A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups

Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO c...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Dang, Junhui [verfasserIn] Mei, Dajiang [verfasserIn] Wu, Yuandong [verfasserIn] Lin, Zheshuai [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	Ultraviolet and deep ultraviolet Nonlinear optical crystals Phosphates Structure-property relationship

Übergeordnetes Werk:	Enthalten in: Coordination chemistry reviews - Amsterdam [u.a.] : Elsevier Science, 1966, 431
Übergeordnetes Werk:	volume:431

DOI / URN:	10.1016/j.ccr.2020.213692

Katalog-ID:	ELV005518601

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245	1	0	\|a A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups
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520			\|a Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. Meanwhile, it is proposed that the integration of [LiO4] or [MgO4]/[MgO5] groups into the phosphates might be an effective strategy to achieve the good balance between SHG effect and cutoff edge.
650		4	\|a Ultraviolet and deep ultraviolet
650		4	\|a Nonlinear optical crystals
650		4	\|a Phosphates
650		4	\|a Structure-property relationship
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700	1		\|a Wu, Yuandong \|e verfasserin \|4 aut
700	1		\|a Lin, Zheshuai \|e verfasserin \|4 aut
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allfields	10.1016/j.ccr.2020.213692 doi (DE-627)ELV005518601 (ELSEVIER)S0010-8545(20)30773-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Dang, Junhui verfasserin aut A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. Meanwhile, it is proposed that the integration of [LiO4] or [MgO4]/[MgO5] groups into the phosphates might be an effective strategy to achieve the good balance between SHG effect and cutoff edge. Ultraviolet and deep ultraviolet Nonlinear optical crystals Phosphates Structure-property relationship Mei, Dajiang verfasserin aut Wu, Yuandong verfasserin aut Lin, Zheshuai verfasserin aut Enthalten in Coordination chemistry reviews Amsterdam [u.a.] : Elsevier Science, 1966 431 Online-Ressource (DE-627)306655020 (DE-600)1499984-5 (DE-576)081985002 0010-8545 nnns volume:431 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 431
spelling	10.1016/j.ccr.2020.213692 doi (DE-627)ELV005518601 (ELSEVIER)S0010-8545(20)30773-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Dang, Junhui verfasserin aut A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. Meanwhile, it is proposed that the integration of [LiO4] or [MgO4]/[MgO5] groups into the phosphates might be an effective strategy to achieve the good balance between SHG effect and cutoff edge. Ultraviolet and deep ultraviolet Nonlinear optical crystals Phosphates Structure-property relationship Mei, Dajiang verfasserin aut Wu, Yuandong verfasserin aut Lin, Zheshuai verfasserin aut Enthalten in Coordination chemistry reviews Amsterdam [u.a.] : Elsevier Science, 1966 431 Online-Ressource (DE-627)306655020 (DE-600)1499984-5 (DE-576)081985002 0010-8545 nnns volume:431 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 431
allfields_unstemmed	10.1016/j.ccr.2020.213692 doi (DE-627)ELV005518601 (ELSEVIER)S0010-8545(20)30773-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Dang, Junhui verfasserin aut A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. Meanwhile, it is proposed that the integration of [LiO4] or [MgO4]/[MgO5] groups into the phosphates might be an effective strategy to achieve the good balance between SHG effect and cutoff edge. Ultraviolet and deep ultraviolet Nonlinear optical crystals Phosphates Structure-property relationship Mei, Dajiang verfasserin aut Wu, Yuandong verfasserin aut Lin, Zheshuai verfasserin aut Enthalten in Coordination chemistry reviews Amsterdam [u.a.] : Elsevier Science, 1966 431 Online-Ressource (DE-627)306655020 (DE-600)1499984-5 (DE-576)081985002 0010-8545 nnns volume:431 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 431
allfieldsGer	10.1016/j.ccr.2020.213692 doi (DE-627)ELV005518601 (ELSEVIER)S0010-8545(20)30773-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Dang, Junhui verfasserin aut A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. Meanwhile, it is proposed that the integration of [LiO4] or [MgO4]/[MgO5] groups into the phosphates might be an effective strategy to achieve the good balance between SHG effect and cutoff edge. Ultraviolet and deep ultraviolet Nonlinear optical crystals Phosphates Structure-property relationship Mei, Dajiang verfasserin aut Wu, Yuandong verfasserin aut Lin, Zheshuai verfasserin aut Enthalten in Coordination chemistry reviews Amsterdam [u.a.] : Elsevier Science, 1966 431 Online-Ressource (DE-627)306655020 (DE-600)1499984-5 (DE-576)081985002 0010-8545 nnns volume:431 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 431
allfieldsSound	10.1016/j.ccr.2020.213692 doi (DE-627)ELV005518601 (ELSEVIER)S0010-8545(20)30773-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Dang, Junhui verfasserin aut A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. Meanwhile, it is proposed that the integration of [LiO4] or [MgO4]/[MgO5] groups into the phosphates might be an effective strategy to achieve the good balance between SHG effect and cutoff edge. Ultraviolet and deep ultraviolet Nonlinear optical crystals Phosphates Structure-property relationship Mei, Dajiang verfasserin aut Wu, Yuandong verfasserin aut Lin, Zheshuai verfasserin aut Enthalten in Coordination chemistry reviews Amsterdam [u.a.] : Elsevier Science, 1966 431 Online-Ressource (DE-627)306655020 (DE-600)1499984-5 (DE-576)081985002 0010-8545 nnns volume:431 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 431
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author	Dang, Junhui
spellingShingle	Dang, Junhui ddc 540 bkl 35.00 misc Ultraviolet and deep ultraviolet misc Nonlinear optical crystals misc Phosphates misc Structure-property relationship A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups
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topic_title	540 DE-600 35.00 bkl A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups Ultraviolet and deep ultraviolet Nonlinear optical crystals Phosphates Structure-property relationship
topic	ddc 540 bkl 35.00 misc Ultraviolet and deep ultraviolet misc Nonlinear optical crystals misc Phosphates misc Structure-property relationship
topic_unstemmed	ddc 540 bkl 35.00 misc Ultraviolet and deep ultraviolet misc Nonlinear optical crystals misc Phosphates misc Structure-property relationship
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title	A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups
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title_full	A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups
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title_sort	a comprehensive survey on nonlinear optical phosphates: role of multicoordinate groups
title_auth	A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups
abstract	Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. Meanwhile, it is proposed that the integration of [LiO4] or [MgO4]/[MgO5] groups into the phosphates might be an effective strategy to achieve the good balance between SHG effect and cutoff edge.
abstractGer	Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. Meanwhile, it is proposed that the integration of [LiO4] or [MgO4]/[MgO5] groups into the phosphates might be an effective strategy to achieve the good balance between SHG effect and cutoff edge.
abstract_unstemmed	Ultraviolet (UV) and deep ultraviolet (DUV) nonlinear optical (NLO) crystals, which could respectively generate UV and DUV lasers with high photon flux, are of great importance to the laser technologies. Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. Meanwhile, it is proposed that the integration of [LiO4] or [MgO4]/[MgO5] groups into the phosphates might be an effective strategy to achieve the good balance between SHG effect and cutoff edge.
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title_short	A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups
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author2	Mei, Dajiang Wu, Yuandong Lin, Zheshuai
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doi_str	10.1016/j.ccr.2020.213692
up_date	2024-07-06T18:14:33.044Z
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Phosphates possess short cutoff edges and then are widely regarded as promising UV and DUV NLO candidates. In this review, we aim to present the development of NLO phosphates from the perspective of structure-property relationships. Therefore, we focus on the structural motifs in NLO phosphates, including diverse P-O groups and other multicoordinate anionic groups, and uncover their impact on the second harmonic generation (SHG) effect, cutoff edge and phase-matching (PM) output. 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A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups

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