Effects of Bi

We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ord...
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Autor*in:	Shang, C. [verfasserIn] Xia, Z.C. [verfasserIn] Zhao, B. [verfasserIn] Liu, D.W. [verfasserIn] Wang, Y.Q. [verfasserIn] Su, Y.L. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	A. Magnetic materials B. Magnetic properties B. Phase transitions D. Electrical properties

Übergeordnetes Werk:	Enthalten in: Materials research bulletin - New York, NY [u.a.] : Elsevier, 1966, 121
Übergeordnetes Werk:	volume:121

DOI / URN:	10.1016/j.materresbull.2019.110611

Katalog-ID:	ELV002958880

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520			\|a We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ordering is significantly enhanced upon Bi3+ doping, and the charge ordering temperature increases with increasing Bi3+ content. With applying pulsed high magnetic field, the charge ordering phase collapses into ferromagnetic phase through a metamagnetic transition. The phase diagram of Nd0.6- x Bi x Ca0.4MnO3 has been determined by the high magnetic field studies, in which the charge ordering and ferromagnetic phase boundary is clearly figured out. The critical fields for melting the charge ordering phase of Nd0.6- x Bi x Ca0.4MnO3 increase significantly with increasing Bi3+ content, which is revealed to reach up to 33.5 T for the sample with x = 0.3. Based on the hybridization between Bi-6s orbitals and O-2p orbitals, we assume that the 6s2 lone-pair character of Bi3+ plays a crucial role in favoring the charge ordering in Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4).
650		4	\|a A. Magnetic materials
650		4	\|a B. Magnetic properties
650		4	\|a B. Phase transitions
650		4	\|a D. Electrical properties
700	1		\|a Xia, Z.C. \|e verfasserin \|4 aut
700	1		\|a Zhao, B. \|e verfasserin \|4 aut
700	1		\|a Liu, D.W. \|e verfasserin \|4 aut
700	1		\|a Wang, Y.Q. \|e verfasserin \|4 aut
700	1		\|a Su, Y.L. \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Materials research bulletin \|d New York, NY [u.a.] : Elsevier, 1966 \|g 121 \|h Online-Ressource \|w (DE-627)302719466 \|w (DE-600)1491970-9 \|w (DE-576)094422036 \|7 nnns
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author_variant	c s cs z x zx b z bz d l dl y w yw y s ys
matchkey_str	shangcxiazczhaobliudwwangyqsuyl:2019----:fet
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publishDate	2019
allfields	10.1016/j.materresbull.2019.110611 doi (DE-627)ELV002958880 (ELSEVIER)S0025-5408(18)33258-6 DE-627 ger DE-627 rda eng 600 670 DE-600 51.00 bkl Shang, C. verfasserin aut Effects of Bi 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ordering is significantly enhanced upon Bi3+ doping, and the charge ordering temperature increases with increasing Bi3+ content. With applying pulsed high magnetic field, the charge ordering phase collapses into ferromagnetic phase through a metamagnetic transition. The phase diagram of Nd0.6- x Bi x Ca0.4MnO3 has been determined by the high magnetic field studies, in which the charge ordering and ferromagnetic phase boundary is clearly figured out. The critical fields for melting the charge ordering phase of Nd0.6- x Bi x Ca0.4MnO3 increase significantly with increasing Bi3+ content, which is revealed to reach up to 33.5 T for the sample with x = 0.3. Based on the hybridization between Bi-6s orbitals and O-2p orbitals, we assume that the 6s2 lone-pair character of Bi3+ plays a crucial role in favoring the charge ordering in Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). A. Magnetic materials B. Magnetic properties B. Phase transitions D. Electrical properties Xia, Z.C. verfasserin aut Zhao, B. verfasserin aut Liu, D.W. verfasserin aut Wang, Y.Q. verfasserin aut Su, Y.L. verfasserin aut Enthalten in Materials research bulletin New York, NY [u.a.] : Elsevier, 1966 121 Online-Ressource (DE-627)302719466 (DE-600)1491970-9 (DE-576)094422036 nnns volume:121 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 121
spelling	10.1016/j.materresbull.2019.110611 doi (DE-627)ELV002958880 (ELSEVIER)S0025-5408(18)33258-6 DE-627 ger DE-627 rda eng 600 670 DE-600 51.00 bkl Shang, C. verfasserin aut Effects of Bi 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ordering is significantly enhanced upon Bi3+ doping, and the charge ordering temperature increases with increasing Bi3+ content. With applying pulsed high magnetic field, the charge ordering phase collapses into ferromagnetic phase through a metamagnetic transition. The phase diagram of Nd0.6- x Bi x Ca0.4MnO3 has been determined by the high magnetic field studies, in which the charge ordering and ferromagnetic phase boundary is clearly figured out. The critical fields for melting the charge ordering phase of Nd0.6- x Bi x Ca0.4MnO3 increase significantly with increasing Bi3+ content, which is revealed to reach up to 33.5 T for the sample with x = 0.3. Based on the hybridization between Bi-6s orbitals and O-2p orbitals, we assume that the 6s2 lone-pair character of Bi3+ plays a crucial role in favoring the charge ordering in Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). A. Magnetic materials B. Magnetic properties B. Phase transitions D. Electrical properties Xia, Z.C. verfasserin aut Zhao, B. verfasserin aut Liu, D.W. verfasserin aut Wang, Y.Q. verfasserin aut Su, Y.L. verfasserin aut Enthalten in Materials research bulletin New York, NY [u.a.] : Elsevier, 1966 121 Online-Ressource (DE-627)302719466 (DE-600)1491970-9 (DE-576)094422036 nnns volume:121 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 121
allfields_unstemmed	10.1016/j.materresbull.2019.110611 doi (DE-627)ELV002958880 (ELSEVIER)S0025-5408(18)33258-6 DE-627 ger DE-627 rda eng 600 670 DE-600 51.00 bkl Shang, C. verfasserin aut Effects of Bi 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ordering is significantly enhanced upon Bi3+ doping, and the charge ordering temperature increases with increasing Bi3+ content. With applying pulsed high magnetic field, the charge ordering phase collapses into ferromagnetic phase through a metamagnetic transition. The phase diagram of Nd0.6- x Bi x Ca0.4MnO3 has been determined by the high magnetic field studies, in which the charge ordering and ferromagnetic phase boundary is clearly figured out. The critical fields for melting the charge ordering phase of Nd0.6- x Bi x Ca0.4MnO3 increase significantly with increasing Bi3+ content, which is revealed to reach up to 33.5 T for the sample with x = 0.3. Based on the hybridization between Bi-6s orbitals and O-2p orbitals, we assume that the 6s2 lone-pair character of Bi3+ plays a crucial role in favoring the charge ordering in Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). A. Magnetic materials B. Magnetic properties B. Phase transitions D. Electrical properties Xia, Z.C. verfasserin aut Zhao, B. verfasserin aut Liu, D.W. verfasserin aut Wang, Y.Q. verfasserin aut Su, Y.L. verfasserin aut Enthalten in Materials research bulletin New York, NY [u.a.] : Elsevier, 1966 121 Online-Ressource (DE-627)302719466 (DE-600)1491970-9 (DE-576)094422036 nnns volume:121 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 121
allfieldsGer	10.1016/j.materresbull.2019.110611 doi (DE-627)ELV002958880 (ELSEVIER)S0025-5408(18)33258-6 DE-627 ger DE-627 rda eng 600 670 DE-600 51.00 bkl Shang, C. verfasserin aut Effects of Bi 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ordering is significantly enhanced upon Bi3+ doping, and the charge ordering temperature increases with increasing Bi3+ content. With applying pulsed high magnetic field, the charge ordering phase collapses into ferromagnetic phase through a metamagnetic transition. The phase diagram of Nd0.6- x Bi x Ca0.4MnO3 has been determined by the high magnetic field studies, in which the charge ordering and ferromagnetic phase boundary is clearly figured out. The critical fields for melting the charge ordering phase of Nd0.6- x Bi x Ca0.4MnO3 increase significantly with increasing Bi3+ content, which is revealed to reach up to 33.5 T for the sample with x = 0.3. Based on the hybridization between Bi-6s orbitals and O-2p orbitals, we assume that the 6s2 lone-pair character of Bi3+ plays a crucial role in favoring the charge ordering in Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). A. Magnetic materials B. Magnetic properties B. Phase transitions D. Electrical properties Xia, Z.C. verfasserin aut Zhao, B. verfasserin aut Liu, D.W. verfasserin aut Wang, Y.Q. verfasserin aut Su, Y.L. verfasserin aut Enthalten in Materials research bulletin New York, NY [u.a.] : Elsevier, 1966 121 Online-Ressource (DE-627)302719466 (DE-600)1491970-9 (DE-576)094422036 nnns volume:121 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 121
allfieldsSound	10.1016/j.materresbull.2019.110611 doi (DE-627)ELV002958880 (ELSEVIER)S0025-5408(18)33258-6 DE-627 ger DE-627 rda eng 600 670 DE-600 51.00 bkl Shang, C. verfasserin aut Effects of Bi 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ordering is significantly enhanced upon Bi3+ doping, and the charge ordering temperature increases with increasing Bi3+ content. With applying pulsed high magnetic field, the charge ordering phase collapses into ferromagnetic phase through a metamagnetic transition. The phase diagram of Nd0.6- x Bi x Ca0.4MnO3 has been determined by the high magnetic field studies, in which the charge ordering and ferromagnetic phase boundary is clearly figured out. The critical fields for melting the charge ordering phase of Nd0.6- x Bi x Ca0.4MnO3 increase significantly with increasing Bi3+ content, which is revealed to reach up to 33.5 T for the sample with x = 0.3. Based on the hybridization between Bi-6s orbitals and O-2p orbitals, we assume that the 6s2 lone-pair character of Bi3+ plays a crucial role in favoring the charge ordering in Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). A. Magnetic materials B. Magnetic properties B. Phase transitions D. Electrical properties Xia, Z.C. verfasserin aut Zhao, B. verfasserin aut Liu, D.W. verfasserin aut Wang, Y.Q. verfasserin aut Su, Y.L. verfasserin aut Enthalten in Materials research bulletin New York, NY [u.a.] : Elsevier, 1966 121 Online-Ressource (DE-627)302719466 (DE-600)1491970-9 (DE-576)094422036 nnns volume:121 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.00 Werkstoffkunde: Allgemeines AR 121
language	English
source	Enthalten in Materials research bulletin 121 volume:121
sourceStr	Enthalten in Materials research bulletin 121 volume:121
format_phy_str_mv	Article
bklname	Werkstoffkunde: Allgemeines
institution	findex.gbv.de
topic_facet	A. Magnetic materials B. Magnetic properties B. Phase transitions D. Electrical properties
dewey-raw	600
isfreeaccess_bool	false
container_title	Materials research bulletin
authorswithroles_txt_mv	Shang, C. @@aut@@ Xia, Z.C. @@aut@@ Zhao, B. @@aut@@ Liu, D.W. @@aut@@ Wang, Y.Q. @@aut@@ Su, Y.L. @@aut@@
publishDateDaySort_date	2019-01-01T00:00:00Z
hierarchy_top_id	302719466
dewey-sort	3600
id	ELV002958880
language_de	englisch
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author	Shang, C.
spellingShingle	Shang, C. ddc 600 bkl 51.00 misc A. Magnetic materials misc B. Magnetic properties misc B. Phase transitions misc D. Electrical properties Effects of Bi
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topic_title	600 670 DE-600 51.00 bkl Effects of Bi A. Magnetic materials B. Magnetic properties B. Phase transitions D. Electrical properties
topic	ddc 600 bkl 51.00 misc A. Magnetic materials misc B. Magnetic properties misc B. Phase transitions misc D. Electrical properties
topic_unstemmed	ddc 600 bkl 51.00 misc A. Magnetic materials misc B. Magnetic properties misc B. Phase transitions misc D. Electrical properties
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title	Effects of Bi
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title_full	Effects of Bi
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title_sort	effects of bi
title_auth	Effects of Bi
abstract	We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ordering is significantly enhanced upon Bi3+ doping, and the charge ordering temperature increases with increasing Bi3+ content. With applying pulsed high magnetic field, the charge ordering phase collapses into ferromagnetic phase through a metamagnetic transition. The phase diagram of Nd0.6- x Bi x Ca0.4MnO3 has been determined by the high magnetic field studies, in which the charge ordering and ferromagnetic phase boundary is clearly figured out. The critical fields for melting the charge ordering phase of Nd0.6- x Bi x Ca0.4MnO3 increase significantly with increasing Bi3+ content, which is revealed to reach up to 33.5 T for the sample with x = 0.3. Based on the hybridization between Bi-6s orbitals and O-2p orbitals, we assume that the 6s2 lone-pair character of Bi3+ plays a crucial role in favoring the charge ordering in Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4).
abstractGer	We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ordering is significantly enhanced upon Bi3+ doping, and the charge ordering temperature increases with increasing Bi3+ content. With applying pulsed high magnetic field, the charge ordering phase collapses into ferromagnetic phase through a metamagnetic transition. The phase diagram of Nd0.6- x Bi x Ca0.4MnO3 has been determined by the high magnetic field studies, in which the charge ordering and ferromagnetic phase boundary is clearly figured out. The critical fields for melting the charge ordering phase of Nd0.6- x Bi x Ca0.4MnO3 increase significantly with increasing Bi3+ content, which is revealed to reach up to 33.5 T for the sample with x = 0.3. Based on the hybridization between Bi-6s orbitals and O-2p orbitals, we assume that the 6s2 lone-pair character of Bi3+ plays a crucial role in favoring the charge ordering in Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4).
abstract_unstemmed	We report the doping effects and pulsed high magnetic field-induced charge ordering to ferromagnetic phase transitions in manganites Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4). The experimental results reveal that the charge ordering is significantly enhanced upon Bi3+ doping, and the charge ordering temperature increases with increasing Bi3+ content. With applying pulsed high magnetic field, the charge ordering phase collapses into ferromagnetic phase through a metamagnetic transition. The phase diagram of Nd0.6- x Bi x Ca0.4MnO3 has been determined by the high magnetic field studies, in which the charge ordering and ferromagnetic phase boundary is clearly figured out. The critical fields for melting the charge ordering phase of Nd0.6- x Bi x Ca0.4MnO3 increase significantly with increasing Bi3+ content, which is revealed to reach up to 33.5 T for the sample with x = 0.3. Based on the hybridization between Bi-6s orbitals and O-2p orbitals, we assume that the 6s2 lone-pair character of Bi3+ plays a crucial role in favoring the charge ordering in Nd0.6- x Bi x Ca0.4MnO3 (0 ≤ x ≤ 0.4).
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title_short	Effects of Bi
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author2	Xia, Z.C. Zhao, B. Liu, D.W. Wang, Y.Q. Su, Y.L.
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doi_str	10.1016/j.materresbull.2019.110611
up_date	2024-07-06T18:01:28.308Z
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score	7.4006586

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