Composition dependent characteristic transition temperatures of Co-B melts
The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid struct...
Ausführliche Beschreibung
Autor*in: |
He, Yixuan [verfasserIn] Li, Jinshan [verfasserIn] Li, Liyuan [verfasserIn] Wang, Jun [verfasserIn] Yildiz, Eyub [verfasserIn] Beaugnon, Eric [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2019 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Journal of non-crystalline solids - Amsterdam [u.a.] : Elsevier Science, 1968, 522 |
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Übergeordnetes Werk: |
volume:522 |
DOI / URN: |
10.1016/j.jnoncrysol.2019.119583 |
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Katalog-ID: |
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520 | |a The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid structure transition. This anomalous behavior was found to be a universal formula for the Co-B binary alloy system. The transition point (T 0) and two paramagnetic Curie temperatures (θ p (LI), θ p (LII)) corresponding to two distinct kinds of liquids (i.e., high-magnetization liquid (HML) I and low-magnetization liquid (LML) II) were measured. With the increased concentration of Co, T 0, θ p (LI) and θ p (LII) shift to higher temperatures and the Curie constants for the HML and LML decrease. Based on the location of T 0, a guideline is drawn above the liquidus in the Co-B phase diagram, which could provide a significant guidance to the practical melt treatment. | ||
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2019 |
allfields |
10.1016/j.jnoncrysol.2019.119583 doi (DE-627)ELV002869063 (ELSEVIER)S0022-3093(19)30454-5 DE-627 ger DE-627 rda eng 660 670 DE-600 51.45 bkl 51.60 bkl 33.61 bkl 35.90 bkl He, Yixuan verfasserin aut Composition dependent characteristic transition temperatures of Co-B melts 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid structure transition. This anomalous behavior was found to be a universal formula for the Co-B binary alloy system. The transition point (T 0) and two paramagnetic Curie temperatures (θ p (LI), θ p (LII)) corresponding to two distinct kinds of liquids (i.e., high-magnetization liquid (HML) I and low-magnetization liquid (LML) II) were measured. With the increased concentration of Co, T 0, θ p (LI) and θ p (LII) shift to higher temperatures and the Curie constants for the HML and LML decrease. Based on the location of T 0, a guideline is drawn above the liquidus in the Co-B phase diagram, which could provide a significant guidance to the practical melt treatment. Magnetization Liquid Liquid-liquid structure transition Magnetic property Li, Jinshan verfasserin (orcid)0000-0002-6894-9760 aut Li, Liyuan verfasserin aut Wang, Jun verfasserin (orcid)0000-0001-8101-2967 aut Yildiz, Eyub verfasserin aut Beaugnon, Eric verfasserin aut Enthalten in Journal of non-crystalline solids Amsterdam [u.a.] : Elsevier Science, 1968 522 Online-Ressource (DE-627)306659808 (DE-600)1500501-X (DE-576)096806486 0022-3093 nnns volume:522 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.45 Werkstoffe mit besonderen Eigenschaften 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 33.61 Festkörperphysik 35.90 Festkörperchemie AR 522 |
spelling |
10.1016/j.jnoncrysol.2019.119583 doi (DE-627)ELV002869063 (ELSEVIER)S0022-3093(19)30454-5 DE-627 ger DE-627 rda eng 660 670 DE-600 51.45 bkl 51.60 bkl 33.61 bkl 35.90 bkl He, Yixuan verfasserin aut Composition dependent characteristic transition temperatures of Co-B melts 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid structure transition. This anomalous behavior was found to be a universal formula for the Co-B binary alloy system. The transition point (T 0) and two paramagnetic Curie temperatures (θ p (LI), θ p (LII)) corresponding to two distinct kinds of liquids (i.e., high-magnetization liquid (HML) I and low-magnetization liquid (LML) II) were measured. With the increased concentration of Co, T 0, θ p (LI) and θ p (LII) shift to higher temperatures and the Curie constants for the HML and LML decrease. Based on the location of T 0, a guideline is drawn above the liquidus in the Co-B phase diagram, which could provide a significant guidance to the practical melt treatment. Magnetization Liquid Liquid-liquid structure transition Magnetic property Li, Jinshan verfasserin (orcid)0000-0002-6894-9760 aut Li, Liyuan verfasserin aut Wang, Jun verfasserin (orcid)0000-0001-8101-2967 aut Yildiz, Eyub verfasserin aut Beaugnon, Eric verfasserin aut Enthalten in Journal of non-crystalline solids Amsterdam [u.a.] : Elsevier Science, 1968 522 Online-Ressource (DE-627)306659808 (DE-600)1500501-X (DE-576)096806486 0022-3093 nnns volume:522 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.45 Werkstoffe mit besonderen Eigenschaften 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 33.61 Festkörperphysik 35.90 Festkörperchemie AR 522 |
allfields_unstemmed |
10.1016/j.jnoncrysol.2019.119583 doi (DE-627)ELV002869063 (ELSEVIER)S0022-3093(19)30454-5 DE-627 ger DE-627 rda eng 660 670 DE-600 51.45 bkl 51.60 bkl 33.61 bkl 35.90 bkl He, Yixuan verfasserin aut Composition dependent characteristic transition temperatures of Co-B melts 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid structure transition. This anomalous behavior was found to be a universal formula for the Co-B binary alloy system. The transition point (T 0) and two paramagnetic Curie temperatures (θ p (LI), θ p (LII)) corresponding to two distinct kinds of liquids (i.e., high-magnetization liquid (HML) I and low-magnetization liquid (LML) II) were measured. With the increased concentration of Co, T 0, θ p (LI) and θ p (LII) shift to higher temperatures and the Curie constants for the HML and LML decrease. Based on the location of T 0, a guideline is drawn above the liquidus in the Co-B phase diagram, which could provide a significant guidance to the practical melt treatment. Magnetization Liquid Liquid-liquid structure transition Magnetic property Li, Jinshan verfasserin (orcid)0000-0002-6894-9760 aut Li, Liyuan verfasserin aut Wang, Jun verfasserin (orcid)0000-0001-8101-2967 aut Yildiz, Eyub verfasserin aut Beaugnon, Eric verfasserin aut Enthalten in Journal of non-crystalline solids Amsterdam [u.a.] : Elsevier Science, 1968 522 Online-Ressource (DE-627)306659808 (DE-600)1500501-X (DE-576)096806486 0022-3093 nnns volume:522 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.45 Werkstoffe mit besonderen Eigenschaften 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 33.61 Festkörperphysik 35.90 Festkörperchemie AR 522 |
allfieldsGer |
10.1016/j.jnoncrysol.2019.119583 doi (DE-627)ELV002869063 (ELSEVIER)S0022-3093(19)30454-5 DE-627 ger DE-627 rda eng 660 670 DE-600 51.45 bkl 51.60 bkl 33.61 bkl 35.90 bkl He, Yixuan verfasserin aut Composition dependent characteristic transition temperatures of Co-B melts 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid structure transition. This anomalous behavior was found to be a universal formula for the Co-B binary alloy system. The transition point (T 0) and two paramagnetic Curie temperatures (θ p (LI), θ p (LII)) corresponding to two distinct kinds of liquids (i.e., high-magnetization liquid (HML) I and low-magnetization liquid (LML) II) were measured. With the increased concentration of Co, T 0, θ p (LI) and θ p (LII) shift to higher temperatures and the Curie constants for the HML and LML decrease. Based on the location of T 0, a guideline is drawn above the liquidus in the Co-B phase diagram, which could provide a significant guidance to the practical melt treatment. Magnetization Liquid Liquid-liquid structure transition Magnetic property Li, Jinshan verfasserin (orcid)0000-0002-6894-9760 aut Li, Liyuan verfasserin aut Wang, Jun verfasserin (orcid)0000-0001-8101-2967 aut Yildiz, Eyub verfasserin aut Beaugnon, Eric verfasserin aut Enthalten in Journal of non-crystalline solids Amsterdam [u.a.] : Elsevier Science, 1968 522 Online-Ressource (DE-627)306659808 (DE-600)1500501-X (DE-576)096806486 0022-3093 nnns volume:522 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.45 Werkstoffe mit besonderen Eigenschaften 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 33.61 Festkörperphysik 35.90 Festkörperchemie AR 522 |
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10.1016/j.jnoncrysol.2019.119583 doi (DE-627)ELV002869063 (ELSEVIER)S0022-3093(19)30454-5 DE-627 ger DE-627 rda eng 660 670 DE-600 51.45 bkl 51.60 bkl 33.61 bkl 35.90 bkl He, Yixuan verfasserin aut Composition dependent characteristic transition temperatures of Co-B melts 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid structure transition. This anomalous behavior was found to be a universal formula for the Co-B binary alloy system. The transition point (T 0) and two paramagnetic Curie temperatures (θ p (LI), θ p (LII)) corresponding to two distinct kinds of liquids (i.e., high-magnetization liquid (HML) I and low-magnetization liquid (LML) II) were measured. With the increased concentration of Co, T 0, θ p (LI) and θ p (LII) shift to higher temperatures and the Curie constants for the HML and LML decrease. Based on the location of T 0, a guideline is drawn above the liquidus in the Co-B phase diagram, which could provide a significant guidance to the practical melt treatment. Magnetization Liquid Liquid-liquid structure transition Magnetic property Li, Jinshan verfasserin (orcid)0000-0002-6894-9760 aut Li, Liyuan verfasserin aut Wang, Jun verfasserin (orcid)0000-0001-8101-2967 aut Yildiz, Eyub verfasserin aut Beaugnon, Eric verfasserin aut Enthalten in Journal of non-crystalline solids Amsterdam [u.a.] : Elsevier Science, 1968 522 Online-Ressource (DE-627)306659808 (DE-600)1500501-X (DE-576)096806486 0022-3093 nnns volume:522 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.45 Werkstoffe mit besonderen Eigenschaften 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 33.61 Festkörperphysik 35.90 Festkörperchemie AR 522 |
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He, Yixuan @@aut@@ Li, Jinshan @@aut@@ Li, Liyuan @@aut@@ Wang, Jun @@aut@@ Yildiz, Eyub @@aut@@ Beaugnon, Eric @@aut@@ |
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He, Yixuan ddc 660 bkl 51.45 bkl 51.60 bkl 33.61 bkl 35.90 misc Magnetization misc Liquid misc Liquid-liquid structure transition misc Magnetic property Composition dependent characteristic transition temperatures of Co-B melts |
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660 670 DE-600 51.45 bkl 51.60 bkl 33.61 bkl 35.90 bkl Composition dependent characteristic transition temperatures of Co-B melts Magnetization Liquid Liquid-liquid structure transition Magnetic property |
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Composition dependent characteristic transition temperatures of Co-B melts |
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Composition dependent characteristic transition temperatures of Co-B melts |
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composition dependent characteristic transition temperatures of co-b melts |
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Composition dependent characteristic transition temperatures of Co-B melts |
abstract |
The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid structure transition. This anomalous behavior was found to be a universal formula for the Co-B binary alloy system. The transition point (T 0) and two paramagnetic Curie temperatures (θ p (LI), θ p (LII)) corresponding to two distinct kinds of liquids (i.e., high-magnetization liquid (HML) I and low-magnetization liquid (LML) II) were measured. With the increased concentration of Co, T 0, θ p (LI) and θ p (LII) shift to higher temperatures and the Curie constants for the HML and LML decrease. Based on the location of T 0, a guideline is drawn above the liquidus in the Co-B phase diagram, which could provide a significant guidance to the practical melt treatment. |
abstractGer |
The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid structure transition. This anomalous behavior was found to be a universal formula for the Co-B binary alloy system. The transition point (T 0) and two paramagnetic Curie temperatures (θ p (LI), θ p (LII)) corresponding to two distinct kinds of liquids (i.e., high-magnetization liquid (HML) I and low-magnetization liquid (LML) II) were measured. With the increased concentration of Co, T 0, θ p (LI) and θ p (LII) shift to higher temperatures and the Curie constants for the HML and LML decrease. Based on the location of T 0, a guideline is drawn above the liquidus in the Co-B phase diagram, which could provide a significant guidance to the practical melt treatment. |
abstract_unstemmed |
The temperature-dependent liquid structures of Co-B melts were studied by in-situ measuring the magnetization. A magnetization anomaly in term of the non-Curie-Weiss temperature dependence of magnetization was observed in the overheated state, demonstrating a temperature-induced liquid-liquid structure transition. This anomalous behavior was found to be a universal formula for the Co-B binary alloy system. The transition point (T 0) and two paramagnetic Curie temperatures (θ p (LI), θ p (LII)) corresponding to two distinct kinds of liquids (i.e., high-magnetization liquid (HML) I and low-magnetization liquid (LML) II) were measured. With the increased concentration of Co, T 0, θ p (LI) and θ p (LII) shift to higher temperatures and the Curie constants for the HML and LML decrease. Based on the location of T 0, a guideline is drawn above the liquidus in the Co-B phase diagram, which could provide a significant guidance to the practical melt treatment. |
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Composition dependent characteristic transition temperatures of Co-B melts |
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