Electrical and mechanical properties of water-stable NASICON-type Li

Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASI...
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Autor*in:	Bai, Fan [verfasserIn] Mori, Daisuke [verfasserIn] Taminato, Sou [verfasserIn] Takeda, Yasuo [verfasserIn] Yamamoto, Osamu [verfasserIn] Nemori, Hiroyoshi [verfasserIn] Nomura, Masaya [verfasserIn] Imanishi, Nobuyuki [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Solid electrolyte Lithium ion conductor NASICON-type

Übergeordnetes Werk:	Enthalten in: Solid state ionics - Amsterdam [u.a.] : Elsevier Science, 1980, 345
Übergeordnetes Werk:	volume:345

DOI / URN:	10.1016/j.ssi.2019.115151

Katalog-ID:	ELV003531597

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520			\|a Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3 (LAGTP; x = 0.25–0.55) sintered at 900–1000 °C. The highest lithium-ion conductivity of 1.58 × 10− 3 S cm− 1 at 25 °C was observed for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C, the conductivity of which is the highest in the NASICON-type lithium-ion conductivity solid electrolytes reported previously. The high conductivity could be explained by the high grain boundary conductivity of 6.58 × 10− 3 S cm− 1 at 25 °C. The conductivity showed no effect of aging after more than one month immersed in saturated LiCl aqueous solution. A 3-point bending strength of 110 N mm− 2 was also recorded for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C.
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700	1		\|a Nomura, Masaya \|e verfasserin \|4 aut
700	1		\|a Imanishi, Nobuyuki \|e verfasserin \|4 aut
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912			\|a GBV_ILN_2048
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912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
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912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 33.61 \|j Festkörperphysik
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Indexfelder

author_variant	f b fb d m dm s t st y t yt o y oy h n hn m n mn n i ni
matchkey_str	article:01672738:2019----::lcrclnmcaiapoeteowtrt
hierarchy_sort_str	2019
bklnumber	33.61
publishDate	2019
allfields	10.1016/j.ssi.2019.115151 doi (DE-627)ELV003531597 (ELSEVIER)S0167-2738(19)30765-9 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut Electrical and mechanical properties of water-stable NASICON-type Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3 (LAGTP; x = 0.25–0.55) sintered at 900–1000 °C. The highest lithium-ion conductivity of 1.58 × 10− 3 S cm− 1 at 25 °C was observed for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C, the conductivity of which is the highest in the NASICON-type lithium-ion conductivity solid electrolytes reported previously. The high conductivity could be explained by the high grain boundary conductivity of 6.58 × 10− 3 S cm− 1 at 25 °C. The conductivity showed no effect of aging after more than one month immersed in saturated LiCl aqueous solution. A 3-point bending strength of 110 N mm− 2 was also recorded for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C. Solid electrolyte Lithium ion conductor NASICON-type Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 345 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:345 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 345
spelling	10.1016/j.ssi.2019.115151 doi (DE-627)ELV003531597 (ELSEVIER)S0167-2738(19)30765-9 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut Electrical and mechanical properties of water-stable NASICON-type Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3 (LAGTP; x = 0.25–0.55) sintered at 900–1000 °C. The highest lithium-ion conductivity of 1.58 × 10− 3 S cm− 1 at 25 °C was observed for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C, the conductivity of which is the highest in the NASICON-type lithium-ion conductivity solid electrolytes reported previously. The high conductivity could be explained by the high grain boundary conductivity of 6.58 × 10− 3 S cm− 1 at 25 °C. The conductivity showed no effect of aging after more than one month immersed in saturated LiCl aqueous solution. A 3-point bending strength of 110 N mm− 2 was also recorded for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C. Solid electrolyte Lithium ion conductor NASICON-type Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 345 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:345 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 345
allfields_unstemmed	10.1016/j.ssi.2019.115151 doi (DE-627)ELV003531597 (ELSEVIER)S0167-2738(19)30765-9 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut Electrical and mechanical properties of water-stable NASICON-type Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3 (LAGTP; x = 0.25–0.55) sintered at 900–1000 °C. The highest lithium-ion conductivity of 1.58 × 10− 3 S cm− 1 at 25 °C was observed for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C, the conductivity of which is the highest in the NASICON-type lithium-ion conductivity solid electrolytes reported previously. The high conductivity could be explained by the high grain boundary conductivity of 6.58 × 10− 3 S cm− 1 at 25 °C. The conductivity showed no effect of aging after more than one month immersed in saturated LiCl aqueous solution. A 3-point bending strength of 110 N mm− 2 was also recorded for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C. Solid electrolyte Lithium ion conductor NASICON-type Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 345 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:345 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 345
allfieldsGer	10.1016/j.ssi.2019.115151 doi (DE-627)ELV003531597 (ELSEVIER)S0167-2738(19)30765-9 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut Electrical and mechanical properties of water-stable NASICON-type Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3 (LAGTP; x = 0.25–0.55) sintered at 900–1000 °C. The highest lithium-ion conductivity of 1.58 × 10− 3 S cm− 1 at 25 °C was observed for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C, the conductivity of which is the highest in the NASICON-type lithium-ion conductivity solid electrolytes reported previously. The high conductivity could be explained by the high grain boundary conductivity of 6.58 × 10− 3 S cm− 1 at 25 °C. The conductivity showed no effect of aging after more than one month immersed in saturated LiCl aqueous solution. A 3-point bending strength of 110 N mm− 2 was also recorded for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C. Solid electrolyte Lithium ion conductor NASICON-type Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 345 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:345 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 345
allfieldsSound	10.1016/j.ssi.2019.115151 doi (DE-627)ELV003531597 (ELSEVIER)S0167-2738(19)30765-9 DE-627 ger DE-627 rda eng 530 DE-600 33.61 bkl Bai, Fan verfasserin aut Electrical and mechanical properties of water-stable NASICON-type Li 2019 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3 (LAGTP; x = 0.25–0.55) sintered at 900–1000 °C. The highest lithium-ion conductivity of 1.58 × 10− 3 S cm− 1 at 25 °C was observed for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C, the conductivity of which is the highest in the NASICON-type lithium-ion conductivity solid electrolytes reported previously. The high conductivity could be explained by the high grain boundary conductivity of 6.58 × 10− 3 S cm− 1 at 25 °C. The conductivity showed no effect of aging after more than one month immersed in saturated LiCl aqueous solution. A 3-point bending strength of 110 N mm− 2 was also recorded for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C. Solid electrolyte Lithium ion conductor NASICON-type Mori, Daisuke verfasserin aut Taminato, Sou verfasserin aut Takeda, Yasuo verfasserin aut Yamamoto, Osamu verfasserin aut Nemori, Hiroyoshi verfasserin aut Nomura, Masaya verfasserin aut Imanishi, Nobuyuki verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 345 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:345 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 33.61 Festkörperphysik AR 345
language	English
source	Enthalten in Solid state ionics 345 volume:345
sourceStr	Enthalten in Solid state ionics 345 volume:345
format_phy_str_mv	Article
bklname	Festkörperphysik
institution	findex.gbv.de
topic_facet	Solid electrolyte Lithium ion conductor NASICON-type
dewey-raw	530
isfreeaccess_bool	false
container_title	Solid state ionics
authorswithroles_txt_mv	Bai, Fan @@aut@@ Mori, Daisuke @@aut@@ Taminato, Sou @@aut@@ Takeda, Yasuo @@aut@@ Yamamoto, Osamu @@aut@@ Nemori, Hiroyoshi @@aut@@ Nomura, Masaya @@aut@@ Imanishi, Nobuyuki @@aut@@
publishDateDaySort_date	2019-01-01T00:00:00Z
hierarchy_top_id	306710544
dewey-sort	3530
id	ELV003531597
language_de	englisch
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author	Bai, Fan
spellingShingle	Bai, Fan ddc 530 bkl 33.61 misc Solid electrolyte misc Lithium ion conductor misc NASICON-type Electrical and mechanical properties of water-stable NASICON-type Li
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topic_title	530 DE-600 33.61 bkl Electrical and mechanical properties of water-stable NASICON-type Li Solid electrolyte Lithium ion conductor NASICON-type
topic	ddc 530 bkl 33.61 misc Solid electrolyte misc Lithium ion conductor misc NASICON-type
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title	Electrical and mechanical properties of water-stable NASICON-type Li
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title_full	Electrical and mechanical properties of water-stable NASICON-type Li
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author_browse	Bai, Fan Mori, Daisuke Taminato, Sou Takeda, Yasuo Yamamoto, Osamu Nemori, Hiroyoshi Nomura, Masaya Imanishi, Nobuyuki
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title_sort	electrical and mechanical properties of water-stable nasicon-type li
title_auth	Electrical and mechanical properties of water-stable NASICON-type Li
abstract	Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3 (LAGTP; x = 0.25–0.55) sintered at 900–1000 °C. The highest lithium-ion conductivity of 1.58 × 10− 3 S cm− 1 at 25 °C was observed for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C, the conductivity of which is the highest in the NASICON-type lithium-ion conductivity solid electrolytes reported previously. The high conductivity could be explained by the high grain boundary conductivity of 6.58 × 10− 3 S cm− 1 at 25 °C. The conductivity showed no effect of aging after more than one month immersed in saturated LiCl aqueous solution. A 3-point bending strength of 110 N mm− 2 was also recorded for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C.
abstractGer	Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3 (LAGTP; x = 0.25–0.55) sintered at 900–1000 °C. The highest lithium-ion conductivity of 1.58 × 10− 3 S cm− 1 at 25 °C was observed for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C, the conductivity of which is the highest in the NASICON-type lithium-ion conductivity solid electrolytes reported previously. The high conductivity could be explained by the high grain boundary conductivity of 6.58 × 10− 3 S cm− 1 at 25 °C. The conductivity showed no effect of aging after more than one month immersed in saturated LiCl aqueous solution. A 3-point bending strength of 110 N mm− 2 was also recorded for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C.
abstract_unstemmed	Water-stable and high lithium-ion conductivity solid electrolytes have potential for application as the separator in aqueous lithium-air batteries and as the electrolyte in all-solid-state batteries. Herein we have systematically examined the electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3 (LAGTP; x = 0.25–0.55) sintered at 900–1000 °C. The highest lithium-ion conductivity of 1.58 × 10− 3 S cm− 1 at 25 °C was observed for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C, the conductivity of which is the highest in the NASICON-type lithium-ion conductivity solid electrolytes reported previously. The high conductivity could be explained by the high grain boundary conductivity of 6.58 × 10− 3 S cm− 1 at 25 °C. The conductivity showed no effect of aging after more than one month immersed in saturated LiCl aqueous solution. A 3-point bending strength of 110 N mm− 2 was also recorded for Li1.35Al0.35Ge0.2Ti1.45(PO4)3 sintered at 950 °C.
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title_short	Electrical and mechanical properties of water-stable NASICON-type Li
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author2	Mori, Daisuke Taminato, Sou Takeda, Yasuo Yamamoto, Osamu Nemori, Hiroyoshi Nomura, Masaya Imanishi, Nobuyuki
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up_date	2024-07-06T19:56:20.101Z
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Electrical and mechanical properties of water-stable NASICON-type Li

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