A comparative study of LiTi

NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound...
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Gespeichert in:

Autor*in:	Pang, Jianyu [verfasserIn] Kuang, Quan [verfasserIn] Zhao, Yanming [verfasserIn] Han, Wei [verfasserIn] Fan, Qinghua [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2017

Schlagwörter:	LiTi Li-ion batteries Anode material Electrochemical performance

Übergeordnetes Werk:	Enthalten in: Electrochimica acta - New York, NY [u.a.] : Elsevier, 1959, 260, Seite 384-390
Übergeordnetes Werk:	volume:260 ; pages:384-390

DOI / URN:	10.1016/j.electacta.2017.12.073

Katalog-ID:	ELV000640670

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520			\|a NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound LiTi2(P8/9V1/9O4)3 (LTPV) has been synthesized by using a selective vanadic source of Li3VO4 at an adjusted sintering temperature of 700 °C. The PO4 3− radicals partly replaced by VO4 3− radicals are confirmed via XRD refinement, SEM, Raman and infrared spectra. The electronic conductivity of LTPV is two orders of magnitude higher than that of the undoped one, and meanwhile the charge-transfer impedance observably decreases after V substitution. More importantly, the V5+ cations are electrochemical active in LTPV and contribute additional capacity during discharge and recharge processes. Benefitted from the increased electronic conductivity and the reduced charge-transfer impedance, the rate performance of LTPV is also distinctly improved when compared with the pristine LTP.
650		4	\|a LiTi
650		4	\|a LiTi
650		4	\|a Li-ion batteries
650		4	\|a Anode material
650		4	\|a Electrochemical performance
700	1		\|a Kuang, Quan \|e verfasserin \|4 aut
700	1		\|a Zhao, Yanming \|e verfasserin \|4 aut
700	1		\|a Han, Wei \|e verfasserin \|4 aut
700	1		\|a Fan, Qinghua \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Electrochimica acta \|d New York, NY [u.a.] : Elsevier, 1959 \|g 260, Seite 384-390 \|h Online-Ressource \|w (DE-627)300897561 \|w (DE-600)1483548-4 \|w (DE-576)094752451 \|x 1873-3859 \|7 nnns
773	1	8	\|g volume:260 \|g pages:384-390
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936	b	k	\|a 35.00 \|j Chemie: Allgemeines
951			\|a AR
952			\|d 260 \|h 384-390

Indexfelder

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matchkey_str	article:18733859:2017----::cmaaiet
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publishDate	2017
allfields	10.1016/j.electacta.2017.12.073 doi (DE-627)ELV000640670 (ELSEVIER)S0013-4686(17)32633-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Pang, Jianyu verfasserin aut A comparative study of LiTi 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound LiTi2(P8/9V1/9O4)3 (LTPV) has been synthesized by using a selective vanadic source of Li3VO4 at an adjusted sintering temperature of 700 °C. The PO4 3− radicals partly replaced by VO4 3− radicals are confirmed via XRD refinement, SEM, Raman and infrared spectra. The electronic conductivity of LTPV is two orders of magnitude higher than that of the undoped one, and meanwhile the charge-transfer impedance observably decreases after V substitution. More importantly, the V5+ cations are electrochemical active in LTPV and contribute additional capacity during discharge and recharge processes. Benefitted from the increased electronic conductivity and the reduced charge-transfer impedance, the rate performance of LTPV is also distinctly improved when compared with the pristine LTP. LiTi LiTi Li-ion batteries Anode material Electrochemical performance Kuang, Quan verfasserin aut Zhao, Yanming verfasserin aut Han, Wei verfasserin aut Fan, Qinghua verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 260, Seite 384-390 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:260 pages:384-390 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 260 384-390
spelling	10.1016/j.electacta.2017.12.073 doi (DE-627)ELV000640670 (ELSEVIER)S0013-4686(17)32633-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Pang, Jianyu verfasserin aut A comparative study of LiTi 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound LiTi2(P8/9V1/9O4)3 (LTPV) has been synthesized by using a selective vanadic source of Li3VO4 at an adjusted sintering temperature of 700 °C. The PO4 3− radicals partly replaced by VO4 3− radicals are confirmed via XRD refinement, SEM, Raman and infrared spectra. The electronic conductivity of LTPV is two orders of magnitude higher than that of the undoped one, and meanwhile the charge-transfer impedance observably decreases after V substitution. More importantly, the V5+ cations are electrochemical active in LTPV and contribute additional capacity during discharge and recharge processes. Benefitted from the increased electronic conductivity and the reduced charge-transfer impedance, the rate performance of LTPV is also distinctly improved when compared with the pristine LTP. LiTi LiTi Li-ion batteries Anode material Electrochemical performance Kuang, Quan verfasserin aut Zhao, Yanming verfasserin aut Han, Wei verfasserin aut Fan, Qinghua verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 260, Seite 384-390 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:260 pages:384-390 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 260 384-390
allfields_unstemmed	10.1016/j.electacta.2017.12.073 doi (DE-627)ELV000640670 (ELSEVIER)S0013-4686(17)32633-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Pang, Jianyu verfasserin aut A comparative study of LiTi 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound LiTi2(P8/9V1/9O4)3 (LTPV) has been synthesized by using a selective vanadic source of Li3VO4 at an adjusted sintering temperature of 700 °C. The PO4 3− radicals partly replaced by VO4 3− radicals are confirmed via XRD refinement, SEM, Raman and infrared spectra. The electronic conductivity of LTPV is two orders of magnitude higher than that of the undoped one, and meanwhile the charge-transfer impedance observably decreases after V substitution. More importantly, the V5+ cations are electrochemical active in LTPV and contribute additional capacity during discharge and recharge processes. Benefitted from the increased electronic conductivity and the reduced charge-transfer impedance, the rate performance of LTPV is also distinctly improved when compared with the pristine LTP. LiTi LiTi Li-ion batteries Anode material Electrochemical performance Kuang, Quan verfasserin aut Zhao, Yanming verfasserin aut Han, Wei verfasserin aut Fan, Qinghua verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 260, Seite 384-390 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:260 pages:384-390 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 260 384-390
allfieldsGer	10.1016/j.electacta.2017.12.073 doi (DE-627)ELV000640670 (ELSEVIER)S0013-4686(17)32633-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Pang, Jianyu verfasserin aut A comparative study of LiTi 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound LiTi2(P8/9V1/9O4)3 (LTPV) has been synthesized by using a selective vanadic source of Li3VO4 at an adjusted sintering temperature of 700 °C. The PO4 3− radicals partly replaced by VO4 3− radicals are confirmed via XRD refinement, SEM, Raman and infrared spectra. The electronic conductivity of LTPV is two orders of magnitude higher than that of the undoped one, and meanwhile the charge-transfer impedance observably decreases after V substitution. More importantly, the V5+ cations are electrochemical active in LTPV and contribute additional capacity during discharge and recharge processes. Benefitted from the increased electronic conductivity and the reduced charge-transfer impedance, the rate performance of LTPV is also distinctly improved when compared with the pristine LTP. LiTi LiTi Li-ion batteries Anode material Electrochemical performance Kuang, Quan verfasserin aut Zhao, Yanming verfasserin aut Han, Wei verfasserin aut Fan, Qinghua verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 260, Seite 384-390 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:260 pages:384-390 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 260 384-390
allfieldsSound	10.1016/j.electacta.2017.12.073 doi (DE-627)ELV000640670 (ELSEVIER)S0013-4686(17)32633-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Pang, Jianyu verfasserin aut A comparative study of LiTi 2017 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound LiTi2(P8/9V1/9O4)3 (LTPV) has been synthesized by using a selective vanadic source of Li3VO4 at an adjusted sintering temperature of 700 °C. The PO4 3− radicals partly replaced by VO4 3− radicals are confirmed via XRD refinement, SEM, Raman and infrared spectra. The electronic conductivity of LTPV is two orders of magnitude higher than that of the undoped one, and meanwhile the charge-transfer impedance observably decreases after V substitution. More importantly, the V5+ cations are electrochemical active in LTPV and contribute additional capacity during discharge and recharge processes. Benefitted from the increased electronic conductivity and the reduced charge-transfer impedance, the rate performance of LTPV is also distinctly improved when compared with the pristine LTP. LiTi LiTi Li-ion batteries Anode material Electrochemical performance Kuang, Quan verfasserin aut Zhao, Yanming verfasserin aut Han, Wei verfasserin aut Fan, Qinghua verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 260, Seite 384-390 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:260 pages:384-390 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2098 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 260 384-390
language	English
source	Enthalten in Electrochimica acta 260, Seite 384-390 volume:260 pages:384-390
sourceStr	Enthalten in Electrochimica acta 260, Seite 384-390 volume:260 pages:384-390
format_phy_str_mv	Article
bklname	Chemie: Allgemeines
institution	findex.gbv.de
topic_facet	LiTi Li-ion batteries Anode material Electrochemical performance
dewey-raw	540
isfreeaccess_bool	false
container_title	Electrochimica acta
authorswithroles_txt_mv	Pang, Jianyu @@aut@@ Kuang, Quan @@aut@@ Zhao, Yanming @@aut@@ Han, Wei @@aut@@ Fan, Qinghua @@aut@@
publishDateDaySort_date	2017-01-01T00:00:00Z
hierarchy_top_id	300897561
dewey-sort	3540
id	ELV000640670
language_de	englisch
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author	Pang, Jianyu
spellingShingle	Pang, Jianyu ddc 540 bkl 35.00 misc LiTi misc Li-ion batteries misc Anode material misc Electrochemical performance A comparative study of LiTi
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topic_title	540 DE-600 35.00 bkl A comparative study of LiTi LiTi Li-ion batteries Anode material Electrochemical performance
topic	ddc 540 bkl 35.00 misc LiTi misc Li-ion batteries misc Anode material misc Electrochemical performance
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title	A comparative study of LiTi
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title_full	A comparative study of LiTi
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title_sort	a comparative study of liti
title_auth	A comparative study of LiTi
abstract	NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound LiTi2(P8/9V1/9O4)3 (LTPV) has been synthesized by using a selective vanadic source of Li3VO4 at an adjusted sintering temperature of 700 °C. The PO4 3− radicals partly replaced by VO4 3− radicals are confirmed via XRD refinement, SEM, Raman and infrared spectra. The electronic conductivity of LTPV is two orders of magnitude higher than that of the undoped one, and meanwhile the charge-transfer impedance observably decreases after V substitution. More importantly, the V5+ cations are electrochemical active in LTPV and contribute additional capacity during discharge and recharge processes. Benefitted from the increased electronic conductivity and the reduced charge-transfer impedance, the rate performance of LTPV is also distinctly improved when compared with the pristine LTP.
abstractGer	NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound LiTi2(P8/9V1/9O4)3 (LTPV) has been synthesized by using a selective vanadic source of Li3VO4 at an adjusted sintering temperature of 700 °C. The PO4 3− radicals partly replaced by VO4 3− radicals are confirmed via XRD refinement, SEM, Raman and infrared spectra. The electronic conductivity of LTPV is two orders of magnitude higher than that of the undoped one, and meanwhile the charge-transfer impedance observably decreases after V substitution. More importantly, the V5+ cations are electrochemical active in LTPV and contribute additional capacity during discharge and recharge processes. Benefitted from the increased electronic conductivity and the reduced charge-transfer impedance, the rate performance of LTPV is also distinctly improved when compared with the pristine LTP.
abstract_unstemmed	NASICON-type LiTi2(PO4)3 (LTP) is a representative solid-state electrolyte and promising anode for rechargeable Li batteries. However, the electronic conductivity and specific capacity of LTP anode are encumbered by its massy and sluggish phosphate groups. Herein, vanadium (V) substitution compound LiTi2(P8/9V1/9O4)3 (LTPV) has been synthesized by using a selective vanadic source of Li3VO4 at an adjusted sintering temperature of 700 °C. The PO4 3− radicals partly replaced by VO4 3− radicals are confirmed via XRD refinement, SEM, Raman and infrared spectra. The electronic conductivity of LTPV is two orders of magnitude higher than that of the undoped one, and meanwhile the charge-transfer impedance observably decreases after V substitution. More importantly, the V5+ cations are electrochemical active in LTPV and contribute additional capacity during discharge and recharge processes. Benefitted from the increased electronic conductivity and the reduced charge-transfer impedance, the rate performance of LTPV is also distinctly improved when compared with the pristine LTP.
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title_short	A comparative study of LiTi
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author2	Kuang, Quan Zhao, Yanming Han, Wei Fan, Qinghua
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doi_str	10.1016/j.electacta.2017.12.073
up_date	2024-07-06T18:39:49.942Z
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score	7.399967

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A comparative study of LiTi

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