Further insights into platinum carbonyl Chini clusters
The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]...
Ausführliche Beschreibung
Autor*in: |
Berti, Beatrice [verfasserIn] Bortoluzzi, Marco [verfasserIn] Ceriotti, Alessandro [verfasserIn] Cesari, Cristiana [verfasserIn] Femoni, Cristina [verfasserIn] Carmela Iapalucci, Maria [verfasserIn] Zacchini, Stefano [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2020 |
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Übergeordnetes Werk: |
Enthalten in: Inorganica chimica acta - New York, NY [u.a.] : Elsevier, 1967, 512 |
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Übergeordnetes Werk: |
volume:512 |
DOI / URN: |
10.1016/j.ica.2020.119904 |
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ELV004643968 |
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245 | 1 | 0 | |a Further insights into platinum carbonyl Chini clusters |
264 | 1 | |c 2020 | |
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520 | |a The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]− units. The solid state structure of [Ph3P(CH2)12PPh3][Pt18(CO)36] may be viewed as a snapshot in which [Pt9(CO)18]− units are approaching and ready to exchange outer Pt3(CO)6 fragments. The reactions of Chini clusters with isonitriles proceed via redox-fragmentation, at difference with those involving phosphines that may occur both via non-redox substitution and redox fragmentation, depending on the experimental conditions. Thus, the reaction of [Pt6(CO)12]2− with CNXyl afforded Pt5(CNXyl)10, whereas Pt9(CNXyl)13(CO) was obtained from the reaction of [Pt15(CO)30]2− with CNXyl. These two new neutral clusters have been structurally characterized as their Pt5(CNXyl)10 ·2toluene and Pt9(CNXyl)13(CO)·solv solvates. DFT studies on the CO exchange of [Pt6(CO)12]2− suggest an associative interchange mechanism, which may be extended also to larger Chini clusters and the initial steps of their reactions with other soft nucleophiles. | ||
650 | 4 | |a Cluster compounds | |
650 | 4 | |a Carbonyl ligands | |
650 | 4 | |a Platinum | |
650 | 4 | |a Self-assembly | |
650 | 4 | |a Nanoscience | |
700 | 1 | |a Bortoluzzi, Marco |e verfasserin |4 aut | |
700 | 1 | |a Ceriotti, Alessandro |e verfasserin |4 aut | |
700 | 1 | |a Cesari, Cristiana |e verfasserin |4 aut | |
700 | 1 | |a Femoni, Cristina |e verfasserin |4 aut | |
700 | 1 | |a Carmela Iapalucci, Maria |e verfasserin |4 aut | |
700 | 1 | |a Zacchini, Stefano |e verfasserin |0 (orcid)0000-0003-0739-0518 |4 aut | |
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10.1016/j.ica.2020.119904 doi (DE-627)ELV004643968 (ELSEVIER)S0020-1693(20)31103-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Further insights into platinum carbonyl Chini clusters 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]− units. The solid state structure of [Ph3P(CH2)12PPh3][Pt18(CO)36] may be viewed as a snapshot in which [Pt9(CO)18]− units are approaching and ready to exchange outer Pt3(CO)6 fragments. The reactions of Chini clusters with isonitriles proceed via redox-fragmentation, at difference with those involving phosphines that may occur both via non-redox substitution and redox fragmentation, depending on the experimental conditions. Thus, the reaction of [Pt6(CO)12]2− with CNXyl afforded Pt5(CNXyl)10, whereas Pt9(CNXyl)13(CO) was obtained from the reaction of [Pt15(CO)30]2− with CNXyl. These two new neutral clusters have been structurally characterized as their Pt5(CNXyl)10 ·2toluene and Pt9(CNXyl)13(CO)·solv solvates. DFT studies on the CO exchange of [Pt6(CO)12]2− suggest an associative interchange mechanism, which may be extended also to larger Chini clusters and the initial steps of their reactions with other soft nucleophiles. Cluster compounds Carbonyl ligands Platinum Self-assembly Nanoscience Bortoluzzi, Marco verfasserin aut Ceriotti, Alessandro verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Carmela Iapalucci, Maria verfasserin aut Zacchini, Stefano verfasserin (orcid)0000-0003-0739-0518 aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 512 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:512 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 512 |
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10.1016/j.ica.2020.119904 doi (DE-627)ELV004643968 (ELSEVIER)S0020-1693(20)31103-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Further insights into platinum carbonyl Chini clusters 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]− units. The solid state structure of [Ph3P(CH2)12PPh3][Pt18(CO)36] may be viewed as a snapshot in which [Pt9(CO)18]− units are approaching and ready to exchange outer Pt3(CO)6 fragments. The reactions of Chini clusters with isonitriles proceed via redox-fragmentation, at difference with those involving phosphines that may occur both via non-redox substitution and redox fragmentation, depending on the experimental conditions. Thus, the reaction of [Pt6(CO)12]2− with CNXyl afforded Pt5(CNXyl)10, whereas Pt9(CNXyl)13(CO) was obtained from the reaction of [Pt15(CO)30]2− with CNXyl. These two new neutral clusters have been structurally characterized as their Pt5(CNXyl)10 ·2toluene and Pt9(CNXyl)13(CO)·solv solvates. DFT studies on the CO exchange of [Pt6(CO)12]2− suggest an associative interchange mechanism, which may be extended also to larger Chini clusters and the initial steps of their reactions with other soft nucleophiles. Cluster compounds Carbonyl ligands Platinum Self-assembly Nanoscience Bortoluzzi, Marco verfasserin aut Ceriotti, Alessandro verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Carmela Iapalucci, Maria verfasserin aut Zacchini, Stefano verfasserin (orcid)0000-0003-0739-0518 aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 512 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:512 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 512 |
allfields_unstemmed |
10.1016/j.ica.2020.119904 doi (DE-627)ELV004643968 (ELSEVIER)S0020-1693(20)31103-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Further insights into platinum carbonyl Chini clusters 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]− units. The solid state structure of [Ph3P(CH2)12PPh3][Pt18(CO)36] may be viewed as a snapshot in which [Pt9(CO)18]− units are approaching and ready to exchange outer Pt3(CO)6 fragments. The reactions of Chini clusters with isonitriles proceed via redox-fragmentation, at difference with those involving phosphines that may occur both via non-redox substitution and redox fragmentation, depending on the experimental conditions. Thus, the reaction of [Pt6(CO)12]2− with CNXyl afforded Pt5(CNXyl)10, whereas Pt9(CNXyl)13(CO) was obtained from the reaction of [Pt15(CO)30]2− with CNXyl. These two new neutral clusters have been structurally characterized as their Pt5(CNXyl)10 ·2toluene and Pt9(CNXyl)13(CO)·solv solvates. DFT studies on the CO exchange of [Pt6(CO)12]2− suggest an associative interchange mechanism, which may be extended also to larger Chini clusters and the initial steps of their reactions with other soft nucleophiles. Cluster compounds Carbonyl ligands Platinum Self-assembly Nanoscience Bortoluzzi, Marco verfasserin aut Ceriotti, Alessandro verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Carmela Iapalucci, Maria verfasserin aut Zacchini, Stefano verfasserin (orcid)0000-0003-0739-0518 aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 512 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:512 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 512 |
allfieldsGer |
10.1016/j.ica.2020.119904 doi (DE-627)ELV004643968 (ELSEVIER)S0020-1693(20)31103-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Further insights into platinum carbonyl Chini clusters 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]− units. The solid state structure of [Ph3P(CH2)12PPh3][Pt18(CO)36] may be viewed as a snapshot in which [Pt9(CO)18]− units are approaching and ready to exchange outer Pt3(CO)6 fragments. The reactions of Chini clusters with isonitriles proceed via redox-fragmentation, at difference with those involving phosphines that may occur both via non-redox substitution and redox fragmentation, depending on the experimental conditions. Thus, the reaction of [Pt6(CO)12]2− with CNXyl afforded Pt5(CNXyl)10, whereas Pt9(CNXyl)13(CO) was obtained from the reaction of [Pt15(CO)30]2− with CNXyl. These two new neutral clusters have been structurally characterized as their Pt5(CNXyl)10 ·2toluene and Pt9(CNXyl)13(CO)·solv solvates. DFT studies on the CO exchange of [Pt6(CO)12]2− suggest an associative interchange mechanism, which may be extended also to larger Chini clusters and the initial steps of their reactions with other soft nucleophiles. Cluster compounds Carbonyl ligands Platinum Self-assembly Nanoscience Bortoluzzi, Marco verfasserin aut Ceriotti, Alessandro verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Carmela Iapalucci, Maria verfasserin aut Zacchini, Stefano verfasserin (orcid)0000-0003-0739-0518 aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 512 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:512 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 512 |
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10.1016/j.ica.2020.119904 doi (DE-627)ELV004643968 (ELSEVIER)S0020-1693(20)31103-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Berti, Beatrice verfasserin aut Further insights into platinum carbonyl Chini clusters 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]− units. The solid state structure of [Ph3P(CH2)12PPh3][Pt18(CO)36] may be viewed as a snapshot in which [Pt9(CO)18]− units are approaching and ready to exchange outer Pt3(CO)6 fragments. The reactions of Chini clusters with isonitriles proceed via redox-fragmentation, at difference with those involving phosphines that may occur both via non-redox substitution and redox fragmentation, depending on the experimental conditions. Thus, the reaction of [Pt6(CO)12]2− with CNXyl afforded Pt5(CNXyl)10, whereas Pt9(CNXyl)13(CO) was obtained from the reaction of [Pt15(CO)30]2− with CNXyl. These two new neutral clusters have been structurally characterized as their Pt5(CNXyl)10 ·2toluene and Pt9(CNXyl)13(CO)·solv solvates. DFT studies on the CO exchange of [Pt6(CO)12]2− suggest an associative interchange mechanism, which may be extended also to larger Chini clusters and the initial steps of their reactions with other soft nucleophiles. Cluster compounds Carbonyl ligands Platinum Self-assembly Nanoscience Bortoluzzi, Marco verfasserin aut Ceriotti, Alessandro verfasserin aut Cesari, Cristiana verfasserin aut Femoni, Cristina verfasserin aut Carmela Iapalucci, Maria verfasserin aut Zacchini, Stefano verfasserin (orcid)0000-0003-0739-0518 aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 512 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:512 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 512 |
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540 DE-600 35.00 bkl Further insights into platinum carbonyl Chini clusters Cluster compounds Carbonyl ligands Platinum Self-assembly Nanoscience |
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Further insights into platinum carbonyl Chini clusters |
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Further insights into platinum carbonyl Chini clusters |
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Berti, Beatrice |
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Berti, Beatrice Bortoluzzi, Marco Ceriotti, Alessandro Cesari, Cristiana Femoni, Cristina Carmela Iapalucci, Maria Zacchini, Stefano |
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10.1016/j.ica.2020.119904 |
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further insights into platinum carbonyl chini clusters |
title_auth |
Further insights into platinum carbonyl Chini clusters |
abstract |
The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]− units. The solid state structure of [Ph3P(CH2)12PPh3][Pt18(CO)36] may be viewed as a snapshot in which [Pt9(CO)18]− units are approaching and ready to exchange outer Pt3(CO)6 fragments. The reactions of Chini clusters with isonitriles proceed via redox-fragmentation, at difference with those involving phosphines that may occur both via non-redox substitution and redox fragmentation, depending on the experimental conditions. Thus, the reaction of [Pt6(CO)12]2− with CNXyl afforded Pt5(CNXyl)10, whereas Pt9(CNXyl)13(CO) was obtained from the reaction of [Pt15(CO)30]2− with CNXyl. These two new neutral clusters have been structurally characterized as their Pt5(CNXyl)10 ·2toluene and Pt9(CNXyl)13(CO)·solv solvates. DFT studies on the CO exchange of [Pt6(CO)12]2− suggest an associative interchange mechanism, which may be extended also to larger Chini clusters and the initial steps of their reactions with other soft nucleophiles. |
abstractGer |
The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]− units. The solid state structure of [Ph3P(CH2)12PPh3][Pt18(CO)36] may be viewed as a snapshot in which [Pt9(CO)18]− units are approaching and ready to exchange outer Pt3(CO)6 fragments. The reactions of Chini clusters with isonitriles proceed via redox-fragmentation, at difference with those involving phosphines that may occur both via non-redox substitution and redox fragmentation, depending on the experimental conditions. Thus, the reaction of [Pt6(CO)12]2− with CNXyl afforded Pt5(CNXyl)10, whereas Pt9(CNXyl)13(CO) was obtained from the reaction of [Pt15(CO)30]2− with CNXyl. These two new neutral clusters have been structurally characterized as their Pt5(CNXyl)10 ·2toluene and Pt9(CNXyl)13(CO)·solv solvates. DFT studies on the CO exchange of [Pt6(CO)12]2− suggest an associative interchange mechanism, which may be extended also to larger Chini clusters and the initial steps of their reactions with other soft nucleophiles. |
abstract_unstemmed |
The oxidation of [Ph3P(CH2)12PPh3][Pt15(CO)30] with CF3COOH in THF afforded [Ph3P(CH2)12PPh3][Pt18(CO)36] as a precipitate which was re-crystallized from dmf/isopropanol. This salt self-assembles in the solid state adopting an unprecedented morphology which consists of infinite chains of [Pt9(CO)18]− units. The solid state structure of [Ph3P(CH2)12PPh3][Pt18(CO)36] may be viewed as a snapshot in which [Pt9(CO)18]− units are approaching and ready to exchange outer Pt3(CO)6 fragments. The reactions of Chini clusters with isonitriles proceed via redox-fragmentation, at difference with those involving phosphines that may occur both via non-redox substitution and redox fragmentation, depending on the experimental conditions. Thus, the reaction of [Pt6(CO)12]2− with CNXyl afforded Pt5(CNXyl)10, whereas Pt9(CNXyl)13(CO) was obtained from the reaction of [Pt15(CO)30]2− with CNXyl. These two new neutral clusters have been structurally characterized as their Pt5(CNXyl)10 ·2toluene and Pt9(CNXyl)13(CO)·solv solvates. DFT studies on the CO exchange of [Pt6(CO)12]2− suggest an associative interchange mechanism, which may be extended also to larger Chini clusters and the initial steps of their reactions with other soft nucleophiles. |
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title_short |
Further insights into platinum carbonyl Chini clusters |
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Bortoluzzi, Marco Ceriotti, Alessandro Cesari, Cristiana Femoni, Cristina Carmela Iapalucci, Maria Zacchini, Stefano |
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up_date |
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