Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect

With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there wer...
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Gespeichert in:

Autor*in:	Long, Canghai [verfasserIn] Li, Libo [verfasserIn] Zhai, Mo [verfasserIn] Shan, Yuhang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Solid-state Incombustibility GITT Li Shuttle effect

Übergeordnetes Werk:	Enthalten in: Journal of physics and chemistry of solids - New York, NY [u.a.] : Elsevier, 1956, 134, Seite 255-261
Übergeordnetes Werk:	volume:134 ; pages:255-261

DOI / URN:	10.1016/j.jpcs.2019.06.017

Katalog-ID:	ELV002629437

Internformat


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520			\|a With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there were some main challenges stemming from the polysulphide dissolution and the high flammability of the sulfur which limited the further application of the lithium sulfur Li–S batteries. Here, we reported a facile method to prepare the quasi solid-state Li–S batteries (LSBs) with sulfur nanoparticles electrode and PVDF-based solid polymer electrolyte (SPE), which had less flammability, electrochemical stability and ionic conductivity. The prepared PVDF-based solid polymer electrolyte possessed the conductivity ∼10−4 S cm−1 at 25 °C and the lithium ions transference number of 0.49. GITT demonstrated the Li+ transport diffusion mechanism in the active Snano-TiO2 cathode of the quasi solid-state lithium–sulfur battery. It was important to get the smooth diffusion path for the lower resistance in the charging process. Because of the high content and the sulfur uniform distribution on the nanoscale titanium dioxide (TiO2), the S@nano-TiO2 cathode exhibited its performance. The first cycle discahrge specific capacity was 1160 mAh g−1 at 0.15C at room temperature.
650		4	\|a Solid-state
650		4	\|a Incombustibility
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700	1		\|a Zhai, Mo \|e verfasserin \|4 aut
700	1		\|a Shan, Yuhang \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Journal of physics and chemistry of solids \|d New York, NY [u.a.] : Elsevier, 1956 \|g 134, Seite 255-261 \|h Online-Ressource \|w (DE-627)302718915 \|w (DE-600)1491914-X \|w (DE-576)094950334 \|7 nnns
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912			\|a GBV_ILN_63
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
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912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
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912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
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936	b	k	\|a 33.60 \|j Kondensierte Materie: Allgemeines
936	b	k	\|a 35.90 \|j Festkörperchemie
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Indexfelder

author_variant	c l cl l l ll m z mz y s ys
matchkey_str	longcanghaililibozhaimoshanyuhang:2019----:aierprtoadlcrceityefracoqaioisaeoyeltimufratrw
hierarchy_sort_str	2019
bklnumber	33.60 35.90
publishDate	2019
allfields	10.1016/j.jpcs.2019.06.017 doi (DE-627)ELV002629437 (ELSEVIER)S0022-3697(19)30611-0 DE-627 ger DE-627 rda eng 530 540 DE-600 33.60 bkl 35.90 bkl Long, Canghai verfasserin aut Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there were some main challenges stemming from the polysulphide dissolution and the high flammability of the sulfur which limited the further application of the lithium sulfur Li–S batteries. Here, we reported a facile method to prepare the quasi solid-state Li–S batteries (LSBs) with sulfur nanoparticles electrode and PVDF-based solid polymer electrolyte (SPE), which had less flammability, electrochemical stability and ionic conductivity. The prepared PVDF-based solid polymer electrolyte possessed the conductivity ∼10−4 S cm−1 at 25 °C and the lithium ions transference number of 0.49. GITT demonstrated the Li+ transport diffusion mechanism in the active Snano-TiO2 cathode of the quasi solid-state lithium–sulfur battery. It was important to get the smooth diffusion path for the lower resistance in the charging process. Because of the high content and the sulfur uniform distribution on the nanoscale titanium dioxide (TiO2), the S@nano-TiO2 cathode exhibited its performance. The first cycle discahrge specific capacity was 1160 mAh g−1 at 0.15C at room temperature. Solid-state Incombustibility GITT Li Shuttle effect Li, Libo verfasserin aut Zhai, Mo verfasserin aut Shan, Yuhang verfasserin aut Enthalten in Journal of physics and chemistry of solids New York, NY [u.a.] : Elsevier, 1956 134, Seite 255-261 Online-Ressource (DE-627)302718915 (DE-600)1491914-X (DE-576)094950334 nnns volume:134 pages:255-261 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.60 Kondensierte Materie: Allgemeines 35.90 Festkörperchemie AR 134 255-261
spelling	10.1016/j.jpcs.2019.06.017 doi (DE-627)ELV002629437 (ELSEVIER)S0022-3697(19)30611-0 DE-627 ger DE-627 rda eng 530 540 DE-600 33.60 bkl 35.90 bkl Long, Canghai verfasserin aut Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there were some main challenges stemming from the polysulphide dissolution and the high flammability of the sulfur which limited the further application of the lithium sulfur Li–S batteries. Here, we reported a facile method to prepare the quasi solid-state Li–S batteries (LSBs) with sulfur nanoparticles electrode and PVDF-based solid polymer electrolyte (SPE), which had less flammability, electrochemical stability and ionic conductivity. The prepared PVDF-based solid polymer electrolyte possessed the conductivity ∼10−4 S cm−1 at 25 °C and the lithium ions transference number of 0.49. GITT demonstrated the Li+ transport diffusion mechanism in the active Snano-TiO2 cathode of the quasi solid-state lithium–sulfur battery. It was important to get the smooth diffusion path for the lower resistance in the charging process. Because of the high content and the sulfur uniform distribution on the nanoscale titanium dioxide (TiO2), the S@nano-TiO2 cathode exhibited its performance. The first cycle discahrge specific capacity was 1160 mAh g−1 at 0.15C at room temperature. Solid-state Incombustibility GITT Li Shuttle effect Li, Libo verfasserin aut Zhai, Mo verfasserin aut Shan, Yuhang verfasserin aut Enthalten in Journal of physics and chemistry of solids New York, NY [u.a.] : Elsevier, 1956 134, Seite 255-261 Online-Ressource (DE-627)302718915 (DE-600)1491914-X (DE-576)094950334 nnns volume:134 pages:255-261 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.60 Kondensierte Materie: Allgemeines 35.90 Festkörperchemie AR 134 255-261
allfields_unstemmed	10.1016/j.jpcs.2019.06.017 doi (DE-627)ELV002629437 (ELSEVIER)S0022-3697(19)30611-0 DE-627 ger DE-627 rda eng 530 540 DE-600 33.60 bkl 35.90 bkl Long, Canghai verfasserin aut Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there were some main challenges stemming from the polysulphide dissolution and the high flammability of the sulfur which limited the further application of the lithium sulfur Li–S batteries. Here, we reported a facile method to prepare the quasi solid-state Li–S batteries (LSBs) with sulfur nanoparticles electrode and PVDF-based solid polymer electrolyte (SPE), which had less flammability, electrochemical stability and ionic conductivity. The prepared PVDF-based solid polymer electrolyte possessed the conductivity ∼10−4 S cm−1 at 25 °C and the lithium ions transference number of 0.49. GITT demonstrated the Li+ transport diffusion mechanism in the active Snano-TiO2 cathode of the quasi solid-state lithium–sulfur battery. It was important to get the smooth diffusion path for the lower resistance in the charging process. Because of the high content and the sulfur uniform distribution on the nanoscale titanium dioxide (TiO2), the S@nano-TiO2 cathode exhibited its performance. The first cycle discahrge specific capacity was 1160 mAh g−1 at 0.15C at room temperature. Solid-state Incombustibility GITT Li Shuttle effect Li, Libo verfasserin aut Zhai, Mo verfasserin aut Shan, Yuhang verfasserin aut Enthalten in Journal of physics and chemistry of solids New York, NY [u.a.] : Elsevier, 1956 134, Seite 255-261 Online-Ressource (DE-627)302718915 (DE-600)1491914-X (DE-576)094950334 nnns volume:134 pages:255-261 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.60 Kondensierte Materie: Allgemeines 35.90 Festkörperchemie AR 134 255-261
allfieldsGer	10.1016/j.jpcs.2019.06.017 doi (DE-627)ELV002629437 (ELSEVIER)S0022-3697(19)30611-0 DE-627 ger DE-627 rda eng 530 540 DE-600 33.60 bkl 35.90 bkl Long, Canghai verfasserin aut Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there were some main challenges stemming from the polysulphide dissolution and the high flammability of the sulfur which limited the further application of the lithium sulfur Li–S batteries. Here, we reported a facile method to prepare the quasi solid-state Li–S batteries (LSBs) with sulfur nanoparticles electrode and PVDF-based solid polymer electrolyte (SPE), which had less flammability, electrochemical stability and ionic conductivity. The prepared PVDF-based solid polymer electrolyte possessed the conductivity ∼10−4 S cm−1 at 25 °C and the lithium ions transference number of 0.49. GITT demonstrated the Li+ transport diffusion mechanism in the active Snano-TiO2 cathode of the quasi solid-state lithium–sulfur battery. It was important to get the smooth diffusion path for the lower resistance in the charging process. Because of the high content and the sulfur uniform distribution on the nanoscale titanium dioxide (TiO2), the S@nano-TiO2 cathode exhibited its performance. The first cycle discahrge specific capacity was 1160 mAh g−1 at 0.15C at room temperature. Solid-state Incombustibility GITT Li Shuttle effect Li, Libo verfasserin aut Zhai, Mo verfasserin aut Shan, Yuhang verfasserin aut Enthalten in Journal of physics and chemistry of solids New York, NY [u.a.] : Elsevier, 1956 134, Seite 255-261 Online-Ressource (DE-627)302718915 (DE-600)1491914-X (DE-576)094950334 nnns volume:134 pages:255-261 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.60 Kondensierte Materie: Allgemeines 35.90 Festkörperchemie AR 134 255-261
allfieldsSound	10.1016/j.jpcs.2019.06.017 doi (DE-627)ELV002629437 (ELSEVIER)S0022-3697(19)30611-0 DE-627 ger DE-627 rda eng 530 540 DE-600 33.60 bkl 35.90 bkl Long, Canghai verfasserin aut Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there were some main challenges stemming from the polysulphide dissolution and the high flammability of the sulfur which limited the further application of the lithium sulfur Li–S batteries. Here, we reported a facile method to prepare the quasi solid-state Li–S batteries (LSBs) with sulfur nanoparticles electrode and PVDF-based solid polymer electrolyte (SPE), which had less flammability, electrochemical stability and ionic conductivity. The prepared PVDF-based solid polymer electrolyte possessed the conductivity ∼10−4 S cm−1 at 25 °C and the lithium ions transference number of 0.49. GITT demonstrated the Li+ transport diffusion mechanism in the active Snano-TiO2 cathode of the quasi solid-state lithium–sulfur battery. It was important to get the smooth diffusion path for the lower resistance in the charging process. Because of the high content and the sulfur uniform distribution on the nanoscale titanium dioxide (TiO2), the S@nano-TiO2 cathode exhibited its performance. The first cycle discahrge specific capacity was 1160 mAh g−1 at 0.15C at room temperature. Solid-state Incombustibility GITT Li Shuttle effect Li, Libo verfasserin aut Zhai, Mo verfasserin aut Shan, Yuhang verfasserin aut Enthalten in Journal of physics and chemistry of solids New York, NY [u.a.] : Elsevier, 1956 134, Seite 255-261 Online-Ressource (DE-627)302718915 (DE-600)1491914-X (DE-576)094950334 nnns volume:134 pages:255-261 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.60 Kondensierte Materie: Allgemeines 35.90 Festkörperchemie AR 134 255-261
language	English
source	Enthalten in Journal of physics and chemistry of solids 134, Seite 255-261 volume:134 pages:255-261
sourceStr	Enthalten in Journal of physics and chemistry of solids 134, Seite 255-261 volume:134 pages:255-261
format_phy_str_mv	Article
bklname	Kondensierte Materie: Allgemeines Festkörperchemie
institution	findex.gbv.de
topic_facet	Solid-state Incombustibility GITT Li Shuttle effect
dewey-raw	530
isfreeaccess_bool	false
container_title	Journal of physics and chemistry of solids
authorswithroles_txt_mv	Long, Canghai @@aut@@ Li, Libo @@aut@@ Zhai, Mo @@aut@@ Shan, Yuhang @@aut@@
publishDateDaySort_date	2019-01-01T00:00:00Z
hierarchy_top_id	302718915
dewey-sort	3530
id	ELV002629437
language_de	englisch
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author	Long, Canghai
spellingShingle	Long, Canghai ddc 530 bkl 33.60 bkl 35.90 misc Solid-state misc Incombustibility misc GITT misc Li misc Shuttle effect Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect
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topic_title	530 540 DE-600 33.60 bkl 35.90 bkl Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect Solid-state Incombustibility GITT Li Shuttle effect
topic	ddc 530 bkl 33.60 bkl 35.90 misc Solid-state misc Incombustibility misc GITT misc Li misc Shuttle effect
topic_unstemmed	ddc 530 bkl 33.60 bkl 35.90 misc Solid-state misc Incombustibility misc GITT misc Li misc Shuttle effect
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title	Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect
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title_full	Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect
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author_browse	Long, Canghai Li, Libo Zhai, Mo Shan, Yuhang
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doi_str_mv	10.1016/j.jpcs.2019.06.017
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title_sort	facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect
title_auth	Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect
abstract	With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there were some main challenges stemming from the polysulphide dissolution and the high flammability of the sulfur which limited the further application of the lithium sulfur Li–S batteries. Here, we reported a facile method to prepare the quasi solid-state Li–S batteries (LSBs) with sulfur nanoparticles electrode and PVDF-based solid polymer electrolyte (SPE), which had less flammability, electrochemical stability and ionic conductivity. The prepared PVDF-based solid polymer electrolyte possessed the conductivity ∼10−4 S cm−1 at 25 °C and the lithium ions transference number of 0.49. GITT demonstrated the Li+ transport diffusion mechanism in the active Snano-TiO2 cathode of the quasi solid-state lithium–sulfur battery. It was important to get the smooth diffusion path for the lower resistance in the charging process. Because of the high content and the sulfur uniform distribution on the nanoscale titanium dioxide (TiO2), the S@nano-TiO2 cathode exhibited its performance. The first cycle discahrge specific capacity was 1160 mAh g−1 at 0.15C at room temperature.
abstractGer	With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there were some main challenges stemming from the polysulphide dissolution and the high flammability of the sulfur which limited the further application of the lithium sulfur Li–S batteries. Here, we reported a facile method to prepare the quasi solid-state Li–S batteries (LSBs) with sulfur nanoparticles electrode and PVDF-based solid polymer electrolyte (SPE), which had less flammability, electrochemical stability and ionic conductivity. The prepared PVDF-based solid polymer electrolyte possessed the conductivity ∼10−4 S cm−1 at 25 °C and the lithium ions transference number of 0.49. GITT demonstrated the Li+ transport diffusion mechanism in the active Snano-TiO2 cathode of the quasi solid-state lithium–sulfur battery. It was important to get the smooth diffusion path for the lower resistance in the charging process. Because of the high content and the sulfur uniform distribution on the nanoscale titanium dioxide (TiO2), the S@nano-TiO2 cathode exhibited its performance. The first cycle discahrge specific capacity was 1160 mAh g−1 at 0.15C at room temperature.
abstract_unstemmed	With a higher theoretical energy density relative to Li ion batteries (LIBs) and abundance of elemental sulfur, the lithium sulfur (L-S) batteries were regarded as the promising next-generation high energy density storage devices for the protable electronics and electric vehicles. However, there were some main challenges stemming from the polysulphide dissolution and the high flammability of the sulfur which limited the further application of the lithium sulfur Li–S batteries. Here, we reported a facile method to prepare the quasi solid-state Li–S batteries (LSBs) with sulfur nanoparticles electrode and PVDF-based solid polymer electrolyte (SPE), which had less flammability, electrochemical stability and ionic conductivity. The prepared PVDF-based solid polymer electrolyte possessed the conductivity ∼10−4 S cm−1 at 25 °C and the lithium ions transference number of 0.49. GITT demonstrated the Li+ transport diffusion mechanism in the active Snano-TiO2 cathode of the quasi solid-state lithium–sulfur battery. It was important to get the smooth diffusion path for the lower resistance in the charging process. Because of the high content and the sulfur uniform distribution on the nanoscale titanium dioxide (TiO2), the S@nano-TiO2 cathode exhibited its performance. The first cycle discahrge specific capacity was 1160 mAh g−1 at 0.15C at room temperature.
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title_short	Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect
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up_date	2024-07-06T16:55:05.323Z
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Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect

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