An insight of sodium-ion storage, diffusivity into TiO
To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and...
Ausführliche Beschreibung
Autor*in: |
Ghosh, Sourav [verfasserIn] Kiran Kumar, V. [verfasserIn] Kumar, S. Krishna [verfasserIn] Biswas, Sanjay [verfasserIn] Martha, Surendra K. [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2019 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Electrochimica acta - New York, NY [u.a.] : Elsevier, 1959, 316, Seite 69-78 |
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Übergeordnetes Werk: |
volume:316 ; pages:69-78 |
DOI / URN: |
10.1016/j.electacta.2019.05.109 |
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Katalog-ID: |
ELV002419483 |
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520 | |a To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and half times enhancement in electrochemical performance in the presence of carbon nanotube. The hybrid shows discharge capacity of 100 mAh g−1 at a current density of 1 Ag-1, stable for 1000 cycles with little capacity fade. The overall charge storage properties of pristine TiO2 and carbon nanotube-TiO2 hybrid is due to pseudocapacitive and diffusion-control Na+ intercalation. Two times increase in Na+ diffusivity in carbon nanotube-TiO2 hybrid is achievable in relation to pristine TiO2. The superb electrochemical performance is due to the synergetic effect of TiO2 nanoparticles and conducting carbon nanotube network which provides efficient charge storage and Na+ diffusivity. Finally, the realization of practical sodium-ion full cells by using carbon nanotube -TiO2 hybrid as anode and F-containing vanadium phosphate cathode which deliver a capacity of 184 mAh g−1 at a current density of 30 mAg−1. This work is the fundamental understanding of Na+ storage, the kinetics of the TiO2 electrode and its practical realization in sodium-ion full cell. | ||
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10.1016/j.electacta.2019.05.109 doi (DE-627)ELV002419483 (ELSEVIER)S0013-4686(19)31042-4 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Ghosh, Sourav verfasserin aut An insight of sodium-ion storage, diffusivity into TiO 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and half times enhancement in electrochemical performance in the presence of carbon nanotube. The hybrid shows discharge capacity of 100 mAh g−1 at a current density of 1 Ag-1, stable for 1000 cycles with little capacity fade. The overall charge storage properties of pristine TiO2 and carbon nanotube-TiO2 hybrid is due to pseudocapacitive and diffusion-control Na+ intercalation. Two times increase in Na+ diffusivity in carbon nanotube-TiO2 hybrid is achievable in relation to pristine TiO2. The superb electrochemical performance is due to the synergetic effect of TiO2 nanoparticles and conducting carbon nanotube network which provides efficient charge storage and Na+ diffusivity. Finally, the realization of practical sodium-ion full cells by using carbon nanotube -TiO2 hybrid as anode and F-containing vanadium phosphate cathode which deliver a capacity of 184 mAh g−1 at a current density of 30 mAg−1. This work is the fundamental understanding of Na+ storage, the kinetics of the TiO2 electrode and its practical realization in sodium-ion full cell. CNT-TiO Pseudocapacitive Diffusion coefficient GITT Sodium-ion full cell Kiran Kumar, V. verfasserin aut Kumar, S. Krishna verfasserin aut Biswas, Sanjay verfasserin aut Martha, Surendra K. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 316, Seite 69-78 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:316 pages:69-78 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 316 69-78 |
spelling |
10.1016/j.electacta.2019.05.109 doi (DE-627)ELV002419483 (ELSEVIER)S0013-4686(19)31042-4 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Ghosh, Sourav verfasserin aut An insight of sodium-ion storage, diffusivity into TiO 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and half times enhancement in electrochemical performance in the presence of carbon nanotube. The hybrid shows discharge capacity of 100 mAh g−1 at a current density of 1 Ag-1, stable for 1000 cycles with little capacity fade. The overall charge storage properties of pristine TiO2 and carbon nanotube-TiO2 hybrid is due to pseudocapacitive and diffusion-control Na+ intercalation. Two times increase in Na+ diffusivity in carbon nanotube-TiO2 hybrid is achievable in relation to pristine TiO2. The superb electrochemical performance is due to the synergetic effect of TiO2 nanoparticles and conducting carbon nanotube network which provides efficient charge storage and Na+ diffusivity. Finally, the realization of practical sodium-ion full cells by using carbon nanotube -TiO2 hybrid as anode and F-containing vanadium phosphate cathode which deliver a capacity of 184 mAh g−1 at a current density of 30 mAg−1. This work is the fundamental understanding of Na+ storage, the kinetics of the TiO2 electrode and its practical realization in sodium-ion full cell. CNT-TiO Pseudocapacitive Diffusion coefficient GITT Sodium-ion full cell Kiran Kumar, V. verfasserin aut Kumar, S. Krishna verfasserin aut Biswas, Sanjay verfasserin aut Martha, Surendra K. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 316, Seite 69-78 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:316 pages:69-78 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 316 69-78 |
allfields_unstemmed |
10.1016/j.electacta.2019.05.109 doi (DE-627)ELV002419483 (ELSEVIER)S0013-4686(19)31042-4 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Ghosh, Sourav verfasserin aut An insight of sodium-ion storage, diffusivity into TiO 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and half times enhancement in electrochemical performance in the presence of carbon nanotube. The hybrid shows discharge capacity of 100 mAh g−1 at a current density of 1 Ag-1, stable for 1000 cycles with little capacity fade. The overall charge storage properties of pristine TiO2 and carbon nanotube-TiO2 hybrid is due to pseudocapacitive and diffusion-control Na+ intercalation. Two times increase in Na+ diffusivity in carbon nanotube-TiO2 hybrid is achievable in relation to pristine TiO2. The superb electrochemical performance is due to the synergetic effect of TiO2 nanoparticles and conducting carbon nanotube network which provides efficient charge storage and Na+ diffusivity. Finally, the realization of practical sodium-ion full cells by using carbon nanotube -TiO2 hybrid as anode and F-containing vanadium phosphate cathode which deliver a capacity of 184 mAh g−1 at a current density of 30 mAg−1. This work is the fundamental understanding of Na+ storage, the kinetics of the TiO2 electrode and its practical realization in sodium-ion full cell. CNT-TiO Pseudocapacitive Diffusion coefficient GITT Sodium-ion full cell Kiran Kumar, V. verfasserin aut Kumar, S. Krishna verfasserin aut Biswas, Sanjay verfasserin aut Martha, Surendra K. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 316, Seite 69-78 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:316 pages:69-78 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 316 69-78 |
allfieldsGer |
10.1016/j.electacta.2019.05.109 doi (DE-627)ELV002419483 (ELSEVIER)S0013-4686(19)31042-4 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Ghosh, Sourav verfasserin aut An insight of sodium-ion storage, diffusivity into TiO 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and half times enhancement in electrochemical performance in the presence of carbon nanotube. The hybrid shows discharge capacity of 100 mAh g−1 at a current density of 1 Ag-1, stable for 1000 cycles with little capacity fade. The overall charge storage properties of pristine TiO2 and carbon nanotube-TiO2 hybrid is due to pseudocapacitive and diffusion-control Na+ intercalation. Two times increase in Na+ diffusivity in carbon nanotube-TiO2 hybrid is achievable in relation to pristine TiO2. The superb electrochemical performance is due to the synergetic effect of TiO2 nanoparticles and conducting carbon nanotube network which provides efficient charge storage and Na+ diffusivity. Finally, the realization of practical sodium-ion full cells by using carbon nanotube -TiO2 hybrid as anode and F-containing vanadium phosphate cathode which deliver a capacity of 184 mAh g−1 at a current density of 30 mAg−1. This work is the fundamental understanding of Na+ storage, the kinetics of the TiO2 electrode and its practical realization in sodium-ion full cell. CNT-TiO Pseudocapacitive Diffusion coefficient GITT Sodium-ion full cell Kiran Kumar, V. verfasserin aut Kumar, S. Krishna verfasserin aut Biswas, Sanjay verfasserin aut Martha, Surendra K. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 316, Seite 69-78 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:316 pages:69-78 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 316 69-78 |
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10.1016/j.electacta.2019.05.109 doi (DE-627)ELV002419483 (ELSEVIER)S0013-4686(19)31042-4 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Ghosh, Sourav verfasserin aut An insight of sodium-ion storage, diffusivity into TiO 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and half times enhancement in electrochemical performance in the presence of carbon nanotube. The hybrid shows discharge capacity of 100 mAh g−1 at a current density of 1 Ag-1, stable for 1000 cycles with little capacity fade. The overall charge storage properties of pristine TiO2 and carbon nanotube-TiO2 hybrid is due to pseudocapacitive and diffusion-control Na+ intercalation. Two times increase in Na+ diffusivity in carbon nanotube-TiO2 hybrid is achievable in relation to pristine TiO2. The superb electrochemical performance is due to the synergetic effect of TiO2 nanoparticles and conducting carbon nanotube network which provides efficient charge storage and Na+ diffusivity. Finally, the realization of practical sodium-ion full cells by using carbon nanotube -TiO2 hybrid as anode and F-containing vanadium phosphate cathode which deliver a capacity of 184 mAh g−1 at a current density of 30 mAg−1. This work is the fundamental understanding of Na+ storage, the kinetics of the TiO2 electrode and its practical realization in sodium-ion full cell. CNT-TiO Pseudocapacitive Diffusion coefficient GITT Sodium-ion full cell Kiran Kumar, V. verfasserin aut Kumar, S. Krishna verfasserin aut Biswas, Sanjay verfasserin aut Martha, Surendra K. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 316, Seite 69-78 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:316 pages:69-78 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 316 69-78 |
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An insight of sodium-ion storage, diffusivity into TiO |
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An insight of sodium-ion storage, diffusivity into TiO |
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Ghosh, Sourav |
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Electrochimica acta |
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Ghosh, Sourav Kiran Kumar, V. Kumar, S. Krishna Biswas, Sanjay Martha, Surendra K. |
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Ghosh, Sourav |
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10.1016/j.electacta.2019.05.109 |
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an insight of sodium-ion storage, diffusivity into tio |
title_auth |
An insight of sodium-ion storage, diffusivity into TiO |
abstract |
To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and half times enhancement in electrochemical performance in the presence of carbon nanotube. The hybrid shows discharge capacity of 100 mAh g−1 at a current density of 1 Ag-1, stable for 1000 cycles with little capacity fade. The overall charge storage properties of pristine TiO2 and carbon nanotube-TiO2 hybrid is due to pseudocapacitive and diffusion-control Na+ intercalation. Two times increase in Na+ diffusivity in carbon nanotube-TiO2 hybrid is achievable in relation to pristine TiO2. The superb electrochemical performance is due to the synergetic effect of TiO2 nanoparticles and conducting carbon nanotube network which provides efficient charge storage and Na+ diffusivity. Finally, the realization of practical sodium-ion full cells by using carbon nanotube -TiO2 hybrid as anode and F-containing vanadium phosphate cathode which deliver a capacity of 184 mAh g−1 at a current density of 30 mAg−1. This work is the fundamental understanding of Na+ storage, the kinetics of the TiO2 electrode and its practical realization in sodium-ion full cell. |
abstractGer |
To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and half times enhancement in electrochemical performance in the presence of carbon nanotube. The hybrid shows discharge capacity of 100 mAh g−1 at a current density of 1 Ag-1, stable for 1000 cycles with little capacity fade. The overall charge storage properties of pristine TiO2 and carbon nanotube-TiO2 hybrid is due to pseudocapacitive and diffusion-control Na+ intercalation. Two times increase in Na+ diffusivity in carbon nanotube-TiO2 hybrid is achievable in relation to pristine TiO2. The superb electrochemical performance is due to the synergetic effect of TiO2 nanoparticles and conducting carbon nanotube network which provides efficient charge storage and Na+ diffusivity. Finally, the realization of practical sodium-ion full cells by using carbon nanotube -TiO2 hybrid as anode and F-containing vanadium phosphate cathode which deliver a capacity of 184 mAh g−1 at a current density of 30 mAg−1. This work is the fundamental understanding of Na+ storage, the kinetics of the TiO2 electrode and its practical realization in sodium-ion full cell. |
abstract_unstemmed |
To improve the charge storage and kinetics of TiO2 anodes for sodium-ion batteries, a hybrid material of TiO2 nanoparticles is build-in onto multiwall carbon nanotube. The cycling stability and C-rate performance of carbon nanotube -TiO2 hybrid as anodes for sodium-ion batteries demonstrate two and half times enhancement in electrochemical performance in the presence of carbon nanotube. The hybrid shows discharge capacity of 100 mAh g−1 at a current density of 1 Ag-1, stable for 1000 cycles with little capacity fade. The overall charge storage properties of pristine TiO2 and carbon nanotube-TiO2 hybrid is due to pseudocapacitive and diffusion-control Na+ intercalation. Two times increase in Na+ diffusivity in carbon nanotube-TiO2 hybrid is achievable in relation to pristine TiO2. The superb electrochemical performance is due to the synergetic effect of TiO2 nanoparticles and conducting carbon nanotube network which provides efficient charge storage and Na+ diffusivity. Finally, the realization of practical sodium-ion full cells by using carbon nanotube -TiO2 hybrid as anode and F-containing vanadium phosphate cathode which deliver a capacity of 184 mAh g−1 at a current density of 30 mAg−1. This work is the fundamental understanding of Na+ storage, the kinetics of the TiO2 electrode and its practical realization in sodium-ion full cell. |
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title_short |
An insight of sodium-ion storage, diffusivity into TiO |
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Kiran Kumar, V. Kumar, S. Krishna Biswas, Sanjay Martha, Surendra K. |
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up_date |
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