Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO

A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the th...
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Gespeichert in:

Autor*in:	Reedy, Colin N. [verfasserIn] Villa, Eric M. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	Lanthanides Periodate Iodate Sodium bismuthate Crystal structures

Übergeordnetes Werk:	Enthalten in: Polyhedron - Amsterdam [u.a.] : Elsevier Science, 1982, 203
Übergeordnetes Werk:	volume:203

DOI / URN:	10.1016/j.poly.2021.115230

Katalog-ID:	ELV006072887

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520			\|a A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. The resulting products reveal the evolution of compounds formed as these redox reactions proceed forward with time and presence of NaBiO3.
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allfields	10.1016/j.poly.2021.115230 doi (DE-627)ELV006072887 (ELSEVIER)S0277-5387(21)00212-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Reedy, Colin N. verfasserin aut Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. The resulting products reveal the evolution of compounds formed as these redox reactions proceed forward with time and presence of NaBiO3. Lanthanides Periodate Iodate Sodium bismuthate Crystal structures Villa, Eric M. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 203 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 203
spelling	10.1016/j.poly.2021.115230 doi (DE-627)ELV006072887 (ELSEVIER)S0277-5387(21)00212-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Reedy, Colin N. verfasserin aut Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. The resulting products reveal the evolution of compounds formed as these redox reactions proceed forward with time and presence of NaBiO3. Lanthanides Periodate Iodate Sodium bismuthate Crystal structures Villa, Eric M. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 203 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 203
allfields_unstemmed	10.1016/j.poly.2021.115230 doi (DE-627)ELV006072887 (ELSEVIER)S0277-5387(21)00212-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Reedy, Colin N. verfasserin aut Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. The resulting products reveal the evolution of compounds formed as these redox reactions proceed forward with time and presence of NaBiO3. Lanthanides Periodate Iodate Sodium bismuthate Crystal structures Villa, Eric M. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 203 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 203
allfieldsGer	10.1016/j.poly.2021.115230 doi (DE-627)ELV006072887 (ELSEVIER)S0277-5387(21)00212-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Reedy, Colin N. verfasserin aut Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. The resulting products reveal the evolution of compounds formed as these redox reactions proceed forward with time and presence of NaBiO3. Lanthanides Periodate Iodate Sodium bismuthate Crystal structures Villa, Eric M. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 203 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 203
allfieldsSound	10.1016/j.poly.2021.115230 doi (DE-627)ELV006072887 (ELSEVIER)S0277-5387(21)00212-6 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Reedy, Colin N. verfasserin aut Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. The resulting products reveal the evolution of compounds formed as these redox reactions proceed forward with time and presence of NaBiO3. Lanthanides Periodate Iodate Sodium bismuthate Crystal structures Villa, Eric M. verfasserin aut Enthalten in Polyhedron Amsterdam [u.a.] : Elsevier Science, 1982 203 Online-Ressource (DE-627)320402967 (DE-600)2000326-2 (DE-576)096704209 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 203
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author	Reedy, Colin N.
spellingShingle	Reedy, Colin N. ddc 540 bkl 35.00 misc Lanthanides misc Periodate misc Iodate misc Sodium bismuthate misc Crystal structures Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO
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topic_title	540 DE-600 35.00 bkl Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO Lanthanides Periodate Iodate Sodium bismuthate Crystal structures
topic	ddc 540 bkl 35.00 misc Lanthanides misc Periodate misc Iodate misc Sodium bismuthate misc Crystal structures
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title	Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO
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title_full	Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO
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title_sort	stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with nabio
title_auth	Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO
abstract	A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. The resulting products reveal the evolution of compounds formed as these redox reactions proceed forward with time and presence of NaBiO3.
abstractGer	A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. The resulting products reveal the evolution of compounds formed as these redox reactions proceed forward with time and presence of NaBiO3.
abstract_unstemmed	A series of neodymium periodate, mixed periodate-iodate and iodate structures have been synthesized via periodic acid flux reactions and characterized through single-crystal x-ray diffraction. Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. The resulting products reveal the evolution of compounds formed as these redox reactions proceed forward with time and presence of NaBiO3.
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title_short	Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO
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up_date	2024-07-06T20:07:52Z
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Critically, the utilization of a sacrificial oxidant, sodium bismuthate (NaBiO3), helps to stave off the thermal reduction of periodate. Through the precise control of reaction time and amount of NaBiO3, this facile synthetic technique illuminates new pathways to creating mixed valent iodine compounds and a route to new iodate compounds as well. Herein, we explore the in-situ periodic acid flux redox reactions with neodymium nitrate and sodium bismuthate. 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Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO

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