Conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor
The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the pr...
Ausführliche Beschreibung
Autor*in: |
Polianczyk, E.V. [verfasserIn] Dorofeenko, S.O. [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2018 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: International journal of hydrogen energy - New York, NY [u.a.] : Elsevier, 1976, 44 |
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Übergeordnetes Werk: |
volume:44 |
DOI / URN: |
10.1016/j.ijhydene.2018.12.117 |
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Katalog-ID: |
ELV001525360 |
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245 | 1 | 0 | |a Conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor |
264 | 1 | |c 2018 | |
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520 | |a The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the previously considered conversion in a reversed-flow reactor, such embodiment provides a possibility of attaining high combustion temperature due to efficient heat recuperation, while performing the process continuously without transients associated with the flow reverse. In the moving bed process, the flowrate of the granular material becomes an independent control parameter. A thermodynamic assessment of the macrokinetic conversion regimes as dependent on fuel composition and oxidant gas and fuel supply rates and granular solid flowrate is performed under the assumption that the combustion temperature is self-consistent according to thermodynamic equilibrium with the composition of syngas. Calculations for the methane/air-steam and 2-propanol/air-steam conversion are provided as examples. The calculations show that the process provides a possibility to combine in a stationary continuous process a high combustion temperature with low net heat effect and thus, a high chemical efficiency of conversion. The parametric domain for control parameters providing highly efficient conversion is determined. | ||
650 | 4 | |a Partial oxidation | |
650 | 4 | |a Syngas production | |
650 | 4 | |a Filtration combustion | |
650 | 4 | |a Porous media | |
650 | 4 | |a Reactor design | |
700 | 1 | |a Dorofeenko, S.O. |e verfasserin |4 aut | |
773 | 0 | 8 | |i Enthalten in |t International journal of hydrogen energy |d New York, NY [u.a.] : Elsevier, 1976 |g 44 |h Online-Ressource |w (DE-627)301511357 |w (DE-600)1484487-4 |w (DE-576)096806397 |x 1879-3487 |7 nnns |
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912 | |a GBV_ILN_4393 | ||
936 | b | k | |a 52.56 |j Regenerative Energieformen |j alternative Energieformen |
951 | |a AR | ||
952 | |d 44 |
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article:18793487:2018----::ovrinfyrcrosoyteigsncutrlwoigeflr |
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2018 |
bklnumber |
52.56 |
publishDate |
2018 |
allfields |
10.1016/j.ijhydene.2018.12.117 doi (DE-627)ELV001525360 (ELSEVIER)S0360-3199(18)34085-0 DE-627 ger DE-627 rda eng 660 620 DE-600 52.56 bkl Polianczyk, E.V. verfasserin aut Conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the previously considered conversion in a reversed-flow reactor, such embodiment provides a possibility of attaining high combustion temperature due to efficient heat recuperation, while performing the process continuously without transients associated with the flow reverse. In the moving bed process, the flowrate of the granular material becomes an independent control parameter. A thermodynamic assessment of the macrokinetic conversion regimes as dependent on fuel composition and oxidant gas and fuel supply rates and granular solid flowrate is performed under the assumption that the combustion temperature is self-consistent according to thermodynamic equilibrium with the composition of syngas. Calculations for the methane/air-steam and 2-propanol/air-steam conversion are provided as examples. The calculations show that the process provides a possibility to combine in a stationary continuous process a high combustion temperature with low net heat effect and thus, a high chemical efficiency of conversion. The parametric domain for control parameters providing highly efficient conversion is determined. Partial oxidation Syngas production Filtration combustion Porous media Reactor design Dorofeenko, S.O. verfasserin aut Enthalten in International journal of hydrogen energy New York, NY [u.a.] : Elsevier, 1976 44 Online-Ressource (DE-627)301511357 (DE-600)1484487-4 (DE-576)096806397 1879-3487 nnns volume:44 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.56 Regenerative Energieformen alternative Energieformen AR 44 |
spelling |
10.1016/j.ijhydene.2018.12.117 doi (DE-627)ELV001525360 (ELSEVIER)S0360-3199(18)34085-0 DE-627 ger DE-627 rda eng 660 620 DE-600 52.56 bkl Polianczyk, E.V. verfasserin aut Conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the previously considered conversion in a reversed-flow reactor, such embodiment provides a possibility of attaining high combustion temperature due to efficient heat recuperation, while performing the process continuously without transients associated with the flow reverse. In the moving bed process, the flowrate of the granular material becomes an independent control parameter. A thermodynamic assessment of the macrokinetic conversion regimes as dependent on fuel composition and oxidant gas and fuel supply rates and granular solid flowrate is performed under the assumption that the combustion temperature is self-consistent according to thermodynamic equilibrium with the composition of syngas. Calculations for the methane/air-steam and 2-propanol/air-steam conversion are provided as examples. The calculations show that the process provides a possibility to combine in a stationary continuous process a high combustion temperature with low net heat effect and thus, a high chemical efficiency of conversion. The parametric domain for control parameters providing highly efficient conversion is determined. Partial oxidation Syngas production Filtration combustion Porous media Reactor design Dorofeenko, S.O. verfasserin aut Enthalten in International journal of hydrogen energy New York, NY [u.a.] : Elsevier, 1976 44 Online-Ressource (DE-627)301511357 (DE-600)1484487-4 (DE-576)096806397 1879-3487 nnns volume:44 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.56 Regenerative Energieformen alternative Energieformen AR 44 |
allfields_unstemmed |
10.1016/j.ijhydene.2018.12.117 doi (DE-627)ELV001525360 (ELSEVIER)S0360-3199(18)34085-0 DE-627 ger DE-627 rda eng 660 620 DE-600 52.56 bkl Polianczyk, E.V. verfasserin aut Conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the previously considered conversion in a reversed-flow reactor, such embodiment provides a possibility of attaining high combustion temperature due to efficient heat recuperation, while performing the process continuously without transients associated with the flow reverse. In the moving bed process, the flowrate of the granular material becomes an independent control parameter. A thermodynamic assessment of the macrokinetic conversion regimes as dependent on fuel composition and oxidant gas and fuel supply rates and granular solid flowrate is performed under the assumption that the combustion temperature is self-consistent according to thermodynamic equilibrium with the composition of syngas. Calculations for the methane/air-steam and 2-propanol/air-steam conversion are provided as examples. The calculations show that the process provides a possibility to combine in a stationary continuous process a high combustion temperature with low net heat effect and thus, a high chemical efficiency of conversion. The parametric domain for control parameters providing highly efficient conversion is determined. Partial oxidation Syngas production Filtration combustion Porous media Reactor design Dorofeenko, S.O. verfasserin aut Enthalten in International journal of hydrogen energy New York, NY [u.a.] : Elsevier, 1976 44 Online-Ressource (DE-627)301511357 (DE-600)1484487-4 (DE-576)096806397 1879-3487 nnns volume:44 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.56 Regenerative Energieformen alternative Energieformen AR 44 |
allfieldsGer |
10.1016/j.ijhydene.2018.12.117 doi (DE-627)ELV001525360 (ELSEVIER)S0360-3199(18)34085-0 DE-627 ger DE-627 rda eng 660 620 DE-600 52.56 bkl Polianczyk, E.V. verfasserin aut Conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the previously considered conversion in a reversed-flow reactor, such embodiment provides a possibility of attaining high combustion temperature due to efficient heat recuperation, while performing the process continuously without transients associated with the flow reverse. In the moving bed process, the flowrate of the granular material becomes an independent control parameter. A thermodynamic assessment of the macrokinetic conversion regimes as dependent on fuel composition and oxidant gas and fuel supply rates and granular solid flowrate is performed under the assumption that the combustion temperature is self-consistent according to thermodynamic equilibrium with the composition of syngas. Calculations for the methane/air-steam and 2-propanol/air-steam conversion are provided as examples. The calculations show that the process provides a possibility to combine in a stationary continuous process a high combustion temperature with low net heat effect and thus, a high chemical efficiency of conversion. The parametric domain for control parameters providing highly efficient conversion is determined. Partial oxidation Syngas production Filtration combustion Porous media Reactor design Dorofeenko, S.O. verfasserin aut Enthalten in International journal of hydrogen energy New York, NY [u.a.] : Elsevier, 1976 44 Online-Ressource (DE-627)301511357 (DE-600)1484487-4 (DE-576)096806397 1879-3487 nnns volume:44 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.56 Regenerative Energieformen alternative Energieformen AR 44 |
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10.1016/j.ijhydene.2018.12.117 doi (DE-627)ELV001525360 (ELSEVIER)S0360-3199(18)34085-0 DE-627 ger DE-627 rda eng 660 620 DE-600 52.56 bkl Polianczyk, E.V. verfasserin aut Conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the previously considered conversion in a reversed-flow reactor, such embodiment provides a possibility of attaining high combustion temperature due to efficient heat recuperation, while performing the process continuously without transients associated with the flow reverse. In the moving bed process, the flowrate of the granular material becomes an independent control parameter. A thermodynamic assessment of the macrokinetic conversion regimes as dependent on fuel composition and oxidant gas and fuel supply rates and granular solid flowrate is performed under the assumption that the combustion temperature is self-consistent according to thermodynamic equilibrium with the composition of syngas. Calculations for the methane/air-steam and 2-propanol/air-steam conversion are provided as examples. The calculations show that the process provides a possibility to combine in a stationary continuous process a high combustion temperature with low net heat effect and thus, a high chemical efficiency of conversion. The parametric domain for control parameters providing highly efficient conversion is determined. Partial oxidation Syngas production Filtration combustion Porous media Reactor design Dorofeenko, S.O. verfasserin aut Enthalten in International journal of hydrogen energy New York, NY [u.a.] : Elsevier, 1976 44 Online-Ressource (DE-627)301511357 (DE-600)1484487-4 (DE-576)096806397 1879-3487 nnns volume:44 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.56 Regenerative Energieformen alternative Energieformen AR 44 |
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International journal of hydrogen energy |
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International journal of hydrogen energy |
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600 - Technology |
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Polianczyk, E.V. Dorofeenko, S.O. |
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Elektronische Aufsätze |
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Polianczyk, E.V. |
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10.1016/j.ijhydene.2018.12.117 |
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660 620 |
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title_sort |
conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor |
title_auth |
Conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor |
abstract |
The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the previously considered conversion in a reversed-flow reactor, such embodiment provides a possibility of attaining high combustion temperature due to efficient heat recuperation, while performing the process continuously without transients associated with the flow reverse. In the moving bed process, the flowrate of the granular material becomes an independent control parameter. A thermodynamic assessment of the macrokinetic conversion regimes as dependent on fuel composition and oxidant gas and fuel supply rates and granular solid flowrate is performed under the assumption that the combustion temperature is self-consistent according to thermodynamic equilibrium with the composition of syngas. Calculations for the methane/air-steam and 2-propanol/air-steam conversion are provided as examples. The calculations show that the process provides a possibility to combine in a stationary continuous process a high combustion temperature with low net heat effect and thus, a high chemical efficiency of conversion. The parametric domain for control parameters providing highly efficient conversion is determined. |
abstractGer |
The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the previously considered conversion in a reversed-flow reactor, such embodiment provides a possibility of attaining high combustion temperature due to efficient heat recuperation, while performing the process continuously without transients associated with the flow reverse. In the moving bed process, the flowrate of the granular material becomes an independent control parameter. A thermodynamic assessment of the macrokinetic conversion regimes as dependent on fuel composition and oxidant gas and fuel supply rates and granular solid flowrate is performed under the assumption that the combustion temperature is self-consistent according to thermodynamic equilibrium with the composition of syngas. Calculations for the methane/air-steam and 2-propanol/air-steam conversion are provided as examples. The calculations show that the process provides a possibility to combine in a stationary continuous process a high combustion temperature with low net heat effect and thus, a high chemical efficiency of conversion. The parametric domain for control parameters providing highly efficient conversion is determined. |
abstract_unstemmed |
The conversion of hydrocarbons to synthesis gases via partial oxidation in a non-premixed filtration combustion is considered in a continuous reactor wherein filtration medium/inert solid matrix comprises a moving bed of a granular material flowing countercurrently to the gas flow. Similar to the previously considered conversion in a reversed-flow reactor, such embodiment provides a possibility of attaining high combustion temperature due to efficient heat recuperation, while performing the process continuously without transients associated with the flow reverse. In the moving bed process, the flowrate of the granular material becomes an independent control parameter. A thermodynamic assessment of the macrokinetic conversion regimes as dependent on fuel composition and oxidant gas and fuel supply rates and granular solid flowrate is performed under the assumption that the combustion temperature is self-consistent according to thermodynamic equilibrium with the composition of syngas. Calculations for the methane/air-steam and 2-propanol/air-steam conversion are provided as examples. The calculations show that the process provides a possibility to combine in a stationary continuous process a high combustion temperature with low net heat effect and thus, a high chemical efficiency of conversion. The parametric domain for control parameters providing highly efficient conversion is determined. |
collection_details |
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title_short |
Conversion of hydrocarbons to synthesis gas in a counterflow moving bed filtration combustion reactor |
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Dorofeenko, S.O. |
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doi_str |
10.1016/j.ijhydene.2018.12.117 |
up_date |
2024-07-06T21:40:18.037Z |
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