Ultra-high specific capacity of Cr
Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly i...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Qian, Delai [verfasserIn] Gu, Yijie [verfasserIn] Chen, Yunbo [verfasserIn] Liu, Hongquan [verfasserIn] Wang, Juan [verfasserIn] Zhou, Henghui [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Materials letters - New York, NY [u.a.] : Elsevier, 1982, 238, Seite 102-106 |
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| Übergeordnetes Werk: |
volume:238 ; pages:102-106 |
| DOI / URN: |
10.1016/j.matlet.2018.11.163 |
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| 520 | |a Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly improved the discharge specific capacity but also maintained the original 1.55-V discharge platform. During the process of discharge–charge, Cr3+-doped LTO showed a long discharge plateau (91.4% of the entire discharge process) at 1.55 V and an ultra-high initial discharge specific capacity of 240.6 mAh g−1 at 0.1 °C. Furthermore, it can maintain 144.7 mAh g−1 at 5.0 °C after 200cycles, which is 92% of its initial discharge capacity. | ||
| 650 | 4 | |a Li | |
| 650 | 4 | |a Cr | |
| 650 | 4 | |a Ultra-high specific capacity | |
| 650 | 4 | |a 1.55-V discharge platform | |
| 650 | 4 | |a Lithium-ion batteries | |
| 700 | 1 | |a Gu, Yijie |e verfasserin |0 (orcid)0000-0002-6607-2125 |4 aut | |
| 700 | 1 | |a Chen, Yunbo |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Hongquan |e verfasserin |0 (orcid)0000-0002-2431-6099 |4 aut | |
| 700 | 1 | |a Wang, Juan |e verfasserin |4 aut | |
| 700 | 1 | |a Zhou, Henghui |e verfasserin |4 aut | |
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10.1016/j.matlet.2018.11.163 doi (DE-627)ELV001406000 (ELSEVIER)S0167-577X(18)31938-4 DE-627 ger DE-627 rda eng 530 600 670 DE-600 51.00 bkl Qian, Delai verfasserin aut Ultra-high specific capacity of Cr 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly improved the discharge specific capacity but also maintained the original 1.55-V discharge platform. During the process of discharge–charge, Cr3+-doped LTO showed a long discharge plateau (91.4% of the entire discharge process) at 1.55 V and an ultra-high initial discharge specific capacity of 240.6 mAh g−1 at 0.1 °C. Furthermore, it can maintain 144.7 mAh g−1 at 5.0 °C after 200cycles, which is 92% of its initial discharge capacity. Li Cr Ultra-high specific capacity 1.55-V discharge platform Lithium-ion batteries Gu, Yijie verfasserin (orcid)0000-0002-6607-2125 aut Chen, Yunbo verfasserin aut Liu, Hongquan verfasserin (orcid)0000-0002-2431-6099 aut Wang, Juan verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Materials letters New York, NY [u.a.] : Elsevier, 1982 238, Seite 102-106 Online-Ressource (DE-627)302719407 (DE-600)1491964-3 (DE-576)259483974 1873-4979 nnns volume:238 pages:102-106 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 238 102-106 |
| spelling |
10.1016/j.matlet.2018.11.163 doi (DE-627)ELV001406000 (ELSEVIER)S0167-577X(18)31938-4 DE-627 ger DE-627 rda eng 530 600 670 DE-600 51.00 bkl Qian, Delai verfasserin aut Ultra-high specific capacity of Cr 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly improved the discharge specific capacity but also maintained the original 1.55-V discharge platform. During the process of discharge–charge, Cr3+-doped LTO showed a long discharge plateau (91.4% of the entire discharge process) at 1.55 V and an ultra-high initial discharge specific capacity of 240.6 mAh g−1 at 0.1 °C. Furthermore, it can maintain 144.7 mAh g−1 at 5.0 °C after 200cycles, which is 92% of its initial discharge capacity. Li Cr Ultra-high specific capacity 1.55-V discharge platform Lithium-ion batteries Gu, Yijie verfasserin (orcid)0000-0002-6607-2125 aut Chen, Yunbo verfasserin aut Liu, Hongquan verfasserin (orcid)0000-0002-2431-6099 aut Wang, Juan verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Materials letters New York, NY [u.a.] : Elsevier, 1982 238, Seite 102-106 Online-Ressource (DE-627)302719407 (DE-600)1491964-3 (DE-576)259483974 1873-4979 nnns volume:238 pages:102-106 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 238 102-106 |
| allfields_unstemmed |
10.1016/j.matlet.2018.11.163 doi (DE-627)ELV001406000 (ELSEVIER)S0167-577X(18)31938-4 DE-627 ger DE-627 rda eng 530 600 670 DE-600 51.00 bkl Qian, Delai verfasserin aut Ultra-high specific capacity of Cr 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly improved the discharge specific capacity but also maintained the original 1.55-V discharge platform. During the process of discharge–charge, Cr3+-doped LTO showed a long discharge plateau (91.4% of the entire discharge process) at 1.55 V and an ultra-high initial discharge specific capacity of 240.6 mAh g−1 at 0.1 °C. Furthermore, it can maintain 144.7 mAh g−1 at 5.0 °C after 200cycles, which is 92% of its initial discharge capacity. Li Cr Ultra-high specific capacity 1.55-V discharge platform Lithium-ion batteries Gu, Yijie verfasserin (orcid)0000-0002-6607-2125 aut Chen, Yunbo verfasserin aut Liu, Hongquan verfasserin (orcid)0000-0002-2431-6099 aut Wang, Juan verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Materials letters New York, NY [u.a.] : Elsevier, 1982 238, Seite 102-106 Online-Ressource (DE-627)302719407 (DE-600)1491964-3 (DE-576)259483974 1873-4979 nnns volume:238 pages:102-106 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 238 102-106 |
| allfieldsGer |
10.1016/j.matlet.2018.11.163 doi (DE-627)ELV001406000 (ELSEVIER)S0167-577X(18)31938-4 DE-627 ger DE-627 rda eng 530 600 670 DE-600 51.00 bkl Qian, Delai verfasserin aut Ultra-high specific capacity of Cr 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly improved the discharge specific capacity but also maintained the original 1.55-V discharge platform. During the process of discharge–charge, Cr3+-doped LTO showed a long discharge plateau (91.4% of the entire discharge process) at 1.55 V and an ultra-high initial discharge specific capacity of 240.6 mAh g−1 at 0.1 °C. Furthermore, it can maintain 144.7 mAh g−1 at 5.0 °C after 200cycles, which is 92% of its initial discharge capacity. Li Cr Ultra-high specific capacity 1.55-V discharge platform Lithium-ion batteries Gu, Yijie verfasserin (orcid)0000-0002-6607-2125 aut Chen, Yunbo verfasserin aut Liu, Hongquan verfasserin (orcid)0000-0002-2431-6099 aut Wang, Juan verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Materials letters New York, NY [u.a.] : Elsevier, 1982 238, Seite 102-106 Online-Ressource (DE-627)302719407 (DE-600)1491964-3 (DE-576)259483974 1873-4979 nnns volume:238 pages:102-106 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 238 102-106 |
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10.1016/j.matlet.2018.11.163 doi (DE-627)ELV001406000 (ELSEVIER)S0167-577X(18)31938-4 DE-627 ger DE-627 rda eng 530 600 670 DE-600 51.00 bkl Qian, Delai verfasserin aut Ultra-high specific capacity of Cr 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly improved the discharge specific capacity but also maintained the original 1.55-V discharge platform. During the process of discharge–charge, Cr3+-doped LTO showed a long discharge plateau (91.4% of the entire discharge process) at 1.55 V and an ultra-high initial discharge specific capacity of 240.6 mAh g−1 at 0.1 °C. Furthermore, it can maintain 144.7 mAh g−1 at 5.0 °C after 200cycles, which is 92% of its initial discharge capacity. Li Cr Ultra-high specific capacity 1.55-V discharge platform Lithium-ion batteries Gu, Yijie verfasserin (orcid)0000-0002-6607-2125 aut Chen, Yunbo verfasserin aut Liu, Hongquan verfasserin (orcid)0000-0002-2431-6099 aut Wang, Juan verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Materials letters New York, NY [u.a.] : Elsevier, 1982 238, Seite 102-106 Online-Ressource (DE-627)302719407 (DE-600)1491964-3 (DE-576)259483974 1873-4979 nnns volume:238 pages:102-106 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 238 102-106 |
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Ultra-high specific capacity of Cr |
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Ultra-high specific capacity of Cr |
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Qian, Delai Gu, Yijie Chen, Yunbo Liu, Hongquan Wang, Juan Zhou, Henghui |
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ultra-high specific capacity of cr |
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Ultra-high specific capacity of Cr |
| abstract |
Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly improved the discharge specific capacity but also maintained the original 1.55-V discharge platform. During the process of discharge–charge, Cr3+-doped LTO showed a long discharge plateau (91.4% of the entire discharge process) at 1.55 V and an ultra-high initial discharge specific capacity of 240.6 mAh g−1 at 0.1 °C. Furthermore, it can maintain 144.7 mAh g−1 at 5.0 °C after 200cycles, which is 92% of its initial discharge capacity. |
| abstractGer |
Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly improved the discharge specific capacity but also maintained the original 1.55-V discharge platform. During the process of discharge–charge, Cr3+-doped LTO showed a long discharge plateau (91.4% of the entire discharge process) at 1.55 V and an ultra-high initial discharge specific capacity of 240.6 mAh g−1 at 0.1 °C. Furthermore, it can maintain 144.7 mAh g−1 at 5.0 °C after 200cycles, which is 92% of its initial discharge capacity. |
| abstract_unstemmed |
Cr3+-doped Li4Ti5O12 (LTO) was fabricated by spray drying followed by a solid-state reaction. The crystal structure and morphology of the sample was tested using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that Cr3+-doped LTO not only significantly improved the discharge specific capacity but also maintained the original 1.55-V discharge platform. During the process of discharge–charge, Cr3+-doped LTO showed a long discharge plateau (91.4% of the entire discharge process) at 1.55 V and an ultra-high initial discharge specific capacity of 240.6 mAh g−1 at 0.1 °C. Furthermore, it can maintain 144.7 mAh g−1 at 5.0 °C after 200cycles, which is 92% of its initial discharge capacity. |
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Ultra-high specific capacity of Cr |
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Gu, Yijie Chen, Yunbo Liu, Hongquan Wang, Juan Zhou, Henghui |
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