Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends
Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacryl...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Doi, Takahiro [verfasserIn] Takagi, Hideaki [verfasserIn] Shimizu, Nobutaka [verfasserIn] Igarashi, Noriyuki [verfasserIn] Sakurai, Shinichi [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2020 |
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| Schlagwörter: |
2-Dimensional small-angle X-ray scattering Di- and triblock copolymer blends |
|---|
| Übergeordnetes Werk: |
Enthalten in: Progress in organic coatings - Amsterdam [u.a.] : Elsevier Science, 1972, 152 |
|---|---|
| Übergeordnetes Werk: |
volume:152 |
| DOI / URN: |
10.1016/j.porgcoat.2020.106115 |
|---|
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ELV005504317 |
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| 520 | |a Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacrylate) diblock copolymer and a poly(methylmethacrylate)-block-poly(n-butylacrylate)-block-poly(methylmethacrylate) triblock copolymer, respectively. It was found that the hot-melt coated specimen had the anisotropic distribution of the spheres where the d spacing of the nanostructure in the machine direction (MD) is longer than that in the transverse direction (TD) and had a lower ordering regularity of the spherical microdomains in the MD due to shear and elongational deformation. The change of the macroscopic size upon the release of the coated layer from the substrate also confirmed the elongation of the soft-segment (poly (n-butylacrylate)) chains in the MD during the hot-melt coating by exhibiting the macroscopic shrinkage in the MD upon the release. However, the extent of the microscopic elongation (d spacing) was lower than the macroscopic elongation in the MD. This implies that the soft-segment chains are relaxed due to pulling-out of the poly (methylmethacrylate) chains from the hard spherical microdomains. As for the effects of the coating rate, the extent of the chain stretching of the soft segment was increased with the coating rate when the discharge rate (the flux of materials provided onto the substrate through the die lip) was kept constant. However, no effects were confirmed when the discharge rate was so controlled to maintain the thickness of the as-coated layer constant. Thus, the effects of the coating rate and the discharge rate were compensated, and the effects on the chain stretching of the soft segment can be recognized simply in terms of the thickness of the as-coated layer. As for the effects of the cooling-roll temperature, it was found that the extent of the chain stretching of the soft segment was decreased with an increase in the cooling-roll temperature. | ||
| 650 | 4 | |a 2-Dimensional small-angle X-ray scattering | |
| 650 | 4 | |a Di- and triblock copolymer blends | |
| 650 | 4 | |a Hot-melt coating | |
| 650 | 4 | |a Microphase-separated structures | |
| 650 | 4 | |a Pressure-sensitive adhesive | |
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| 700 | 1 | |a Shimizu, Nobutaka |e verfasserin |4 aut | |
| 700 | 1 | |a Igarashi, Noriyuki |e verfasserin |4 aut | |
| 700 | 1 | |a Sakurai, Shinichi |e verfasserin |4 aut | |
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10.1016/j.porgcoat.2020.106115 doi (DE-627)ELV005504317 (ELSEVIER)S0300-9440(20)31326-6 DE-627 ger DE-627 rda eng 540 DE-600 52.78 bkl Doi, Takahiro verfasserin aut Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacrylate) diblock copolymer and a poly(methylmethacrylate)-block-poly(n-butylacrylate)-block-poly(methylmethacrylate) triblock copolymer, respectively. It was found that the hot-melt coated specimen had the anisotropic distribution of the spheres where the d spacing of the nanostructure in the machine direction (MD) is longer than that in the transverse direction (TD) and had a lower ordering regularity of the spherical microdomains in the MD due to shear and elongational deformation. The change of the macroscopic size upon the release of the coated layer from the substrate also confirmed the elongation of the soft-segment (poly (n-butylacrylate)) chains in the MD during the hot-melt coating by exhibiting the macroscopic shrinkage in the MD upon the release. However, the extent of the microscopic elongation (d spacing) was lower than the macroscopic elongation in the MD. This implies that the soft-segment chains are relaxed due to pulling-out of the poly (methylmethacrylate) chains from the hard spherical microdomains. As for the effects of the coating rate, the extent of the chain stretching of the soft segment was increased with the coating rate when the discharge rate (the flux of materials provided onto the substrate through the die lip) was kept constant. However, no effects were confirmed when the discharge rate was so controlled to maintain the thickness of the as-coated layer constant. Thus, the effects of the coating rate and the discharge rate were compensated, and the effects on the chain stretching of the soft segment can be recognized simply in terms of the thickness of the as-coated layer. As for the effects of the cooling-roll temperature, it was found that the extent of the chain stretching of the soft segment was decreased with an increase in the cooling-roll temperature. 2-Dimensional small-angle X-ray scattering Di- and triblock copolymer blends Hot-melt coating Microphase-separated structures Pressure-sensitive adhesive Takagi, Hideaki verfasserin aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin aut Enthalten in Progress in organic coatings Amsterdam [u.a.] : Elsevier Science, 1972 152 Online-Ressource (DE-627)320530647 (DE-600)2015714-9 (DE-576)25948492X nnns volume:152 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.78 Oberflächentechnik Wärmebehandlung AR 152 |
| spelling |
10.1016/j.porgcoat.2020.106115 doi (DE-627)ELV005504317 (ELSEVIER)S0300-9440(20)31326-6 DE-627 ger DE-627 rda eng 540 DE-600 52.78 bkl Doi, Takahiro verfasserin aut Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacrylate) diblock copolymer and a poly(methylmethacrylate)-block-poly(n-butylacrylate)-block-poly(methylmethacrylate) triblock copolymer, respectively. It was found that the hot-melt coated specimen had the anisotropic distribution of the spheres where the d spacing of the nanostructure in the machine direction (MD) is longer than that in the transverse direction (TD) and had a lower ordering regularity of the spherical microdomains in the MD due to shear and elongational deformation. The change of the macroscopic size upon the release of the coated layer from the substrate also confirmed the elongation of the soft-segment (poly (n-butylacrylate)) chains in the MD during the hot-melt coating by exhibiting the macroscopic shrinkage in the MD upon the release. However, the extent of the microscopic elongation (d spacing) was lower than the macroscopic elongation in the MD. This implies that the soft-segment chains are relaxed due to pulling-out of the poly (methylmethacrylate) chains from the hard spherical microdomains. As for the effects of the coating rate, the extent of the chain stretching of the soft segment was increased with the coating rate when the discharge rate (the flux of materials provided onto the substrate through the die lip) was kept constant. However, no effects were confirmed when the discharge rate was so controlled to maintain the thickness of the as-coated layer constant. Thus, the effects of the coating rate and the discharge rate were compensated, and the effects on the chain stretching of the soft segment can be recognized simply in terms of the thickness of the as-coated layer. As for the effects of the cooling-roll temperature, it was found that the extent of the chain stretching of the soft segment was decreased with an increase in the cooling-roll temperature. 2-Dimensional small-angle X-ray scattering Di- and triblock copolymer blends Hot-melt coating Microphase-separated structures Pressure-sensitive adhesive Takagi, Hideaki verfasserin aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin aut Enthalten in Progress in organic coatings Amsterdam [u.a.] : Elsevier Science, 1972 152 Online-Ressource (DE-627)320530647 (DE-600)2015714-9 (DE-576)25948492X nnns volume:152 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.78 Oberflächentechnik Wärmebehandlung AR 152 |
| allfields_unstemmed |
10.1016/j.porgcoat.2020.106115 doi (DE-627)ELV005504317 (ELSEVIER)S0300-9440(20)31326-6 DE-627 ger DE-627 rda eng 540 DE-600 52.78 bkl Doi, Takahiro verfasserin aut Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacrylate) diblock copolymer and a poly(methylmethacrylate)-block-poly(n-butylacrylate)-block-poly(methylmethacrylate) triblock copolymer, respectively. It was found that the hot-melt coated specimen had the anisotropic distribution of the spheres where the d spacing of the nanostructure in the machine direction (MD) is longer than that in the transverse direction (TD) and had a lower ordering regularity of the spherical microdomains in the MD due to shear and elongational deformation. The change of the macroscopic size upon the release of the coated layer from the substrate also confirmed the elongation of the soft-segment (poly (n-butylacrylate)) chains in the MD during the hot-melt coating by exhibiting the macroscopic shrinkage in the MD upon the release. However, the extent of the microscopic elongation (d spacing) was lower than the macroscopic elongation in the MD. This implies that the soft-segment chains are relaxed due to pulling-out of the poly (methylmethacrylate) chains from the hard spherical microdomains. As for the effects of the coating rate, the extent of the chain stretching of the soft segment was increased with the coating rate when the discharge rate (the flux of materials provided onto the substrate through the die lip) was kept constant. However, no effects were confirmed when the discharge rate was so controlled to maintain the thickness of the as-coated layer constant. Thus, the effects of the coating rate and the discharge rate were compensated, and the effects on the chain stretching of the soft segment can be recognized simply in terms of the thickness of the as-coated layer. As for the effects of the cooling-roll temperature, it was found that the extent of the chain stretching of the soft segment was decreased with an increase in the cooling-roll temperature. 2-Dimensional small-angle X-ray scattering Di- and triblock copolymer blends Hot-melt coating Microphase-separated structures Pressure-sensitive adhesive Takagi, Hideaki verfasserin aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin aut Enthalten in Progress in organic coatings Amsterdam [u.a.] : Elsevier Science, 1972 152 Online-Ressource (DE-627)320530647 (DE-600)2015714-9 (DE-576)25948492X nnns volume:152 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.78 Oberflächentechnik Wärmebehandlung AR 152 |
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10.1016/j.porgcoat.2020.106115 doi (DE-627)ELV005504317 (ELSEVIER)S0300-9440(20)31326-6 DE-627 ger DE-627 rda eng 540 DE-600 52.78 bkl Doi, Takahiro verfasserin aut Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacrylate) diblock copolymer and a poly(methylmethacrylate)-block-poly(n-butylacrylate)-block-poly(methylmethacrylate) triblock copolymer, respectively. It was found that the hot-melt coated specimen had the anisotropic distribution of the spheres where the d spacing of the nanostructure in the machine direction (MD) is longer than that in the transverse direction (TD) and had a lower ordering regularity of the spherical microdomains in the MD due to shear and elongational deformation. The change of the macroscopic size upon the release of the coated layer from the substrate also confirmed the elongation of the soft-segment (poly (n-butylacrylate)) chains in the MD during the hot-melt coating by exhibiting the macroscopic shrinkage in the MD upon the release. However, the extent of the microscopic elongation (d spacing) was lower than the macroscopic elongation in the MD. This implies that the soft-segment chains are relaxed due to pulling-out of the poly (methylmethacrylate) chains from the hard spherical microdomains. As for the effects of the coating rate, the extent of the chain stretching of the soft segment was increased with the coating rate when the discharge rate (the flux of materials provided onto the substrate through the die lip) was kept constant. However, no effects were confirmed when the discharge rate was so controlled to maintain the thickness of the as-coated layer constant. Thus, the effects of the coating rate and the discharge rate were compensated, and the effects on the chain stretching of the soft segment can be recognized simply in terms of the thickness of the as-coated layer. As for the effects of the cooling-roll temperature, it was found that the extent of the chain stretching of the soft segment was decreased with an increase in the cooling-roll temperature. 2-Dimensional small-angle X-ray scattering Di- and triblock copolymer blends Hot-melt coating Microphase-separated structures Pressure-sensitive adhesive Takagi, Hideaki verfasserin aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin aut Enthalten in Progress in organic coatings Amsterdam [u.a.] : Elsevier Science, 1972 152 Online-Ressource (DE-627)320530647 (DE-600)2015714-9 (DE-576)25948492X nnns volume:152 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.78 Oberflächentechnik Wärmebehandlung AR 152 |
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10.1016/j.porgcoat.2020.106115 doi (DE-627)ELV005504317 (ELSEVIER)S0300-9440(20)31326-6 DE-627 ger DE-627 rda eng 540 DE-600 52.78 bkl Doi, Takahiro verfasserin aut Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacrylate) diblock copolymer and a poly(methylmethacrylate)-block-poly(n-butylacrylate)-block-poly(methylmethacrylate) triblock copolymer, respectively. It was found that the hot-melt coated specimen had the anisotropic distribution of the spheres where the d spacing of the nanostructure in the machine direction (MD) is longer than that in the transverse direction (TD) and had a lower ordering regularity of the spherical microdomains in the MD due to shear and elongational deformation. The change of the macroscopic size upon the release of the coated layer from the substrate also confirmed the elongation of the soft-segment (poly (n-butylacrylate)) chains in the MD during the hot-melt coating by exhibiting the macroscopic shrinkage in the MD upon the release. However, the extent of the microscopic elongation (d spacing) was lower than the macroscopic elongation in the MD. This implies that the soft-segment chains are relaxed due to pulling-out of the poly (methylmethacrylate) chains from the hard spherical microdomains. As for the effects of the coating rate, the extent of the chain stretching of the soft segment was increased with the coating rate when the discharge rate (the flux of materials provided onto the substrate through the die lip) was kept constant. However, no effects were confirmed when the discharge rate was so controlled to maintain the thickness of the as-coated layer constant. Thus, the effects of the coating rate and the discharge rate were compensated, and the effects on the chain stretching of the soft segment can be recognized simply in terms of the thickness of the as-coated layer. As for the effects of the cooling-roll temperature, it was found that the extent of the chain stretching of the soft segment was decreased with an increase in the cooling-roll temperature. 2-Dimensional small-angle X-ray scattering Di- and triblock copolymer blends Hot-melt coating Microphase-separated structures Pressure-sensitive adhesive Takagi, Hideaki verfasserin aut Shimizu, Nobutaka verfasserin aut Igarashi, Noriyuki verfasserin aut Sakurai, Shinichi verfasserin aut Enthalten in Progress in organic coatings Amsterdam [u.a.] : Elsevier Science, 1972 152 Online-Ressource (DE-627)320530647 (DE-600)2015714-9 (DE-576)25948492X nnns volume:152 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 52.78 Oberflächentechnik Wärmebehandlung AR 152 |
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Doi, Takahiro |
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Doi, Takahiro ddc 540 bkl 52.78 misc 2-Dimensional small-angle X-ray scattering misc Di- and triblock copolymer blends misc Hot-melt coating misc Microphase-separated structures misc Pressure-sensitive adhesive Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends |
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540 DE-600 52.78 bkl Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends 2-Dimensional small-angle X-ray scattering Di- and triblock copolymer blends Hot-melt coating Microphase-separated structures Pressure-sensitive adhesive |
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ddc 540 bkl 52.78 misc 2-Dimensional small-angle X-ray scattering misc Di- and triblock copolymer blends misc Hot-melt coating misc Microphase-separated structures misc Pressure-sensitive adhesive |
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ddc 540 bkl 52.78 misc 2-Dimensional small-angle X-ray scattering misc Di- and triblock copolymer blends misc Hot-melt coating misc Microphase-separated structures misc Pressure-sensitive adhesive |
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ddc 540 bkl 52.78 misc 2-Dimensional small-angle X-ray scattering misc Di- and triblock copolymer blends misc Hot-melt coating misc Microphase-separated structures misc Pressure-sensitive adhesive |
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Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends |
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Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends |
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Doi, Takahiro |
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Progress in organic coatings |
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Doi, Takahiro Takagi, Hideaki Shimizu, Nobutaka Igarashi, Noriyuki Sakurai, Shinichi |
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10.1016/j.porgcoat.2020.106115 |
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effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends |
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Effects of conditions in hot-melt coating process on microphase-separated structures and macroscopic deformation in coated layers composed of di- and triblock copolymer blends |
| abstract |
Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacrylate) diblock copolymer and a poly(methylmethacrylate)-block-poly(n-butylacrylate)-block-poly(methylmethacrylate) triblock copolymer, respectively. It was found that the hot-melt coated specimen had the anisotropic distribution of the spheres where the d spacing of the nanostructure in the machine direction (MD) is longer than that in the transverse direction (TD) and had a lower ordering regularity of the spherical microdomains in the MD due to shear and elongational deformation. The change of the macroscopic size upon the release of the coated layer from the substrate also confirmed the elongation of the soft-segment (poly (n-butylacrylate)) chains in the MD during the hot-melt coating by exhibiting the macroscopic shrinkage in the MD upon the release. However, the extent of the microscopic elongation (d spacing) was lower than the macroscopic elongation in the MD. This implies that the soft-segment chains are relaxed due to pulling-out of the poly (methylmethacrylate) chains from the hard spherical microdomains. As for the effects of the coating rate, the extent of the chain stretching of the soft segment was increased with the coating rate when the discharge rate (the flux of materials provided onto the substrate through the die lip) was kept constant. However, no effects were confirmed when the discharge rate was so controlled to maintain the thickness of the as-coated layer constant. Thus, the effects of the coating rate and the discharge rate were compensated, and the effects on the chain stretching of the soft segment can be recognized simply in terms of the thickness of the as-coated layer. As for the effects of the cooling-roll temperature, it was found that the extent of the chain stretching of the soft segment was decreased with an increase in the cooling-roll temperature. |
| abstractGer |
Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacrylate) diblock copolymer and a poly(methylmethacrylate)-block-poly(n-butylacrylate)-block-poly(methylmethacrylate) triblock copolymer, respectively. It was found that the hot-melt coated specimen had the anisotropic distribution of the spheres where the d spacing of the nanostructure in the machine direction (MD) is longer than that in the transverse direction (TD) and had a lower ordering regularity of the spherical microdomains in the MD due to shear and elongational deformation. The change of the macroscopic size upon the release of the coated layer from the substrate also confirmed the elongation of the soft-segment (poly (n-butylacrylate)) chains in the MD during the hot-melt coating by exhibiting the macroscopic shrinkage in the MD upon the release. However, the extent of the microscopic elongation (d spacing) was lower than the macroscopic elongation in the MD. This implies that the soft-segment chains are relaxed due to pulling-out of the poly (methylmethacrylate) chains from the hard spherical microdomains. As for the effects of the coating rate, the extent of the chain stretching of the soft segment was increased with the coating rate when the discharge rate (the flux of materials provided onto the substrate through the die lip) was kept constant. However, no effects were confirmed when the discharge rate was so controlled to maintain the thickness of the as-coated layer constant. Thus, the effects of the coating rate and the discharge rate were compensated, and the effects on the chain stretching of the soft segment can be recognized simply in terms of the thickness of the as-coated layer. As for the effects of the cooling-roll temperature, it was found that the extent of the chain stretching of the soft segment was decreased with an increase in the cooling-roll temperature. |
| abstract_unstemmed |
Effects of the coating rate, the cooling temperature and the discharge rate in the hot-melt coating process on the microphase-separated structure and the macroscopic deformation have been revealed using blend specimens of MA/MAM where MA and MAM are a poly(methylmethacrylate)-block-poly(n-butylacrylate) diblock copolymer and a poly(methylmethacrylate)-block-poly(n-butylacrylate)-block-poly(methylmethacrylate) triblock copolymer, respectively. It was found that the hot-melt coated specimen had the anisotropic distribution of the spheres where the d spacing of the nanostructure in the machine direction (MD) is longer than that in the transverse direction (TD) and had a lower ordering regularity of the spherical microdomains in the MD due to shear and elongational deformation. The change of the macroscopic size upon the release of the coated layer from the substrate also confirmed the elongation of the soft-segment (poly (n-butylacrylate)) chains in the MD during the hot-melt coating by exhibiting the macroscopic shrinkage in the MD upon the release. However, the extent of the microscopic elongation (d spacing) was lower than the macroscopic elongation in the MD. This implies that the soft-segment chains are relaxed due to pulling-out of the poly (methylmethacrylate) chains from the hard spherical microdomains. As for the effects of the coating rate, the extent of the chain stretching of the soft segment was increased with the coating rate when the discharge rate (the flux of materials provided onto the substrate through the die lip) was kept constant. However, no effects were confirmed when the discharge rate was so controlled to maintain the thickness of the as-coated layer constant. Thus, the effects of the coating rate and the discharge rate were compensated, and the effects on the chain stretching of the soft segment can be recognized simply in terms of the thickness of the as-coated layer. As for the effects of the cooling-roll temperature, it was found that the extent of the chain stretching of the soft segment was decreased with an increase in the cooling-roll temperature. |
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