Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage

Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the...
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Autor*in:	Shi, Zhuqun [verfasserIn] Xu, Haiyu [verfasserIn] Yang, Quanling [verfasserIn] Xiong, Chuanxi [verfasserIn] Zhao, Mengchen [verfasserIn] Kobayashi, Kayoko [verfasserIn] Saito, Tsuguyuki [verfasserIn] Isogai, Akira [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Cellulose nanofibril Poly(ethylene oxide) Solid–solid phase change Mechanical properties Coefficient of thermal expansion

Übergeordnetes Werk:	Enthalten in: Carbohydrate polymers - Amsterdam [u.a.] : Elsevier Science, 1981, 225
Übergeordnetes Werk:	volume:225

DOI / URN:	10.1016/j.carbpol.2019.115215

Katalog-ID:	ELV002851458

Internformat


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245	1	0	\|a Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage
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520			\|a Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the 100% PEO film was translucent. The addition of CNFs to the PEO matrix resulted in decreases of the crystallinity and crystal size of spherical PEO. The Young’s modulus and tensile strength of the 100% PEO film were 0.2 GPa and 6.1 MPa, respectively, and remarkably increased to 2.4 GPa and 86 MPa, respectively, with the addition of 20% CNF. The CNF/PEO composite films had clear melting and crystallization temperatures in the heating and cooling processes, respectively. Nevertheless, the coefficients of thermal expansion at temperatures above the melting point of PEO significantly decreased with the CNF addition. The CNF/PEO composite films are therefore promising solid–solid phase-change materials for energy storage with high film dimensional stability.
650		4	\|a Cellulose nanofibril
650		4	\|a Poly(ethylene oxide)
650		4	\|a Solid–solid phase change
650		4	\|a Mechanical properties
650		4	\|a Coefficient of thermal expansion
700	1		\|a Xu, Haiyu \|e verfasserin \|4 aut
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936	b	k	\|a 58.34 \|j Lebensmitteltechnologie
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matchkey_str	article:18791344:2019----::abxltdaoellsplehlnoieopstflssoisldhscagm
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publishDate	2019
allfields	10.1016/j.carbpol.2019.115215 doi (DE-627)ELV002851458 (ELSEVIER)S0144-8617(19)30882-3 DE-627 ger DE-627 rda eng 540 660 DE-600 58.34 bkl 49.25 bkl Shi, Zhuqun verfasserin aut Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the 100% PEO film was translucent. The addition of CNFs to the PEO matrix resulted in decreases of the crystallinity and crystal size of spherical PEO. The Young’s modulus and tensile strength of the 100% PEO film were 0.2 GPa and 6.1 MPa, respectively, and remarkably increased to 2.4 GPa and 86 MPa, respectively, with the addition of 20% CNF. The CNF/PEO composite films had clear melting and crystallization temperatures in the heating and cooling processes, respectively. Nevertheless, the coefficients of thermal expansion at temperatures above the melting point of PEO significantly decreased with the CNF addition. The CNF/PEO composite films are therefore promising solid–solid phase-change materials for energy storage with high film dimensional stability. Cellulose nanofibril Poly(ethylene oxide) Solid–solid phase change Mechanical properties Coefficient of thermal expansion Xu, Haiyu verfasserin aut Yang, Quanling verfasserin (orcid)0000-0002-7013-419X aut Xiong, Chuanxi verfasserin (orcid)0000-0003-0878-0884 aut Zhao, Mengchen verfasserin aut Kobayashi, Kayoko verfasserin aut Saito, Tsuguyuki verfasserin aut Isogai, Akira verfasserin (orcid)0000-0001-8095-0441 aut Enthalten in Carbohydrate polymers Amsterdam [u.a.] : Elsevier Science, 1981 225 Online-Ressource (DE-627)306717611 (DE-600)1501516-6 (DE-576)109967178 1879-1344 nnns volume:225 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie 49.25 Lebensmittelkunde Ernährungslehre AR 225
spelling	10.1016/j.carbpol.2019.115215 doi (DE-627)ELV002851458 (ELSEVIER)S0144-8617(19)30882-3 DE-627 ger DE-627 rda eng 540 660 DE-600 58.34 bkl 49.25 bkl Shi, Zhuqun verfasserin aut Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the 100% PEO film was translucent. The addition of CNFs to the PEO matrix resulted in decreases of the crystallinity and crystal size of spherical PEO. The Young’s modulus and tensile strength of the 100% PEO film were 0.2 GPa and 6.1 MPa, respectively, and remarkably increased to 2.4 GPa and 86 MPa, respectively, with the addition of 20% CNF. The CNF/PEO composite films had clear melting and crystallization temperatures in the heating and cooling processes, respectively. Nevertheless, the coefficients of thermal expansion at temperatures above the melting point of PEO significantly decreased with the CNF addition. The CNF/PEO composite films are therefore promising solid–solid phase-change materials for energy storage with high film dimensional stability. Cellulose nanofibril Poly(ethylene oxide) Solid–solid phase change Mechanical properties Coefficient of thermal expansion Xu, Haiyu verfasserin aut Yang, Quanling verfasserin (orcid)0000-0002-7013-419X aut Xiong, Chuanxi verfasserin (orcid)0000-0003-0878-0884 aut Zhao, Mengchen verfasserin aut Kobayashi, Kayoko verfasserin aut Saito, Tsuguyuki verfasserin aut Isogai, Akira verfasserin (orcid)0000-0001-8095-0441 aut Enthalten in Carbohydrate polymers Amsterdam [u.a.] : Elsevier Science, 1981 225 Online-Ressource (DE-627)306717611 (DE-600)1501516-6 (DE-576)109967178 1879-1344 nnns volume:225 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie 49.25 Lebensmittelkunde Ernährungslehre AR 225
allfields_unstemmed	10.1016/j.carbpol.2019.115215 doi (DE-627)ELV002851458 (ELSEVIER)S0144-8617(19)30882-3 DE-627 ger DE-627 rda eng 540 660 DE-600 58.34 bkl 49.25 bkl Shi, Zhuqun verfasserin aut Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the 100% PEO film was translucent. The addition of CNFs to the PEO matrix resulted in decreases of the crystallinity and crystal size of spherical PEO. The Young’s modulus and tensile strength of the 100% PEO film were 0.2 GPa and 6.1 MPa, respectively, and remarkably increased to 2.4 GPa and 86 MPa, respectively, with the addition of 20% CNF. The CNF/PEO composite films had clear melting and crystallization temperatures in the heating and cooling processes, respectively. Nevertheless, the coefficients of thermal expansion at temperatures above the melting point of PEO significantly decreased with the CNF addition. The CNF/PEO composite films are therefore promising solid–solid phase-change materials for energy storage with high film dimensional stability. Cellulose nanofibril Poly(ethylene oxide) Solid–solid phase change Mechanical properties Coefficient of thermal expansion Xu, Haiyu verfasserin aut Yang, Quanling verfasserin (orcid)0000-0002-7013-419X aut Xiong, Chuanxi verfasserin (orcid)0000-0003-0878-0884 aut Zhao, Mengchen verfasserin aut Kobayashi, Kayoko verfasserin aut Saito, Tsuguyuki verfasserin aut Isogai, Akira verfasserin (orcid)0000-0001-8095-0441 aut Enthalten in Carbohydrate polymers Amsterdam [u.a.] : Elsevier Science, 1981 225 Online-Ressource (DE-627)306717611 (DE-600)1501516-6 (DE-576)109967178 1879-1344 nnns volume:225 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie 49.25 Lebensmittelkunde Ernährungslehre AR 225
allfieldsGer	10.1016/j.carbpol.2019.115215 doi (DE-627)ELV002851458 (ELSEVIER)S0144-8617(19)30882-3 DE-627 ger DE-627 rda eng 540 660 DE-600 58.34 bkl 49.25 bkl Shi, Zhuqun verfasserin aut Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the 100% PEO film was translucent. The addition of CNFs to the PEO matrix resulted in decreases of the crystallinity and crystal size of spherical PEO. The Young’s modulus and tensile strength of the 100% PEO film were 0.2 GPa and 6.1 MPa, respectively, and remarkably increased to 2.4 GPa and 86 MPa, respectively, with the addition of 20% CNF. The CNF/PEO composite films had clear melting and crystallization temperatures in the heating and cooling processes, respectively. Nevertheless, the coefficients of thermal expansion at temperatures above the melting point of PEO significantly decreased with the CNF addition. The CNF/PEO composite films are therefore promising solid–solid phase-change materials for energy storage with high film dimensional stability. Cellulose nanofibril Poly(ethylene oxide) Solid–solid phase change Mechanical properties Coefficient of thermal expansion Xu, Haiyu verfasserin aut Yang, Quanling verfasserin (orcid)0000-0002-7013-419X aut Xiong, Chuanxi verfasserin (orcid)0000-0003-0878-0884 aut Zhao, Mengchen verfasserin aut Kobayashi, Kayoko verfasserin aut Saito, Tsuguyuki verfasserin aut Isogai, Akira verfasserin (orcid)0000-0001-8095-0441 aut Enthalten in Carbohydrate polymers Amsterdam [u.a.] : Elsevier Science, 1981 225 Online-Ressource (DE-627)306717611 (DE-600)1501516-6 (DE-576)109967178 1879-1344 nnns volume:225 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie 49.25 Lebensmittelkunde Ernährungslehre AR 225
allfieldsSound	10.1016/j.carbpol.2019.115215 doi (DE-627)ELV002851458 (ELSEVIER)S0144-8617(19)30882-3 DE-627 ger DE-627 rda eng 540 660 DE-600 58.34 bkl 49.25 bkl Shi, Zhuqun verfasserin aut Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the 100% PEO film was translucent. The addition of CNFs to the PEO matrix resulted in decreases of the crystallinity and crystal size of spherical PEO. The Young’s modulus and tensile strength of the 100% PEO film were 0.2 GPa and 6.1 MPa, respectively, and remarkably increased to 2.4 GPa and 86 MPa, respectively, with the addition of 20% CNF. The CNF/PEO composite films had clear melting and crystallization temperatures in the heating and cooling processes, respectively. Nevertheless, the coefficients of thermal expansion at temperatures above the melting point of PEO significantly decreased with the CNF addition. The CNF/PEO composite films are therefore promising solid–solid phase-change materials for energy storage with high film dimensional stability. Cellulose nanofibril Poly(ethylene oxide) Solid–solid phase change Mechanical properties Coefficient of thermal expansion Xu, Haiyu verfasserin aut Yang, Quanling verfasserin (orcid)0000-0002-7013-419X aut Xiong, Chuanxi verfasserin (orcid)0000-0003-0878-0884 aut Zhao, Mengchen verfasserin aut Kobayashi, Kayoko verfasserin aut Saito, Tsuguyuki verfasserin aut Isogai, Akira verfasserin (orcid)0000-0001-8095-0441 aut Enthalten in Carbohydrate polymers Amsterdam [u.a.] : Elsevier Science, 1981 225 Online-Ressource (DE-627)306717611 (DE-600)1501516-6 (DE-576)109967178 1879-1344 nnns volume:225 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie 49.25 Lebensmittelkunde Ernährungslehre AR 225
language	English
source	Enthalten in Carbohydrate polymers 225 volume:225
sourceStr	Enthalten in Carbohydrate polymers 225 volume:225
format_phy_str_mv	Article
bklname	Lebensmitteltechnologie Lebensmittelkunde Ernährungslehre
institution	findex.gbv.de
topic_facet	Cellulose nanofibril Poly(ethylene oxide) Solid–solid phase change Mechanical properties Coefficient of thermal expansion
dewey-raw	540
isfreeaccess_bool	false
container_title	Carbohydrate polymers
authorswithroles_txt_mv	Shi, Zhuqun @@aut@@ Xu, Haiyu @@aut@@ Yang, Quanling @@aut@@ Xiong, Chuanxi @@aut@@ Zhao, Mengchen @@aut@@ Kobayashi, Kayoko @@aut@@ Saito, Tsuguyuki @@aut@@ Isogai, Akira @@aut@@
publishDateDaySort_date	2019-01-01T00:00:00Z
hierarchy_top_id	306717611
dewey-sort	3540
id	ELV002851458
language_de	englisch
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author	Shi, Zhuqun
spellingShingle	Shi, Zhuqun ddc 540 bkl 58.34 bkl 49.25 misc Cellulose nanofibril misc Poly(ethylene oxide) misc Solid–solid phase change misc Mechanical properties misc Coefficient of thermal expansion Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage
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topic_title	540 660 DE-600 58.34 bkl 49.25 bkl Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage Cellulose nanofibril Poly(ethylene oxide) Solid–solid phase change Mechanical properties Coefficient of thermal expansion
topic	ddc 540 bkl 58.34 bkl 49.25 misc Cellulose nanofibril misc Poly(ethylene oxide) misc Solid–solid phase change misc Mechanical properties misc Coefficient of thermal expansion
topic_unstemmed	ddc 540 bkl 58.34 bkl 49.25 misc Cellulose nanofibril misc Poly(ethylene oxide) misc Solid–solid phase change misc Mechanical properties misc Coefficient of thermal expansion
topic_browse	ddc 540 bkl 58.34 bkl 49.25 misc Cellulose nanofibril misc Poly(ethylene oxide) misc Solid–solid phase change misc Mechanical properties misc Coefficient of thermal expansion
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title	Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage
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title_full	Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage
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title_sort	carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage
title_auth	Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage
abstract	Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the 100% PEO film was translucent. The addition of CNFs to the PEO matrix resulted in decreases of the crystallinity and crystal size of spherical PEO. The Young’s modulus and tensile strength of the 100% PEO film were 0.2 GPa and 6.1 MPa, respectively, and remarkably increased to 2.4 GPa and 86 MPa, respectively, with the addition of 20% CNF. The CNF/PEO composite films had clear melting and crystallization temperatures in the heating and cooling processes, respectively. Nevertheless, the coefficients of thermal expansion at temperatures above the melting point of PEO significantly decreased with the CNF addition. The CNF/PEO composite films are therefore promising solid–solid phase-change materials for energy storage with high film dimensional stability.
abstractGer	Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the 100% PEO film was translucent. The addition of CNFs to the PEO matrix resulted in decreases of the crystallinity and crystal size of spherical PEO. The Young’s modulus and tensile strength of the 100% PEO film were 0.2 GPa and 6.1 MPa, respectively, and remarkably increased to 2.4 GPa and 86 MPa, respectively, with the addition of 20% CNF. The CNF/PEO composite films had clear melting and crystallization temperatures in the heating and cooling processes, respectively. Nevertheless, the coefficients of thermal expansion at temperatures above the melting point of PEO significantly decreased with the CNF addition. The CNF/PEO composite films are therefore promising solid–solid phase-change materials for energy storage with high film dimensional stability.
abstract_unstemmed	Composite films of poly(ethylene oxide) (PEO) and 0%–20% surface-carboxylated cellulose nanofibrils (CNFs) were prepared by mixing the aqueous CNF dispersion and aqueous PEO solution at various weight ratios followed by casting and drying. The 20% CNF/PEO composite film was transparent, whereas the 100% PEO film was translucent. The addition of CNFs to the PEO matrix resulted in decreases of the crystallinity and crystal size of spherical PEO. The Young’s modulus and tensile strength of the 100% PEO film were 0.2 GPa and 6.1 MPa, respectively, and remarkably increased to 2.4 GPa and 86 MPa, respectively, with the addition of 20% CNF. The CNF/PEO composite films had clear melting and crystallization temperatures in the heating and cooling processes, respectively. Nevertheless, the coefficients of thermal expansion at temperatures above the melting point of PEO significantly decreased with the CNF addition. The CNF/PEO composite films are therefore promising solid–solid phase-change materials for energy storage with high film dimensional stability.
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title_short	Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage
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author2	Xu, Haiyu Yang, Quanling Xiong, Chuanxi Zhao, Mengchen Kobayashi, Kayoko Saito, Tsuguyuki Isogai, Akira
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doi_str	10.1016/j.carbpol.2019.115215
up_date	2024-07-06T17:40:04.261Z
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Carboxylated nanocellulose/poly(ethylene oxide) composite films as solid–solid phase-change materials for thermal energy storage

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