Degradation of odorous sulfide compounds by different oxidation processes in drinking water: Performance, reaction kinetics and mechanism
Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Junzhi [verfasserIn] Liao, Yu [verfasserIn] Wang, Qi [verfasserIn] Wang, Chunmiao [verfasserIn] Yu, Jianwei [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2020 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Water research - Amsterdam [u.a.] : Elsevier Science, 1967, 189 |
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| Übergeordnetes Werk: |
volume:189 |
| DOI / URN: |
10.1016/j.watres.2020.116643 |
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| Katalog-ID: |
ELV005292018 |
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| 245 | 1 | 0 | |a Degradation of odorous sulfide compounds by different oxidation processes in drinking water: Performance, reaction kinetics and mechanism |
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| 520 | |a Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work, four sulfide odorants, diamyl sulfide (DAS), dipropyl sulfide (DPS), dimethyl disulfide (DMDS) and diethyl disulfide (DEDS), were selected to evaluate the treatment performance of different oxidation processes in drinking water. The results demonstrated that DMDS, DEDS, DPS and DAS could be oxidized effectively by KMnO4, NaClO and ClO2. The oxidation processes could be well described by the second-order kinetic model, in which k values of selected sulfides followed the order DMDS≈DEDS ≪ DPS≈DAS. As for the three oxidants, the order of reactivity was KMnO4 ≪ ClO2 < NaClO, which was also verified in raw water. The results of oxidation treatability, reaction kinetics and mechanisms confirmed that the characteristics of the central sulfur atom rather than the side chain is the decisive factor in controlling the oxidation rate and transformation pathway of sulfides. The transformation products and pathways were significantly different for the three oxidants. Sulfones (DPSO, DASO) were always formed by cycloaddition reactions during KMnO4 oxidation, yet recombination reactions proceeded during ClO2 oxidation and formed more products, such as MADS, DADS and EADS. Density functional theory (DFT) calculations confirmed that the differences in transformation pathways were caused by the variations in the activity of the oxidants and sulfides. Finally, NaClO was certified as the most effective oxidant for controlling sulfide odorants in drinking water treatment. | ||
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10.1016/j.watres.2020.116643 doi (DE-627)ELV005292018 (ELSEVIER)S0043-1354(20)31178-7 DE-627 ger DE-627 rda eng 550 DE-600 38.85 bkl 43.50 bkl 58.51 bkl Zhang, Junzhi verfasserin aut Degradation of odorous sulfide compounds by different oxidation processes in drinking water: Performance, reaction kinetics and mechanism 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work, four sulfide odorants, diamyl sulfide (DAS), dipropyl sulfide (DPS), dimethyl disulfide (DMDS) and diethyl disulfide (DEDS), were selected to evaluate the treatment performance of different oxidation processes in drinking water. The results demonstrated that DMDS, DEDS, DPS and DAS could be oxidized effectively by KMnO4, NaClO and ClO2. The oxidation processes could be well described by the second-order kinetic model, in which k values of selected sulfides followed the order DMDS≈DEDS ≪ DPS≈DAS. As for the three oxidants, the order of reactivity was KMnO4 ≪ ClO2 < NaClO, which was also verified in raw water. The results of oxidation treatability, reaction kinetics and mechanisms confirmed that the characteristics of the central sulfur atom rather than the side chain is the decisive factor in controlling the oxidation rate and transformation pathway of sulfides. The transformation products and pathways were significantly different for the three oxidants. Sulfones (DPSO, DASO) were always formed by cycloaddition reactions during KMnO4 oxidation, yet recombination reactions proceeded during ClO2 oxidation and formed more products, such as MADS, DADS and EADS. Density functional theory (DFT) calculations confirmed that the differences in transformation pathways were caused by the variations in the activity of the oxidants and sulfides. Finally, NaClO was certified as the most effective oxidant for controlling sulfide odorants in drinking water treatment. Sulfides oxidation treatability kinetics transformation pathways mechanisms Liao, Yu verfasserin (orcid)0000-0001-6921-817X aut Wang, Qi verfasserin aut Wang, Chunmiao verfasserin (orcid)0000-0003-3697-482X aut Yu, Jianwei verfasserin aut Enthalten in Water research Amsterdam [u.a.] : Elsevier Science, 1967 189 Online-Ressource (DE-627)306713780 (DE-600)1501098-3 (DE-576)098330284 1879-2448 nnns volume:189 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.85 Hydrologie: Allgemeines 43.50 Umweltbelastungen 58.51 Abwassertechnik Wasseraufbereitung AR 189 |
| spelling |
10.1016/j.watres.2020.116643 doi (DE-627)ELV005292018 (ELSEVIER)S0043-1354(20)31178-7 DE-627 ger DE-627 rda eng 550 DE-600 38.85 bkl 43.50 bkl 58.51 bkl Zhang, Junzhi verfasserin aut Degradation of odorous sulfide compounds by different oxidation processes in drinking water: Performance, reaction kinetics and mechanism 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work, four sulfide odorants, diamyl sulfide (DAS), dipropyl sulfide (DPS), dimethyl disulfide (DMDS) and diethyl disulfide (DEDS), were selected to evaluate the treatment performance of different oxidation processes in drinking water. The results demonstrated that DMDS, DEDS, DPS and DAS could be oxidized effectively by KMnO4, NaClO and ClO2. The oxidation processes could be well described by the second-order kinetic model, in which k values of selected sulfides followed the order DMDS≈DEDS ≪ DPS≈DAS. As for the three oxidants, the order of reactivity was KMnO4 ≪ ClO2 < NaClO, which was also verified in raw water. The results of oxidation treatability, reaction kinetics and mechanisms confirmed that the characteristics of the central sulfur atom rather than the side chain is the decisive factor in controlling the oxidation rate and transformation pathway of sulfides. The transformation products and pathways were significantly different for the three oxidants. Sulfones (DPSO, DASO) were always formed by cycloaddition reactions during KMnO4 oxidation, yet recombination reactions proceeded during ClO2 oxidation and formed more products, such as MADS, DADS and EADS. Density functional theory (DFT) calculations confirmed that the differences in transformation pathways were caused by the variations in the activity of the oxidants and sulfides. Finally, NaClO was certified as the most effective oxidant for controlling sulfide odorants in drinking water treatment. Sulfides oxidation treatability kinetics transformation pathways mechanisms Liao, Yu verfasserin (orcid)0000-0001-6921-817X aut Wang, Qi verfasserin aut Wang, Chunmiao verfasserin (orcid)0000-0003-3697-482X aut Yu, Jianwei verfasserin aut Enthalten in Water research Amsterdam [u.a.] : Elsevier Science, 1967 189 Online-Ressource (DE-627)306713780 (DE-600)1501098-3 (DE-576)098330284 1879-2448 nnns volume:189 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.85 Hydrologie: Allgemeines 43.50 Umweltbelastungen 58.51 Abwassertechnik Wasseraufbereitung AR 189 |
| allfields_unstemmed |
10.1016/j.watres.2020.116643 doi (DE-627)ELV005292018 (ELSEVIER)S0043-1354(20)31178-7 DE-627 ger DE-627 rda eng 550 DE-600 38.85 bkl 43.50 bkl 58.51 bkl Zhang, Junzhi verfasserin aut Degradation of odorous sulfide compounds by different oxidation processes in drinking water: Performance, reaction kinetics and mechanism 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work, four sulfide odorants, diamyl sulfide (DAS), dipropyl sulfide (DPS), dimethyl disulfide (DMDS) and diethyl disulfide (DEDS), were selected to evaluate the treatment performance of different oxidation processes in drinking water. The results demonstrated that DMDS, DEDS, DPS and DAS could be oxidized effectively by KMnO4, NaClO and ClO2. The oxidation processes could be well described by the second-order kinetic model, in which k values of selected sulfides followed the order DMDS≈DEDS ≪ DPS≈DAS. As for the three oxidants, the order of reactivity was KMnO4 ≪ ClO2 < NaClO, which was also verified in raw water. The results of oxidation treatability, reaction kinetics and mechanisms confirmed that the characteristics of the central sulfur atom rather than the side chain is the decisive factor in controlling the oxidation rate and transformation pathway of sulfides. The transformation products and pathways were significantly different for the three oxidants. Sulfones (DPSO, DASO) were always formed by cycloaddition reactions during KMnO4 oxidation, yet recombination reactions proceeded during ClO2 oxidation and formed more products, such as MADS, DADS and EADS. Density functional theory (DFT) calculations confirmed that the differences in transformation pathways were caused by the variations in the activity of the oxidants and sulfides. Finally, NaClO was certified as the most effective oxidant for controlling sulfide odorants in drinking water treatment. Sulfides oxidation treatability kinetics transformation pathways mechanisms Liao, Yu verfasserin (orcid)0000-0001-6921-817X aut Wang, Qi verfasserin aut Wang, Chunmiao verfasserin (orcid)0000-0003-3697-482X aut Yu, Jianwei verfasserin aut Enthalten in Water research Amsterdam [u.a.] : Elsevier Science, 1967 189 Online-Ressource (DE-627)306713780 (DE-600)1501098-3 (DE-576)098330284 1879-2448 nnns volume:189 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.85 Hydrologie: Allgemeines 43.50 Umweltbelastungen 58.51 Abwassertechnik Wasseraufbereitung AR 189 |
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10.1016/j.watres.2020.116643 doi (DE-627)ELV005292018 (ELSEVIER)S0043-1354(20)31178-7 DE-627 ger DE-627 rda eng 550 DE-600 38.85 bkl 43.50 bkl 58.51 bkl Zhang, Junzhi verfasserin aut Degradation of odorous sulfide compounds by different oxidation processes in drinking water: Performance, reaction kinetics and mechanism 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work, four sulfide odorants, diamyl sulfide (DAS), dipropyl sulfide (DPS), dimethyl disulfide (DMDS) and diethyl disulfide (DEDS), were selected to evaluate the treatment performance of different oxidation processes in drinking water. The results demonstrated that DMDS, DEDS, DPS and DAS could be oxidized effectively by KMnO4, NaClO and ClO2. The oxidation processes could be well described by the second-order kinetic model, in which k values of selected sulfides followed the order DMDS≈DEDS ≪ DPS≈DAS. As for the three oxidants, the order of reactivity was KMnO4 ≪ ClO2 < NaClO, which was also verified in raw water. The results of oxidation treatability, reaction kinetics and mechanisms confirmed that the characteristics of the central sulfur atom rather than the side chain is the decisive factor in controlling the oxidation rate and transformation pathway of sulfides. The transformation products and pathways were significantly different for the three oxidants. Sulfones (DPSO, DASO) were always formed by cycloaddition reactions during KMnO4 oxidation, yet recombination reactions proceeded during ClO2 oxidation and formed more products, such as MADS, DADS and EADS. Density functional theory (DFT) calculations confirmed that the differences in transformation pathways were caused by the variations in the activity of the oxidants and sulfides. Finally, NaClO was certified as the most effective oxidant for controlling sulfide odorants in drinking water treatment. Sulfides oxidation treatability kinetics transformation pathways mechanisms Liao, Yu verfasserin (orcid)0000-0001-6921-817X aut Wang, Qi verfasserin aut Wang, Chunmiao verfasserin (orcid)0000-0003-3697-482X aut Yu, Jianwei verfasserin aut Enthalten in Water research Amsterdam [u.a.] : Elsevier Science, 1967 189 Online-Ressource (DE-627)306713780 (DE-600)1501098-3 (DE-576)098330284 1879-2448 nnns volume:189 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.85 Hydrologie: Allgemeines 43.50 Umweltbelastungen 58.51 Abwassertechnik Wasseraufbereitung AR 189 |
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10.1016/j.watres.2020.116643 doi (DE-627)ELV005292018 (ELSEVIER)S0043-1354(20)31178-7 DE-627 ger DE-627 rda eng 550 DE-600 38.85 bkl 43.50 bkl 58.51 bkl Zhang, Junzhi verfasserin aut Degradation of odorous sulfide compounds by different oxidation processes in drinking water: Performance, reaction kinetics and mechanism 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work, four sulfide odorants, diamyl sulfide (DAS), dipropyl sulfide (DPS), dimethyl disulfide (DMDS) and diethyl disulfide (DEDS), were selected to evaluate the treatment performance of different oxidation processes in drinking water. The results demonstrated that DMDS, DEDS, DPS and DAS could be oxidized effectively by KMnO4, NaClO and ClO2. The oxidation processes could be well described by the second-order kinetic model, in which k values of selected sulfides followed the order DMDS≈DEDS ≪ DPS≈DAS. As for the three oxidants, the order of reactivity was KMnO4 ≪ ClO2 < NaClO, which was also verified in raw water. The results of oxidation treatability, reaction kinetics and mechanisms confirmed that the characteristics of the central sulfur atom rather than the side chain is the decisive factor in controlling the oxidation rate and transformation pathway of sulfides. The transformation products and pathways were significantly different for the three oxidants. Sulfones (DPSO, DASO) were always formed by cycloaddition reactions during KMnO4 oxidation, yet recombination reactions proceeded during ClO2 oxidation and formed more products, such as MADS, DADS and EADS. Density functional theory (DFT) calculations confirmed that the differences in transformation pathways were caused by the variations in the activity of the oxidants and sulfides. Finally, NaClO was certified as the most effective oxidant for controlling sulfide odorants in drinking water treatment. Sulfides oxidation treatability kinetics transformation pathways mechanisms Liao, Yu verfasserin (orcid)0000-0001-6921-817X aut Wang, Qi verfasserin aut Wang, Chunmiao verfasserin (orcid)0000-0003-3697-482X aut Yu, Jianwei verfasserin aut Enthalten in Water research Amsterdam [u.a.] : Elsevier Science, 1967 189 Online-Ressource (DE-627)306713780 (DE-600)1501098-3 (DE-576)098330284 1879-2448 nnns volume:189 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.85 Hydrologie: Allgemeines 43.50 Umweltbelastungen 58.51 Abwassertechnik Wasseraufbereitung AR 189 |
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Zhang, Junzhi @@aut@@ Liao, Yu @@aut@@ Wang, Qi @@aut@@ Wang, Chunmiao @@aut@@ Yu, Jianwei @@aut@@ |
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550 DE-600 38.85 bkl 43.50 bkl 58.51 bkl Degradation of odorous sulfide compounds by different oxidation processes in drinking water: Performance, reaction kinetics and mechanism Sulfides oxidation treatability kinetics transformation pathways mechanisms |
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degradation of odorous sulfide compounds by different oxidation processes in drinking water: performance, reaction kinetics and mechanism |
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Degradation of odorous sulfide compounds by different oxidation processes in drinking water: Performance, reaction kinetics and mechanism |
| abstract |
Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work, four sulfide odorants, diamyl sulfide (DAS), dipropyl sulfide (DPS), dimethyl disulfide (DMDS) and diethyl disulfide (DEDS), were selected to evaluate the treatment performance of different oxidation processes in drinking water. The results demonstrated that DMDS, DEDS, DPS and DAS could be oxidized effectively by KMnO4, NaClO and ClO2. The oxidation processes could be well described by the second-order kinetic model, in which k values of selected sulfides followed the order DMDS≈DEDS ≪ DPS≈DAS. As for the three oxidants, the order of reactivity was KMnO4 ≪ ClO2 < NaClO, which was also verified in raw water. The results of oxidation treatability, reaction kinetics and mechanisms confirmed that the characteristics of the central sulfur atom rather than the side chain is the decisive factor in controlling the oxidation rate and transformation pathway of sulfides. The transformation products and pathways were significantly different for the three oxidants. Sulfones (DPSO, DASO) were always formed by cycloaddition reactions during KMnO4 oxidation, yet recombination reactions proceeded during ClO2 oxidation and formed more products, such as MADS, DADS and EADS. Density functional theory (DFT) calculations confirmed that the differences in transformation pathways were caused by the variations in the activity of the oxidants and sulfides. Finally, NaClO was certified as the most effective oxidant for controlling sulfide odorants in drinking water treatment. |
| abstractGer |
Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work, four sulfide odorants, diamyl sulfide (DAS), dipropyl sulfide (DPS), dimethyl disulfide (DMDS) and diethyl disulfide (DEDS), were selected to evaluate the treatment performance of different oxidation processes in drinking water. The results demonstrated that DMDS, DEDS, DPS and DAS could be oxidized effectively by KMnO4, NaClO and ClO2. The oxidation processes could be well described by the second-order kinetic model, in which k values of selected sulfides followed the order DMDS≈DEDS ≪ DPS≈DAS. As for the three oxidants, the order of reactivity was KMnO4 ≪ ClO2 < NaClO, which was also verified in raw water. The results of oxidation treatability, reaction kinetics and mechanisms confirmed that the characteristics of the central sulfur atom rather than the side chain is the decisive factor in controlling the oxidation rate and transformation pathway of sulfides. The transformation products and pathways were significantly different for the three oxidants. Sulfones (DPSO, DASO) were always formed by cycloaddition reactions during KMnO4 oxidation, yet recombination reactions proceeded during ClO2 oxidation and formed more products, such as MADS, DADS and EADS. Density functional theory (DFT) calculations confirmed that the differences in transformation pathways were caused by the variations in the activity of the oxidants and sulfides. Finally, NaClO was certified as the most effective oxidant for controlling sulfide odorants in drinking water treatment. |
| abstract_unstemmed |
Swampy/septic odor caused by various sulfides is one of the most frequently encountered odor problems in drinking water. However, even though it is much more offensive, few studies have specifically focused on swampy/septic odor compared to the extensively studied musty/earthy problems. In this work, four sulfide odorants, diamyl sulfide (DAS), dipropyl sulfide (DPS), dimethyl disulfide (DMDS) and diethyl disulfide (DEDS), were selected to evaluate the treatment performance of different oxidation processes in drinking water. The results demonstrated that DMDS, DEDS, DPS and DAS could be oxidized effectively by KMnO4, NaClO and ClO2. The oxidation processes could be well described by the second-order kinetic model, in which k values of selected sulfides followed the order DMDS≈DEDS ≪ DPS≈DAS. As for the three oxidants, the order of reactivity was KMnO4 ≪ ClO2 < NaClO, which was also verified in raw water. The results of oxidation treatability, reaction kinetics and mechanisms confirmed that the characteristics of the central sulfur atom rather than the side chain is the decisive factor in controlling the oxidation rate and transformation pathway of sulfides. The transformation products and pathways were significantly different for the three oxidants. Sulfones (DPSO, DASO) were always formed by cycloaddition reactions during KMnO4 oxidation, yet recombination reactions proceeded during ClO2 oxidation and formed more products, such as MADS, DADS and EADS. Density functional theory (DFT) calculations confirmed that the differences in transformation pathways were caused by the variations in the activity of the oxidants and sulfides. Finally, NaClO was certified as the most effective oxidant for controlling sulfide odorants in drinking water treatment. |
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| score |
7.4010477 |