Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding
In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Chernikov, D.A. [verfasserIn] Shishlyannikova, T.A. [verfasserIn] Kashevskii, A.V. [verfasserIn] Bazhenov, B.N. [verfasserIn] Kuzmin, A.V. [verfasserIn] Gorshkov, A.G. [verfasserIn] Safronov, A.Y. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Electrochimica acta - New York, NY [u.a.] : Elsevier, 1959, 271, Seite 560-566 |
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| Übergeordnetes Werk: |
volume:271 ; pages:560-566 |
| DOI / URN: |
10.1016/j.electacta.2018.03.179 |
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| 520 | |a In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV–vis and MS detection have been coupled. The taxifolin diffusion coefficient has been evaluated in the aqueous solution as 3.63 × 10−6 cm2/s. The experimentally obtained number of electrons per one taxifolin molecule falls between 2 and 3 demonstrating that under electrochemical oxidation conditions only part of initially oxidized taxifolin molecules participates in dimerization and further transformation. | ||
| 650 | 4 | |a Electrooxidation | |
| 650 | 4 | |a Cyclic voltammetry | |
| 650 | 4 | |a Bulk electrolysis | |
| 650 | 4 | |a Taxifolin | |
| 650 | 4 | |a Dimer | |
| 650 | 4 | |a Trimer | |
| 700 | 1 | |a Shishlyannikova, T.A. |e verfasserin |4 aut | |
| 700 | 1 | |a Kashevskii, A.V. |e verfasserin |4 aut | |
| 700 | 1 | |a Bazhenov, B.N. |e verfasserin |4 aut | |
| 700 | 1 | |a Kuzmin, A.V. |e verfasserin |4 aut | |
| 700 | 1 | |a Gorshkov, A.G. |e verfasserin |4 aut | |
| 700 | 1 | |a Safronov, A.Y. |e verfasserin |4 aut | |
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10.1016/j.electacta.2018.03.179 doi (DE-627)ELV000661716 (ELSEVIER)S0013-4686(18)30696-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Chernikov, D.A. verfasserin aut Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV–vis and MS detection have been coupled. The taxifolin diffusion coefficient has been evaluated in the aqueous solution as 3.63 × 10−6 cm2/s. The experimentally obtained number of electrons per one taxifolin molecule falls between 2 and 3 demonstrating that under electrochemical oxidation conditions only part of initially oxidized taxifolin molecules participates in dimerization and further transformation. Electrooxidation Cyclic voltammetry Bulk electrolysis Taxifolin Dimer Trimer Shishlyannikova, T.A. verfasserin aut Kashevskii, A.V. verfasserin aut Bazhenov, B.N. verfasserin aut Kuzmin, A.V. verfasserin aut Gorshkov, A.G. verfasserin aut Safronov, A.Y. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 271, Seite 560-566 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:271 pages:560-566 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 271 560-566 |
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10.1016/j.electacta.2018.03.179 doi (DE-627)ELV000661716 (ELSEVIER)S0013-4686(18)30696-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Chernikov, D.A. verfasserin aut Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV–vis and MS detection have been coupled. The taxifolin diffusion coefficient has been evaluated in the aqueous solution as 3.63 × 10−6 cm2/s. The experimentally obtained number of electrons per one taxifolin molecule falls between 2 and 3 demonstrating that under electrochemical oxidation conditions only part of initially oxidized taxifolin molecules participates in dimerization and further transformation. Electrooxidation Cyclic voltammetry Bulk electrolysis Taxifolin Dimer Trimer Shishlyannikova, T.A. verfasserin aut Kashevskii, A.V. verfasserin aut Bazhenov, B.N. verfasserin aut Kuzmin, A.V. verfasserin aut Gorshkov, A.G. verfasserin aut Safronov, A.Y. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 271, Seite 560-566 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:271 pages:560-566 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 271 560-566 |
| allfields_unstemmed |
10.1016/j.electacta.2018.03.179 doi (DE-627)ELV000661716 (ELSEVIER)S0013-4686(18)30696-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Chernikov, D.A. verfasserin aut Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV–vis and MS detection have been coupled. The taxifolin diffusion coefficient has been evaluated in the aqueous solution as 3.63 × 10−6 cm2/s. The experimentally obtained number of electrons per one taxifolin molecule falls between 2 and 3 demonstrating that under electrochemical oxidation conditions only part of initially oxidized taxifolin molecules participates in dimerization and further transformation. Electrooxidation Cyclic voltammetry Bulk electrolysis Taxifolin Dimer Trimer Shishlyannikova, T.A. verfasserin aut Kashevskii, A.V. verfasserin aut Bazhenov, B.N. verfasserin aut Kuzmin, A.V. verfasserin aut Gorshkov, A.G. verfasserin aut Safronov, A.Y. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 271, Seite 560-566 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:271 pages:560-566 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 271 560-566 |
| allfieldsGer |
10.1016/j.electacta.2018.03.179 doi (DE-627)ELV000661716 (ELSEVIER)S0013-4686(18)30696-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Chernikov, D.A. verfasserin aut Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV–vis and MS detection have been coupled. The taxifolin diffusion coefficient has been evaluated in the aqueous solution as 3.63 × 10−6 cm2/s. The experimentally obtained number of electrons per one taxifolin molecule falls between 2 and 3 demonstrating that under electrochemical oxidation conditions only part of initially oxidized taxifolin molecules participates in dimerization and further transformation. Electrooxidation Cyclic voltammetry Bulk electrolysis Taxifolin Dimer Trimer Shishlyannikova, T.A. verfasserin aut Kashevskii, A.V. verfasserin aut Bazhenov, B.N. verfasserin aut Kuzmin, A.V. verfasserin aut Gorshkov, A.G. verfasserin aut Safronov, A.Y. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 271, Seite 560-566 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:271 pages:560-566 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 271 560-566 |
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10.1016/j.electacta.2018.03.179 doi (DE-627)ELV000661716 (ELSEVIER)S0013-4686(18)30696-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Chernikov, D.A. verfasserin aut Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV–vis and MS detection have been coupled. The taxifolin diffusion coefficient has been evaluated in the aqueous solution as 3.63 × 10−6 cm2/s. The experimentally obtained number of electrons per one taxifolin molecule falls between 2 and 3 demonstrating that under electrochemical oxidation conditions only part of initially oxidized taxifolin molecules participates in dimerization and further transformation. Electrooxidation Cyclic voltammetry Bulk electrolysis Taxifolin Dimer Trimer Shishlyannikova, T.A. verfasserin aut Kashevskii, A.V. verfasserin aut Bazhenov, B.N. verfasserin aut Kuzmin, A.V. verfasserin aut Gorshkov, A.G. verfasserin aut Safronov, A.Y. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 271, Seite 560-566 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:271 pages:560-566 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 271 560-566 |
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Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding |
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Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding |
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Chernikov, D.A. |
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Electrochimica acta |
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Electrochimica acta |
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Chernikov, D.A. Shishlyannikova, T.A. Kashevskii, A.V. Bazhenov, B.N. Kuzmin, A.V. Gorshkov, A.G. Safronov, A.Y. |
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Chernikov, D.A. |
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10.1016/j.electacta.2018.03.179 |
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some peculiarities of taxifolin electrooxidation in the aqueous media: the dimers formation as a key to the mechanism understanding |
| title_auth |
Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding |
| abstract |
In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV–vis and MS detection have been coupled. The taxifolin diffusion coefficient has been evaluated in the aqueous solution as 3.63 × 10−6 cm2/s. The experimentally obtained number of electrons per one taxifolin molecule falls between 2 and 3 demonstrating that under electrochemical oxidation conditions only part of initially oxidized taxifolin molecules participates in dimerization and further transformation. |
| abstractGer |
In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV–vis and MS detection have been coupled. The taxifolin diffusion coefficient has been evaluated in the aqueous solution as 3.63 × 10−6 cm2/s. The experimentally obtained number of electrons per one taxifolin molecule falls between 2 and 3 demonstrating that under electrochemical oxidation conditions only part of initially oxidized taxifolin molecules participates in dimerization and further transformation. |
| abstract_unstemmed |
In order to elucidate the mechanism of the flavonoid taxifolin (dihydroquercetin) oxidation under the electrochemical experiment conditions in the aqueous solutions the chronoamperometry and bulk electrolysis with following characterization of the oxidation products by means of the HPLC with both UV–vis and MS detection have been coupled. The taxifolin diffusion coefficient has been evaluated in the aqueous solution as 3.63 × 10−6 cm2/s. The experimentally obtained number of electrons per one taxifolin molecule falls between 2 and 3 demonstrating that under electrochemical oxidation conditions only part of initially oxidized taxifolin molecules participates in dimerization and further transformation. |
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Some peculiarities of taxifolin electrooxidation in the aqueous media: The dimers formation as a key to the mechanism understanding |
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Shishlyannikova, T.A. Kashevskii, A.V. Bazhenov, B.N. Kuzmin, A.V. Gorshkov, A.G. Safronov, A.Y. |
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2024-07-06T18:44:15.640Z |
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