Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation

The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and struc...
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Autor*in:	Chakraborty, Jeet [verfasserIn] Nath, Ipsita [verfasserIn] Song, Shaoxian [verfasserIn] Mohamed, Sharmarke [verfasserIn] Khan, Anish [verfasserIn] Heynderickx, Philippe M. [verfasserIn] Verpoort, Francis [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Porous organic polymers Reactive intermediate species HOMO-LUMO Photocatalysis environmental remediation

Übergeordnetes Werk:	Enthalten in: Journal of photochemistry and photobiology / C - Amsterdam [u.a.] : Elsevier Science, 2000, 41
Übergeordnetes Werk:	volume:41

DOI / URN:	10.1016/j.jphotochemrev.2019.100319

Katalog-ID:	ELV003196313

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520			\|a The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field.
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allfields	10.1016/j.jphotochemrev.2019.100319 doi (DE-627)ELV003196313 (ELSEVIER)S1389-5567(19)30021-8 DE-627 ger DE-627 rda eng 570 540 DE-600 BIODIV DE-30 fid 35.16 bkl Chakraborty, Jeet verfasserin aut Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field. Porous organic polymers Reactive intermediate species HOMO-LUMO Photocatalysis environmental remediation Nath, Ipsita verfasserin aut Song, Shaoxian verfasserin aut Mohamed, Sharmarke verfasserin aut Khan, Anish verfasserin aut Heynderickx, Philippe M. verfasserin aut Verpoort, Francis verfasserin aut Enthalten in Journal of photochemistry and photobiology / C Amsterdam [u.a.] : Elsevier Science, 2000 41 Online-Ressource (DE-627)325049882 (DE-600)2034027-8 (DE-576)259485624 1389-5567 nnns volume:41 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-BIODIV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.16 Photochemie AR 41
spelling	10.1016/j.jphotochemrev.2019.100319 doi (DE-627)ELV003196313 (ELSEVIER)S1389-5567(19)30021-8 DE-627 ger DE-627 rda eng 570 540 DE-600 BIODIV DE-30 fid 35.16 bkl Chakraborty, Jeet verfasserin aut Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field. Porous organic polymers Reactive intermediate species HOMO-LUMO Photocatalysis environmental remediation Nath, Ipsita verfasserin aut Song, Shaoxian verfasserin aut Mohamed, Sharmarke verfasserin aut Khan, Anish verfasserin aut Heynderickx, Philippe M. verfasserin aut Verpoort, Francis verfasserin aut Enthalten in Journal of photochemistry and photobiology / C Amsterdam [u.a.] : Elsevier Science, 2000 41 Online-Ressource (DE-627)325049882 (DE-600)2034027-8 (DE-576)259485624 1389-5567 nnns volume:41 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-BIODIV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.16 Photochemie AR 41
allfields_unstemmed	10.1016/j.jphotochemrev.2019.100319 doi (DE-627)ELV003196313 (ELSEVIER)S1389-5567(19)30021-8 DE-627 ger DE-627 rda eng 570 540 DE-600 BIODIV DE-30 fid 35.16 bkl Chakraborty, Jeet verfasserin aut Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field. Porous organic polymers Reactive intermediate species HOMO-LUMO Photocatalysis environmental remediation Nath, Ipsita verfasserin aut Song, Shaoxian verfasserin aut Mohamed, Sharmarke verfasserin aut Khan, Anish verfasserin aut Heynderickx, Philippe M. verfasserin aut Verpoort, Francis verfasserin aut Enthalten in Journal of photochemistry and photobiology / C Amsterdam [u.a.] : Elsevier Science, 2000 41 Online-Ressource (DE-627)325049882 (DE-600)2034027-8 (DE-576)259485624 1389-5567 nnns volume:41 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-BIODIV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.16 Photochemie AR 41
allfieldsGer	10.1016/j.jphotochemrev.2019.100319 doi (DE-627)ELV003196313 (ELSEVIER)S1389-5567(19)30021-8 DE-627 ger DE-627 rda eng 570 540 DE-600 BIODIV DE-30 fid 35.16 bkl Chakraborty, Jeet verfasserin aut Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field. Porous organic polymers Reactive intermediate species HOMO-LUMO Photocatalysis environmental remediation Nath, Ipsita verfasserin aut Song, Shaoxian verfasserin aut Mohamed, Sharmarke verfasserin aut Khan, Anish verfasserin aut Heynderickx, Philippe M. verfasserin aut Verpoort, Francis verfasserin aut Enthalten in Journal of photochemistry and photobiology / C Amsterdam [u.a.] : Elsevier Science, 2000 41 Online-Ressource (DE-627)325049882 (DE-600)2034027-8 (DE-576)259485624 1389-5567 nnns volume:41 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-BIODIV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.16 Photochemie AR 41
allfieldsSound	10.1016/j.jphotochemrev.2019.100319 doi (DE-627)ELV003196313 (ELSEVIER)S1389-5567(19)30021-8 DE-627 ger DE-627 rda eng 570 540 DE-600 BIODIV DE-30 fid 35.16 bkl Chakraborty, Jeet verfasserin aut Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field. Porous organic polymers Reactive intermediate species HOMO-LUMO Photocatalysis environmental remediation Nath, Ipsita verfasserin aut Song, Shaoxian verfasserin aut Mohamed, Sharmarke verfasserin aut Khan, Anish verfasserin aut Heynderickx, Philippe M. verfasserin aut Verpoort, Francis verfasserin aut Enthalten in Journal of photochemistry and photobiology / C Amsterdam [u.a.] : Elsevier Science, 2000 41 Online-Ressource (DE-627)325049882 (DE-600)2034027-8 (DE-576)259485624 1389-5567 nnns volume:41 GBV_USEFLAG_U SYSFLAG_U GBV_ELV FID-BIODIV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.16 Photochemie AR 41
language	English
source	Enthalten in Journal of photochemistry and photobiology / C 41 volume:41
sourceStr	Enthalten in Journal of photochemistry and photobiology / C 41 volume:41
format_phy_str_mv	Article
bklname	Photochemie
institution	findex.gbv.de
topic_facet	Porous organic polymers Reactive intermediate species HOMO-LUMO Photocatalysis environmental remediation
dewey-raw	570
isfreeaccess_bool	false
container_title	Journal of photochemistry and photobiology / C
authorswithroles_txt_mv	Chakraborty, Jeet @@aut@@ Nath, Ipsita @@aut@@ Song, Shaoxian @@aut@@ Mohamed, Sharmarke @@aut@@ Khan, Anish @@aut@@ Heynderickx, Philippe M. @@aut@@ Verpoort, Francis @@aut@@
publishDateDaySort_date	2019-01-01T00:00:00Z
hierarchy_top_id	325049882
dewey-sort	3570
id	ELV003196313
language_de	englisch
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author	Chakraborty, Jeet
spellingShingle	Chakraborty, Jeet ddc 570 fid BIODIV bkl 35.16 misc Porous organic polymers misc Reactive intermediate species misc HOMO-LUMO misc Photocatalysis environmental remediation Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation
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topic_title	570 540 DE-600 BIODIV DE-30 fid 35.16 bkl Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation Porous organic polymers Reactive intermediate species HOMO-LUMO Photocatalysis environmental remediation
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title	Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation
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title_full	Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation
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title_sort	porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation
title_auth	Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation
abstract	The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field.
abstractGer	The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field.
abstract_unstemmed	The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field.
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title_short	Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation
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author2	Nath, Ipsita Song, Shaoxian Mohamed, Sharmarke Khan, Anish Heynderickx, Philippe M. Verpoort, Francis
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up_date	2024-07-06T18:48:59.501Z
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Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation

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