Sheet-like garnet structure design for upgrading PEO-based electrolyte

Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SS...
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Gespeichert in:

Autor*in:	Cheng, Jun [verfasserIn] Hou, Guangmei [verfasserIn] Chen, Qiong [verfasserIn] Li, Deping [verfasserIn] Li, Kaikai [verfasserIn] Yuan, Qunhui [verfasserIn] Wang, Jiajun [verfasserIn] Ci, Lijie [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	Sheet-like LLZO PEO-based electrolyte Lithium dendrites suppression Cycling stability

Übergeordnetes Werk:	Enthalten in: The chemical engineering journal - Amsterdam : Elsevier, 1997, 429
Übergeordnetes Werk:	volume:429

DOI / URN:	10.1016/j.cej.2021.132343

Katalog-ID:	ELV006967973

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520			\|a Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SSE. However, the lack of comprehensive research is hindering the understanding over the growth mechanism of the structured active fillers. Especially, compared with other dimensions, the studies on the growth mechanism of two-dimensional (2D) active fillers are quite limited due to the difficulties in physical methods such as exfoliation. Herein, sheet-like LLZAO (Li6.25La3Zr2Al0.25O12) (SL) is synthesized by bottom-up method to upgrade PEO matrix (SLPEO). In addition, the growth mechanism of SL is proposed, which provides a new sight for morphology control over inorganic solid electrolytes. The SL structure provides continuous interfaces between the fillers and the polymer matrix, which ensures rapid diffusion of lithium ions. In addition, the SL can provide more nature barriers for electrolyte to suppress the lithium dendrites growth. The lithium symmetric cells adopting SL@PEO present prolonged cycling stability and higher critical current density compared with the control samples. The assembled all-solid-state LiFePO4/SL@PEO/Li batteries exhibit superior cycling stability and rate capability.
650		4	\|a Sheet-like LLZO
650		4	\|a PEO-based electrolyte
650		4	\|a Lithium dendrites suppression
650		4	\|a Cycling stability
700	1		\|a Hou, Guangmei \|e verfasserin \|4 aut
700	1		\|a Chen, Qiong \|e verfasserin \|4 aut
700	1		\|a Li, Deping \|e verfasserin \|4 aut
700	1		\|a Li, Kaikai \|e verfasserin \|4 aut
700	1		\|a Yuan, Qunhui \|e verfasserin \|4 aut
700	1		\|a Wang, Jiajun \|e verfasserin \|4 aut
700	1		\|a Ci, Lijie \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t The chemical engineering journal \|d Amsterdam : Elsevier, 1997 \|g 429 \|h Online-Ressource \|w (DE-627)320500322 \|w (DE-600)2012137-4 \|w (DE-576)098330152 \|x 1873-3212 \|7 nnns
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publishDate	2021
allfields	10.1016/j.cej.2021.132343 doi (DE-627)ELV006967973 (ELSEVIER)S1385-8947(21)03921-8 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Cheng, Jun verfasserin aut Sheet-like garnet structure design for upgrading PEO-based electrolyte 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SSE. However, the lack of comprehensive research is hindering the understanding over the growth mechanism of the structured active fillers. Especially, compared with other dimensions, the studies on the growth mechanism of two-dimensional (2D) active fillers are quite limited due to the difficulties in physical methods such as exfoliation. Herein, sheet-like LLZAO (Li6.25La3Zr2Al0.25O12) (SL) is synthesized by bottom-up method to upgrade PEO matrix (SLPEO). In addition, the growth mechanism of SL is proposed, which provides a new sight for morphology control over inorganic solid electrolytes. The SL structure provides continuous interfaces between the fillers and the polymer matrix, which ensures rapid diffusion of lithium ions. In addition, the SL can provide more nature barriers for electrolyte to suppress the lithium dendrites growth. The lithium symmetric cells adopting SL@PEO present prolonged cycling stability and higher critical current density compared with the control samples. The assembled all-solid-state LiFePO4/SL@PEO/Li batteries exhibit superior cycling stability and rate capability. Sheet-like LLZO PEO-based electrolyte Lithium dendrites suppression Cycling stability Hou, Guangmei verfasserin aut Chen, Qiong verfasserin aut Li, Deping verfasserin aut Li, Kaikai verfasserin aut Yuan, Qunhui verfasserin aut Wang, Jiajun verfasserin aut Ci, Lijie verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 429 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:429 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 429 045F 660.05
spelling	10.1016/j.cej.2021.132343 doi (DE-627)ELV006967973 (ELSEVIER)S1385-8947(21)03921-8 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Cheng, Jun verfasserin aut Sheet-like garnet structure design for upgrading PEO-based electrolyte 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SSE. However, the lack of comprehensive research is hindering the understanding over the growth mechanism of the structured active fillers. Especially, compared with other dimensions, the studies on the growth mechanism of two-dimensional (2D) active fillers are quite limited due to the difficulties in physical methods such as exfoliation. Herein, sheet-like LLZAO (Li6.25La3Zr2Al0.25O12) (SL) is synthesized by bottom-up method to upgrade PEO matrix (SLPEO). In addition, the growth mechanism of SL is proposed, which provides a new sight for morphology control over inorganic solid electrolytes. The SL structure provides continuous interfaces between the fillers and the polymer matrix, which ensures rapid diffusion of lithium ions. In addition, the SL can provide more nature barriers for electrolyte to suppress the lithium dendrites growth. The lithium symmetric cells adopting SL@PEO present prolonged cycling stability and higher critical current density compared with the control samples. The assembled all-solid-state LiFePO4/SL@PEO/Li batteries exhibit superior cycling stability and rate capability. Sheet-like LLZO PEO-based electrolyte Lithium dendrites suppression Cycling stability Hou, Guangmei verfasserin aut Chen, Qiong verfasserin aut Li, Deping verfasserin aut Li, Kaikai verfasserin aut Yuan, Qunhui verfasserin aut Wang, Jiajun verfasserin aut Ci, Lijie verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 429 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:429 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 429 045F 660.05
allfields_unstemmed	10.1016/j.cej.2021.132343 doi (DE-627)ELV006967973 (ELSEVIER)S1385-8947(21)03921-8 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Cheng, Jun verfasserin aut Sheet-like garnet structure design for upgrading PEO-based electrolyte 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SSE. However, the lack of comprehensive research is hindering the understanding over the growth mechanism of the structured active fillers. Especially, compared with other dimensions, the studies on the growth mechanism of two-dimensional (2D) active fillers are quite limited due to the difficulties in physical methods such as exfoliation. Herein, sheet-like LLZAO (Li6.25La3Zr2Al0.25O12) (SL) is synthesized by bottom-up method to upgrade PEO matrix (SLPEO). In addition, the growth mechanism of SL is proposed, which provides a new sight for morphology control over inorganic solid electrolytes. The SL structure provides continuous interfaces between the fillers and the polymer matrix, which ensures rapid diffusion of lithium ions. In addition, the SL can provide more nature barriers for electrolyte to suppress the lithium dendrites growth. The lithium symmetric cells adopting SL@PEO present prolonged cycling stability and higher critical current density compared with the control samples. The assembled all-solid-state LiFePO4/SL@PEO/Li batteries exhibit superior cycling stability and rate capability. Sheet-like LLZO PEO-based electrolyte Lithium dendrites suppression Cycling stability Hou, Guangmei verfasserin aut Chen, Qiong verfasserin aut Li, Deping verfasserin aut Li, Kaikai verfasserin aut Yuan, Qunhui verfasserin aut Wang, Jiajun verfasserin aut Ci, Lijie verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 429 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:429 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 429 045F 660.05
allfieldsGer	10.1016/j.cej.2021.132343 doi (DE-627)ELV006967973 (ELSEVIER)S1385-8947(21)03921-8 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Cheng, Jun verfasserin aut Sheet-like garnet structure design for upgrading PEO-based electrolyte 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SSE. However, the lack of comprehensive research is hindering the understanding over the growth mechanism of the structured active fillers. Especially, compared with other dimensions, the studies on the growth mechanism of two-dimensional (2D) active fillers are quite limited due to the difficulties in physical methods such as exfoliation. Herein, sheet-like LLZAO (Li6.25La3Zr2Al0.25O12) (SL) is synthesized by bottom-up method to upgrade PEO matrix (SLPEO). In addition, the growth mechanism of SL is proposed, which provides a new sight for morphology control over inorganic solid electrolytes. The SL structure provides continuous interfaces between the fillers and the polymer matrix, which ensures rapid diffusion of lithium ions. In addition, the SL can provide more nature barriers for electrolyte to suppress the lithium dendrites growth. The lithium symmetric cells adopting SL@PEO present prolonged cycling stability and higher critical current density compared with the control samples. The assembled all-solid-state LiFePO4/SL@PEO/Li batteries exhibit superior cycling stability and rate capability. Sheet-like LLZO PEO-based electrolyte Lithium dendrites suppression Cycling stability Hou, Guangmei verfasserin aut Chen, Qiong verfasserin aut Li, Deping verfasserin aut Li, Kaikai verfasserin aut Yuan, Qunhui verfasserin aut Wang, Jiajun verfasserin aut Ci, Lijie verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 429 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:429 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 429 045F 660.05
allfieldsSound	10.1016/j.cej.2021.132343 doi (DE-627)ELV006967973 (ELSEVIER)S1385-8947(21)03921-8 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Cheng, Jun verfasserin aut Sheet-like garnet structure design for upgrading PEO-based electrolyte 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SSE. However, the lack of comprehensive research is hindering the understanding over the growth mechanism of the structured active fillers. Especially, compared with other dimensions, the studies on the growth mechanism of two-dimensional (2D) active fillers are quite limited due to the difficulties in physical methods such as exfoliation. Herein, sheet-like LLZAO (Li6.25La3Zr2Al0.25O12) (SL) is synthesized by bottom-up method to upgrade PEO matrix (SLPEO). In addition, the growth mechanism of SL is proposed, which provides a new sight for morphology control over inorganic solid electrolytes. The SL structure provides continuous interfaces between the fillers and the polymer matrix, which ensures rapid diffusion of lithium ions. In addition, the SL can provide more nature barriers for electrolyte to suppress the lithium dendrites growth. The lithium symmetric cells adopting SL@PEO present prolonged cycling stability and higher critical current density compared with the control samples. The assembled all-solid-state LiFePO4/SL@PEO/Li batteries exhibit superior cycling stability and rate capability. Sheet-like LLZO PEO-based electrolyte Lithium dendrites suppression Cycling stability Hou, Guangmei verfasserin aut Chen, Qiong verfasserin aut Li, Deping verfasserin aut Li, Kaikai verfasserin aut Yuan, Qunhui verfasserin aut Wang, Jiajun verfasserin aut Ci, Lijie verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 429 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:429 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 429 045F 660.05
language	English
source	Enthalten in The chemical engineering journal 429 volume:429
sourceStr	Enthalten in The chemical engineering journal 429 volume:429
format_phy_str_mv	Article
bklname	Verfahrenstechnik: Allgemeines
institution	findex.gbv.de
topic_facet	Sheet-like LLZO PEO-based electrolyte Lithium dendrites suppression Cycling stability
dewey-raw	660.05
isfreeaccess_bool	false
container_title	The chemical engineering journal
authorswithroles_txt_mv	Cheng, Jun @@aut@@ Hou, Guangmei @@aut@@ Chen, Qiong @@aut@@ Li, Deping @@aut@@ Li, Kaikai @@aut@@ Yuan, Qunhui @@aut@@ Wang, Jiajun @@aut@@ Ci, Lijie @@aut@@
publishDateDaySort_date	2021-01-01T00:00:00Z
hierarchy_top_id	320500322
dewey-sort	3660.05
id	ELV006967973
language_de	englisch
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author	Cheng, Jun
spellingShingle	Cheng, Jun ddc 660.05 ddc 660 bkl 58.10 misc Sheet-like LLZO misc PEO-based electrolyte misc Lithium dendrites suppression misc Cycling stability Sheet-like garnet structure design for upgrading PEO-based electrolyte
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topic_title	660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Sheet-like garnet structure design for upgrading PEO-based electrolyte Sheet-like LLZO PEO-based electrolyte Lithium dendrites suppression Cycling stability
topic	ddc 660.05 ddc 660 bkl 58.10 misc Sheet-like LLZO misc PEO-based electrolyte misc Lithium dendrites suppression misc Cycling stability
topic_unstemmed	ddc 660.05 ddc 660 bkl 58.10 misc Sheet-like LLZO misc PEO-based electrolyte misc Lithium dendrites suppression misc Cycling stability
topic_browse	ddc 660.05 ddc 660 bkl 58.10 misc Sheet-like LLZO misc PEO-based electrolyte misc Lithium dendrites suppression misc Cycling stability
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title	Sheet-like garnet structure design for upgrading PEO-based electrolyte
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title_full	Sheet-like garnet structure design for upgrading PEO-based electrolyte
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author_browse	Cheng, Jun Hou, Guangmei Chen, Qiong Li, Deping Li, Kaikai Yuan, Qunhui Wang, Jiajun Ci, Lijie
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title_sort	sheet-like garnet structure design for upgrading peo-based electrolyte
title_auth	Sheet-like garnet structure design for upgrading PEO-based electrolyte
abstract	Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SSE. However, the lack of comprehensive research is hindering the understanding over the growth mechanism of the structured active fillers. Especially, compared with other dimensions, the studies on the growth mechanism of two-dimensional (2D) active fillers are quite limited due to the difficulties in physical methods such as exfoliation. Herein, sheet-like LLZAO (Li6.25La3Zr2Al0.25O12) (SL) is synthesized by bottom-up method to upgrade PEO matrix (SLPEO). In addition, the growth mechanism of SL is proposed, which provides a new sight for morphology control over inorganic solid electrolytes. The SL structure provides continuous interfaces between the fillers and the polymer matrix, which ensures rapid diffusion of lithium ions. In addition, the SL can provide more nature barriers for electrolyte to suppress the lithium dendrites growth. The lithium symmetric cells adopting SL@PEO present prolonged cycling stability and higher critical current density compared with the control samples. The assembled all-solid-state LiFePO4/SL@PEO/Li batteries exhibit superior cycling stability and rate capability.
abstractGer	Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SSE. However, the lack of comprehensive research is hindering the understanding over the growth mechanism of the structured active fillers. Especially, compared with other dimensions, the studies on the growth mechanism of two-dimensional (2D) active fillers are quite limited due to the difficulties in physical methods such as exfoliation. Herein, sheet-like LLZAO (Li6.25La3Zr2Al0.25O12) (SL) is synthesized by bottom-up method to upgrade PEO matrix (SLPEO). In addition, the growth mechanism of SL is proposed, which provides a new sight for morphology control over inorganic solid electrolytes. The SL structure provides continuous interfaces between the fillers and the polymer matrix, which ensures rapid diffusion of lithium ions. In addition, the SL can provide more nature barriers for electrolyte to suppress the lithium dendrites growth. The lithium symmetric cells adopting SL@PEO present prolonged cycling stability and higher critical current density compared with the control samples. The assembled all-solid-state LiFePO4/SL@PEO/Li batteries exhibit superior cycling stability and rate capability.
abstract_unstemmed	Polyoxyethylene (PEO)-based electrolyte is one of the most promising solid-state electrolyte (SSE) candidates for all-solid-state batteries due to its high flexible and salt solubility. Recently, morphological control on active fillers is confirmed as a critical issue affecting the performance of SSE. However, the lack of comprehensive research is hindering the understanding over the growth mechanism of the structured active fillers. Especially, compared with other dimensions, the studies on the growth mechanism of two-dimensional (2D) active fillers are quite limited due to the difficulties in physical methods such as exfoliation. Herein, sheet-like LLZAO (Li6.25La3Zr2Al0.25O12) (SL) is synthesized by bottom-up method to upgrade PEO matrix (SLPEO). In addition, the growth mechanism of SL is proposed, which provides a new sight for morphology control over inorganic solid electrolytes. The SL structure provides continuous interfaces between the fillers and the polymer matrix, which ensures rapid diffusion of lithium ions. In addition, the SL can provide more nature barriers for electrolyte to suppress the lithium dendrites growth. The lithium symmetric cells adopting SL@PEO present prolonged cycling stability and higher critical current density compared with the control samples. The assembled all-solid-state LiFePO4/SL@PEO/Li batteries exhibit superior cycling stability and rate capability.
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title_short	Sheet-like garnet structure design for upgrading PEO-based electrolyte
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author2	Hou, Guangmei Chen, Qiong Li, Deping Li, Kaikai Yuan, Qunhui Wang, Jiajun Ci, Lijie
author2Str	Hou, Guangmei Chen, Qiong Li, Deping Li, Kaikai Yuan, Qunhui Wang, Jiajun Ci, Lijie
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doi_str	10.1016/j.cej.2021.132343
up_date	2024-07-06T23:09:58.068Z
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Sheet-like garnet structure design for upgrading PEO-based electrolyte

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