High lithium-ion conducting solid electrolyte thin film of Li

The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors h...
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Autor*in:	Bai, Fan [verfasserIn] Shang, Xuefu [verfasserIn] Mori, Daisuke [verfasserIn] Taminato, Sou [verfasserIn] Matsumoto, Mitsuhiro [verfasserIn] Watanabe, Shinya [verfasserIn] Takeda, Yasuo [verfasserIn] Yamamoto, Osamu [verfasserIn] Nemori, Hiroyoshi [verfasserIn] Nomura, Masaya [verfasserIn] Imanishi, Nobuyuki [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Solid electrolyte Lithium-ion conductor NASICON-type Lithium-secondary battery

Übergeordnetes Werk:	Enthalten in: Solid state ionics - Amsterdam [u.a.] : Elsevier Science, 1980, 338, Seite 127-133
Übergeordnetes Werk:	volume:338 ; pages:127-133

DOI / URN:	10.1016/j.ssi.2019.05.017

Katalog-ID:	ELV002689871

Internformat


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520			\|a The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors have been proved to be stable in an aqueous solution with a high content of lithium ions, but its relatively low robustness and high resistance is still a barrier towards fabricating high performance battery. Herein, a Li1.4Al0.4Ge0.2Ti1.4(PO4)3 (LAGTP)-10 wt% TiO2 composite with a greatly reduced 90 μm thickness was managed by the route of tape casting. The lithium-ion conductivity, bending strength and water penetration of the film were systematically investigated in this study. The electrical conduction of the film was 8.70 × 10−4 S cm−1 and the mechanical bending strength of the film was improved more than three times to 200 N mm−2 measured at ambient temperature. Water impermeable function was realized by coupling a small amount of ca. 2 wt% epoxy resin into the open pores of the film. Finally, the assembled Li/Li(FSO2)2N in glyme/LAGTP-10 wt% TiO2-epoxy resin/10 M LiCl-1.5 M LiOH/MnO2, air cell presented a reduced total areal resistance to around 240 Ω cm2 at 25 °C and was successfully cycled at 1.0 mA cm−2 in air.
650		4	\|a Solid electrolyte
650		4	\|a Lithium-ion conductor
650		4	\|a NASICON-type
650		4	\|a Lithium-secondary battery
700	1		\|a Shang, Xuefu \|e verfasserin \|4 aut
700	1		\|a Mori, Daisuke \|e verfasserin \|4 aut
700	1		\|a Taminato, Sou \|e verfasserin \|4 aut
700	1		\|a Matsumoto, Mitsuhiro \|e verfasserin \|4 aut
700	1		\|a Watanabe, Shinya \|e verfasserin \|4 aut
700	1		\|a Takeda, Yasuo \|e verfasserin \|4 aut
700	1		\|a Yamamoto, Osamu \|e verfasserin \|4 aut
700	1		\|a Nemori, Hiroyoshi \|e verfasserin \|4 aut
700	1		\|a Nomura, Masaya \|e verfasserin \|4 aut
700	1		\|a Imanishi, Nobuyuki \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Solid state ionics \|d Amsterdam [u.a.] : Elsevier Science, 1980 \|g 338, Seite 127-133 \|h Online-Ressource \|w (DE-627)306710544 \|w (DE-600)1500750-9 \|w (DE-576)25193814X \|x 0167-2738 \|7 nnns
773	1	8	\|g volume:338 \|g pages:127-133
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912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_101
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 33.61 \|j Festkörperphysik
951			\|a AR
952			\|d 338 \|h 127-133

Indexfelder

author_variant	f b fb x s xs d m dm s t st m m mm s w sw y t yt o y oy h n hn m n mn n i ni
matchkey_str	article:01672738:2019----::ihihuinodcigoieetoy
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allfields	10.1016/j.ssi.2019.05.017 doi (DE-627)ELV002689871 (ELSEVIER)S0167-2738(19)30351-0 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut High lithium-ion conducting solid electrolyte thin film of Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors have been proved to be stable in an aqueous solution with a high content of lithium ions, but its relatively low robustness and high resistance is still a barrier towards fabricating high performance battery. Herein, a Li1.4Al0.4Ge0.2Ti1.4(PO4)3 (LAGTP)-10 wt% TiO2 composite with a greatly reduced 90 μm thickness was managed by the route of tape casting. The lithium-ion conductivity, bending strength and water penetration of the film were systematically investigated in this study. The electrical conduction of the film was 8.70 × 10−4 S cm−1 and the mechanical bending strength of the film was improved more than three times to 200 N mm−2 measured at ambient temperature. Water impermeable function was realized by coupling a small amount of ca. 2 wt% epoxy resin into the open pores of the film. Finally, the assembled Li/Li(FSO2)2N in glyme/LAGTP-10 wt% TiO2-epoxy resin/10 M LiCl-1.5 M LiOH/MnO2, air cell presented a reduced total areal resistance to around 240 Ω cm2 at 25 °C and was successfully cycled at 1.0 mA cm−2 in air. Solid electrolyte Lithium-ion conductor NASICON-type Lithium-secondary battery Shang, Xuefu verfasserin aut Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Matsumoto, Mitsuhiro verfasserin aut Watanabe, Shinya verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 338, Seite 127-133 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:338 pages:127-133 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 338 127-133
spelling	10.1016/j.ssi.2019.05.017 doi (DE-627)ELV002689871 (ELSEVIER)S0167-2738(19)30351-0 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut High lithium-ion conducting solid electrolyte thin film of Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors have been proved to be stable in an aqueous solution with a high content of lithium ions, but its relatively low robustness and high resistance is still a barrier towards fabricating high performance battery. Herein, a Li1.4Al0.4Ge0.2Ti1.4(PO4)3 (LAGTP)-10 wt% TiO2 composite with a greatly reduced 90 μm thickness was managed by the route of tape casting. The lithium-ion conductivity, bending strength and water penetration of the film were systematically investigated in this study. The electrical conduction of the film was 8.70 × 10−4 S cm−1 and the mechanical bending strength of the film was improved more than three times to 200 N mm−2 measured at ambient temperature. Water impermeable function was realized by coupling a small amount of ca. 2 wt% epoxy resin into the open pores of the film. Finally, the assembled Li/Li(FSO2)2N in glyme/LAGTP-10 wt% TiO2-epoxy resin/10 M LiCl-1.5 M LiOH/MnO2, air cell presented a reduced total areal resistance to around 240 Ω cm2 at 25 °C and was successfully cycled at 1.0 mA cm−2 in air. Solid electrolyte Lithium-ion conductor NASICON-type Lithium-secondary battery Shang, Xuefu verfasserin aut Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Matsumoto, Mitsuhiro verfasserin aut Watanabe, Shinya verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 338, Seite 127-133 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:338 pages:127-133 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 338 127-133
allfields_unstemmed	10.1016/j.ssi.2019.05.017 doi (DE-627)ELV002689871 (ELSEVIER)S0167-2738(19)30351-0 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut High lithium-ion conducting solid electrolyte thin film of Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors have been proved to be stable in an aqueous solution with a high content of lithium ions, but its relatively low robustness and high resistance is still a barrier towards fabricating high performance battery. Herein, a Li1.4Al0.4Ge0.2Ti1.4(PO4)3 (LAGTP)-10 wt% TiO2 composite with a greatly reduced 90 μm thickness was managed by the route of tape casting. The lithium-ion conductivity, bending strength and water penetration of the film were systematically investigated in this study. The electrical conduction of the film was 8.70 × 10−4 S cm−1 and the mechanical bending strength of the film was improved more than three times to 200 N mm−2 measured at ambient temperature. Water impermeable function was realized by coupling a small amount of ca. 2 wt% epoxy resin into the open pores of the film. Finally, the assembled Li/Li(FSO2)2N in glyme/LAGTP-10 wt% TiO2-epoxy resin/10 M LiCl-1.5 M LiOH/MnO2, air cell presented a reduced total areal resistance to around 240 Ω cm2 at 25 °C and was successfully cycled at 1.0 mA cm−2 in air. Solid electrolyte Lithium-ion conductor NASICON-type Lithium-secondary battery Shang, Xuefu verfasserin aut Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Matsumoto, Mitsuhiro verfasserin aut Watanabe, Shinya verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 338, Seite 127-133 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:338 pages:127-133 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 338 127-133
allfieldsGer	10.1016/j.ssi.2019.05.017 doi (DE-627)ELV002689871 (ELSEVIER)S0167-2738(19)30351-0 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut High lithium-ion conducting solid electrolyte thin film of Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors have been proved to be stable in an aqueous solution with a high content of lithium ions, but its relatively low robustness and high resistance is still a barrier towards fabricating high performance battery. Herein, a Li1.4Al0.4Ge0.2Ti1.4(PO4)3 (LAGTP)-10 wt% TiO2 composite with a greatly reduced 90 μm thickness was managed by the route of tape casting. The lithium-ion conductivity, bending strength and water penetration of the film were systematically investigated in this study. The electrical conduction of the film was 8.70 × 10−4 S cm−1 and the mechanical bending strength of the film was improved more than three times to 200 N mm−2 measured at ambient temperature. Water impermeable function was realized by coupling a small amount of ca. 2 wt% epoxy resin into the open pores of the film. Finally, the assembled Li/Li(FSO2)2N in glyme/LAGTP-10 wt% TiO2-epoxy resin/10 M LiCl-1.5 M LiOH/MnO2, air cell presented a reduced total areal resistance to around 240 Ω cm2 at 25 °C and was successfully cycled at 1.0 mA cm−2 in air. Solid electrolyte Lithium-ion conductor NASICON-type Lithium-secondary battery Shang, Xuefu verfasserin aut Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Matsumoto, Mitsuhiro verfasserin aut Watanabe, Shinya verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 338, Seite 127-133 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:338 pages:127-133 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 338 127-133
allfieldsSound	10.1016/j.ssi.2019.05.017 doi (DE-627)ELV002689871 (ELSEVIER)S0167-2738(19)30351-0 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut High lithium-ion conducting solid electrolyte thin film of Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors have been proved to be stable in an aqueous solution with a high content of lithium ions, but its relatively low robustness and high resistance is still a barrier towards fabricating high performance battery. Herein, a Li1.4Al0.4Ge0.2Ti1.4(PO4)3 (LAGTP)-10 wt% TiO2 composite with a greatly reduced 90 μm thickness was managed by the route of tape casting. The lithium-ion conductivity, bending strength and water penetration of the film were systematically investigated in this study. The electrical conduction of the film was 8.70 × 10−4 S cm−1 and the mechanical bending strength of the film was improved more than three times to 200 N mm−2 measured at ambient temperature. Water impermeable function was realized by coupling a small amount of ca. 2 wt% epoxy resin into the open pores of the film. Finally, the assembled Li/Li(FSO2)2N in glyme/LAGTP-10 wt% TiO2-epoxy resin/10 M LiCl-1.5 M LiOH/MnO2, air cell presented a reduced total areal resistance to around 240 Ω cm2 at 25 °C and was successfully cycled at 1.0 mA cm−2 in air. Solid electrolyte Lithium-ion conductor NASICON-type Lithium-secondary battery Shang, Xuefu verfasserin aut Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Matsumoto, Mitsuhiro verfasserin aut Watanabe, Shinya verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 338, Seite 127-133 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:338 pages:127-133 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 338 127-133
language	English
source	Enthalten in Solid state ionics 338, Seite 127-133 volume:338 pages:127-133
sourceStr	Enthalten in Solid state ionics 338, Seite 127-133 volume:338 pages:127-133
format_phy_str_mv	Article
bklname	Festkörperphysik
institution	findex.gbv.de
topic_facet	Solid electrolyte Lithium-ion conductor NASICON-type Lithium-secondary battery
dewey-raw	530
isfreeaccess_bool	false
container_title	Solid state ionics
authorswithroles_txt_mv	Bai, Fan @@aut@@ Shang, Xuefu @@aut@@ Mori, Daisuke @@aut@@ Taminato, Sou @@aut@@ Matsumoto, Mitsuhiro @@aut@@ Watanabe, Shinya @@aut@@ Takeda, Yasuo @@aut@@ Yamamoto, Osamu @@aut@@ Nemori, Hiroyoshi @@aut@@ Nomura, Masaya @@aut@@ Imanishi, Nobuyuki @@aut@@
publishDateDaySort_date	2019-01-01T00:00:00Z
hierarchy_top_id	306710544
dewey-sort	3530
id	ELV002689871
language_de	englisch
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author	Bai, Fan
spellingShingle	Bai, Fan ddc 530 bkl 33.61 misc Solid electrolyte misc Lithium-ion conductor misc NASICON-type misc Lithium-secondary battery High lithium-ion conducting solid electrolyte thin film of Li
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topic_title	530 DE-600 33.61 bkl High lithium-ion conducting solid electrolyte thin film of Li Solid electrolyte Lithium-ion conductor NASICON-type Lithium-secondary battery
topic	ddc 530 bkl 33.61 misc Solid electrolyte misc Lithium-ion conductor misc NASICON-type misc Lithium-secondary battery
topic_unstemmed	ddc 530 bkl 33.61 misc Solid electrolyte misc Lithium-ion conductor misc NASICON-type misc Lithium-secondary battery
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title	High lithium-ion conducting solid electrolyte thin film of Li
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title_full	High lithium-ion conducting solid electrolyte thin film of Li
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author_browse	Bai, Fan Shang, Xuefu Mori, Daisuke Taminato, Sou Matsumoto, Mitsuhiro Watanabe, Shinya Takeda, Yasuo Yamamoto, Osamu Nemori, Hiroyoshi Nomura, Masaya Imanishi, Nobuyuki
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doi_str_mv	10.1016/j.ssi.2019.05.017
dewey-full	530
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title_sort	high lithium-ion conducting solid electrolyte thin film of li
title_auth	High lithium-ion conducting solid electrolyte thin film of Li
abstract	The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors have been proved to be stable in an aqueous solution with a high content of lithium ions, but its relatively low robustness and high resistance is still a barrier towards fabricating high performance battery. Herein, a Li1.4Al0.4Ge0.2Ti1.4(PO4)3 (LAGTP)-10 wt% TiO2 composite with a greatly reduced 90 μm thickness was managed by the route of tape casting. The lithium-ion conductivity, bending strength and water penetration of the film were systematically investigated in this study. The electrical conduction of the film was 8.70 × 10−4 S cm−1 and the mechanical bending strength of the film was improved more than three times to 200 N mm−2 measured at ambient temperature. Water impermeable function was realized by coupling a small amount of ca. 2 wt% epoxy resin into the open pores of the film. Finally, the assembled Li/Li(FSO2)2N in glyme/LAGTP-10 wt% TiO2-epoxy resin/10 M LiCl-1.5 M LiOH/MnO2, air cell presented a reduced total areal resistance to around 240 Ω cm2 at 25 °C and was successfully cycled at 1.0 mA cm−2 in air.
abstractGer	The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors have been proved to be stable in an aqueous solution with a high content of lithium ions, but its relatively low robustness and high resistance is still a barrier towards fabricating high performance battery. Herein, a Li1.4Al0.4Ge0.2Ti1.4(PO4)3 (LAGTP)-10 wt% TiO2 composite with a greatly reduced 90 μm thickness was managed by the route of tape casting. The lithium-ion conductivity, bending strength and water penetration of the film were systematically investigated in this study. The electrical conduction of the film was 8.70 × 10−4 S cm−1 and the mechanical bending strength of the film was improved more than three times to 200 N mm−2 measured at ambient temperature. Water impermeable function was realized by coupling a small amount of ca. 2 wt% epoxy resin into the open pores of the film. Finally, the assembled Li/Li(FSO2)2N in glyme/LAGTP-10 wt% TiO2-epoxy resin/10 M LiCl-1.5 M LiOH/MnO2, air cell presented a reduced total areal resistance to around 240 Ω cm2 at 25 °C and was successfully cycled at 1.0 mA cm−2 in air.
abstract_unstemmed	The water-impermeable solid electrolyte is the key part to aqueous lithium secondary battery design at it serves as both separator and lithium-ion conducting pass way between the lithium metal anode and the aqueous electrolyte. Up to now, NASICON-type doped LiTi2(PO4)3 solid lithium-ion conductors have been proved to be stable in an aqueous solution with a high content of lithium ions, but its relatively low robustness and high resistance is still a barrier towards fabricating high performance battery. Herein, a Li1.4Al0.4Ge0.2Ti1.4(PO4)3 (LAGTP)-10 wt% TiO2 composite with a greatly reduced 90 μm thickness was managed by the route of tape casting. The lithium-ion conductivity, bending strength and water penetration of the film were systematically investigated in this study. The electrical conduction of the film was 8.70 × 10−4 S cm−1 and the mechanical bending strength of the film was improved more than three times to 200 N mm−2 measured at ambient temperature. Water impermeable function was realized by coupling a small amount of ca. 2 wt% epoxy resin into the open pores of the film. Finally, the assembled Li/Li(FSO2)2N in glyme/LAGTP-10 wt% TiO2-epoxy resin/10 M LiCl-1.5 M LiOH/MnO2, air cell presented a reduced total areal resistance to around 240 Ω cm2 at 25 °C and was successfully cycled at 1.0 mA cm−2 in air.
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title_short	High lithium-ion conducting solid electrolyte thin film of Li
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author2	Shang, Xuefu Mori, Daisuke Taminato, Sou Matsumoto, Mitsuhiro Watanabe, Shinya Takeda, Yasuo Yamamoto, Osamu Nemori, Hiroyoshi Nomura, Masaya Imanishi, Nobuyuki
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up_date	2024-07-06T17:07:18.555Z
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High lithium-ion conducting solid electrolyte thin film of Li

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