Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli

A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties....
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Xu, Taoshan [verfasserIn] Yan, Chaoxian [verfasserIn] Wu, Yuewei [verfasserIn] Yuan, Chengshan [verfasserIn] Shao, Xiangfeng [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	BODIPY dye Donor-acceptor system Intramolecular charge-transfer Photoinduced hole-transfer Fluorescence sensor

Übergeordnetes Werk:	Enthalten in: Dyes and pigments - Amsterdam [u.a.] : Elsevier Science, 1980, 168, Seite 235-247
Übergeordnetes Werk:	volume:168 ; pages:235-247

DOI / URN:	10.1016/j.dyepig.2019.04.069

Katalog-ID:	ELV002310546

Internformat


LEADER	01000caa a22002652 4500
001	ELV002310546
003	DE-627
005	20230524145500.0
007	cr uuu---uuuuu
008	230429s2019 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.1016/j.dyepig.2019.04.069 \|2 doi
035			\|a (DE-627)ELV002310546
035			\|a (ELSEVIER)S0143-7208(19)30325-0
040			\|a DE-627 \|b ger \|c DE-627 \|e rda
041			\|a eng
082	0	4	\|a 660 \|q DE-600
084			\|a 58.26 \|2 bkl
100	1		\|a Xu, Taoshan \|e verfasserin \|4 aut
245	1	0	\|a Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli
264		1	\|c 2019
336			\|a nicht spezifiziert \|b zzz \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli.
650		4	\|a BODIPY dye
650		4	\|a Donor-acceptor system
650		4	\|a Intramolecular charge-transfer
650		4	\|a Photoinduced hole-transfer
650		4	\|a Fluorescence sensor
700	1		\|a Yan, Chaoxian \|e verfasserin \|4 aut
700	1		\|a Wu, Yuewei \|e verfasserin \|4 aut
700	1		\|a Yuan, Chengshan \|e verfasserin \|4 aut
700	1		\|a Shao, Xiangfeng \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Dyes and pigments \|d Amsterdam [u.a.] : Elsevier Science, 1980 \|g 168, Seite 235-247 \|h Online-Ressource \|w (DE-627)306658755 \|w (DE-600)1500382-6 \|w (DE-576)116550910 \|x 0143-7208 \|7 nnns
773	1	8	\|g volume:168 \|g pages:235-247
912			\|a GBV_USEFLAG_U
912			\|a SYSFLAG_U
912			\|a GBV_ELV
912			\|a SSG-OLC-PHA
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 58.26 \|j Technologie der Farben und Lacke
951			\|a AR
952			\|d 168 \|h 235-247

Indexfelder

author_variant	t x tx c y cy y w yw c y cy x s xs
matchkey_str	article:01437208:2019----::eoaigoiyihlcrnihnthtpncbsdlooercesroadeoie
hierarchy_sort_str	2019
bklnumber	58.26
publishDate	2019
allfields	10.1016/j.dyepig.2019.04.069 doi (DE-627)ELV002310546 (ELSEVIER)S0143-7208(19)30325-0 DE-627 ger DE-627 rda eng 660 DE-600 58.26 bkl Xu, Taoshan verfasserin aut Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli. BODIPY dye Donor-acceptor system Intramolecular charge-transfer Photoinduced hole-transfer Fluorescence sensor Yan, Chaoxian verfasserin aut Wu, Yuewei verfasserin aut Yuan, Chengshan verfasserin aut Shao, Xiangfeng verfasserin aut Enthalten in Dyes and pigments Amsterdam [u.a.] : Elsevier Science, 1980 168, Seite 235-247 Online-Ressource (DE-627)306658755 (DE-600)1500382-6 (DE-576)116550910 0143-7208 nnns volume:168 pages:235-247 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.26 Technologie der Farben und Lacke AR 168 235-247
spelling	10.1016/j.dyepig.2019.04.069 doi (DE-627)ELV002310546 (ELSEVIER)S0143-7208(19)30325-0 DE-627 ger DE-627 rda eng 660 DE-600 58.26 bkl Xu, Taoshan verfasserin aut Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli. BODIPY dye Donor-acceptor system Intramolecular charge-transfer Photoinduced hole-transfer Fluorescence sensor Yan, Chaoxian verfasserin aut Wu, Yuewei verfasserin aut Yuan, Chengshan verfasserin aut Shao, Xiangfeng verfasserin aut Enthalten in Dyes and pigments Amsterdam [u.a.] : Elsevier Science, 1980 168, Seite 235-247 Online-Ressource (DE-627)306658755 (DE-600)1500382-6 (DE-576)116550910 0143-7208 nnns volume:168 pages:235-247 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.26 Technologie der Farben und Lacke AR 168 235-247
allfields_unstemmed	10.1016/j.dyepig.2019.04.069 doi (DE-627)ELV002310546 (ELSEVIER)S0143-7208(19)30325-0 DE-627 ger DE-627 rda eng 660 DE-600 58.26 bkl Xu, Taoshan verfasserin aut Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli. BODIPY dye Donor-acceptor system Intramolecular charge-transfer Photoinduced hole-transfer Fluorescence sensor Yan, Chaoxian verfasserin aut Wu, Yuewei verfasserin aut Yuan, Chengshan verfasserin aut Shao, Xiangfeng verfasserin aut Enthalten in Dyes and pigments Amsterdam [u.a.] : Elsevier Science, 1980 168, Seite 235-247 Online-Ressource (DE-627)306658755 (DE-600)1500382-6 (DE-576)116550910 0143-7208 nnns volume:168 pages:235-247 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.26 Technologie der Farben und Lacke AR 168 235-247
allfieldsGer	10.1016/j.dyepig.2019.04.069 doi (DE-627)ELV002310546 (ELSEVIER)S0143-7208(19)30325-0 DE-627 ger DE-627 rda eng 660 DE-600 58.26 bkl Xu, Taoshan verfasserin aut Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli. BODIPY dye Donor-acceptor system Intramolecular charge-transfer Photoinduced hole-transfer Fluorescence sensor Yan, Chaoxian verfasserin aut Wu, Yuewei verfasserin aut Yuan, Chengshan verfasserin aut Shao, Xiangfeng verfasserin aut Enthalten in Dyes and pigments Amsterdam [u.a.] : Elsevier Science, 1980 168, Seite 235-247 Online-Ressource (DE-627)306658755 (DE-600)1500382-6 (DE-576)116550910 0143-7208 nnns volume:168 pages:235-247 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.26 Technologie der Farben und Lacke AR 168 235-247
allfieldsSound	10.1016/j.dyepig.2019.04.069 doi (DE-627)ELV002310546 (ELSEVIER)S0143-7208(19)30325-0 DE-627 ger DE-627 rda eng 660 DE-600 58.26 bkl Xu, Taoshan verfasserin aut Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli. BODIPY dye Donor-acceptor system Intramolecular charge-transfer Photoinduced hole-transfer Fluorescence sensor Yan, Chaoxian verfasserin aut Wu, Yuewei verfasserin aut Yuan, Chengshan verfasserin aut Shao, Xiangfeng verfasserin aut Enthalten in Dyes and pigments Amsterdam [u.a.] : Elsevier Science, 1980 168, Seite 235-247 Online-Ressource (DE-627)306658755 (DE-600)1500382-6 (DE-576)116550910 0143-7208 nnns volume:168 pages:235-247 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.26 Technologie der Farben und Lacke AR 168 235-247
language	English
source	Enthalten in Dyes and pigments 168, Seite 235-247 volume:168 pages:235-247
sourceStr	Enthalten in Dyes and pigments 168, Seite 235-247 volume:168 pages:235-247
format_phy_str_mv	Article
bklname	Technologie der Farben und Lacke
institution	findex.gbv.de
topic_facet	BODIPY dye Donor-acceptor system Intramolecular charge-transfer Photoinduced hole-transfer Fluorescence sensor
dewey-raw	660
isfreeaccess_bool	false
container_title	Dyes and pigments
authorswithroles_txt_mv	Xu, Taoshan @@aut@@ Yan, Chaoxian @@aut@@ Wu, Yuewei @@aut@@ Yuan, Chengshan @@aut@@ Shao, Xiangfeng @@aut@@
publishDateDaySort_date	2019-01-01T00:00:00Z
hierarchy_top_id	306658755
dewey-sort	3660
id	ELV002310546
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV002310546</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524145500.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230429s2019 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.dyepig.2019.04.069</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV002310546</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0143-7208(19)30325-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.26</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Xu, Taoshan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">BODIPY dye</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Donor-acceptor system</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Intramolecular charge-transfer</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Photoinduced hole-transfer</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fluorescence sensor</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yan, Chaoxian</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wu, Yuewei</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yuan, Chengshan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Shao, Xiangfeng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Dyes and pigments</subfield><subfield code="d">Amsterdam [u.a.] : Elsevier Science, 1980</subfield><subfield code="g">168, Seite 235-247</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)306658755</subfield><subfield code="w">(DE-600)1500382-6</subfield><subfield code="w">(DE-576)116550910</subfield><subfield code="x">0143-7208</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:168</subfield><subfield code="g">pages:235-247</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.26</subfield><subfield code="j">Technologie der Farben und Lacke</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">168</subfield><subfield code="h">235-247</subfield></datafield></record></collection>
author	Xu, Taoshan
spellingShingle	Xu, Taoshan ddc 660 bkl 58.26 misc BODIPY dye misc Donor-acceptor system misc Intramolecular charge-transfer misc Photoinduced hole-transfer misc Fluorescence sensor Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli
authorStr	Xu, Taoshan
ppnlink_with_tag_str_mv	@@773@@(DE-627)306658755
format	electronic Article
dewey-ones	660 - Chemical engineering
delete_txt_mv	keep
author_role	aut aut aut aut aut
collection	elsevier
remote_str	true
illustrated	Not Illustrated
issn	0143-7208
topic_title	660 DE-600 58.26 bkl Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli BODIPY dye Donor-acceptor system Intramolecular charge-transfer Photoinduced hole-transfer Fluorescence sensor
topic	ddc 660 bkl 58.26 misc BODIPY dye misc Donor-acceptor system misc Intramolecular charge-transfer misc Photoinduced hole-transfer misc Fluorescence sensor
topic_unstemmed	ddc 660 bkl 58.26 misc BODIPY dye misc Donor-acceptor system misc Intramolecular charge-transfer misc Photoinduced hole-transfer misc Fluorescence sensor
topic_browse	ddc 660 bkl 58.26 misc BODIPY dye misc Donor-acceptor system misc Intramolecular charge-transfer misc Photoinduced hole-transfer misc Fluorescence sensor
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	Dyes and pigments
hierarchy_parent_id	306658755
dewey-tens	660 - Chemical engineering
hierarchy_top_title	Dyes and pigments
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)306658755 (DE-600)1500382-6 (DE-576)116550910
title	Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli
ctrlnum	(DE-627)ELV002310546 (ELSEVIER)S0143-7208(19)30325-0
title_full	Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli
author_sort	Xu, Taoshan
journal	Dyes and pigments
journalStr	Dyes and pigments
lang_code	eng
isOA_bool	false
dewey-hundreds	600 - Technology
recordtype	marc
publishDateSort	2019
contenttype_str_mv	zzz
container_start_page	235
author_browse	Xu, Taoshan Yan, Chaoxian Wu, Yuewei Yuan, Chengshan Shao, Xiangfeng
container_volume	168
class	660 DE-600 58.26 bkl
format_se	Elektronische Aufsätze
author-letter	Xu, Taoshan
doi_str_mv	10.1016/j.dyepig.2019.04.069
dewey-full	660
author2-role	verfasserin
title_sort	decorating bodipy with electron-rich unit thdtap: an ict-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli
title_auth	Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli
abstract	A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli.
abstractGer	A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli.
abstract_unstemmed	A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli.
collection_details	GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393
title_short	Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli
remote_bool	true
author2	Yan, Chaoxian Wu, Yuewei Yuan, Chengshan Shao, Xiangfeng
author2Str	Yan, Chaoxian Wu, Yuewei Yuan, Chengshan Shao, Xiangfeng
ppnlink	306658755
mediatype_str_mv	c
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1016/j.dyepig.2019.04.069
up_date	2024-07-07T00:18:28.893Z
_version_	1803877360752132096
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV002310546</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524145500.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230429s2019 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.dyepig.2019.04.069</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV002310546</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0143-7208(19)30325-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.26</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Xu, Taoshan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">A new type of BODIPY dye, compound 2 which possesses donor-acceptor (D-A) type structure, is synthesized by decorating electron-rich THDTAP unit onto the meso-position of BODIPY. The THDTAP has two chemically active sites (S and N atoms) that are utilized to manipulate the optoelectronic properties. By stepwise oxidation of two S-atoms on THDTAP moiety with m-CPBA, the 2 was converted to 3, trans -4, syn -4, 5, and 6. This transformation results in large influence on optoelectronic properties. The theoretical calculations reveal that the LUMOs of 2–6 are all located on BODIPY core, whereas their HOMOs show the different distributions. The 2 and 3 show the intramolecular charge-transfer (ICT) transition as proved by TD-DFT calculations, red-shifts of absorption and emission bands, and solvatochromism. The ICT process is inhibited in trans -4, syn -4, 5, and 6 due to the high oxidation states of S-atoms on THDTAP moieties. As a result, these four compounds display characteristic fluorescence of BODIPY. The femtosecond transient absorption (fs-TA) spectroscopic study reveals that 2 shows photoinduced hole-transfer (PHT) process in dichloromethane (DCM) solution. Upon acidification and neutralization of N-atom on THDTAP moiety, the ICT/PHT process of 2 in DCM is reversibly manipulated to result in fluorescence ON/OFF of BODIPY core. Moreover, the fluorescence of BODIPY core on 2 can be switched on through electrochemical oxidation of N-atom on THDTAP moiety. The compound 2 is thus a promising fluorometric sensor toward peroxide, acid, and electrochemical stimuli.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">BODIPY dye</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Donor-acceptor system</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Intramolecular charge-transfer</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Photoinduced hole-transfer</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fluorescence sensor</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yan, Chaoxian</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wu, Yuewei</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yuan, Chengshan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Shao, Xiangfeng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Dyes and pigments</subfield><subfield code="d">Amsterdam [u.a.] : Elsevier Science, 1980</subfield><subfield code="g">168, Seite 235-247</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)306658755</subfield><subfield code="w">(DE-600)1500382-6</subfield><subfield code="w">(DE-576)116550910</subfield><subfield code="x">0143-7208</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:168</subfield><subfield code="g">pages:235-247</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.26</subfield><subfield code="j">Technologie der Farben und Lacke</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">168</subfield><subfield code="h">235-247</subfield></datafield></record></collection>
score	7.4016895

Nicht das Richtige dabei?

Schreiben Sie uns!

Decorating BODIPY with electron-rich unit THDTAP: An ICT-based fluorometric sensor toward peroxide, acid, and electrochemical stimuli

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?