Stability, rheological behaviors, and curing properties of 3Y–ZrO
The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Cheng [verfasserIn] Jiang, Zhaoliang [verfasserIn] Zhao, Li [verfasserIn] Guo, Weiwei [verfasserIn] Gao, Xueqing [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Ceramics international - Amsterdam [u.a.] : Elsevier Science, 1995, 47, Seite 13344-13350 |
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| Übergeordnetes Werk: |
volume:47 ; pages:13344-13350 |
| DOI / URN: |
10.1016/j.ceramint.2021.01.191 |
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| 520 | |a The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and 3Y–ZrO2/graphene oxide (GO) powders dispersed in ultraviolet curable acrylic-based resins are developed. A sedimentation experiment is performed to evaluate various ratios of monomers and dispersants to ensure good stability and dispersion of the suspensions. The hydrophobic structures of KH560 are introduced on the surfaces of ceramic powders, representing better wettability performances with 40 vol% NPG2PODA and 60 vol% Di-TMPTA. Moreover, the effects of premixed solvents and solid contents on the rheological behaviors of suspensions are investigated to confirm shear thinning and pseudo plasticity, with the experimental results fitting the Krieger–Dougherty curves. Further, the cure depth and width of the ceramic suspensions are studied, the results of which show that the penetration depth and critical exposure of the 3Y–ZrO2 (3Y–ZrO2/GO) pastes are 17.2 ± 0.50 μm and 4.80 ± 0.62 mJ/cm2 (11.8 ± 1.20 μm and 22.80 ± 9.34 mJ/cm2), respectively. The addition of GO results in a sharp increase in critical exposure, which intensifies the light scattering and hinders the curing of the ceramic paste. The research is expected to serve as a technical guide for the fabrication of ceramic suspensions for dental implants using SLA technology. | ||
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10.1016/j.ceramint.2021.01.191 doi (DE-627)ELV005782910 (ELSEVIER)S0272-8842(21)00228-5 DE-627 ger DE-627 rda eng 670 DE-600 51.60 bkl 58.45 bkl Zhang, Cheng verfasserin aut Stability, rheological behaviors, and curing properties of 3Y–ZrO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and 3Y–ZrO2/graphene oxide (GO) powders dispersed in ultraviolet curable acrylic-based resins are developed. A sedimentation experiment is performed to evaluate various ratios of monomers and dispersants to ensure good stability and dispersion of the suspensions. The hydrophobic structures of KH560 are introduced on the surfaces of ceramic powders, representing better wettability performances with 40 vol% NPG2PODA and 60 vol% Di-TMPTA. Moreover, the effects of premixed solvents and solid contents on the rheological behaviors of suspensions are investigated to confirm shear thinning and pseudo plasticity, with the experimental results fitting the Krieger–Dougherty curves. Further, the cure depth and width of the ceramic suspensions are studied, the results of which show that the penetration depth and critical exposure of the 3Y–ZrO2 (3Y–ZrO2/GO) pastes are 17.2 ± 0.50 μm and 4.80 ± 0.62 mJ/cm2 (11.8 ± 1.20 μm and 22.80 ± 9.34 mJ/cm2), respectively. The addition of GO results in a sharp increase in critical exposure, which intensifies the light scattering and hinders the curing of the ceramic paste. The research is expected to serve as a technical guide for the fabrication of ceramic suspensions for dental implants using SLA technology. Stability Rheological behavior Curing property Ceramic suspension SLA Jiang, Zhaoliang verfasserin (orcid)0000-0002-6258-7869 aut Zhao, Li verfasserin aut Guo, Weiwei verfasserin (orcid)0000-0003-2713-6883 aut Gao, Xueqing verfasserin (orcid)0000-0001-9247-7516 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 47, Seite 13344-13350 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:47 pages:13344-13350 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 58.45 Gesteinshüttenkunde AR 47 13344-13350 |
| spelling |
10.1016/j.ceramint.2021.01.191 doi (DE-627)ELV005782910 (ELSEVIER)S0272-8842(21)00228-5 DE-627 ger DE-627 rda eng 670 DE-600 51.60 bkl 58.45 bkl Zhang, Cheng verfasserin aut Stability, rheological behaviors, and curing properties of 3Y–ZrO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and 3Y–ZrO2/graphene oxide (GO) powders dispersed in ultraviolet curable acrylic-based resins are developed. A sedimentation experiment is performed to evaluate various ratios of monomers and dispersants to ensure good stability and dispersion of the suspensions. The hydrophobic structures of KH560 are introduced on the surfaces of ceramic powders, representing better wettability performances with 40 vol% NPG2PODA and 60 vol% Di-TMPTA. Moreover, the effects of premixed solvents and solid contents on the rheological behaviors of suspensions are investigated to confirm shear thinning and pseudo plasticity, with the experimental results fitting the Krieger–Dougherty curves. Further, the cure depth and width of the ceramic suspensions are studied, the results of which show that the penetration depth and critical exposure of the 3Y–ZrO2 (3Y–ZrO2/GO) pastes are 17.2 ± 0.50 μm and 4.80 ± 0.62 mJ/cm2 (11.8 ± 1.20 μm and 22.80 ± 9.34 mJ/cm2), respectively. The addition of GO results in a sharp increase in critical exposure, which intensifies the light scattering and hinders the curing of the ceramic paste. The research is expected to serve as a technical guide for the fabrication of ceramic suspensions for dental implants using SLA technology. Stability Rheological behavior Curing property Ceramic suspension SLA Jiang, Zhaoliang verfasserin (orcid)0000-0002-6258-7869 aut Zhao, Li verfasserin aut Guo, Weiwei verfasserin (orcid)0000-0003-2713-6883 aut Gao, Xueqing verfasserin (orcid)0000-0001-9247-7516 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 47, Seite 13344-13350 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:47 pages:13344-13350 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 58.45 Gesteinshüttenkunde AR 47 13344-13350 |
| allfields_unstemmed |
10.1016/j.ceramint.2021.01.191 doi (DE-627)ELV005782910 (ELSEVIER)S0272-8842(21)00228-5 DE-627 ger DE-627 rda eng 670 DE-600 51.60 bkl 58.45 bkl Zhang, Cheng verfasserin aut Stability, rheological behaviors, and curing properties of 3Y–ZrO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and 3Y–ZrO2/graphene oxide (GO) powders dispersed in ultraviolet curable acrylic-based resins are developed. A sedimentation experiment is performed to evaluate various ratios of monomers and dispersants to ensure good stability and dispersion of the suspensions. The hydrophobic structures of KH560 are introduced on the surfaces of ceramic powders, representing better wettability performances with 40 vol% NPG2PODA and 60 vol% Di-TMPTA. Moreover, the effects of premixed solvents and solid contents on the rheological behaviors of suspensions are investigated to confirm shear thinning and pseudo plasticity, with the experimental results fitting the Krieger–Dougherty curves. Further, the cure depth and width of the ceramic suspensions are studied, the results of which show that the penetration depth and critical exposure of the 3Y–ZrO2 (3Y–ZrO2/GO) pastes are 17.2 ± 0.50 μm and 4.80 ± 0.62 mJ/cm2 (11.8 ± 1.20 μm and 22.80 ± 9.34 mJ/cm2), respectively. The addition of GO results in a sharp increase in critical exposure, which intensifies the light scattering and hinders the curing of the ceramic paste. The research is expected to serve as a technical guide for the fabrication of ceramic suspensions for dental implants using SLA technology. Stability Rheological behavior Curing property Ceramic suspension SLA Jiang, Zhaoliang verfasserin (orcid)0000-0002-6258-7869 aut Zhao, Li verfasserin aut Guo, Weiwei verfasserin (orcid)0000-0003-2713-6883 aut Gao, Xueqing verfasserin (orcid)0000-0001-9247-7516 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 47, Seite 13344-13350 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:47 pages:13344-13350 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 58.45 Gesteinshüttenkunde AR 47 13344-13350 |
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10.1016/j.ceramint.2021.01.191 doi (DE-627)ELV005782910 (ELSEVIER)S0272-8842(21)00228-5 DE-627 ger DE-627 rda eng 670 DE-600 51.60 bkl 58.45 bkl Zhang, Cheng verfasserin aut Stability, rheological behaviors, and curing properties of 3Y–ZrO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and 3Y–ZrO2/graphene oxide (GO) powders dispersed in ultraviolet curable acrylic-based resins are developed. A sedimentation experiment is performed to evaluate various ratios of monomers and dispersants to ensure good stability and dispersion of the suspensions. The hydrophobic structures of KH560 are introduced on the surfaces of ceramic powders, representing better wettability performances with 40 vol% NPG2PODA and 60 vol% Di-TMPTA. Moreover, the effects of premixed solvents and solid contents on the rheological behaviors of suspensions are investigated to confirm shear thinning and pseudo plasticity, with the experimental results fitting the Krieger–Dougherty curves. Further, the cure depth and width of the ceramic suspensions are studied, the results of which show that the penetration depth and critical exposure of the 3Y–ZrO2 (3Y–ZrO2/GO) pastes are 17.2 ± 0.50 μm and 4.80 ± 0.62 mJ/cm2 (11.8 ± 1.20 μm and 22.80 ± 9.34 mJ/cm2), respectively. The addition of GO results in a sharp increase in critical exposure, which intensifies the light scattering and hinders the curing of the ceramic paste. The research is expected to serve as a technical guide for the fabrication of ceramic suspensions for dental implants using SLA technology. Stability Rheological behavior Curing property Ceramic suspension SLA Jiang, Zhaoliang verfasserin (orcid)0000-0002-6258-7869 aut Zhao, Li verfasserin aut Guo, Weiwei verfasserin (orcid)0000-0003-2713-6883 aut Gao, Xueqing verfasserin (orcid)0000-0001-9247-7516 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 47, Seite 13344-13350 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:47 pages:13344-13350 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 58.45 Gesteinshüttenkunde AR 47 13344-13350 |
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10.1016/j.ceramint.2021.01.191 doi (DE-627)ELV005782910 (ELSEVIER)S0272-8842(21)00228-5 DE-627 ger DE-627 rda eng 670 DE-600 51.60 bkl 58.45 bkl Zhang, Cheng verfasserin aut Stability, rheological behaviors, and curing properties of 3Y–ZrO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and 3Y–ZrO2/graphene oxide (GO) powders dispersed in ultraviolet curable acrylic-based resins are developed. A sedimentation experiment is performed to evaluate various ratios of monomers and dispersants to ensure good stability and dispersion of the suspensions. The hydrophobic structures of KH560 are introduced on the surfaces of ceramic powders, representing better wettability performances with 40 vol% NPG2PODA and 60 vol% Di-TMPTA. Moreover, the effects of premixed solvents and solid contents on the rheological behaviors of suspensions are investigated to confirm shear thinning and pseudo plasticity, with the experimental results fitting the Krieger–Dougherty curves. Further, the cure depth and width of the ceramic suspensions are studied, the results of which show that the penetration depth and critical exposure of the 3Y–ZrO2 (3Y–ZrO2/GO) pastes are 17.2 ± 0.50 μm and 4.80 ± 0.62 mJ/cm2 (11.8 ± 1.20 μm and 22.80 ± 9.34 mJ/cm2), respectively. The addition of GO results in a sharp increase in critical exposure, which intensifies the light scattering and hinders the curing of the ceramic paste. The research is expected to serve as a technical guide for the fabrication of ceramic suspensions for dental implants using SLA technology. Stability Rheological behavior Curing property Ceramic suspension SLA Jiang, Zhaoliang verfasserin (orcid)0000-0002-6258-7869 aut Zhao, Li verfasserin aut Guo, Weiwei verfasserin (orcid)0000-0003-2713-6883 aut Gao, Xueqing verfasserin (orcid)0000-0001-9247-7516 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 47, Seite 13344-13350 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:47 pages:13344-13350 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde 58.45 Gesteinshüttenkunde AR 47 13344-13350 |
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Enthalten in Ceramics international 47, Seite 13344-13350 volume:47 pages:13344-13350 |
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stability, rheological behaviors, and curing properties of 3y–zro |
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Stability, rheological behaviors, and curing properties of 3Y–ZrO |
| abstract |
The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and 3Y–ZrO2/graphene oxide (GO) powders dispersed in ultraviolet curable acrylic-based resins are developed. A sedimentation experiment is performed to evaluate various ratios of monomers and dispersants to ensure good stability and dispersion of the suspensions. The hydrophobic structures of KH560 are introduced on the surfaces of ceramic powders, representing better wettability performances with 40 vol% NPG2PODA and 60 vol% Di-TMPTA. Moreover, the effects of premixed solvents and solid contents on the rheological behaviors of suspensions are investigated to confirm shear thinning and pseudo plasticity, with the experimental results fitting the Krieger–Dougherty curves. Further, the cure depth and width of the ceramic suspensions are studied, the results of which show that the penetration depth and critical exposure of the 3Y–ZrO2 (3Y–ZrO2/GO) pastes are 17.2 ± 0.50 μm and 4.80 ± 0.62 mJ/cm2 (11.8 ± 1.20 μm and 22.80 ± 9.34 mJ/cm2), respectively. The addition of GO results in a sharp increase in critical exposure, which intensifies the light scattering and hinders the curing of the ceramic paste. The research is expected to serve as a technical guide for the fabrication of ceramic suspensions for dental implants using SLA technology. |
| abstractGer |
The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and 3Y–ZrO2/graphene oxide (GO) powders dispersed in ultraviolet curable acrylic-based resins are developed. A sedimentation experiment is performed to evaluate various ratios of monomers and dispersants to ensure good stability and dispersion of the suspensions. The hydrophobic structures of KH560 are introduced on the surfaces of ceramic powders, representing better wettability performances with 40 vol% NPG2PODA and 60 vol% Di-TMPTA. Moreover, the effects of premixed solvents and solid contents on the rheological behaviors of suspensions are investigated to confirm shear thinning and pseudo plasticity, with the experimental results fitting the Krieger–Dougherty curves. Further, the cure depth and width of the ceramic suspensions are studied, the results of which show that the penetration depth and critical exposure of the 3Y–ZrO2 (3Y–ZrO2/GO) pastes are 17.2 ± 0.50 μm and 4.80 ± 0.62 mJ/cm2 (11.8 ± 1.20 μm and 22.80 ± 9.34 mJ/cm2), respectively. The addition of GO results in a sharp increase in critical exposure, which intensifies the light scattering and hinders the curing of the ceramic paste. The research is expected to serve as a technical guide for the fabrication of ceramic suspensions for dental implants using SLA technology. |
| abstract_unstemmed |
The combination of yttria-zirconia (3Y–ZrO2) and stereolithography (SLA) is essential for forming alternative bioceramics for complex, custom-designed dental implants. In addition, suitable bioceramic suspensions are preconditions for such fabrication using SLA technology. In this study, 3Y–ZrO2 and 3Y–ZrO2/graphene oxide (GO) powders dispersed in ultraviolet curable acrylic-based resins are developed. A sedimentation experiment is performed to evaluate various ratios of monomers and dispersants to ensure good stability and dispersion of the suspensions. The hydrophobic structures of KH560 are introduced on the surfaces of ceramic powders, representing better wettability performances with 40 vol% NPG2PODA and 60 vol% Di-TMPTA. Moreover, the effects of premixed solvents and solid contents on the rheological behaviors of suspensions are investigated to confirm shear thinning and pseudo plasticity, with the experimental results fitting the Krieger–Dougherty curves. Further, the cure depth and width of the ceramic suspensions are studied, the results of which show that the penetration depth and critical exposure of the 3Y–ZrO2 (3Y–ZrO2/GO) pastes are 17.2 ± 0.50 μm and 4.80 ± 0.62 mJ/cm2 (11.8 ± 1.20 μm and 22.80 ± 9.34 mJ/cm2), respectively. The addition of GO results in a sharp increase in critical exposure, which intensifies the light scattering and hinders the curing of the ceramic paste. The research is expected to serve as a technical guide for the fabrication of ceramic suspensions for dental implants using SLA technology. |
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| score |
7.399868 |