TiCr

As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizi...
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Autor*in:	Hu, Lei [verfasserIn] Lu, Ruohan [verfasserIn] Tang, Lingfei [verfasserIn] Xia, Ran [verfasserIn] Lin, Chunfu [verfasserIn] Luo, Zhibin [verfasserIn] Chen, Yongjun [verfasserIn] Li, Jianbao [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2017

Schlagwörter:	Energy storage materials Electrode materials Composite materials Nanofabrications Electrical transport Electrochemical reactions

Übergeordnetes Werk:	Enthalten in: Journal of alloys and compounds - Lausanne : Elsevier, 1991, 732, Seite 116-123
Übergeordnetes Werk:	volume:732 ; pages:116-123

DOI / URN:	10.1016/j.jallcom.2017.10.145

Katalog-ID:	ELV000510106

Internformat


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024	7		\|a 10.1016/j.jallcom.2017.10.145 \|2 doi
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337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage.
650		4	\|a Energy storage materials
650		4	\|a Electrode materials
650		4	\|a Composite materials
650		4	\|a Nanofabrications
650		4	\|a Electrical transport
650		4	\|a Electrochemical reactions
700	1		\|a Lu, Ruohan \|e verfasserin \|4 aut
700	1		\|a Tang, Lingfei \|e verfasserin \|4 aut
700	1		\|a Xia, Ran \|e verfasserin \|4 aut
700	1		\|a Lin, Chunfu \|e verfasserin \|0 (orcid)0000-0003-0251-7938 \|4 aut
700	1		\|a Luo, Zhibin \|e verfasserin \|4 aut
700	1		\|a Chen, Yongjun \|e verfasserin \|4 aut
700	1		\|a Li, Jianbao \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Journal of alloys and compounds \|d Lausanne : Elsevier, 1991 \|g 732, Seite 116-123 \|h Online-Ressource \|w (DE-627)320504646 \|w (DE-600)2012675-X \|w (DE-576)098615009 \|7 nnns
773	1	8	\|g volume:732 \|g pages:116-123
912			\|a GBV_USEFLAG_U
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912			\|a GBV_ELV
912			\|a SSG-OLC-PHA
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912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_101
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_187
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2098
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2188
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2232
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 51.54 \|j Nichteisenmetalle und ihre Legierungen
936	b	k	\|a 33.61 \|j Festkörperphysik
936	b	k	\|a 35.90 \|j Festkörperchemie
951			\|a AR
952			\|d 732 \|h 116-123

Indexfelder

author_variant	l h lh r l rl l t lt r x rx c l cl z l zl y c yc j l jl
matchkey_str	huleiluruohantanglingfeixiaranlinchunful:2017----:i
hierarchy_sort_str	2017
bklnumber	51.54 33.61 35.90
publishDate	2017
allfields	10.1016/j.jallcom.2017.10.145 doi (DE-627)ELV000510106 (ELSEVIER)S0925-8388(17)33581-8 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Hu, Lei verfasserin aut TiCr 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage. Energy storage materials Electrode materials Composite materials Nanofabrications Electrical transport Electrochemical reactions Lu, Ruohan verfasserin aut Tang, Lingfei verfasserin aut Xia, Ran verfasserin aut Lin, Chunfu verfasserin (orcid)0000-0003-0251-7938 aut Luo, Zhibin verfasserin aut Chen, Yongjun verfasserin aut Li, Jianbao verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 732, Seite 116-123 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:732 pages:116-123 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 732 116-123
spelling	10.1016/j.jallcom.2017.10.145 doi (DE-627)ELV000510106 (ELSEVIER)S0925-8388(17)33581-8 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Hu, Lei verfasserin aut TiCr 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage. Energy storage materials Electrode materials Composite materials Nanofabrications Electrical transport Electrochemical reactions Lu, Ruohan verfasserin aut Tang, Lingfei verfasserin aut Xia, Ran verfasserin aut Lin, Chunfu verfasserin (orcid)0000-0003-0251-7938 aut Luo, Zhibin verfasserin aut Chen, Yongjun verfasserin aut Li, Jianbao verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 732, Seite 116-123 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:732 pages:116-123 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 732 116-123
allfields_unstemmed	10.1016/j.jallcom.2017.10.145 doi (DE-627)ELV000510106 (ELSEVIER)S0925-8388(17)33581-8 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Hu, Lei verfasserin aut TiCr 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage. Energy storage materials Electrode materials Composite materials Nanofabrications Electrical transport Electrochemical reactions Lu, Ruohan verfasserin aut Tang, Lingfei verfasserin aut Xia, Ran verfasserin aut Lin, Chunfu verfasserin (orcid)0000-0003-0251-7938 aut Luo, Zhibin verfasserin aut Chen, Yongjun verfasserin aut Li, Jianbao verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 732, Seite 116-123 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:732 pages:116-123 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 732 116-123
allfieldsGer	10.1016/j.jallcom.2017.10.145 doi (DE-627)ELV000510106 (ELSEVIER)S0925-8388(17)33581-8 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Hu, Lei verfasserin aut TiCr 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage. Energy storage materials Electrode materials Composite materials Nanofabrications Electrical transport Electrochemical reactions Lu, Ruohan verfasserin aut Tang, Lingfei verfasserin aut Xia, Ran verfasserin aut Lin, Chunfu verfasserin (orcid)0000-0003-0251-7938 aut Luo, Zhibin verfasserin aut Chen, Yongjun verfasserin aut Li, Jianbao verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 732, Seite 116-123 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:732 pages:116-123 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 732 116-123
allfieldsSound	10.1016/j.jallcom.2017.10.145 doi (DE-627)ELV000510106 (ELSEVIER)S0925-8388(17)33581-8 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Hu, Lei verfasserin aut TiCr 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage. Energy storage materials Electrode materials Composite materials Nanofabrications Electrical transport Electrochemical reactions Lu, Ruohan verfasserin aut Tang, Lingfei verfasserin aut Xia, Ran verfasserin aut Lin, Chunfu verfasserin (orcid)0000-0003-0251-7938 aut Luo, Zhibin verfasserin aut Chen, Yongjun verfasserin aut Li, Jianbao verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 732, Seite 116-123 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:732 pages:116-123 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 732 116-123
language	English
source	Enthalten in Journal of alloys and compounds 732, Seite 116-123 volume:732 pages:116-123
sourceStr	Enthalten in Journal of alloys and compounds 732, Seite 116-123 volume:732 pages:116-123
format_phy_str_mv	Article
bklname	Nichteisenmetalle und ihre Legierungen Festkörperphysik Festkörperchemie
institution	findex.gbv.de
topic_facet	Energy storage materials Electrode materials Composite materials Nanofabrications Electrical transport Electrochemical reactions
dewey-raw	670
isfreeaccess_bool	false
container_title	Journal of alloys and compounds
authorswithroles_txt_mv	Hu, Lei @@aut@@ Lu, Ruohan @@aut@@ Tang, Lingfei @@aut@@ Xia, Ran @@aut@@ Lin, Chunfu @@aut@@ Luo, Zhibin @@aut@@ Chen, Yongjun @@aut@@ Li, Jianbao @@aut@@
publishDateDaySort_date	2017-01-01T00:00:00Z
hierarchy_top_id	320504646
dewey-sort	3670
id	ELV000510106
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV000510106</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524134423.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230427s2017 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jallcom.2017.10.145</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV000510106</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0925-8388(17)33581-8</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="a">540</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.54</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">33.61</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.90</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Hu, Lei</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">TiCr</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). 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author	Hu, Lei
spellingShingle	Hu, Lei ddc 670 bkl 51.54 bkl 33.61 bkl 35.90 misc Energy storage materials misc Electrode materials misc Composite materials misc Nanofabrications misc Electrical transport misc Electrochemical reactions TiCr
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topic_title	670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl TiCr Energy storage materials Electrode materials Composite materials Nanofabrications Electrical transport Electrochemical reactions
topic	ddc 670 bkl 51.54 bkl 33.61 bkl 35.90 misc Energy storage materials misc Electrode materials misc Composite materials misc Nanofabrications misc Electrical transport misc Electrochemical reactions
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title	TiCr
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title_full	TiCr
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author_browse	Hu, Lei Lu, Ruohan Tang, Lingfei Xia, Ran Lin, Chunfu Luo, Zhibin Chen, Yongjun Li, Jianbao
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title_sort	ticr
title_auth	TiCr
abstract	As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage.
abstractGer	As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage.
abstract_unstemmed	As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage.
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title_short	TiCr
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author2	Lu, Ruohan Tang, Lingfei Xia, Ran Lin, Chunfu Luo, Zhibin Chen, Yongjun Li, Jianbao
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doi_str	10.1016/j.jallcom.2017.10.145
up_date	2024-07-06T18:13:08.023Z
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fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV000510106</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524134423.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230427s2017 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jallcom.2017.10.145</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV000510106</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0925-8388(17)33581-8</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="a">540</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.54</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">33.61</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.90</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Hu, Lei</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">TiCr</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">As a recently developed anode material for lithium-ion batteries, Ti2Nb10O29 shows high theoretical/practical capacities and safety, but suffers from a poor rate capability due to its insulator nature and insufficient Li+-ion diffusion coefficient. To tackle this issue, a strategy combining nanosizing, Cr3+–Nb5+ co-doping and carbon nanotube (CNT) compositing is employed. A novel TiCr0.5Nb10.5O29/CNTs nanocomposite with 9.1 wt% CNTs is fabricated by a direct hydrolysis process followed by calcination in N2. The Cr3+–Nb5+ co-doping significantly improves the electronic conductivity and Li+-ion diffusion coefficient of Ti2Nb10O29 by three orders and one order of magnitude, respectively. The CNT compositing not only enhances the electrical conduction among the TiCr0.5Nb10.5O29 particles but also hinders the particle growth in the hydrolysis process, leading to the small particle sizes. Due to the synergistic effect of these advantages, the TiCr0.5Nb10.5O29/CNTs nanocomposite exhibits a high rate capability with a high capacity of 206 mAh g−1 at 20 C, surpassing those of Ti2Nb10O29 (145 mAh g−1) and TiCr0.5Nb10.5O29 nanoparticles (187 mAh g−1). Additionally, TiCr0.5Nb10.5O29/CNTs delivers a high reversible capacity (297 mAh g−1 at 0.1 C) and cyclic stability (95.0% capacity retention after 100 cycles at 10 C). This good electrochemical performance reveals that TiCr0.5Nb10.5O29/CNTs can be an advanced anode material for high-performance Li+-ion storage.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Energy storage materials</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Electrode materials</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Composite materials</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nanofabrications</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Electrical transport</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Electrochemical reactions</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lu, Ruohan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield 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