Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)”

An error is found in the thermodynamic equation used by Singh and coworkers to calculate the apparent molar volume of paracetamol in water and in several binary aqueous-urea solvent mixtures. The negative apparent molar volumes reported in the published paper are highly questionable. A search of the...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Acree, William E. [verfasserIn] Martínez, Fleming [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Apparent molar volume Paracetamol Aqueous solution Binary aqueous-urea solvent mixtures

Übergeordnetes Werk:	Enthalten in: Journal of molecular liquids - New York, NY [u.a.] : Elsevier, 1983, 283, Seite 548-549
Übergeordnetes Werk:	volume:283 ; pages:548-549

DOI / URN:	10.1016/j.molliq.2019.03.123

Katalog-ID:	ELV002176459

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allfields	10.1016/j.molliq.2019.03.123 doi (DE-627)ELV002176459 (ELSEVIER)S0167-7322(19)31109-2 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Acree, William E. verfasserin aut Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)” 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An error is found in the thermodynamic equation used by Singh and coworkers to calculate the apparent molar volume of paracetamol in water and in several binary aqueous-urea solvent mixtures. The negative apparent molar volumes reported in the published paper are highly questionable. A search of the published chemical literature found three sets of independently determined values for the apparent molar volume of paracetamol in water. Published literature values differ significantly from the values reported by Singh and coworkers. Apparent molar volume Paracetamol Aqueous solution Binary aqueous-urea solvent mixtures Martínez, Fleming verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 283, Seite 548-549 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:283 pages:548-549 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 283 548-549
spelling	10.1016/j.molliq.2019.03.123 doi (DE-627)ELV002176459 (ELSEVIER)S0167-7322(19)31109-2 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Acree, William E. verfasserin aut Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)” 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An error is found in the thermodynamic equation used by Singh and coworkers to calculate the apparent molar volume of paracetamol in water and in several binary aqueous-urea solvent mixtures. The negative apparent molar volumes reported in the published paper are highly questionable. A search of the published chemical literature found three sets of independently determined values for the apparent molar volume of paracetamol in water. Published literature values differ significantly from the values reported by Singh and coworkers. Apparent molar volume Paracetamol Aqueous solution Binary aqueous-urea solvent mixtures Martínez, Fleming verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 283, Seite 548-549 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:283 pages:548-549 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 283 548-549
allfields_unstemmed	10.1016/j.molliq.2019.03.123 doi (DE-627)ELV002176459 (ELSEVIER)S0167-7322(19)31109-2 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Acree, William E. verfasserin aut Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)” 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An error is found in the thermodynamic equation used by Singh and coworkers to calculate the apparent molar volume of paracetamol in water and in several binary aqueous-urea solvent mixtures. The negative apparent molar volumes reported in the published paper are highly questionable. A search of the published chemical literature found three sets of independently determined values for the apparent molar volume of paracetamol in water. Published literature values differ significantly from the values reported by Singh and coworkers. Apparent molar volume Paracetamol Aqueous solution Binary aqueous-urea solvent mixtures Martínez, Fleming verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 283, Seite 548-549 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:283 pages:548-549 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 283 548-549
allfieldsGer	10.1016/j.molliq.2019.03.123 doi (DE-627)ELV002176459 (ELSEVIER)S0167-7322(19)31109-2 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Acree, William E. verfasserin aut Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)” 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An error is found in the thermodynamic equation used by Singh and coworkers to calculate the apparent molar volume of paracetamol in water and in several binary aqueous-urea solvent mixtures. The negative apparent molar volumes reported in the published paper are highly questionable. A search of the published chemical literature found three sets of independently determined values for the apparent molar volume of paracetamol in water. Published literature values differ significantly from the values reported by Singh and coworkers. Apparent molar volume Paracetamol Aqueous solution Binary aqueous-urea solvent mixtures Martínez, Fleming verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 283, Seite 548-549 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:283 pages:548-549 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 283 548-549
allfieldsSound	10.1016/j.molliq.2019.03.123 doi (DE-627)ELV002176459 (ELSEVIER)S0167-7322(19)31109-2 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Acree, William E. verfasserin aut Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)” 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An error is found in the thermodynamic equation used by Singh and coworkers to calculate the apparent molar volume of paracetamol in water and in several binary aqueous-urea solvent mixtures. The negative apparent molar volumes reported in the published paper are highly questionable. A search of the published chemical literature found three sets of independently determined values for the apparent molar volume of paracetamol in water. Published literature values differ significantly from the values reported by Singh and coworkers. Apparent molar volume Paracetamol Aqueous solution Binary aqueous-urea solvent mixtures Martínez, Fleming verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 283, Seite 548-549 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:283 pages:548-549 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 283 548-549
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author	Acree, William E.
spellingShingle	Acree, William E. ddc 540 bkl 35.21 misc Apparent molar volume misc Paracetamol misc Aqueous solution misc Binary aqueous-urea solvent mixtures Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)”
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topic_title	540 DE-600 35.21 bkl Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)” Apparent molar volume Paracetamol Aqueous solution Binary aqueous-urea solvent mixtures
topic	ddc 540 bkl 35.21 misc Apparent molar volume misc Paracetamol misc Aqueous solution misc Binary aqueous-urea solvent mixtures
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title	Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)”
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title_full	Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)”
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title_sort	comment on “studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (n-(4-hydroxyphenyl)ethanamide)”
title_auth	Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)”
abstract	An error is found in the thermodynamic equation used by Singh and coworkers to calculate the apparent molar volume of paracetamol in water and in several binary aqueous-urea solvent mixtures. The negative apparent molar volumes reported in the published paper are highly questionable. A search of the published chemical literature found three sets of independently determined values for the apparent molar volume of paracetamol in water. Published literature values differ significantly from the values reported by Singh and coworkers.
abstractGer	An error is found in the thermodynamic equation used by Singh and coworkers to calculate the apparent molar volume of paracetamol in water and in several binary aqueous-urea solvent mixtures. The negative apparent molar volumes reported in the published paper are highly questionable. A search of the published chemical literature found three sets of independently determined values for the apparent molar volume of paracetamol in water. Published literature values differ significantly from the values reported by Singh and coworkers.
abstract_unstemmed	An error is found in the thermodynamic equation used by Singh and coworkers to calculate the apparent molar volume of paracetamol in water and in several binary aqueous-urea solvent mixtures. The negative apparent molar volumes reported in the published paper are highly questionable. A search of the published chemical literature found three sets of independently determined values for the apparent molar volume of paracetamol in water. Published literature values differ significantly from the values reported by Singh and coworkers.
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title_short	Comment on “Studies on molecular interactions in aqueous and aqueous urea systems of paracetamol (N-(4-hydroxyphenyl)ethanamide)”
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up_date	2024-07-06T23:52:07.207Z
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The negative apparent molar volumes reported in the published paper are highly questionable. A search of the published chemical literature found three sets of independently determined values for the apparent molar volume of paracetamol in water. 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