Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution

4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Xu, Hongxing [verfasserIn] Wang, Qiaochun [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Diazonium salts Cucurbiturils Host-guest complexes Supramolecular chemistry CuCl

Übergeordnetes Werk:	Enthalten in: Chinese chemical letters - Amsterdam : Elsevier, 1990, 30, Seite 337-339
Übergeordnetes Werk:	volume:30 ; pages:337-339

DOI / URN:	10.1016/j.cclet.2018.03.014

Katalog-ID:	ELV001460595

Internformat


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520			\|a 4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in a high total yield (61%+33%) in the presence of CuCl, unlike the decomposition of 4-NBD in the presence of either CB[7] or CuCl, or both absence, where would result in significant amounts of unknown byproducts. This work might provide an economic and effective way to obtain arenes or phenols through the substitution of diazonium salts.
650		4	\|a Diazonium salts
650		4	\|a Cucurbiturils
650		4	\|a Host-guest complexes
650		4	\|a Supramolecular chemistry
650		4	\|a CuCl
700	1		\|a Wang, Qiaochun \|e verfasserin \|0 (orcid)0000-0002-2852-2463 \|4 aut
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936	b	k	\|a 35.00 \|j Chemie: Allgemeines
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matchkey_str	article:18785964:2019----::uubtuiccpooigeopstoo4irbneeizn
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bklnumber	35.00 35.04
publishDate	2019
allfields	10.1016/j.cclet.2018.03.014 doi (DE-627)ELV001460595 (ELSEVIER)S1001-8417(18)30117-7 DE-627 ger DE-627 rda eng 540 DE-600 6,25 ssgn ASIEN DE-1a fid 35.00 bkl 35.04 bkl Xu, Hongxing verfasserin aut Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in a high total yield (61%+33%) in the presence of CuCl, unlike the decomposition of 4-NBD in the presence of either CB[7] or CuCl, or both absence, where would result in significant amounts of unknown byproducts. This work might provide an economic and effective way to obtain arenes or phenols through the substitution of diazonium salts. Diazonium salts Cucurbiturils Host-guest complexes Supramolecular chemistry CuCl Wang, Qiaochun verfasserin (orcid)0000-0002-2852-2463 aut Enthalten in Chinese chemical letters Amsterdam : Elsevier, 1990 30, Seite 337-339 Online-Ressource (DE-627)358144019 (DE-600)2096242-3 (DE-576)267762151 1878-5964 nnns volume:30 pages:337-339 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-ASIEN GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines 35.04 Ausbildung Beruf Organisationen Chemie AR 30 337-339
spelling	10.1016/j.cclet.2018.03.014 doi (DE-627)ELV001460595 (ELSEVIER)S1001-8417(18)30117-7 DE-627 ger DE-627 rda eng 540 DE-600 6,25 ssgn ASIEN DE-1a fid 35.00 bkl 35.04 bkl Xu, Hongxing verfasserin aut Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in a high total yield (61%+33%) in the presence of CuCl, unlike the decomposition of 4-NBD in the presence of either CB[7] or CuCl, or both absence, where would result in significant amounts of unknown byproducts. This work might provide an economic and effective way to obtain arenes or phenols through the substitution of diazonium salts. Diazonium salts Cucurbiturils Host-guest complexes Supramolecular chemistry CuCl Wang, Qiaochun verfasserin (orcid)0000-0002-2852-2463 aut Enthalten in Chinese chemical letters Amsterdam : Elsevier, 1990 30, Seite 337-339 Online-Ressource (DE-627)358144019 (DE-600)2096242-3 (DE-576)267762151 1878-5964 nnns volume:30 pages:337-339 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-ASIEN GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines 35.04 Ausbildung Beruf Organisationen Chemie AR 30 337-339
allfields_unstemmed	10.1016/j.cclet.2018.03.014 doi (DE-627)ELV001460595 (ELSEVIER)S1001-8417(18)30117-7 DE-627 ger DE-627 rda eng 540 DE-600 6,25 ssgn ASIEN DE-1a fid 35.00 bkl 35.04 bkl Xu, Hongxing verfasserin aut Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in a high total yield (61%+33%) in the presence of CuCl, unlike the decomposition of 4-NBD in the presence of either CB[7] or CuCl, or both absence, where would result in significant amounts of unknown byproducts. This work might provide an economic and effective way to obtain arenes or phenols through the substitution of diazonium salts. Diazonium salts Cucurbiturils Host-guest complexes Supramolecular chemistry CuCl Wang, Qiaochun verfasserin (orcid)0000-0002-2852-2463 aut Enthalten in Chinese chemical letters Amsterdam : Elsevier, 1990 30, Seite 337-339 Online-Ressource (DE-627)358144019 (DE-600)2096242-3 (DE-576)267762151 1878-5964 nnns volume:30 pages:337-339 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-ASIEN GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines 35.04 Ausbildung Beruf Organisationen Chemie AR 30 337-339
allfieldsGer	10.1016/j.cclet.2018.03.014 doi (DE-627)ELV001460595 (ELSEVIER)S1001-8417(18)30117-7 DE-627 ger DE-627 rda eng 540 DE-600 6,25 ssgn ASIEN DE-1a fid 35.00 bkl 35.04 bkl Xu, Hongxing verfasserin aut Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in a high total yield (61%+33%) in the presence of CuCl, unlike the decomposition of 4-NBD in the presence of either CB[7] or CuCl, or both absence, where would result in significant amounts of unknown byproducts. This work might provide an economic and effective way to obtain arenes or phenols through the substitution of diazonium salts. Diazonium salts Cucurbiturils Host-guest complexes Supramolecular chemistry CuCl Wang, Qiaochun verfasserin (orcid)0000-0002-2852-2463 aut Enthalten in Chinese chemical letters Amsterdam : Elsevier, 1990 30, Seite 337-339 Online-Ressource (DE-627)358144019 (DE-600)2096242-3 (DE-576)267762151 1878-5964 nnns volume:30 pages:337-339 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-ASIEN GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines 35.04 Ausbildung Beruf Organisationen Chemie AR 30 337-339
allfieldsSound	10.1016/j.cclet.2018.03.014 doi (DE-627)ELV001460595 (ELSEVIER)S1001-8417(18)30117-7 DE-627 ger DE-627 rda eng 540 DE-600 6,25 ssgn ASIEN DE-1a fid 35.00 bkl 35.04 bkl Xu, Hongxing verfasserin aut Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in a high total yield (61%+33%) in the presence of CuCl, unlike the decomposition of 4-NBD in the presence of either CB[7] or CuCl, or both absence, where would result in significant amounts of unknown byproducts. This work might provide an economic and effective way to obtain arenes or phenols through the substitution of diazonium salts. Diazonium salts Cucurbiturils Host-guest complexes Supramolecular chemistry CuCl Wang, Qiaochun verfasserin (orcid)0000-0002-2852-2463 aut Enthalten in Chinese chemical letters Amsterdam : Elsevier, 1990 30, Seite 337-339 Online-Ressource (DE-627)358144019 (DE-600)2096242-3 (DE-576)267762151 1878-5964 nnns volume:30 pages:337-339 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-ASIEN GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines 35.04 Ausbildung Beruf Organisationen Chemie AR 30 337-339
language	English
source	Enthalten in Chinese chemical letters 30, Seite 337-339 volume:30 pages:337-339
sourceStr	Enthalten in Chinese chemical letters 30, Seite 337-339 volume:30 pages:337-339
format_phy_str_mv	Article
bklname	Chemie: Allgemeines Ausbildung Beruf Organisationen
institution	findex.gbv.de
topic_facet	Diazonium salts Cucurbiturils Host-guest complexes Supramolecular chemistry CuCl
dewey-raw	540
isfreeaccess_bool	false
container_title	Chinese chemical letters
authorswithroles_txt_mv	Xu, Hongxing @@aut@@ Wang, Qiaochun @@aut@@
publishDateDaySort_date	2019-01-01T00:00:00Z
hierarchy_top_id	358144019
dewey-sort	3540
id	ELV001460595
language_de	englisch
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author	Xu, Hongxing
spellingShingle	Xu, Hongxing ddc 540 ssgn 6,25 fid ASIEN bkl 35.00 bkl 35.04 misc Diazonium salts misc Cucurbiturils misc Host-guest complexes misc Supramolecular chemistry misc CuCl Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution
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topic_title	540 DE-600 6,25 ssgn ASIEN DE-1a fid 35.00 bkl 35.04 bkl Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution Diazonium salts Cucurbiturils Host-guest complexes Supramolecular chemistry CuCl
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title	Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution
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title_full	Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution
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title_sort	cucurbit[7]uril/cucl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution
title_auth	Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution
abstract	4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in a high total yield (61%+33%) in the presence of CuCl, unlike the decomposition of 4-NBD in the presence of either CB[7] or CuCl, or both absence, where would result in significant amounts of unknown byproducts. This work might provide an economic and effective way to obtain arenes or phenols through the substitution of diazonium salts.
abstractGer	4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in a high total yield (61%+33%) in the presence of CuCl, unlike the decomposition of 4-NBD in the presence of either CB[7] or CuCl, or both absence, where would result in significant amounts of unknown byproducts. This work might provide an economic and effective way to obtain arenes or phenols through the substitution of diazonium salts.
abstract_unstemmed	4-Nitro-benzendiazonium (4-NBD) was found to form a 1:1 host-guest complex (NBDCB) with cucurbit[7]uril (CB[7]) in aqueous solution and 4-NBD enters into the cavity of CB[7] with a binding constant of 1.28×105 L/mol. NBD@CB can be decomposed into a nitrobenzene/4-nitrophenol mixture in a high total yield (61%+33%) in the presence of CuCl, unlike the decomposition of 4-NBD in the presence of either CB[7] or CuCl, or both absence, where would result in significant amounts of unknown byproducts. This work might provide an economic and effective way to obtain arenes or phenols through the substitution of diazonium salts.
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title_short	Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution
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doi_str	10.1016/j.cclet.2018.03.014
up_date	2024-07-06T21:27:02.728Z
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Cucurbit[7]uril/CuCl promoting decomposition of 4-nitrobenzenediazonium in aqueous solution

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