Modulation of the ordering temperature in anilato-based magnets

Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordina...
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Gespeichert in:

Autor*in:	Martínez-Hernández, Cristian [verfasserIn] Benmansour, Samia [verfasserIn] Gómez García, Carlos J. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Anilato complexes Layered compounds Magnetic properties Ferrimagnetic layers Ferrimagnetic order

Übergeordnetes Werk:	Enthalten in: Polyhedron - Amsterdam [u.a.] : Elsevier Science, 1982, 170, Seite 122-131
Übergeordnetes Werk:	volume:170 ; pages:122-131

DOI / URN:	10.1016/j.poly.2019.05.034

Katalog-ID:	ELV002898802

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520			\|a Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4) in the magnetic properties. Compounds 1–4 constitute a unique series of 2D magnets where the ordering temperature can be triply-modulated (with a ligand, a solvent and the X group of the anilato ligand).
650		4	\|a Anilato complexes
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650		4	\|a Magnetic properties
650		4	\|a Ferrimagnetic layers
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700	1		\|a Benmansour, Samia \|e verfasserin \|0 (orcid)0000-0002-5482-8554 \|4 aut
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Indexfelder

author_variant	c m h cmh s b sb g c j g gcj gcjg
matchkey_str	martnezhernndezcristianbenmansoursamiagm:2019----:ouainfhodrntmeauenn
hierarchy_sort_str	2019
bklnumber	35.00
publishDate	2019
allfields	10.1016/j.poly.2019.05.034 doi (DE-627)ELV002898802 (ELSEVIER)S0277-5387(19)30364-X DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Martínez-Hernández, Cristian verfasserin (orcid)0000-0001-5532-1694 aut Modulation of the ordering temperature in anilato-based magnets 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4) in the magnetic properties. Compounds 1–4 constitute a unique series of 2D magnets where the ordering temperature can be triply-modulated (with a ligand, a solvent and the X group of the anilato ligand). Anilato complexes Layered compounds Magnetic properties Ferrimagnetic layers Ferrimagnetic order Benmansour, Samia verfasserin (orcid)0000-0002-5482-8554 aut Gómez García, Carlos J. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 170, Seite 122-131 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:170 pages:122-131 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 170 122-131
spelling	10.1016/j.poly.2019.05.034 doi (DE-627)ELV002898802 (ELSEVIER)S0277-5387(19)30364-X DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Martínez-Hernández, Cristian verfasserin (orcid)0000-0001-5532-1694 aut Modulation of the ordering temperature in anilato-based magnets 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4) in the magnetic properties. Compounds 1–4 constitute a unique series of 2D magnets where the ordering temperature can be triply-modulated (with a ligand, a solvent and the X group of the anilato ligand). Anilato complexes Layered compounds Magnetic properties Ferrimagnetic layers Ferrimagnetic order Benmansour, Samia verfasserin (orcid)0000-0002-5482-8554 aut Gómez García, Carlos J. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 170, Seite 122-131 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:170 pages:122-131 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 170 122-131
allfields_unstemmed	10.1016/j.poly.2019.05.034 doi (DE-627)ELV002898802 (ELSEVIER)S0277-5387(19)30364-X DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Martínez-Hernández, Cristian verfasserin (orcid)0000-0001-5532-1694 aut Modulation of the ordering temperature in anilato-based magnets 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4) in the magnetic properties. Compounds 1–4 constitute a unique series of 2D magnets where the ordering temperature can be triply-modulated (with a ligand, a solvent and the X group of the anilato ligand). Anilato complexes Layered compounds Magnetic properties Ferrimagnetic layers Ferrimagnetic order Benmansour, Samia verfasserin (orcid)0000-0002-5482-8554 aut Gómez García, Carlos J. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 170, Seite 122-131 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:170 pages:122-131 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 170 122-131
allfieldsGer	10.1016/j.poly.2019.05.034 doi (DE-627)ELV002898802 (ELSEVIER)S0277-5387(19)30364-X DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Martínez-Hernández, Cristian verfasserin (orcid)0000-0001-5532-1694 aut Modulation of the ordering temperature in anilato-based magnets 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4) in the magnetic properties. Compounds 1–4 constitute a unique series of 2D magnets where the ordering temperature can be triply-modulated (with a ligand, a solvent and the X group of the anilato ligand). Anilato complexes Layered compounds Magnetic properties Ferrimagnetic layers Ferrimagnetic order Benmansour, Samia verfasserin (orcid)0000-0002-5482-8554 aut Gómez García, Carlos J. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 170, Seite 122-131 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:170 pages:122-131 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 170 122-131
allfieldsSound	10.1016/j.poly.2019.05.034 doi (DE-627)ELV002898802 (ELSEVIER)S0277-5387(19)30364-X DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Martínez-Hernández, Cristian verfasserin (orcid)0000-0001-5532-1694 aut Modulation of the ordering temperature in anilato-based magnets 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4) in the magnetic properties. Compounds 1–4 constitute a unique series of 2D magnets where the ordering temperature can be triply-modulated (with a ligand, a solvent and the X group of the anilato ligand). Anilato complexes Layered compounds Magnetic properties Ferrimagnetic layers Ferrimagnetic order Benmansour, Samia verfasserin (orcid)0000-0002-5482-8554 aut Gómez García, Carlos J. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 170, Seite 122-131 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:170 pages:122-131 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 170 122-131
language	English
source	Enthalten in Polyhedron 170, Seite 122-131 volume:170 pages:122-131
sourceStr	Enthalten in Polyhedron 170, Seite 122-131 volume:170 pages:122-131
format_phy_str_mv	Article
bklname	Chemie: Allgemeines
institution	findex.gbv.de
topic_facet	Anilato complexes Layered compounds Magnetic properties Ferrimagnetic layers Ferrimagnetic order
dewey-raw	540
isfreeaccess_bool	false
container_title	Polyhedron
authorswithroles_txt_mv	Martínez-Hernández, Cristian @@aut@@ Benmansour, Samia @@aut@@ Gómez García, Carlos J. @@aut@@
publishDateDaySort_date	2019-01-01T00:00:00Z
hierarchy_top_id	320402967
dewey-sort	3540
id	ELV002898802
language_de	englisch
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author	Martínez-Hernández, Cristian
spellingShingle	Martínez-Hernández, Cristian ddc 540 bkl 35.00 misc Anilato complexes misc Layered compounds misc Magnetic properties misc Ferrimagnetic layers misc Ferrimagnetic order Modulation of the ordering temperature in anilato-based magnets
authorStr	Martínez-Hernández, Cristian
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topic_title	540 DE-600 35.00 bkl Modulation of the ordering temperature in anilato-based magnets Anilato complexes Layered compounds Magnetic properties Ferrimagnetic layers Ferrimagnetic order
topic	ddc 540 bkl 35.00 misc Anilato complexes misc Layered compounds misc Magnetic properties misc Ferrimagnetic layers misc Ferrimagnetic order
topic_unstemmed	ddc 540 bkl 35.00 misc Anilato complexes misc Layered compounds misc Magnetic properties misc Ferrimagnetic layers misc Ferrimagnetic order
topic_browse	ddc 540 bkl 35.00 misc Anilato complexes misc Layered compounds misc Magnetic properties misc Ferrimagnetic layers misc Ferrimagnetic order
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title	Modulation of the ordering temperature in anilato-based magnets
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title_full	Modulation of the ordering temperature in anilato-based magnets
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title_sort	modulation of the ordering temperature in anilato-based magnets
title_auth	Modulation of the ordering temperature in anilato-based magnets
abstract	Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4) in the magnetic properties. Compounds 1–4 constitute a unique series of 2D magnets where the ordering temperature can be triply-modulated (with a ligand, a solvent and the X group of the anilato ligand).
abstractGer	Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4) in the magnetic properties. Compounds 1–4 constitute a unique series of 2D magnets where the ordering temperature can be triply-modulated (with a ligand, a solvent and the X group of the anilato ligand).
abstract_unstemmed	Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4) in the magnetic properties. Compounds 1–4 constitute a unique series of 2D magnets where the ordering temperature can be triply-modulated (with a ligand, a solvent and the X group of the anilato ligand).
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title_short	Modulation of the ordering temperature in anilato-based magnets
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up_date	2024-07-06T17:49:30.376Z
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Modulation of the ordering temperature in anilato-based magnets

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