Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery

Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoro...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Jeon, Hyungjoon [verfasserIn] Kim, Dukjoon [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	Lithium ion battery Solid state electrolytes Pore-filling Ionic liquid PTFE

Übergeordnetes Werk:	Enthalten in: Journal of membrane science - New York, NY [u.a.] : Elsevier, 1976, 624
Übergeordnetes Werk:	volume:624

DOI / URN:	10.1016/j.memsci.2020.119029

Katalog-ID:	ELV005626404

Internformat


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245	1	0	\|a Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery
264		1	\|c 2021
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520			\|a Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoromethane sulfonyl) (PYR14-TFSI) for a lithium ion battery application. Lithium ion conductivity, interfacial resistance, thermal, mechanical and dimensional stability were examined along with the morphology. The prepared membranes showed not only the excellent tensile strength of 76.21 MPa and elongation at break of 123% but also the dimensional stability up to 120 °C and the thermal degradation temperature over 300 °C. As the lithium ionic conductivity increased with PYR14-TFSI contents, the membrane containing 70 wt% PYR14-TFSI exhibited the highest conductivity of 5.18ⅹ10−4 S cm−1 at room temperature without any mechanical failure. The LiCoO2/SSE/Li cell assemblies fabricated from this membrane were capable of delivering 126.4 mAh g−1 at a low C-rate.
650		4	\|a Lithium ion battery
650		4	\|a Solid state electrolytes
650		4	\|a Pore-filling
650		4	\|a Ionic liquid
650		4	\|a PTFE
700	1		\|a Kim, Dukjoon \|e verfasserin \|0 (orcid)0000-0002-0160-8830 \|4 aut
773	0	8	\|i Enthalten in \|t Journal of membrane science \|d New York, NY [u.a.] : Elsevier, 1976 \|g 624 \|h Online-Ressource \|w (DE-627)302468927 \|w (DE-600)1491419-0 \|w (DE-576)259483907 \|x 0376-7388 \|7 nnns
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912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
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912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
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912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
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912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 58.11 \|j Mechanische Verfahrenstechnik
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Indexfelder

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matchkey_str	article:03767388:2021----::iutnossalsmnohgcnutvtadehncltbltvaoeilnoprupfsbtaeihoytyeelc
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publishDate	2021
allfields	10.1016/j.memsci.2020.119029 doi (DE-627)ELV005626404 (ELSEVIER)S0376-7388(20)31601-X DE-627 ger DE-627 rda eng 570 DE-600 58.11 bkl Jeon, Hyungjoon verfasserin aut Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoromethane sulfonyl) (PYR14-TFSI) for a lithium ion battery application. Lithium ion conductivity, interfacial resistance, thermal, mechanical and dimensional stability were examined along with the morphology. The prepared membranes showed not only the excellent tensile strength of 76.21 MPa and elongation at break of 123% but also the dimensional stability up to 120 °C and the thermal degradation temperature over 300 °C. As the lithium ionic conductivity increased with PYR14-TFSI contents, the membrane containing 70 wt% PYR14-TFSI exhibited the highest conductivity of 5.18ⅹ10−4 S cm−1 at room temperature without any mechanical failure. The LiCoO2/SSE/Li cell assemblies fabricated from this membrane were capable of delivering 126.4 mAh g−1 at a low C-rate. Lithium ion battery Solid state electrolytes Pore-filling Ionic liquid PTFE Kim, Dukjoon verfasserin (orcid)0000-0002-0160-8830 aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 624 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:624 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik AR 624
spelling	10.1016/j.memsci.2020.119029 doi (DE-627)ELV005626404 (ELSEVIER)S0376-7388(20)31601-X DE-627 ger DE-627 rda eng 570 DE-600 58.11 bkl Jeon, Hyungjoon verfasserin aut Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoromethane sulfonyl) (PYR14-TFSI) for a lithium ion battery application. Lithium ion conductivity, interfacial resistance, thermal, mechanical and dimensional stability were examined along with the morphology. The prepared membranes showed not only the excellent tensile strength of 76.21 MPa and elongation at break of 123% but also the dimensional stability up to 120 °C and the thermal degradation temperature over 300 °C. As the lithium ionic conductivity increased with PYR14-TFSI contents, the membrane containing 70 wt% PYR14-TFSI exhibited the highest conductivity of 5.18ⅹ10−4 S cm−1 at room temperature without any mechanical failure. The LiCoO2/SSE/Li cell assemblies fabricated from this membrane were capable of delivering 126.4 mAh g−1 at a low C-rate. Lithium ion battery Solid state electrolytes Pore-filling Ionic liquid PTFE Kim, Dukjoon verfasserin (orcid)0000-0002-0160-8830 aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 624 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:624 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik AR 624
allfields_unstemmed	10.1016/j.memsci.2020.119029 doi (DE-627)ELV005626404 (ELSEVIER)S0376-7388(20)31601-X DE-627 ger DE-627 rda eng 570 DE-600 58.11 bkl Jeon, Hyungjoon verfasserin aut Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoromethane sulfonyl) (PYR14-TFSI) for a lithium ion battery application. Lithium ion conductivity, interfacial resistance, thermal, mechanical and dimensional stability were examined along with the morphology. The prepared membranes showed not only the excellent tensile strength of 76.21 MPa and elongation at break of 123% but also the dimensional stability up to 120 °C and the thermal degradation temperature over 300 °C. As the lithium ionic conductivity increased with PYR14-TFSI contents, the membrane containing 70 wt% PYR14-TFSI exhibited the highest conductivity of 5.18ⅹ10−4 S cm−1 at room temperature without any mechanical failure. The LiCoO2/SSE/Li cell assemblies fabricated from this membrane were capable of delivering 126.4 mAh g−1 at a low C-rate. Lithium ion battery Solid state electrolytes Pore-filling Ionic liquid PTFE Kim, Dukjoon verfasserin (orcid)0000-0002-0160-8830 aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 624 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:624 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik AR 624
allfieldsGer	10.1016/j.memsci.2020.119029 doi (DE-627)ELV005626404 (ELSEVIER)S0376-7388(20)31601-X DE-627 ger DE-627 rda eng 570 DE-600 58.11 bkl Jeon, Hyungjoon verfasserin aut Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoromethane sulfonyl) (PYR14-TFSI) for a lithium ion battery application. Lithium ion conductivity, interfacial resistance, thermal, mechanical and dimensional stability were examined along with the morphology. The prepared membranes showed not only the excellent tensile strength of 76.21 MPa and elongation at break of 123% but also the dimensional stability up to 120 °C and the thermal degradation temperature over 300 °C. As the lithium ionic conductivity increased with PYR14-TFSI contents, the membrane containing 70 wt% PYR14-TFSI exhibited the highest conductivity of 5.18ⅹ10−4 S cm−1 at room temperature without any mechanical failure. The LiCoO2/SSE/Li cell assemblies fabricated from this membrane were capable of delivering 126.4 mAh g−1 at a low C-rate. Lithium ion battery Solid state electrolytes Pore-filling Ionic liquid PTFE Kim, Dukjoon verfasserin (orcid)0000-0002-0160-8830 aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 624 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:624 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik AR 624
allfieldsSound	10.1016/j.memsci.2020.119029 doi (DE-627)ELV005626404 (ELSEVIER)S0376-7388(20)31601-X DE-627 ger DE-627 rda eng 570 DE-600 58.11 bkl Jeon, Hyungjoon verfasserin aut Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoromethane sulfonyl) (PYR14-TFSI) for a lithium ion battery application. Lithium ion conductivity, interfacial resistance, thermal, mechanical and dimensional stability were examined along with the morphology. The prepared membranes showed not only the excellent tensile strength of 76.21 MPa and elongation at break of 123% but also the dimensional stability up to 120 °C and the thermal degradation temperature over 300 °C. As the lithium ionic conductivity increased with PYR14-TFSI contents, the membrane containing 70 wt% PYR14-TFSI exhibited the highest conductivity of 5.18ⅹ10−4 S cm−1 at room temperature without any mechanical failure. The LiCoO2/SSE/Li cell assemblies fabricated from this membrane were capable of delivering 126.4 mAh g−1 at a low C-rate. Lithium ion battery Solid state electrolytes Pore-filling Ionic liquid PTFE Kim, Dukjoon verfasserin (orcid)0000-0002-0160-8830 aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 624 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:624 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik AR 624
language	English
source	Enthalten in Journal of membrane science 624 volume:624
sourceStr	Enthalten in Journal of membrane science 624 volume:624
format_phy_str_mv	Article
bklname	Mechanische Verfahrenstechnik
institution	findex.gbv.de
topic_facet	Lithium ion battery Solid state electrolytes Pore-filling Ionic liquid PTFE
dewey-raw	570
isfreeaccess_bool	false
container_title	Journal of membrane science
authorswithroles_txt_mv	Jeon, Hyungjoon @@aut@@ Kim, Dukjoon @@aut@@
publishDateDaySort_date	2021-01-01T00:00:00Z
hierarchy_top_id	302468927
dewey-sort	3570
id	ELV005626404
language_de	englisch
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author	Jeon, Hyungjoon
spellingShingle	Jeon, Hyungjoon ddc 570 bkl 58.11 misc Lithium ion battery misc Solid state electrolytes misc Pore-filling misc Ionic liquid misc PTFE Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery
authorStr	Jeon, Hyungjoon
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topic_title	570 DE-600 58.11 bkl Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery Lithium ion battery Solid state electrolytes Pore-filling Ionic liquid PTFE
topic	ddc 570 bkl 58.11 misc Lithium ion battery misc Solid state electrolytes misc Pore-filling misc Ionic liquid misc PTFE
topic_unstemmed	ddc 570 bkl 58.11 misc Lithium ion battery misc Solid state electrolytes misc Pore-filling misc Ionic liquid misc PTFE
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title	Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery
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title_full	Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery
author_sort	Jeon, Hyungjoon
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author_browse	Jeon, Hyungjoon Kim, Dukjoon
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title_sort	simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous ptfe substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery
title_auth	Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery
abstract	Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoromethane sulfonyl) (PYR14-TFSI) for a lithium ion battery application. Lithium ion conductivity, interfacial resistance, thermal, mechanical and dimensional stability were examined along with the morphology. The prepared membranes showed not only the excellent tensile strength of 76.21 MPa and elongation at break of 123% but also the dimensional stability up to 120 °C and the thermal degradation temperature over 300 °C. As the lithium ionic conductivity increased with PYR14-TFSI contents, the membrane containing 70 wt% PYR14-TFSI exhibited the highest conductivity of 5.18ⅹ10−4 S cm−1 at room temperature without any mechanical failure. The LiCoO2/SSE/Li cell assemblies fabricated from this membrane were capable of delivering 126.4 mAh g−1 at a low C-rate.
abstractGer	Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoromethane sulfonyl) (PYR14-TFSI) for a lithium ion battery application. Lithium ion conductivity, interfacial resistance, thermal, mechanical and dimensional stability were examined along with the morphology. The prepared membranes showed not only the excellent tensile strength of 76.21 MPa and elongation at break of 123% but also the dimensional stability up to 120 °C and the thermal degradation temperature over 300 °C. As the lithium ionic conductivity increased with PYR14-TFSI contents, the membrane containing 70 wt% PYR14-TFSI exhibited the highest conductivity of 5.18ⅹ10−4 S cm−1 at room temperature without any mechanical failure. The LiCoO2/SSE/Li cell assemblies fabricated from this membrane were capable of delivering 126.4 mAh g−1 at a low C-rate.
abstract_unstemmed	Highly ion conductive and mechanically stable solid state electrolyte (SSE) membranes were prepared by impregnation of porous poly(tetrafluoroethylene) (PTFE) substrate with poly(ethylene glycol) (PEG), lithium bis(trifluoromethane sulfonyl)imide (Li-TFSI), and 1-butyl-1-methylpyrrollidum bis(fluoromethane sulfonyl) (PYR14-TFSI) for a lithium ion battery application. Lithium ion conductivity, interfacial resistance, thermal, mechanical and dimensional stability were examined along with the morphology. The prepared membranes showed not only the excellent tensile strength of 76.21 MPa and elongation at break of 123% but also the dimensional stability up to 120 °C and the thermal degradation temperature over 300 °C. As the lithium ionic conductivity increased with PYR14-TFSI contents, the membrane containing 70 wt% PYR14-TFSI exhibited the highest conductivity of 5.18ⅹ10−4 S cm−1 at room temperature without any mechanical failure. The LiCoO2/SSE/Li cell assemblies fabricated from this membrane were capable of delivering 126.4 mAh g−1 at a low C-rate.
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title_short	Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery
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doi_str	10.1016/j.memsci.2020.119029
up_date	2024-07-06T18:36:37.703Z
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Simultaneous establishment of high conductivity and mechanical stability via pore-filling of porous PTFE substrate with poly(ethylene glycol) and ionic liquid for lithium secondary battery

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