Reactions of [Pt

The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and...
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Gespeichert in:

Autor*in:	Berti, Beatrice [verfasserIn] Bortoluzzi, Marco [verfasserIn] Cesari, Cristiana [verfasserIn] Femoni, Cristina [verfasserIn] Iapalucci, Maria Carmela [verfasserIn] Zacchini, Stefano [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	Cluster compounds Carbonyl ligands Platinum Tin Structure elucidation

Übergeordnetes Werk:	Enthalten in: Inorganica chimica acta - New York, NY [u.a.] : Elsevier, 1967, 503
Übergeordnetes Werk:	volume:503

DOI / URN:	10.1016/j.ica.2020.119432

Katalog-ID:	ELV003585093

Internformat


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245	1	0	\|a Reactions of [Pt
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520			\|a The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means of single crystal X-ray diffraction. The bonding within these bimetallic Pt–Sn clusters were investigated computationally by means of DFT methods and Atoms-In-Molecules analyses. 3 and 4 displayed a low valent Pt core stabilised by the interaction with CO and Sn(II) based ligands. The solid state structures of these clusters revealed the presence on H-bonds involving the OH-groups of the {X2Sn(μ-OH)SnX2}– ligands.
650		4	\|a Cluster compounds
650		4	\|a Carbonyl ligands
650		4	\|a Platinum
650		4	\|a Tin
650		4	\|a Structure elucidation
700	1		\|a Bortoluzzi, Marco \|e verfasserin \|4 aut
700	1		\|a Cesari, Cristiana \|e verfasserin \|4 aut
700	1		\|a Femoni, Cristina \|e verfasserin \|4 aut
700	1		\|a Iapalucci, Maria Carmela \|e verfasserin \|4 aut
700	1		\|a Zacchini, Stefano \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Inorganica chimica acta \|d New York, NY [u.a.] : Elsevier, 1967 \|g 503 \|h Online-Ressource \|w (DE-627)301510946 \|w (DE-600)1484441-2 \|w (DE-576)081952694 \|x 0020-1693 \|7 nnns
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912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_101
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 35.00 \|j Chemie: Allgemeines
951			\|a AR
952			\|d 503

Indexfelder

author_variant	b b bb m b mb c c cc c f cf m c i mc mci s z sz
matchkey_str	article:00201693:2020----::ecin
hierarchy_sort_str	2020
bklnumber	35.00
publishDate	2020
allfields	10.1016/j.ica.2020.119432 doi (DE-627)ELV003585093 (ELSEVIER)S0020-1693(19)31767-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Reactions of [Pt 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means of single crystal X-ray diffraction. The bonding within these bimetallic Pt–Sn clusters were investigated computationally by means of DFT methods and Atoms-In-Molecules analyses. 3 and 4 displayed a low valent Pt core stabilised by the interaction with CO and Sn(II) based ligands. The solid state structures of these clusters revealed the presence on H-bonds involving the OH-groups of the {X2Sn(μ-OH)SnX2}– ligands. Cluster compounds Carbonyl ligands Platinum Tin Structure elucidation Bortoluzzi, Marco verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Iapalucci, Maria Carmela verfasserin aut Zacchini, Stefano verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 503 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:503 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 503
spelling	10.1016/j.ica.2020.119432 doi (DE-627)ELV003585093 (ELSEVIER)S0020-1693(19)31767-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Reactions of [Pt 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means of single crystal X-ray diffraction. The bonding within these bimetallic Pt–Sn clusters were investigated computationally by means of DFT methods and Atoms-In-Molecules analyses. 3 and 4 displayed a low valent Pt core stabilised by the interaction with CO and Sn(II) based ligands. The solid state structures of these clusters revealed the presence on H-bonds involving the OH-groups of the {X2Sn(μ-OH)SnX2}– ligands. Cluster compounds Carbonyl ligands Platinum Tin Structure elucidation Bortoluzzi, Marco verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Iapalucci, Maria Carmela verfasserin aut Zacchini, Stefano verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 503 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:503 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 503
allfields_unstemmed	10.1016/j.ica.2020.119432 doi (DE-627)ELV003585093 (ELSEVIER)S0020-1693(19)31767-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Reactions of [Pt 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means of single crystal X-ray diffraction. The bonding within these bimetallic Pt–Sn clusters were investigated computationally by means of DFT methods and Atoms-In-Molecules analyses. 3 and 4 displayed a low valent Pt core stabilised by the interaction with CO and Sn(II) based ligands. The solid state structures of these clusters revealed the presence on H-bonds involving the OH-groups of the {X2Sn(μ-OH)SnX2}– ligands. Cluster compounds Carbonyl ligands Platinum Tin Structure elucidation Bortoluzzi, Marco verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Iapalucci, Maria Carmela verfasserin aut Zacchini, Stefano verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 503 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:503 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 503
allfieldsGer	10.1016/j.ica.2020.119432 doi (DE-627)ELV003585093 (ELSEVIER)S0020-1693(19)31767-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Reactions of [Pt 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means of single crystal X-ray diffraction. The bonding within these bimetallic Pt–Sn clusters were investigated computationally by means of DFT methods and Atoms-In-Molecules analyses. 3 and 4 displayed a low valent Pt core stabilised by the interaction with CO and Sn(II) based ligands. The solid state structures of these clusters revealed the presence on H-bonds involving the OH-groups of the {X2Sn(μ-OH)SnX2}– ligands. Cluster compounds Carbonyl ligands Platinum Tin Structure elucidation Bortoluzzi, Marco verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Iapalucci, Maria Carmela verfasserin aut Zacchini, Stefano verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 503 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:503 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 503
allfieldsSound	10.1016/j.ica.2020.119432 doi (DE-627)ELV003585093 (ELSEVIER)S0020-1693(19)31767-0 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Reactions of [Pt 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means of single crystal X-ray diffraction. The bonding within these bimetallic Pt–Sn clusters were investigated computationally by means of DFT methods and Atoms-In-Molecules analyses. 3 and 4 displayed a low valent Pt core stabilised by the interaction with CO and Sn(II) based ligands. The solid state structures of these clusters revealed the presence on H-bonds involving the OH-groups of the {X2Sn(μ-OH)SnX2}– ligands. Cluster compounds Carbonyl ligands Platinum Tin Structure elucidation Bortoluzzi, Marco verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Iapalucci, Maria Carmela verfasserin aut Zacchini, Stefano verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 503 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:503 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 503
language	English
source	Enthalten in Inorganica chimica acta 503 volume:503
sourceStr	Enthalten in Inorganica chimica acta 503 volume:503
format_phy_str_mv	Article
bklname	Chemie: Allgemeines
institution	findex.gbv.de
topic_facet	Cluster compounds Carbonyl ligands Platinum Tin Structure elucidation
dewey-raw	540
isfreeaccess_bool	false
container_title	Inorganica chimica acta
authorswithroles_txt_mv	Berti, Beatrice @@aut@@ Bortoluzzi, Marco @@aut@@ Cesari, Cristiana @@aut@@ Femoni, Cristina @@aut@@ Iapalucci, Maria Carmela @@aut@@ Zacchini, Stefano @@aut@@
publishDateDaySort_date	2020-01-01T00:00:00Z
hierarchy_top_id	301510946
dewey-sort	3540
id	ELV003585093
language_de	englisch
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author	Berti, Beatrice
spellingShingle	Berti, Beatrice ddc 540 bkl 35.00 misc Cluster compounds misc Carbonyl ligands misc Platinum misc Tin misc Structure elucidation Reactions of [Pt
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topic_title	540 DE-600 35.00 bkl Reactions of [Pt Cluster compounds Carbonyl ligands Platinum Tin Structure elucidation
topic	ddc 540 bkl 35.00 misc Cluster compounds misc Carbonyl ligands misc Platinum misc Tin misc Structure elucidation
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title	Reactions of [Pt
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title_full	Reactions of [Pt
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author_browse	Berti, Beatrice Bortoluzzi, Marco Cesari, Cristiana Femoni, Cristina Iapalucci, Maria Carmela Zacchini, Stefano
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author-letter	Berti, Beatrice
doi_str_mv	10.1016/j.ica.2020.119432
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title_sort	reactions of [pt
title_auth	Reactions of [Pt
abstract	The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means of single crystal X-ray diffraction. The bonding within these bimetallic Pt–Sn clusters were investigated computationally by means of DFT methods and Atoms-In-Molecules analyses. 3 and 4 displayed a low valent Pt core stabilised by the interaction with CO and Sn(II) based ligands. The solid state structures of these clusters revealed the presence on H-bonds involving the OH-groups of the {X2Sn(μ-OH)SnX2}– ligands.
abstractGer	The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means of single crystal X-ray diffraction. The bonding within these bimetallic Pt–Sn clusters were investigated computationally by means of DFT methods and Atoms-In-Molecules analyses. 3 and 4 displayed a low valent Pt core stabilised by the interaction with CO and Sn(II) based ligands. The solid state structures of these clusters revealed the presence on H-bonds involving the OH-groups of the {X2Sn(μ-OH)SnX2}– ligands.
abstract_unstemmed	The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4 ·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means of single crystal X-ray diffraction. The bonding within these bimetallic Pt–Sn clusters were investigated computationally by means of DFT methods and Atoms-In-Molecules analyses. 3 and 4 displayed a low valent Pt core stabilised by the interaction with CO and Sn(II) based ligands. The solid state structures of these clusters revealed the presence on H-bonds involving the OH-groups of the {X2Sn(μ-OH)SnX2}– ligands.
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title_short	Reactions of [Pt
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author2	Bortoluzzi, Marco Cesari, Cristiana Femoni, Cristina Iapalucci, Maria Carmela Zacchini, Stefano
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doi_str	10.1016/j.ica.2020.119432
up_date	2024-07-06T20:06:58.139Z
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score	7.3995247

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