online-Ressource (DE-627)302718923 (DE-600)1491915-1 (DE-576)259483958 1873-2755 nnns volume:366 pages:72-79 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.57 Energiespeicherung 53.36 Energiedirektumwandler elektrische Energiespeicher AR 366 72-79 |
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10.1016/j.jpowsour.2017.08.109 doi (DE-627)ELV000447609 (ELSEVIER)S0378-7753(17)31142-4 DE-627 ger DE-627 rda eng 620 DE-600 52.57 bkl 53.36 bkl Fingerle, Mathias verfasserin (orcid)0000-0002-5416-7055 aut Evidence of the chemical stability of the garnet-type solid electrolyte Li 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated on an LLTaO thin film grown by CO2-laser assisted chemical vapor deposition. By annealing of the LLTaO thin film, the Li2CO3 surface layer can be removed, leaving only small traces of Li2CO3, Li2O2 and Li2O behind. The interface formation of LLTaO towards lithium is then monitored by means of X-ray and ultraviolet photoelectron spectroscopy. Neither reaction products related to decomposition nor structural changes in the matrix of the Ta-based garnet-type solid-electrolyte can be detected, indicating that LLTaO exhibits chemical stability under equilibrium conditions. Furthermore, a model for the energy level alignment at the LLTaO/Li interface is discussed. Garnet-type solid electrolyte Photoelectron spectroscopy CO Interface stability Electrolyte-electrode interface All-solid-state battery Loho, Christoph verfasserin aut Ferber, Thimo verfasserin aut Hahn, Horst verfasserin aut Hausbrand, René verfasserin aut Enthalten in Journal of power sources New York, NY [u.a.] : Elsevier, 1976 366, Seite 72-79 Online-Ressource (DE-627)302718923 (DE-600)1491915-1 (DE-576)259483958 1873-2755 nnns volume:366 pages:72-79 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.57 Energiespeicherung 53.36 Energiedirektumwandler elektrische Energiespeicher AR 366 72-79 |
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Enthalten in Journal of power sources 366, Seite 72-79 volume:366 pages:72-79 |
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Garnet-type solid electrolyte Photoelectron spectroscopy CO Interface stability Electrolyte-electrode interface All-solid-state battery |
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Fingerle, Mathias @@aut@@ Loho, Christoph @@aut@@ Ferber, Thimo @@aut@@ Hahn, Horst @@aut@@ Hausbrand, René @@aut@@ |
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Fingerle, Mathias |
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Fingerle, Mathias ddc 620 bkl 52.57 bkl 53.36 misc Garnet-type solid electrolyte misc Photoelectron spectroscopy misc CO misc Interface stability misc Electrolyte-electrode interface misc All-solid-state battery Evidence of the chemical stability of the garnet-type solid electrolyte Li |
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620 DE-600 52.57 bkl 53.36 bkl Evidence of the chemical stability of the garnet-type solid electrolyte Li Garnet-type solid electrolyte Photoelectron spectroscopy CO Interface stability Electrolyte-electrode interface All-solid-state battery |
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Evidence of the chemical stability of the garnet-type solid electrolyte Li |
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Fingerle, Mathias Loho, Christoph Ferber, Thimo Hahn, Horst Hausbrand, René |
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evidence of the chemical stability of the garnet-type solid electrolyte li |
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Evidence of the chemical stability of the garnet-type solid electrolyte Li |
| abstract |
The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated on an LLTaO thin film grown by CO2-laser assisted chemical vapor deposition. By annealing of the LLTaO thin film, the Li2CO3 surface layer can be removed, leaving only small traces of Li2CO3, Li2O2 and Li2O behind. The interface formation of LLTaO towards lithium is then monitored by means of X-ray and ultraviolet photoelectron spectroscopy. Neither reaction products related to decomposition nor structural changes in the matrix of the Ta-based garnet-type solid-electrolyte can be detected, indicating that LLTaO exhibits chemical stability under equilibrium conditions. Furthermore, a model for the energy level alignment at the LLTaO/Li interface is discussed. |
| abstractGer |
The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated on an LLTaO thin film grown by CO2-laser assisted chemical vapor deposition. By annealing of the LLTaO thin film, the Li2CO3 surface layer can be removed, leaving only small traces of Li2CO3, Li2O2 and Li2O behind. The interface formation of LLTaO towards lithium is then monitored by means of X-ray and ultraviolet photoelectron spectroscopy. Neither reaction products related to decomposition nor structural changes in the matrix of the Ta-based garnet-type solid-electrolyte can be detected, indicating that LLTaO exhibits chemical stability under equilibrium conditions. Furthermore, a model for the energy level alignment at the LLTaO/Li interface is discussed. |
| abstract_unstemmed |
The chemical stability between Li metal and garnet-type solid electrolytes is currently under debate, mainly catalyzed by theoretical studies. Here, we investigate the stability of Li5La3Ta2O12 (LLTaO) towards lithium experimentally. Using a surface science approach, lithium is stepwise evaporated on an LLTaO thin film grown by CO2-laser assisted chemical vapor deposition. By annealing of the LLTaO thin film, the Li2CO3 surface layer can be removed, leaving only small traces of Li2CO3, Li2O2 and Li2O behind. The interface formation of LLTaO towards lithium is then monitored by means of X-ray and ultraviolet photoelectron spectroscopy. Neither reaction products related to decomposition nor structural changes in the matrix of the Ta-based garnet-type solid-electrolyte can be detected, indicating that LLTaO exhibits chemical stability under equilibrium conditions. Furthermore, a model for the energy level alignment at the LLTaO/Li interface is discussed. |
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Evidence of the chemical stability of the garnet-type solid electrolyte Li |
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