Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina

Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial wate...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Yaciuk, Pablo A. [verfasserIn] Colombo, Fernando [verfasserIn] Lecomte, Karina L. [verfasserIn] De Micco, Georgina [verfasserIn] Bohé, Ana E. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	Toxic metal AMD Sulfide Sphalerite Rhodochrosite

Übergeordnetes Werk:	Enthalten in: Applied geochemistry - Amsterdam [u.a.] : Elsevier Science, 1986, 136
Übergeordnetes Werk:	volume:136

DOI / URN:	10.1016/j.apgeochem.2021.105152

Katalog-ID:	ELV007198124

Internformat


LEADER	01000caa a22002652 4500
001	ELV007198124
003	DE-627
005	20230524163312.0
007	cr uuu---uuuuu
008	230506s2021 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.1016/j.apgeochem.2021.105152 \|2 doi
035			\|a (DE-627)ELV007198124
035			\|a (ELSEVIER)S0883-2927(21)00283-3
040			\|a DE-627 \|b ger \|c DE-627 \|e rda
041			\|a eng
082	0	4	\|a 550 \|q DE-600
084			\|a 38.32 \|2 bkl
100	1		\|a Yaciuk, Pablo A. \|e verfasserin \|0 (orcid)0000-0003-1743-1993 \|4 aut
245	1	0	\|a Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina
264		1	\|c 2021
336			\|a nicht spezifiziert \|b zzz \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides.
650		4	\|a Toxic metal
650		4	\|a AMD
650		4	\|a Sulfide
650		4	\|a Sphalerite
650		4	\|a Rhodochrosite
700	1		\|a Colombo, Fernando \|e verfasserin \|4 aut
700	1		\|a Lecomte, Karina L. \|e verfasserin \|4 aut
700	1		\|a De Micco, Georgina \|e verfasserin \|4 aut
700	1		\|a Bohé, Ana E. \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Applied geochemistry \|d Amsterdam [u.a.] : Elsevier Science, 1986 \|g 136 \|h Online-Ressource \|w (DE-627)306648091 \|w (DE-600)1499242-5 \|w (DE-576)08198426X \|7 nnns
773	1	8	\|g volume:136
912			\|a GBV_USEFLAG_U
912			\|a SYSFLAG_U
912			\|a GBV_ELV
912			\|a SSG-OPC-GGO
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 38.32 \|j Geochemie
951			\|a AR
952			\|d 136

Indexfelder

author_variant	p a y pa pay f c fc k l l kl kll m g d mg mgd a e b ae aeb
matchkey_str	yaciukpabloacolombofernandolecomtekarina:2021----:amusucsoiiynntrlteutoicnrsigniomnsabntrcadabntpoiteailt
hierarchy_sort_str	2021
bklnumber	38.32
publishDate	2021
allfields	10.1016/j.apgeochem.2021.105152 doi (DE-627)ELV007198124 (ELSEVIER)S0883-2927(21)00283-3 DE-627 ger DE-627 rda eng 550 DE-600 38.32 bkl Yaciuk, Pablo A. verfasserin (orcid)0000-0003-1743-1993 aut Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides. Toxic metal AMD Sulfide Sphalerite Rhodochrosite Colombo, Fernando verfasserin aut Lecomte, Karina L. verfasserin aut De Micco, Georgina verfasserin aut Bohé, Ana E. verfasserin aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 136 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:136 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.32 Geochemie AR 136
spelling	10.1016/j.apgeochem.2021.105152 doi (DE-627)ELV007198124 (ELSEVIER)S0883-2927(21)00283-3 DE-627 ger DE-627 rda eng 550 DE-600 38.32 bkl Yaciuk, Pablo A. verfasserin (orcid)0000-0003-1743-1993 aut Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides. Toxic metal AMD Sulfide Sphalerite Rhodochrosite Colombo, Fernando verfasserin aut Lecomte, Karina L. verfasserin aut De Micco, Georgina verfasserin aut Bohé, Ana E. verfasserin aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 136 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:136 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.32 Geochemie AR 136
allfields_unstemmed	10.1016/j.apgeochem.2021.105152 doi (DE-627)ELV007198124 (ELSEVIER)S0883-2927(21)00283-3 DE-627 ger DE-627 rda eng 550 DE-600 38.32 bkl Yaciuk, Pablo A. verfasserin (orcid)0000-0003-1743-1993 aut Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides. Toxic metal AMD Sulfide Sphalerite Rhodochrosite Colombo, Fernando verfasserin aut Lecomte, Karina L. verfasserin aut De Micco, Georgina verfasserin aut Bohé, Ana E. verfasserin aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 136 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:136 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.32 Geochemie AR 136
allfieldsGer	10.1016/j.apgeochem.2021.105152 doi (DE-627)ELV007198124 (ELSEVIER)S0883-2927(21)00283-3 DE-627 ger DE-627 rda eng 550 DE-600 38.32 bkl Yaciuk, Pablo A. verfasserin (orcid)0000-0003-1743-1993 aut Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides. Toxic metal AMD Sulfide Sphalerite Rhodochrosite Colombo, Fernando verfasserin aut Lecomte, Karina L. verfasserin aut De Micco, Georgina verfasserin aut Bohé, Ana E. verfasserin aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 136 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:136 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.32 Geochemie AR 136
allfieldsSound	10.1016/j.apgeochem.2021.105152 doi (DE-627)ELV007198124 (ELSEVIER)S0883-2927(21)00283-3 DE-627 ger DE-627 rda eng 550 DE-600 38.32 bkl Yaciuk, Pablo A. verfasserin (orcid)0000-0003-1743-1993 aut Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina 2021 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides. Toxic metal AMD Sulfide Sphalerite Rhodochrosite Colombo, Fernando verfasserin aut Lecomte, Karina L. verfasserin aut De Micco, Georgina verfasserin aut Bohé, Ana E. verfasserin aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 136 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:136 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 38.32 Geochemie AR 136
language	English
source	Enthalten in Applied geochemistry 136 volume:136
sourceStr	Enthalten in Applied geochemistry 136 volume:136
format_phy_str_mv	Article
bklname	Geochemie
institution	findex.gbv.de
topic_facet	Toxic metal AMD Sulfide Sphalerite Rhodochrosite
dewey-raw	550
isfreeaccess_bool	false
container_title	Applied geochemistry
authorswithroles_txt_mv	Yaciuk, Pablo A. @@aut@@ Colombo, Fernando @@aut@@ Lecomte, Karina L. @@aut@@ De Micco, Georgina @@aut@@ Bohé, Ana E. @@aut@@
publishDateDaySort_date	2021-01-01T00:00:00Z
hierarchy_top_id	306648091
dewey-sort	3550
id	ELV007198124
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV007198124</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524163312.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230506s2021 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.apgeochem.2021.105152</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV007198124</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0883-2927(21)00283-3</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">550</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">38.32</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yaciuk, Pablo A.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-1743-1993</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2021</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Toxic metal</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">AMD</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sulfide</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sphalerite</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Rhodochrosite</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Colombo, Fernando</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lecomte, Karina L.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">De Micco, Georgina</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Bohé, Ana E.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Applied geochemistry</subfield><subfield code="d">Amsterdam [u.a.] : Elsevier Science, 1986</subfield><subfield code="g">136</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)306648091</subfield><subfield code="w">(DE-600)1499242-5</subfield><subfield code="w">(DE-576)08198426X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:136</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OPC-GGO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">38.32</subfield><subfield code="j">Geochemie</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">136</subfield></datafield></record></collection>
author	Yaciuk, Pablo A.
spellingShingle	Yaciuk, Pablo A. ddc 550 bkl 38.32 misc Toxic metal misc AMD misc Sulfide misc Sphalerite misc Rhodochrosite Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina
authorStr	Yaciuk, Pablo A.
ppnlink_with_tag_str_mv	@@773@@(DE-627)306648091
format	electronic Article
dewey-ones	550 - Earth sciences
delete_txt_mv	keep
author_role	aut aut aut aut aut
collection	elsevier
remote_str	true
illustrated	Not Illustrated
topic_title	550 DE-600 38.32 bkl Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina Toxic metal AMD Sulfide Sphalerite Rhodochrosite
topic	ddc 550 bkl 38.32 misc Toxic metal misc AMD misc Sulfide misc Sphalerite misc Rhodochrosite
topic_unstemmed	ddc 550 bkl 38.32 misc Toxic metal misc AMD misc Sulfide misc Sphalerite misc Rhodochrosite
topic_browse	ddc 550 bkl 38.32 misc Toxic metal misc AMD misc Sulfide misc Sphalerite misc Rhodochrosite
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	Applied geochemistry
hierarchy_parent_id	306648091
dewey-tens	550 - Earth sciences & geology
hierarchy_top_title	Applied geochemistry
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X
title	Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina
ctrlnum	(DE-627)ELV007198124 (ELSEVIER)S0883-2927(21)00283-3
title_full	Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina
author_sort	Yaciuk, Pablo A.
journal	Applied geochemistry
journalStr	Applied geochemistry
lang_code	eng
isOA_bool	false
dewey-hundreds	500 - Science
recordtype	marc
publishDateSort	2021
contenttype_str_mv	zzz
author_browse	Yaciuk, Pablo A. Colombo, Fernando Lecomte, Karina L. De Micco, Georgina Bohé, Ana E.
container_volume	136
class	550 DE-600 38.32 bkl
format_se	Elektronische Aufsätze
author-letter	Yaciuk, Pablo A.
doi_str_mv	10.1016/j.apgeochem.2021.105152
normlink	(ORCID)0000-0003-1743-1993
normlink_prefix_str_mv	(orcid)0000-0003-1743-1993
dewey-full	550
author2-role	verfasserin
title_sort	cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the capillitas polymetallic mineral deposit, nw argentina
title_auth	Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina
abstract	Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides.
abstractGer	Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides.
abstract_unstemmed	Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides.
collection_details	GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393
title_short	Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina
remote_bool	true
author2	Colombo, Fernando Lecomte, Karina L. De Micco, Georgina Bohé, Ana E.
author2Str	Colombo, Fernando Lecomte, Karina L. De Micco, Georgina Bohé, Ana E.
ppnlink	306648091
mediatype_str_mv	c
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1016/j.apgeochem.2021.105152
up_date	2024-07-06T23:56:22.771Z
_version_	1803875970211381248
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV007198124</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524163312.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230506s2021 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.apgeochem.2021.105152</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV007198124</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0883-2927(21)00283-3</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">550</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">38.32</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yaciuk, Pablo A.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-1743-1993</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2021</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Cadmium is one of the most toxic metals commonly released due to mining activities. However, its dynamic in contrasting mining environments has not been exhaustively studied. Through mineralogical and hydrochemical analyses, this study identifies Cd mineral sources and its mobility in surficial waters from two different mining environments (i.e. carbonate-rich and carbonate-poor mineral assemblages) within the polymetallic Capillitas deposit, in NW Argentina. Furthermore, a freshwater tributary stream without mining operations is analyzed as natural background. Results show that sphalerite weathering is the main process releasing Cd into surficial waters in both locations. Sphalerite is Cd-rich in the carbonate-poor rocks of the high-to intermediate-sulfidation environment. At this site, the mineral assemblage is poorly neutralizing and the metal dissolved concentrations increase downstream. The carbonate-rich rocks release Cd up to 1.25 mg L−1, which is higher than similar environments around the world. However, they rapidly decrease downstream to 0.0005 mg L−1 in < 3 km. The main processes that reduce Cd concentrations in the Capillitas hydrological basin are dilution with fresh waters, adsorption, precipitation, and co-precipitation with authigenic minerals such as efflorescent salts and Mn oxy-hydroxides.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Toxic metal</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">AMD</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sulfide</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sphalerite</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Rhodochrosite</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Colombo, Fernando</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lecomte, Karina L.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">De Micco, Georgina</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Bohé, Ana E.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Applied geochemistry</subfield><subfield code="d">Amsterdam [u.a.] : Elsevier Science, 1986</subfield><subfield code="g">136</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)306648091</subfield><subfield code="w">(DE-600)1499242-5</subfield><subfield code="w">(DE-576)08198426X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:136</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OPC-GGO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">38.32</subfield><subfield code="j">Geochemie</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">136</subfield></datafield></record></collection>
score	7.400321

Nicht das Richtige dabei?

Schreiben Sie uns!

Cadmium sources, mobility, and natural attenuation in contrasting environments (carbonate-rich and carbonate-poor) in the Capillitas polymetallic mineral deposit, NW Argentina

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?