Metal oxide/TiO

Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feeds...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Orojlou, Shahin Heydari [verfasserIn] Zargar, Behrooz [verfasserIn] Rastegarzadeh, Saadat [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	Nanocomposites TiO Metal oxide Adsorptive desulfurization Hydrogen sulfide

Übergeordnetes Werk:	Enthalten in: Journal of natural gas science and engineering - Amsterdam [u.a.] : Elsevier, 2009, 59, Seite 363-373
Übergeordnetes Werk:	volume:59 ; pages:363-373

DOI / URN:	10.1016/j.jngse.2018.09.016

Katalog-ID:	ELV001007211

Internformat


LEADER	01000caa a22002652 4500
001	ELV001007211
003	DE-627
005	20230524131244.0
007	cr uuu---uuuuu
008	230428s2018 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.1016/j.jngse.2018.09.016 \|2 doi
035			\|a (DE-627)ELV001007211
035			\|a (ELSEVIER)S1875-5100(18)30445-1
040			\|a DE-627 \|b ger \|c DE-627 \|e rda
041			\|a eng
082	0	4	\|a 660 \|q DE-600
100	1		\|a Orojlou, Shahin Heydari \|e verfasserin \|4 aut
245	1	0	\|a Metal oxide/TiO
264		1	\|c 2018
336			\|a nicht spezifiziert \|b zzz \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature.
650		4	\|a Nanocomposites
650		4	\|a TiO
650		4	\|a Metal oxide
650		4	\|a Adsorptive desulfurization
650		4	\|a Hydrogen sulfide
700	1		\|a Zargar, Behrooz \|e verfasserin \|0 (orcid)0000-0003-4868-0845 \|4 aut
700	1		\|a Rastegarzadeh, Saadat \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Journal of natural gas science and engineering \|d Amsterdam [u.a.] : Elsevier, 2009 \|g 59, Seite 363-373 \|h Online-Ressource \|w (DE-627)608943231 \|w (DE-600)2514802-3 \|w (DE-576)311098436 \|x 1875-5100 \|7 nnns
773	1	8	\|g volume:59 \|g pages:363-373
912			\|a GBV_USEFLAG_U
912			\|a SYSFLAG_U
912			\|a GBV_ELV
912			\|a SSG-OLC-PHA
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_165
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
951			\|a AR
952			\|d 59 \|h 363-373

Indexfelder

author_variant	s h o sh sho b z bz s r sr
matchkey_str	article:18755100:2018----::eaoi
hierarchy_sort_str	2018
publishDate	2018
allfields	10.1016/j.jngse.2018.09.016 doi (DE-627)ELV001007211 (ELSEVIER)S1875-5100(18)30445-1 DE-627 ger DE-627 rda eng 660 DE-600 Orojlou, Shahin Heydari verfasserin aut Metal oxide/TiO 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature. Nanocomposites TiO Metal oxide Adsorptive desulfurization Hydrogen sulfide Zargar, Behrooz verfasserin (orcid)0000-0003-4868-0845 aut Rastegarzadeh, Saadat verfasserin aut Enthalten in Journal of natural gas science and engineering Amsterdam [u.a.] : Elsevier, 2009 59, Seite 363-373 Online-Ressource (DE-627)608943231 (DE-600)2514802-3 (DE-576)311098436 1875-5100 nnns volume:59 pages:363-373 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_165 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 AR 59 363-373
spelling	10.1016/j.jngse.2018.09.016 doi (DE-627)ELV001007211 (ELSEVIER)S1875-5100(18)30445-1 DE-627 ger DE-627 rda eng 660 DE-600 Orojlou, Shahin Heydari verfasserin aut Metal oxide/TiO 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature. Nanocomposites TiO Metal oxide Adsorptive desulfurization Hydrogen sulfide Zargar, Behrooz verfasserin (orcid)0000-0003-4868-0845 aut Rastegarzadeh, Saadat verfasserin aut Enthalten in Journal of natural gas science and engineering Amsterdam [u.a.] : Elsevier, 2009 59, Seite 363-373 Online-Ressource (DE-627)608943231 (DE-600)2514802-3 (DE-576)311098436 1875-5100 nnns volume:59 pages:363-373 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_165 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 AR 59 363-373
allfields_unstemmed	10.1016/j.jngse.2018.09.016 doi (DE-627)ELV001007211 (ELSEVIER)S1875-5100(18)30445-1 DE-627 ger DE-627 rda eng 660 DE-600 Orojlou, Shahin Heydari verfasserin aut Metal oxide/TiO 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature. Nanocomposites TiO Metal oxide Adsorptive desulfurization Hydrogen sulfide Zargar, Behrooz verfasserin (orcid)0000-0003-4868-0845 aut Rastegarzadeh, Saadat verfasserin aut Enthalten in Journal of natural gas science and engineering Amsterdam [u.a.] : Elsevier, 2009 59, Seite 363-373 Online-Ressource (DE-627)608943231 (DE-600)2514802-3 (DE-576)311098436 1875-5100 nnns volume:59 pages:363-373 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_165 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 AR 59 363-373
allfieldsGer	10.1016/j.jngse.2018.09.016 doi (DE-627)ELV001007211 (ELSEVIER)S1875-5100(18)30445-1 DE-627 ger DE-627 rda eng 660 DE-600 Orojlou, Shahin Heydari verfasserin aut Metal oxide/TiO 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature. Nanocomposites TiO Metal oxide Adsorptive desulfurization Hydrogen sulfide Zargar, Behrooz verfasserin (orcid)0000-0003-4868-0845 aut Rastegarzadeh, Saadat verfasserin aut Enthalten in Journal of natural gas science and engineering Amsterdam [u.a.] : Elsevier, 2009 59, Seite 363-373 Online-Ressource (DE-627)608943231 (DE-600)2514802-3 (DE-576)311098436 1875-5100 nnns volume:59 pages:363-373 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_165 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 AR 59 363-373
allfieldsSound	10.1016/j.jngse.2018.09.016 doi (DE-627)ELV001007211 (ELSEVIER)S1875-5100(18)30445-1 DE-627 ger DE-627 rda eng 660 DE-600 Orojlou, Shahin Heydari verfasserin aut Metal oxide/TiO 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature. Nanocomposites TiO Metal oxide Adsorptive desulfurization Hydrogen sulfide Zargar, Behrooz verfasserin (orcid)0000-0003-4868-0845 aut Rastegarzadeh, Saadat verfasserin aut Enthalten in Journal of natural gas science and engineering Amsterdam [u.a.] : Elsevier, 2009 59, Seite 363-373 Online-Ressource (DE-627)608943231 (DE-600)2514802-3 (DE-576)311098436 1875-5100 nnns volume:59 pages:363-373 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_165 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 AR 59 363-373
language	English
source	Enthalten in Journal of natural gas science and engineering 59, Seite 363-373 volume:59 pages:363-373
sourceStr	Enthalten in Journal of natural gas science and engineering 59, Seite 363-373 volume:59 pages:363-373
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Nanocomposites TiO Metal oxide Adsorptive desulfurization Hydrogen sulfide
dewey-raw	660
isfreeaccess_bool	false
container_title	Journal of natural gas science and engineering
authorswithroles_txt_mv	Orojlou, Shahin Heydari @@aut@@ Zargar, Behrooz @@aut@@ Rastegarzadeh, Saadat @@aut@@
publishDateDaySort_date	2018-01-01T00:00:00Z
hierarchy_top_id	608943231
dewey-sort	3660
id	ELV001007211
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV001007211</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524131244.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230428s2018 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jngse.2018.09.016</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV001007211</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S1875-5100(18)30445-1</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Orojlou, Shahin Heydari</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Metal oxide/TiO</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2018</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nanocomposites</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TiO</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Metal oxide</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Adsorptive desulfurization</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrogen sulfide</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zargar, Behrooz</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-4868-0845</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Rastegarzadeh, Saadat</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of natural gas science and engineering</subfield><subfield code="d">Amsterdam [u.a.] : Elsevier, 2009</subfield><subfield code="g">59, Seite 363-373</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)608943231</subfield><subfield code="w">(DE-600)2514802-3</subfield><subfield code="w">(DE-576)311098436</subfield><subfield code="x">1875-5100</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:59</subfield><subfield code="g">pages:363-373</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_165</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">59</subfield><subfield code="h">363-373</subfield></datafield></record></collection>
author	Orojlou, Shahin Heydari
spellingShingle	Orojlou, Shahin Heydari ddc 660 misc Nanocomposites misc TiO misc Metal oxide misc Adsorptive desulfurization misc Hydrogen sulfide Metal oxide/TiO
authorStr	Orojlou, Shahin Heydari
ppnlink_with_tag_str_mv	@@773@@(DE-627)608943231
format	electronic Article
dewey-ones	660 - Chemical engineering
delete_txt_mv	keep
author_role	aut aut aut
collection	elsevier
remote_str	true
illustrated	Not Illustrated
issn	1875-5100
topic_title	660 DE-600 Metal oxide/TiO Nanocomposites TiO Metal oxide Adsorptive desulfurization Hydrogen sulfide
topic	ddc 660 misc Nanocomposites misc TiO misc Metal oxide misc Adsorptive desulfurization misc Hydrogen sulfide
topic_unstemmed	ddc 660 misc Nanocomposites misc TiO misc Metal oxide misc Adsorptive desulfurization misc Hydrogen sulfide
topic_browse	ddc 660 misc Nanocomposites misc TiO misc Metal oxide misc Adsorptive desulfurization misc Hydrogen sulfide
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	Journal of natural gas science and engineering
hierarchy_parent_id	608943231
dewey-tens	660 - Chemical engineering
hierarchy_top_title	Journal of natural gas science and engineering
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)608943231 (DE-600)2514802-3 (DE-576)311098436
title	Metal oxide/TiO
ctrlnum	(DE-627)ELV001007211 (ELSEVIER)S1875-5100(18)30445-1
title_full	Metal oxide/TiO
author_sort	Orojlou, Shahin Heydari
journal	Journal of natural gas science and engineering
journalStr	Journal of natural gas science and engineering
lang_code	eng
isOA_bool	false
dewey-hundreds	600 - Technology
recordtype	marc
publishDateSort	2018
contenttype_str_mv	zzz
container_start_page	363
author_browse	Orojlou, Shahin Heydari Zargar, Behrooz Rastegarzadeh, Saadat
container_volume	59
class	660 DE-600
format_se	Elektronische Aufsätze
author-letter	Orojlou, Shahin Heydari
doi_str_mv	10.1016/j.jngse.2018.09.016
normlink	(ORCID)0000-0003-4868-0845
normlink_prefix_str_mv	(orcid)0000-0003-4868-0845
dewey-full	660
author2-role	verfasserin
title_sort	metal oxide/tio
title_auth	Metal oxide/TiO
abstract	Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature.
abstractGer	Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature.
abstract_unstemmed	Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature.
collection_details	GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_165 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393
title_short	Metal oxide/TiO
remote_bool	true
author2	Zargar, Behrooz Rastegarzadeh, Saadat
author2Str	Zargar, Behrooz Rastegarzadeh, Saadat
ppnlink	608943231
mediatype_str_mv	c
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1016/j.jngse.2018.09.016
up_date	2024-07-06T19:54:43.789Z
_version_	1803860766926831616
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV001007211</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524131244.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230428s2018 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jngse.2018.09.016</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV001007211</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S1875-5100(18)30445-1</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Orojlou, Shahin Heydari</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Metal oxide/TiO</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2018</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Hydrogen sulfide is a highly toxic and corrosive gas that is present in different environments such as hot coal gases. In order to have a clean atmosphere and prolong the life of industrial equipment and metallic catalysts, it is necessary to remove or decrease the concentration of this gas in feedstocks to sub parts per million before their use. To accomplish this task, various nanocomposite sorbents were studied for H2S removal at relatively high temperature. To this end, the NiO/TiO2, CuO/TiO2, and CoO/TiO2 nanocomposites were prepared through wet impregnation. X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) and N2 adsorption/desorption were used for characterizing the prepared nano sorbents. The H2S adsorption reaction experiments were performed at relatively high temperature and effects of the promoter to TiO2 ratio, sorbent mass and desulfurization temperature were studied. The results showed that at 480 °C, the CoO promoted TiO2 shows longer breakthrough time followed by NiO/TiO2 and CuO/TiO2 sorbents. The best results were obtained by using the promoter to TiO2 ratio of 2.5/5 among the ratios used. By decreasing the temperature and performing the experiments at 400 °C, the nickel oxide promoted TiO2 showed better results than the CoO/TiO2 suggesting the lower sulfidation activity of CoO promoter at this temperature.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nanocomposites</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TiO</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Metal oxide</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Adsorptive desulfurization</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrogen sulfide</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zargar, Behrooz</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-4868-0845</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Rastegarzadeh, Saadat</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of natural gas science and engineering</subfield><subfield code="d">Amsterdam [u.a.] : Elsevier, 2009</subfield><subfield code="g">59, Seite 363-373</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)608943231</subfield><subfield code="w">(DE-600)2514802-3</subfield><subfield code="w">(DE-576)311098436</subfield><subfield code="x">1875-5100</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:59</subfield><subfield code="g">pages:363-373</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_165</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">59</subfield><subfield code="h">363-373</subfield></datafield></record></collection>
score	7.4028378

Nicht das Richtige dabei?

Schreiben Sie uns!

Metal oxide/TiO

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?