Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering
An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-bloc...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Doi, Takahiro [verfasserIn] Takagi, Hideaki [verfasserIn] Shimizu, Nobutaka [verfasserIn] Igarashi, Noriyuki [verfasserIn] Sakurai, Shinichi [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Übergeordnetes Werk: |
Enthalten in: Polymer - Oxford : Elsevier Science, 1960, 170, Seite 211-221 |
|---|---|
| Übergeordnetes Werk: |
volume:170 ; pages:211-221 |
| DOI / URN: |
10.1016/j.polymer.2019.02.052 |
|---|
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ELV00201873X |
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| 245 | 1 | 0 | |a Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering |
| 264 | 1 | |c 2019 | |
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| 520 | |a An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-block-polymethylmethacrylate triblock copolymer (MAM) and a polymethylmethacrylate-block-poly(n-butylacrylate) diblock copolymer (MA). The thickness of the prepared specimens was 50 μm, which is typical of the pressure-sensitive adhesives. Atomic force microscope (AFM) observations and two-dimensional small-angle X-ray scattering (2d-SAXS) measurements were performed to analyze the nano structures and to discuss the effects of the drying temperature on the nano structures. Note that better physical properties were obtained in the specimen prepared at the lower drying temperature. The AFM observations revealed cylindrical morphology for the annealed MAM neat specimen. On the other hand, the 2d-SAXS measurements revealed spherical morphology for all of the specimens including MAM neat and MA/MAM blends. The effects of the drying temperature on the ordering regularity of spheres, d spacing, and radius of sphere has been examined quantitatively. It was found that the ordering regularity of spheres was more improved for the higher drying temperature. As for the behaviors of d and R, the experimental results exhibited very complicated behaviors as a function of the drying temperature. Namely, d and R increased as a function of the drying temperature, which is completely opposite to the general behaviors of the block copolymer microdomain structure as d or R ∝ T −1/3 for the upper critical solution temperature system where the interaction between two kinds of the constituent block chains is decreased with an increase in temperature. The effect of structure freezing during the solvent evaporation was taken into account and such complicated behaviors of experimental results (d and R) could be almost perfectly explained. It is concluded by this study that the poor regularity of the sphere ordering provides softer property with larger elongation at break for the coated film, which is more suitable as the pressure-sensitive adhesives. | ||
| 700 | 1 | |a Takagi, Hideaki |e verfasserin |0 (orcid)0000-0003-3389-7945 |4 aut | |
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| 700 | 1 | |a Igarashi, Noriyuki |e verfasserin |4 aut | |
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10.1016/j.polymer.2019.02.052 doi (DE-627)ELV00201873X (ELSEVIER)S0032-3861(19)30192-2 DE-627 ger DE-627 rda eng 540 DE-600 35.80 bkl 51.70 bkl 58.22 bkl Doi, Takahiro verfasserin aut Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-block-polymethylmethacrylate triblock copolymer (MAM) and a polymethylmethacrylate-block-poly(n-butylacrylate) diblock copolymer (MA). The thickness of the prepared specimens was 50 μm, which is typical of the pressure-sensitive adhesives. Atomic force microscope (AFM) observations and two-dimensional small-angle X-ray scattering (2d-SAXS) measurements were performed to analyze the nano structures and to discuss the effects of the drying temperature on the nano structures. Note that better physical properties were obtained in the specimen prepared at the lower drying temperature. The AFM observations revealed cylindrical morphology for the annealed MAM neat specimen. On the other hand, the 2d-SAXS measurements revealed spherical morphology for all of the specimens including MAM neat and MA/MAM blends. The effects of the drying temperature on the ordering regularity of spheres, d spacing, and radius of sphere has been examined quantitatively. It was found that the ordering regularity of spheres was more improved for the higher drying temperature. As for the behaviors of d and R, the experimental results exhibited very complicated behaviors as a function of the drying temperature. Namely, d and R increased as a function of the drying temperature, which is completely opposite to the general behaviors of the block copolymer microdomain structure as d or R ∝ T −1/3 for the upper critical solution temperature system where the interaction between two kinds of the constituent block chains is decreased with an increase in temperature. The effect of structure freezing during the solvent evaporation was taken into account and such complicated behaviors of experimental results (d and R) could be almost perfectly explained. It is concluded by this study that the poor regularity of the sphere ordering provides softer property with larger elongation at break for the coated film, which is more suitable as the pressure-sensitive adhesives. Takagi, Hideaki verfasserin (orcid)0000-0003-3389-7945 aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin (orcid)0000-0002-5756-1066 aut Enthalten in Polymer Oxford : Elsevier Science, 1960 170, Seite 211-221 Online-Ressource (DE-627)32051613X (DE-600)2013972-X (DE-576)093888422 0032-3861 nnns volume:170 pages:211-221 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.80 Makromolekulare Chemie 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde 58.22 Kunststofftechnologie AR 170 211-221 |
| spelling |
10.1016/j.polymer.2019.02.052 doi (DE-627)ELV00201873X (ELSEVIER)S0032-3861(19)30192-2 DE-627 ger DE-627 rda eng 540 DE-600 35.80 bkl 51.70 bkl 58.22 bkl Doi, Takahiro verfasserin aut Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-block-polymethylmethacrylate triblock copolymer (MAM) and a polymethylmethacrylate-block-poly(n-butylacrylate) diblock copolymer (MA). The thickness of the prepared specimens was 50 μm, which is typical of the pressure-sensitive adhesives. Atomic force microscope (AFM) observations and two-dimensional small-angle X-ray scattering (2d-SAXS) measurements were performed to analyze the nano structures and to discuss the effects of the drying temperature on the nano structures. Note that better physical properties were obtained in the specimen prepared at the lower drying temperature. The AFM observations revealed cylindrical morphology for the annealed MAM neat specimen. On the other hand, the 2d-SAXS measurements revealed spherical morphology for all of the specimens including MAM neat and MA/MAM blends. The effects of the drying temperature on the ordering regularity of spheres, d spacing, and radius of sphere has been examined quantitatively. It was found that the ordering regularity of spheres was more improved for the higher drying temperature. As for the behaviors of d and R, the experimental results exhibited very complicated behaviors as a function of the drying temperature. Namely, d and R increased as a function of the drying temperature, which is completely opposite to the general behaviors of the block copolymer microdomain structure as d or R ∝ T −1/3 for the upper critical solution temperature system where the interaction between two kinds of the constituent block chains is decreased with an increase in temperature. The effect of structure freezing during the solvent evaporation was taken into account and such complicated behaviors of experimental results (d and R) could be almost perfectly explained. It is concluded by this study that the poor regularity of the sphere ordering provides softer property with larger elongation at break for the coated film, which is more suitable as the pressure-sensitive adhesives. Takagi, Hideaki verfasserin (orcid)0000-0003-3389-7945 aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin (orcid)0000-0002-5756-1066 aut Enthalten in Polymer Oxford : Elsevier Science, 1960 170, Seite 211-221 Online-Ressource (DE-627)32051613X (DE-600)2013972-X (DE-576)093888422 0032-3861 nnns volume:170 pages:211-221 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.80 Makromolekulare Chemie 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde 58.22 Kunststofftechnologie AR 170 211-221 |
| allfields_unstemmed |
10.1016/j.polymer.2019.02.052 doi (DE-627)ELV00201873X (ELSEVIER)S0032-3861(19)30192-2 DE-627 ger DE-627 rda eng 540 DE-600 35.80 bkl 51.70 bkl 58.22 bkl Doi, Takahiro verfasserin aut Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-block-polymethylmethacrylate triblock copolymer (MAM) and a polymethylmethacrylate-block-poly(n-butylacrylate) diblock copolymer (MA). The thickness of the prepared specimens was 50 μm, which is typical of the pressure-sensitive adhesives. Atomic force microscope (AFM) observations and two-dimensional small-angle X-ray scattering (2d-SAXS) measurements were performed to analyze the nano structures and to discuss the effects of the drying temperature on the nano structures. Note that better physical properties were obtained in the specimen prepared at the lower drying temperature. The AFM observations revealed cylindrical morphology for the annealed MAM neat specimen. On the other hand, the 2d-SAXS measurements revealed spherical morphology for all of the specimens including MAM neat and MA/MAM blends. The effects of the drying temperature on the ordering regularity of spheres, d spacing, and radius of sphere has been examined quantitatively. It was found that the ordering regularity of spheres was more improved for the higher drying temperature. As for the behaviors of d and R, the experimental results exhibited very complicated behaviors as a function of the drying temperature. Namely, d and R increased as a function of the drying temperature, which is completely opposite to the general behaviors of the block copolymer microdomain structure as d or R ∝ T −1/3 for the upper critical solution temperature system where the interaction between two kinds of the constituent block chains is decreased with an increase in temperature. The effect of structure freezing during the solvent evaporation was taken into account and such complicated behaviors of experimental results (d and R) could be almost perfectly explained. It is concluded by this study that the poor regularity of the sphere ordering provides softer property with larger elongation at break for the coated film, which is more suitable as the pressure-sensitive adhesives. Takagi, Hideaki verfasserin (orcid)0000-0003-3389-7945 aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin (orcid)0000-0002-5756-1066 aut Enthalten in Polymer Oxford : Elsevier Science, 1960 170, Seite 211-221 Online-Ressource (DE-627)32051613X (DE-600)2013972-X (DE-576)093888422 0032-3861 nnns volume:170 pages:211-221 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.80 Makromolekulare Chemie 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde 58.22 Kunststofftechnologie AR 170 211-221 |
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10.1016/j.polymer.2019.02.052 doi (DE-627)ELV00201873X (ELSEVIER)S0032-3861(19)30192-2 DE-627 ger DE-627 rda eng 540 DE-600 35.80 bkl 51.70 bkl 58.22 bkl Doi, Takahiro verfasserin aut Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-block-polymethylmethacrylate triblock copolymer (MAM) and a polymethylmethacrylate-block-poly(n-butylacrylate) diblock copolymer (MA). The thickness of the prepared specimens was 50 μm, which is typical of the pressure-sensitive adhesives. Atomic force microscope (AFM) observations and two-dimensional small-angle X-ray scattering (2d-SAXS) measurements were performed to analyze the nano structures and to discuss the effects of the drying temperature on the nano structures. Note that better physical properties were obtained in the specimen prepared at the lower drying temperature. The AFM observations revealed cylindrical morphology for the annealed MAM neat specimen. On the other hand, the 2d-SAXS measurements revealed spherical morphology for all of the specimens including MAM neat and MA/MAM blends. The effects of the drying temperature on the ordering regularity of spheres, d spacing, and radius of sphere has been examined quantitatively. It was found that the ordering regularity of spheres was more improved for the higher drying temperature. As for the behaviors of d and R, the experimental results exhibited very complicated behaviors as a function of the drying temperature. Namely, d and R increased as a function of the drying temperature, which is completely opposite to the general behaviors of the block copolymer microdomain structure as d or R ∝ T −1/3 for the upper critical solution temperature system where the interaction between two kinds of the constituent block chains is decreased with an increase in temperature. The effect of structure freezing during the solvent evaporation was taken into account and such complicated behaviors of experimental results (d and R) could be almost perfectly explained. It is concluded by this study that the poor regularity of the sphere ordering provides softer property with larger elongation at break for the coated film, which is more suitable as the pressure-sensitive adhesives. Takagi, Hideaki verfasserin (orcid)0000-0003-3389-7945 aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin (orcid)0000-0002-5756-1066 aut Enthalten in Polymer Oxford : Elsevier Science, 1960 170, Seite 211-221 Online-Ressource (DE-627)32051613X (DE-600)2013972-X (DE-576)093888422 0032-3861 nnns volume:170 pages:211-221 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.80 Makromolekulare Chemie 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde 58.22 Kunststofftechnologie AR 170 211-221 |
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10.1016/j.polymer.2019.02.052 doi (DE-627)ELV00201873X (ELSEVIER)S0032-3861(19)30192-2 DE-627 ger DE-627 rda eng 540 DE-600 35.80 bkl 51.70 bkl 58.22 bkl Doi, Takahiro verfasserin aut Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-block-polymethylmethacrylate triblock copolymer (MAM) and a polymethylmethacrylate-block-poly(n-butylacrylate) diblock copolymer (MA). The thickness of the prepared specimens was 50 μm, which is typical of the pressure-sensitive adhesives. Atomic force microscope (AFM) observations and two-dimensional small-angle X-ray scattering (2d-SAXS) measurements were performed to analyze the nano structures and to discuss the effects of the drying temperature on the nano structures. Note that better physical properties were obtained in the specimen prepared at the lower drying temperature. The AFM observations revealed cylindrical morphology for the annealed MAM neat specimen. On the other hand, the 2d-SAXS measurements revealed spherical morphology for all of the specimens including MAM neat and MA/MAM blends. The effects of the drying temperature on the ordering regularity of spheres, d spacing, and radius of sphere has been examined quantitatively. It was found that the ordering regularity of spheres was more improved for the higher drying temperature. As for the behaviors of d and R, the experimental results exhibited very complicated behaviors as a function of the drying temperature. Namely, d and R increased as a function of the drying temperature, which is completely opposite to the general behaviors of the block copolymer microdomain structure as d or R ∝ T −1/3 for the upper critical solution temperature system where the interaction between two kinds of the constituent block chains is decreased with an increase in temperature. The effect of structure freezing during the solvent evaporation was taken into account and such complicated behaviors of experimental results (d and R) could be almost perfectly explained. It is concluded by this study that the poor regularity of the sphere ordering provides softer property with larger elongation at break for the coated film, which is more suitable as the pressure-sensitive adhesives. Takagi, Hideaki verfasserin (orcid)0000-0003-3389-7945 aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin (orcid)0000-0002-5756-1066 aut Enthalten in Polymer Oxford : Elsevier Science, 1960 170, Seite 211-221 Online-Ressource (DE-627)32051613X (DE-600)2013972-X (DE-576)093888422 0032-3861 nnns volume:170 pages:211-221 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.80 Makromolekulare Chemie 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde 58.22 Kunststofftechnologie AR 170 211-221 |
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Doi, Takahiro |
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Doi, Takahiro ddc 540 bkl 35.80 bkl 51.70 bkl 58.22 Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering |
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540 DE-600 35.80 bkl 51.70 bkl 58.22 bkl Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering |
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Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering |
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Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering |
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Doi, Takahiro Takagi, Hideaki Shimizu, Nobutaka Igarashi, Noriyuki Sakurai, Shinichi |
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10.1016/j.polymer.2019.02.052 |
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effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle x-ray scattering |
| title_auth |
Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering |
| abstract |
An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-block-polymethylmethacrylate triblock copolymer (MAM) and a polymethylmethacrylate-block-poly(n-butylacrylate) diblock copolymer (MA). The thickness of the prepared specimens was 50 μm, which is typical of the pressure-sensitive adhesives. Atomic force microscope (AFM) observations and two-dimensional small-angle X-ray scattering (2d-SAXS) measurements were performed to analyze the nano structures and to discuss the effects of the drying temperature on the nano structures. Note that better physical properties were obtained in the specimen prepared at the lower drying temperature. The AFM observations revealed cylindrical morphology for the annealed MAM neat specimen. On the other hand, the 2d-SAXS measurements revealed spherical morphology for all of the specimens including MAM neat and MA/MAM blends. The effects of the drying temperature on the ordering regularity of spheres, d spacing, and radius of sphere has been examined quantitatively. It was found that the ordering regularity of spheres was more improved for the higher drying temperature. As for the behaviors of d and R, the experimental results exhibited very complicated behaviors as a function of the drying temperature. Namely, d and R increased as a function of the drying temperature, which is completely opposite to the general behaviors of the block copolymer microdomain structure as d or R ∝ T −1/3 for the upper critical solution temperature system where the interaction between two kinds of the constituent block chains is decreased with an increase in temperature. The effect of structure freezing during the solvent evaporation was taken into account and such complicated behaviors of experimental results (d and R) could be almost perfectly explained. It is concluded by this study that the poor regularity of the sphere ordering provides softer property with larger elongation at break for the coated film, which is more suitable as the pressure-sensitive adhesives. |
| abstractGer |
An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-block-polymethylmethacrylate triblock copolymer (MAM) and a polymethylmethacrylate-block-poly(n-butylacrylate) diblock copolymer (MA). The thickness of the prepared specimens was 50 μm, which is typical of the pressure-sensitive adhesives. Atomic force microscope (AFM) observations and two-dimensional small-angle X-ray scattering (2d-SAXS) measurements were performed to analyze the nano structures and to discuss the effects of the drying temperature on the nano structures. Note that better physical properties were obtained in the specimen prepared at the lower drying temperature. The AFM observations revealed cylindrical morphology for the annealed MAM neat specimen. On the other hand, the 2d-SAXS measurements revealed spherical morphology for all of the specimens including MAM neat and MA/MAM blends. The effects of the drying temperature on the ordering regularity of spheres, d spacing, and radius of sphere has been examined quantitatively. It was found that the ordering regularity of spheres was more improved for the higher drying temperature. As for the behaviors of d and R, the experimental results exhibited very complicated behaviors as a function of the drying temperature. Namely, d and R increased as a function of the drying temperature, which is completely opposite to the general behaviors of the block copolymer microdomain structure as d or R ∝ T −1/3 for the upper critical solution temperature system where the interaction between two kinds of the constituent block chains is decreased with an increase in temperature. The effect of structure freezing during the solvent evaporation was taken into account and such complicated behaviors of experimental results (d and R) could be almost perfectly explained. It is concluded by this study that the poor regularity of the sphere ordering provides softer property with larger elongation at break for the coated film, which is more suitable as the pressure-sensitive adhesives. |
| abstract_unstemmed |
An acrylic block copolymer system is a promising candidate for the functional adhesives bearing good weatherability as well as high transparency. Coated layers of the acrylic block copolymers were prepared by the solution coating method using a polymethylmethacrylate-block-poly(n-butylacrylate)-block-polymethylmethacrylate triblock copolymer (MAM) and a polymethylmethacrylate-block-poly(n-butylacrylate) diblock copolymer (MA). The thickness of the prepared specimens was 50 μm, which is typical of the pressure-sensitive adhesives. Atomic force microscope (AFM) observations and two-dimensional small-angle X-ray scattering (2d-SAXS) measurements were performed to analyze the nano structures and to discuss the effects of the drying temperature on the nano structures. Note that better physical properties were obtained in the specimen prepared at the lower drying temperature. The AFM observations revealed cylindrical morphology for the annealed MAM neat specimen. On the other hand, the 2d-SAXS measurements revealed spherical morphology for all of the specimens including MAM neat and MA/MAM blends. The effects of the drying temperature on the ordering regularity of spheres, d spacing, and radius of sphere has been examined quantitatively. It was found that the ordering regularity of spheres was more improved for the higher drying temperature. As for the behaviors of d and R, the experimental results exhibited very complicated behaviors as a function of the drying temperature. Namely, d and R increased as a function of the drying temperature, which is completely opposite to the general behaviors of the block copolymer microdomain structure as d or R ∝ T −1/3 for the upper critical solution temperature system where the interaction between two kinds of the constituent block chains is decreased with an increase in temperature. The effect of structure freezing during the solvent evaporation was taken into account and such complicated behaviors of experimental results (d and R) could be almost perfectly explained. It is concluded by this study that the poor regularity of the sphere ordering provides softer property with larger elongation at break for the coated film, which is more suitable as the pressure-sensitive adhesives. |
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Effects of drying temperature in solution coating process on microphase-separated structures in coated layers of pressure-sensitive adhesive composed of di- and triblock copolymer blends as revealed by small-angle X-ray scattering |
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