Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems

We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temp...
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Gespeichert in:

Autor*in:	Xu, Siquan [verfasserIn] Pan, Donghui [verfasserIn] Wu, Yuanfeng [verfasserIn] Song, Xianghai [verfasserIn] Gao, Lijing [verfasserIn] Li, Wenqi [verfasserIn] Das, Lalitendu [verfasserIn] Xiao, Guomin [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	Furfural 5-Hydroxymethylfurfural Wheat straw Bifunctional catalyst CrPO

Übergeordnetes Werk:	Enthalten in: Fuel processing technology - New York, NY [u.a.] : Science Direct, 1977, 175, Seite 90-96
Übergeordnetes Werk:	volume:175 ; pages:90-96

DOI / URN:	10.1016/j.fuproc.2018.04.005

Katalog-ID:	ELV001787330

Internformat


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245	1	0	\|a Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems
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520			\|a We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. It was found that the CrPO4 was easily to be recovered and a great catalytic activity was available after four cycles, which not only contributed to a sustainably reduced energy consumption on catalyst recovery, but also reduced the concerns associated with toxic chromium element.
650		4	\|a Furfural
650		4	\|a 5-Hydroxymethylfurfural
650		4	\|a Wheat straw
650		4	\|a Bifunctional catalyst
650		4	\|a CrPO
700	1		\|a Pan, Donghui \|e verfasserin \|4 aut
700	1		\|a Wu, Yuanfeng \|e verfasserin \|4 aut
700	1		\|a Song, Xianghai \|e verfasserin \|4 aut
700	1		\|a Gao, Lijing \|e verfasserin \|4 aut
700	1		\|a Li, Wenqi \|e verfasserin \|4 aut
700	1		\|a Das, Lalitendu \|e verfasserin \|4 aut
700	1		\|a Xiao, Guomin \|e verfasserin \|0 (orcid)0000-0001-8482-1276 \|4 aut
773	0	8	\|i Enthalten in \|t Fuel processing technology \|d New York, NY [u.a.] : Science Direct, 1977 \|g 175, Seite 90-96 \|h Online-Ressource \|w (DE-627)300898681 \|w (DE-600)1483666-X \|w (DE-576)09618860X \|7 nnns
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912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
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912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
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912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
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912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
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936	b	k	\|a 58.21 \|j Brennstoffe \|j Kraftstoffe \|j Explosivstoffe
951			\|a AR
952			\|d 175 \|h 90-96

Indexfelder

author_variant	s x sx d p dp y w yw x s xs l g lg w l wl l d ld g x gx
matchkey_str	xusiquanpandonghuiwuyuanfengsongxianghai:2018----:fiinpoutoofruafoxlsadhasrwyiucinlhoimhsh
hierarchy_sort_str	2018
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publishDate	2018
allfields	10.1016/j.fuproc.2018.04.005 doi (DE-627)ELV001787330 (ELSEVIER)S0378-3820(17)31954-9 DE-627 ger DE-627 rda eng 660 DE-600 58.21 bkl Xu, Siquan verfasserin aut Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. It was found that the CrPO4 was easily to be recovered and a great catalytic activity was available after four cycles, which not only contributed to a sustainably reduced energy consumption on catalyst recovery, but also reduced the concerns associated with toxic chromium element. Furfural 5-Hydroxymethylfurfural Wheat straw Bifunctional catalyst CrPO Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Song, Xianghai verfasserin aut Gao, Lijing verfasserin aut Li, Wenqi verfasserin aut Das, Lalitendu verfasserin aut Xiao, Guomin verfasserin (orcid)0000-0001-8482-1276 aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 175, Seite 90-96 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:175 pages:90-96 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe AR 175 90-96
spelling	10.1016/j.fuproc.2018.04.005 doi (DE-627)ELV001787330 (ELSEVIER)S0378-3820(17)31954-9 DE-627 ger DE-627 rda eng 660 DE-600 58.21 bkl Xu, Siquan verfasserin aut Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. It was found that the CrPO4 was easily to be recovered and a great catalytic activity was available after four cycles, which not only contributed to a sustainably reduced energy consumption on catalyst recovery, but also reduced the concerns associated with toxic chromium element. Furfural 5-Hydroxymethylfurfural Wheat straw Bifunctional catalyst CrPO Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Song, Xianghai verfasserin aut Gao, Lijing verfasserin aut Li, Wenqi verfasserin aut Das, Lalitendu verfasserin aut Xiao, Guomin verfasserin (orcid)0000-0001-8482-1276 aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 175, Seite 90-96 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:175 pages:90-96 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe AR 175 90-96
allfields_unstemmed	10.1016/j.fuproc.2018.04.005 doi (DE-627)ELV001787330 (ELSEVIER)S0378-3820(17)31954-9 DE-627 ger DE-627 rda eng 660 DE-600 58.21 bkl Xu, Siquan verfasserin aut Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. It was found that the CrPO4 was easily to be recovered and a great catalytic activity was available after four cycles, which not only contributed to a sustainably reduced energy consumption on catalyst recovery, but also reduced the concerns associated with toxic chromium element. Furfural 5-Hydroxymethylfurfural Wheat straw Bifunctional catalyst CrPO Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Song, Xianghai verfasserin aut Gao, Lijing verfasserin aut Li, Wenqi verfasserin aut Das, Lalitendu verfasserin aut Xiao, Guomin verfasserin (orcid)0000-0001-8482-1276 aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 175, Seite 90-96 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:175 pages:90-96 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe AR 175 90-96
allfieldsGer	10.1016/j.fuproc.2018.04.005 doi (DE-627)ELV001787330 (ELSEVIER)S0378-3820(17)31954-9 DE-627 ger DE-627 rda eng 660 DE-600 58.21 bkl Xu, Siquan verfasserin aut Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. It was found that the CrPO4 was easily to be recovered and a great catalytic activity was available after four cycles, which not only contributed to a sustainably reduced energy consumption on catalyst recovery, but also reduced the concerns associated with toxic chromium element. Furfural 5-Hydroxymethylfurfural Wheat straw Bifunctional catalyst CrPO Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Song, Xianghai verfasserin aut Gao, Lijing verfasserin aut Li, Wenqi verfasserin aut Das, Lalitendu verfasserin aut Xiao, Guomin verfasserin (orcid)0000-0001-8482-1276 aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 175, Seite 90-96 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:175 pages:90-96 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe AR 175 90-96
allfieldsSound	10.1016/j.fuproc.2018.04.005 doi (DE-627)ELV001787330 (ELSEVIER)S0378-3820(17)31954-9 DE-627 ger DE-627 rda eng 660 DE-600 58.21 bkl Xu, Siquan verfasserin aut Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems 2018 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. It was found that the CrPO4 was easily to be recovered and a great catalytic activity was available after four cycles, which not only contributed to a sustainably reduced energy consumption on catalyst recovery, but also reduced the concerns associated with toxic chromium element. Furfural 5-Hydroxymethylfurfural Wheat straw Bifunctional catalyst CrPO Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Song, Xianghai verfasserin aut Gao, Lijing verfasserin aut Li, Wenqi verfasserin aut Das, Lalitendu verfasserin aut Xiao, Guomin verfasserin (orcid)0000-0001-8482-1276 aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 175, Seite 90-96 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:175 pages:90-96 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe AR 175 90-96
language	English
source	Enthalten in Fuel processing technology 175, Seite 90-96 volume:175 pages:90-96
sourceStr	Enthalten in Fuel processing technology 175, Seite 90-96 volume:175 pages:90-96
format_phy_str_mv	Article
bklname	Brennstoffe Kraftstoffe Explosivstoffe
institution	findex.gbv.de
topic_facet	Furfural 5-Hydroxymethylfurfural Wheat straw Bifunctional catalyst CrPO
dewey-raw	660
isfreeaccess_bool	false
container_title	Fuel processing technology
authorswithroles_txt_mv	Xu, Siquan @@aut@@ Pan, Donghui @@aut@@ Wu, Yuanfeng @@aut@@ Song, Xianghai @@aut@@ Gao, Lijing @@aut@@ Li, Wenqi @@aut@@ Das, Lalitendu @@aut@@ Xiao, Guomin @@aut@@
publishDateDaySort_date	2018-01-01T00:00:00Z
hierarchy_top_id	300898681
dewey-sort	3660
id	ELV001787330
language_de	englisch
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The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. 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author	Xu, Siquan
spellingShingle	Xu, Siquan ddc 660 bkl 58.21 misc Furfural misc 5-Hydroxymethylfurfural misc Wheat straw misc Bifunctional catalyst misc CrPO Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems
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topic_title	660 DE-600 58.21 bkl Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems Furfural 5-Hydroxymethylfurfural Wheat straw Bifunctional catalyst CrPO
topic	ddc 660 bkl 58.21 misc Furfural misc 5-Hydroxymethylfurfural misc Wheat straw misc Bifunctional catalyst misc CrPO
topic_unstemmed	ddc 660 bkl 58.21 misc Furfural misc 5-Hydroxymethylfurfural misc Wheat straw misc Bifunctional catalyst misc CrPO
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title	Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems
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title_full	Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems
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title_sort	efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems
title_auth	Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems
abstract	We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. It was found that the CrPO4 was easily to be recovered and a great catalytic activity was available after four cycles, which not only contributed to a sustainably reduced energy consumption on catalyst recovery, but also reduced the concerns associated with toxic chromium element.
abstractGer	We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. It was found that the CrPO4 was easily to be recovered and a great catalytic activity was available after four cycles, which not only contributed to a sustainably reduced energy consumption on catalyst recovery, but also reduced the concerns associated with toxic chromium element.
abstract_unstemmed	We present here a study of the production of furfural from xylose and wheat straw using the chromium phosphate (CrPO4) with Lewis and Brønsted acidity as a highly efficient catalyst in the water/tetrahydrofuran (THF) biphasic system. The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. It was found that the CrPO4 was easily to be recovered and a great catalytic activity was available after four cycles, which not only contributed to a sustainably reduced energy consumption on catalyst recovery, but also reduced the concerns associated with toxic chromium element.
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title_short	Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems
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author2	Pan, Donghui Wu, Yuanfeng Song, Xianghai Gao, Lijing Li, Wenqi Das, Lalitendu Xiao, Guomin
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up_date	2024-07-06T22:34:23.716Z
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The effects of various reaction parameters including reaction temperature, reaction time, system, and catalyst dosage were explored to evaluate the product yield. Under CrPO4 catalysis, an excellent furfural yield could reach 88% from the xylose at 160 °C for 60 min. Meanwhile, 67% furfural and 32% 5‑hydroxymethylfurfura (HMF) were simultaneously achieved from wheat straw at 180 °C for 90 min. Mechanistic studies suggested that the perfect catalytic activity of CrPO4 was due to its inherent bifunctional catalysis activity. 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Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems

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