Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data

High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4,...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Martucci, Annalisa [verfasserIn] Gigli, Lara [verfasserIn] Plaisier, Jasper Rikkert [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	6-Azonia-spiro-[5,5]-undecane ZSM-12 X-ray synchrotron powder diffraction data SDA conformation Rietveld refinement

Übergeordnetes Werk:	Enthalten in: Microporous and mesoporous materials - Amsterdam [u.a.] : Elsevier, 1998, 307
Übergeordnetes Werk:	volume:307

DOI / URN:	10.1016/j.micromeso.2020.110505

Katalog-ID:	ELV004634969

Internformat


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100	1		\|a Martucci, Annalisa \|e verfasserin \|0 (orcid)0000-0002-6467-881X \|4 aut
245	1	0	\|a Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data
264		1	\|c 2020
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520			\|a High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. AZO-1 and AZO-2 molecules are H-bonded between them thus forming clusters aligned along the b axis. This information is crucial to tailor the physicochemical properties of zeolites as well as to address their hydrophobicity, pore dimensions and cavities thus optimizing the selectivity of zeolite catalysts.
650		4	\|a 6-Azonia-spiro-[5,5]-undecane
650		4	\|a ZSM-12
650		4	\|a X-ray synchrotron powder diffraction data
650		4	\|a SDA conformation
650		4	\|a Rietveld refinement
700	1		\|a Gigli, Lara \|e verfasserin \|4 aut
700	1		\|a Plaisier, Jasper Rikkert \|e verfasserin \|0 (orcid)0000-0003-1981-1498 \|4 aut
773	0	8	\|i Enthalten in \|t Microporous and mesoporous materials \|d Amsterdam [u.a.] : Elsevier, 1998 \|g 307 \|h Online-Ressource \|w (DE-627)318368277 \|w (DE-600)2012505-7 \|w (DE-576)09529998X \|x 1387-1811 \|7 nnns
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912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_101
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 38.30 \|j Mineralogie
936	b	k	\|a 35.68 \|j Organische Verbindungen: Sonstiges
936	b	k	\|a 33.61 \|j Festkörperphysik
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951			\|a AR
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Indexfelder

author_variant	a m am l g lg j r p jr jrp
matchkey_str	article:13871811:2020----::oainfaoisio5neaeoeueizm2snxasnhor
hierarchy_sort_str	2020
bklnumber	38.30 35.68 33.61 35.90 51.45
publishDate	2020
allfields	10.1016/j.micromeso.2020.110505 doi (DE-627)ELV004634969 (ELSEVIER)S1387-1811(20)30507-2 DE-627 ger DE-627 rda eng 530 DE-600 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 bkl Martucci, Annalisa verfasserin (orcid)0000-0002-6467-881X aut Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. AZO-1 and AZO-2 molecules are H-bonded between them thus forming clusters aligned along the b axis. This information is crucial to tailor the physicochemical properties of zeolites as well as to address their hydrophobicity, pore dimensions and cavities thus optimizing the selectivity of zeolite catalysts. 6-Azonia-spiro-[5,5]-undecane ZSM-12 X-ray synchrotron powder diffraction data SDA conformation Rietveld refinement Gigli, Lara verfasserin aut Plaisier, Jasper Rikkert verfasserin (orcid)0000-0003-1981-1498 aut Enthalten in Microporous and mesoporous materials Amsterdam [u.a.] : Elsevier, 1998 307 Online-Ressource (DE-627)318368277 (DE-600)2012505-7 (DE-576)09529998X 1387-1811 nnns volume:307 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.30 Mineralogie 35.68 Organische Verbindungen: Sonstiges 33.61 Festkörperphysik 35.90 Festkörperchemie 51.45 Werkstoffe mit besonderen Eigenschaften AR 307
spelling	10.1016/j.micromeso.2020.110505 doi (DE-627)ELV004634969 (ELSEVIER)S1387-1811(20)30507-2 DE-627 ger DE-627 rda eng 530 DE-600 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 bkl Martucci, Annalisa verfasserin (orcid)0000-0002-6467-881X aut Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. AZO-1 and AZO-2 molecules are H-bonded between them thus forming clusters aligned along the b axis. This information is crucial to tailor the physicochemical properties of zeolites as well as to address their hydrophobicity, pore dimensions and cavities thus optimizing the selectivity of zeolite catalysts. 6-Azonia-spiro-[5,5]-undecane ZSM-12 X-ray synchrotron powder diffraction data SDA conformation Rietveld refinement Gigli, Lara verfasserin aut Plaisier, Jasper Rikkert verfasserin (orcid)0000-0003-1981-1498 aut Enthalten in Microporous and mesoporous materials Amsterdam [u.a.] : Elsevier, 1998 307 Online-Ressource (DE-627)318368277 (DE-600)2012505-7 (DE-576)09529998X 1387-1811 nnns volume:307 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.30 Mineralogie 35.68 Organische Verbindungen: Sonstiges 33.61 Festkörperphysik 35.90 Festkörperchemie 51.45 Werkstoffe mit besonderen Eigenschaften AR 307
allfields_unstemmed	10.1016/j.micromeso.2020.110505 doi (DE-627)ELV004634969 (ELSEVIER)S1387-1811(20)30507-2 DE-627 ger DE-627 rda eng 530 DE-600 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 bkl Martucci, Annalisa verfasserin (orcid)0000-0002-6467-881X aut Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. AZO-1 and AZO-2 molecules are H-bonded between them thus forming clusters aligned along the b axis. This information is crucial to tailor the physicochemical properties of zeolites as well as to address their hydrophobicity, pore dimensions and cavities thus optimizing the selectivity of zeolite catalysts. 6-Azonia-spiro-[5,5]-undecane ZSM-12 X-ray synchrotron powder diffraction data SDA conformation Rietveld refinement Gigli, Lara verfasserin aut Plaisier, Jasper Rikkert verfasserin (orcid)0000-0003-1981-1498 aut Enthalten in Microporous and mesoporous materials Amsterdam [u.a.] : Elsevier, 1998 307 Online-Ressource (DE-627)318368277 (DE-600)2012505-7 (DE-576)09529998X 1387-1811 nnns volume:307 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.30 Mineralogie 35.68 Organische Verbindungen: Sonstiges 33.61 Festkörperphysik 35.90 Festkörperchemie 51.45 Werkstoffe mit besonderen Eigenschaften AR 307
allfieldsGer	10.1016/j.micromeso.2020.110505 doi (DE-627)ELV004634969 (ELSEVIER)S1387-1811(20)30507-2 DE-627 ger DE-627 rda eng 530 DE-600 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 bkl Martucci, Annalisa verfasserin (orcid)0000-0002-6467-881X aut Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. AZO-1 and AZO-2 molecules are H-bonded between them thus forming clusters aligned along the b axis. This information is crucial to tailor the physicochemical properties of zeolites as well as to address their hydrophobicity, pore dimensions and cavities thus optimizing the selectivity of zeolite catalysts. 6-Azonia-spiro-[5,5]-undecane ZSM-12 X-ray synchrotron powder diffraction data SDA conformation Rietveld refinement Gigli, Lara verfasserin aut Plaisier, Jasper Rikkert verfasserin (orcid)0000-0003-1981-1498 aut Enthalten in Microporous and mesoporous materials Amsterdam [u.a.] : Elsevier, 1998 307 Online-Ressource (DE-627)318368277 (DE-600)2012505-7 (DE-576)09529998X 1387-1811 nnns volume:307 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.30 Mineralogie 35.68 Organische Verbindungen: Sonstiges 33.61 Festkörperphysik 35.90 Festkörperchemie 51.45 Werkstoffe mit besonderen Eigenschaften AR 307
allfieldsSound	10.1016/j.micromeso.2020.110505 doi (DE-627)ELV004634969 (ELSEVIER)S1387-1811(20)30507-2 DE-627 ger DE-627 rda eng 530 DE-600 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 bkl Martucci, Annalisa verfasserin (orcid)0000-0002-6467-881X aut Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. AZO-1 and AZO-2 molecules are H-bonded between them thus forming clusters aligned along the b axis. This information is crucial to tailor the physicochemical properties of zeolites as well as to address their hydrophobicity, pore dimensions and cavities thus optimizing the selectivity of zeolite catalysts. 6-Azonia-spiro-[5,5]-undecane ZSM-12 X-ray synchrotron powder diffraction data SDA conformation Rietveld refinement Gigli, Lara verfasserin aut Plaisier, Jasper Rikkert verfasserin (orcid)0000-0003-1981-1498 aut Enthalten in Microporous and mesoporous materials Amsterdam [u.a.] : Elsevier, 1998 307 Online-Ressource (DE-627)318368277 (DE-600)2012505-7 (DE-576)09529998X 1387-1811 nnns volume:307 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.30 Mineralogie 35.68 Organische Verbindungen: Sonstiges 33.61 Festkörperphysik 35.90 Festkörperchemie 51.45 Werkstoffe mit besonderen Eigenschaften AR 307
language	English
source	Enthalten in Microporous and mesoporous materials 307 volume:307
sourceStr	Enthalten in Microporous and mesoporous materials 307 volume:307
format_phy_str_mv	Article
bklname	Mineralogie Organische Verbindungen: Sonstiges Festkörperphysik Festkörperchemie Werkstoffe mit besonderen Eigenschaften
institution	findex.gbv.de
topic_facet	6-Azonia-spiro-[5,5]-undecane ZSM-12 X-ray synchrotron powder diffraction data SDA conformation Rietveld refinement
dewey-raw	530
isfreeaccess_bool	false
container_title	Microporous and mesoporous materials
authorswithroles_txt_mv	Martucci, Annalisa @@aut@@ Gigli, Lara @@aut@@ Plaisier, Jasper Rikkert @@aut@@
publishDateDaySort_date	2020-01-01T00:00:00Z
hierarchy_top_id	318368277
dewey-sort	3530
id	ELV004634969
language_de	englisch
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author	Martucci, Annalisa
spellingShingle	Martucci, Annalisa ddc 530 bkl 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 misc 6-Azonia-spiro-[5,5]-undecane misc ZSM-12 misc X-ray synchrotron powder diffraction data misc SDA conformation misc Rietveld refinement Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data
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topic_title	530 DE-600 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 bkl Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data 6-Azonia-spiro-[5,5]-undecane ZSM-12 X-ray synchrotron powder diffraction data SDA conformation Rietveld refinement
topic	ddc 530 bkl 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 misc 6-Azonia-spiro-[5,5]-undecane misc ZSM-12 misc X-ray synchrotron powder diffraction data misc SDA conformation misc Rietveld refinement
topic_unstemmed	ddc 530 bkl 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 misc 6-Azonia-spiro-[5,5]-undecane misc ZSM-12 misc X-ray synchrotron powder diffraction data misc SDA conformation misc Rietveld refinement
topic_browse	ddc 530 bkl 38.30 bkl 35.68 bkl 33.61 bkl 35.90 bkl 51.45 misc 6-Azonia-spiro-[5,5]-undecane misc ZSM-12 misc X-ray synchrotron powder diffraction data misc SDA conformation misc Rietveld refinement
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title	Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data
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title_full	Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data
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author_browse	Martucci, Annalisa Gigli, Lara Plaisier, Jasper Rikkert
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title_sort	location of 6-azonia-spiro- [5,5]-undecane molecules in zsm-12 using x-ray synchrotron powder diffraction data
title_auth	Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data
abstract	High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. AZO-1 and AZO-2 molecules are H-bonded between them thus forming clusters aligned along the b axis. This information is crucial to tailor the physicochemical properties of zeolites as well as to address their hydrophobicity, pore dimensions and cavities thus optimizing the selectivity of zeolite catalysts.
abstractGer	High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. AZO-1 and AZO-2 molecules are H-bonded between them thus forming clusters aligned along the b axis. This information is crucial to tailor the physicochemical properties of zeolites as well as to address their hydrophobicity, pore dimensions and cavities thus optimizing the selectivity of zeolite catalysts.
abstract_unstemmed	High-silica ZSM-12 (MTW topology), synthesized with 6-azonia-spiro- (Rimer, 2018; Rimer, 2018) [5,5]-undecane as structure directing agent (SDA), was carefully characterized by using X-ray synchrotron powder diffraction. The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. AZO-1 and AZO-2 molecules are H-bonded between them thus forming clusters aligned along the b axis. This information is crucial to tailor the physicochemical properties of zeolites as well as to address their hydrophobicity, pore dimensions and cavities thus optimizing the selectivity of zeolite catalysts.
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title_short	Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data
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author2	Gigli, Lara Plaisier, Jasper Rikkert
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doi_str	10.1016/j.micromeso.2020.110505
up_date	2024-07-06T23:39:17.795Z
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The structure refinement led to a monoclinic unit cell (space group Cc, Z = 4, a = 25.0814(13) Å, b = 15.0987(8) Å, c = 24.4419(17) Å, β = 107.844(6), V = 8810.8(8) Å3) with a three times enlargement of the unit cell along the b axis with respect to the calcined starting ZSM-12 (space group C2/c, Z = 1, a = 24.8633(3) Å, b = 5.01238(7) Å, c = 24.3275(7) Å, β = 107.7215(6)°). The SDAs conformation and position in the framework structure did not maintain the twofold axes coinciding with the crystallographic twofold axis thus changing the space group symmetry from C2/c to Cc. The structure refinement gave an extraframework content 6.13 SDA molecules per unit cell (corresponding to ~9.0 wt%) in good agreement with the weight loss given by the thermogravimetric analysis. The refined bond distances revealed the occurrence of non-bonding interactions of both azonia molecules with the MTW pore wall. 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Location of 6-azonia-spiro- [5,5]-undecane molecules in ZSM-12 using X-ray synchrotron powder diffraction data

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